山东昌乐新生代碱性玄武岩与地幔捕虏体中各类单斜辉石的地球化学特征及其意义

刘晓寒; 孔凡梅; 李旭平; 魏贵东; 刘浩; 王笑; 贺振鹏

doi:10.3799/dqkx.2018.360

山东昌乐新生代碱性玄武岩与地幔捕虏体中各类单斜辉石的地球化学特征及其意义

doi: 10.3799/dqkx.2018.360

山东科技大学地球科学与工程学院, 山东青岛 266590

基金项目:

山东科技大学科研启动基金 2014RCJJ009

山东省自然基金项目 ZR2016DM04

详细信息

作者简介:
刘晓寒(1991-), 男, 硕士研究生, 岩石学、矿物学专业

通讯作者:
孔凡梅

中图分类号: P57
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出版历程
- 收稿日期: 2018-09-17
- 刊出日期: 2019-04-15

Geochemical Characteristics of Clinopyroxenes from Cenozoic Alkalic Basalts and Mantle Xenoliths in Changle, Shandong Province and Its Significance

School of Earth Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

摘要

摘要: 山东昌乐位于华北克拉通东部，郯庐断裂带中段，广泛出露挟裹幔源捕虏体的新生代碱性玄武岩.为深入了解华北克拉通演化，依据岩相学特征、矿物化学成分特征，把昌乐碱性玄武岩中单斜辉石主要分为三大类：第1类为幔源捕虏体中原生单斜辉石，其主、微量元素含量呈现趋势不一致的解耦现象，且LREE、HREE各异特征表明其经历了多期、不同程度的地幔富集交代和部分熔融作用（低于10%的尖晶石相部分熔融），交代熔体包括地幔富碱（K）富Al硅酸盐熔/流体，可能有碳酸盐熔体的贡献；第2类为幔源捕虏体中筛状单斜辉石，是部分熔融和熔体交代作用的共同产物，从无筛孔部位到筛孔周围远离筛孔部位和紧挨着筛孔部位，呈现出受熔体作用逐渐加强趋势，离筛孔较远部位记录了玄武质熔浆作用之前的一次富碱（K）富Al熔体交代的特征，而紧挨着筛孔的部位受晚期玄武质熔浆作用的影响最强；第3类为幔源捕虏体中反应边单斜辉石及玄武岩中斑晶单斜辉石，两者的化学成分及形成条件相似，显示HFSE正异常，LILE负异常，受OIB特征寄主玄武岩浆强烈的影响.昌乐新生代碱性玄武岩地幔捕虏体中单斜辉石显示经历多期"熔体作用"和不同程度的部分熔融特征，是研究区岩石圈地幔不均一性的体现.
- 新生代碱性玄武岩 /
- 单斜辉石 /
- 幔源捕虏体 /
- 地球化学
Abstract: Changle is located both in the eastern section of the North China craton (NCC) and the middle part of Tancheng-Lujiang (Tan-Lu) fault zone that is characterized with widespread Cenozoic alkaline basalts wrapping a number of mantle xenoliths inside. For the better understanding of the evolution mechanism of the North China craton, three major types of clinopyroxenes are recognized on the basis of the petrography, mineralogy and mineral geochemical characteristics in this study. The first type is the protosomatic clinopyroxene occurred in mantle-derived xenoliths.The content of major and trace elements in this kind of clinopyroxenes show decoupling phenomenon with inconsistent tendencies. Moreover, the LREE and HREE characteristics of the protosomatic clinopyroxenes show that they had experienced multi-stage mantle metasomatism and different degrees of partial melting (no more than 10% partial melting in the spinel phase) and the metasomatic melts include mantle-derived alkali (K) and Al-enriched silicate melts/fluids, possibly contain the carbonate melts. The second kind is cribriform clinopyroxene in mantle-derived xenoliths known as the co-product of partial melting and melt metasomatism. The effect of partial melting exhibits a gradually strengthening from the non-meshing part to the areas far away from sieve mesh, then the areas around the sieve mesh. The areas far away from the sieve mesh record characteristics of a prior metasomatism of alkali (K) and Al-enriched melt before the basaltic magmatism while the areas around the sieve mesh show the strongest effect of late stage basaltic melts. The third type is the the clinopyroxenes in the corona of the protosomatic clinopyroxene or sieve-textured clinopyroxene in mantle-derived xenoliths and the clinopyroxene phenocrystsin alkaline basalts that share the similar geochemical compositions and P-T conditions that reveal a HFSE positive anomaly and a LILE negative anomaly that are strongly influenced by the OIB characteristic host basalt. The characteristics of multiple-stage "melt-effect" and different degrees of partial melting of the clinopyroxenes in the Changle Cenozoic alkaline basalt are the performance of the embodiment of lithospheric mantle heterogeneity in the study area.
- Cenozoic alkaline basalts /
- clinopyroxene /
- mantle xenolith /
- geochemistry

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图 1 山东昌乐方山地质简图及取样点

Fig. 1. Simplified geological map and sampling locality in the Fangshan, Changle, Shandong

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图 2 山东昌乐方山幔源捕虏体岩相学特征

a.二辉橄榄岩中矿物间呈三联点重结晶现象(正交偏光)；b.二辉辉石岩中单斜辉石边缘的粉红色反应边(单偏光)；c, d.单辉橄榄岩中筛状单斜辉石边缘的粉红色反应边(单偏光)；Cpx.单斜辉石；Ids.伊丁石；Ol.橄榄石；Spl.尖晶石；Ilm.钛铁矿；Pl.碱性长石

Fig. 2. Photomicrographs of mantle xenoliths in the Fangshan alkali basalt, Changle, Shandong

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图 3 方山单斜辉石中Al₂O₃-MgO(a)，Na₂O-MgO(b)，Al^Ⅳ-Al^Ⅵ(c)图解

世界范围未交代橄榄岩引自Yaxley et al.(1998)

Fig. 3. Al₂O₃-MgO (a), Na₂O-MgO (b), Al^Ⅳ-Al^Ⅵ (c) for the clinopyroxenes in the Fangshan alkali basalts

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图 4 昌乐方山碱性玄武岩与幔源捕虏体中单斜辉石的球粒陨石标准化稀土元素配分模式和原始地幔标准化蛛网图

球粒陨石数据和原始地幔数据来自于Sun and McDonough (1989)；阴影部分为昌乐幔源捕虏体中原生单斜辉石微量元素含量范围、虚线为筛状单斜辉石微量元素配分曲线，数据均取自Su et al.(2014).黑线表示原始Cpx，数据取自Sano and Kimura(2007)

Fig. 4. REE patterns normalized to CI chondrite and multi-trace element patterns normalized to primitive mantle for the clinopyroxenes in the Fangshan alkali basalt and mantle xenoliths, Changle

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图 5 方山地幔岩中单斜辉石部分熔融模拟

原始地幔数据引自McDonough and Sun(1995)，图参考Zheng et al.(2001)，计算据Norman(1998)

Fig. 5. Results of modelling of partial melting fractions using clinopyroxene compositions for Fangshan mantle xenoliths

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图 6 昌乐方山地幔捕虏体中单斜辉石微量元素与La的相关图

Fig. 6. Plots of selected trace element compositions against La in clinopyroxene from the Fangshan mantle xenoliths, Changle

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图 7 昌乐方山地幔捕虏体中单斜辉石(La/Yb)_N-Ti/Eu图解

DM和PM分别代表亏损地幔和普通地幔的单斜辉石；1.硅酸盐交代趋势，2.碳酸盐交代趋势，3.部分熔融的趋势, 图据Coltorti et al.(1999)；原始地幔标准化值引自Sun and McDonough(1989)

Fig. 7. (La/Yb)_N-Ti/Eu diagram for clinopyroxenes from the Fangshan mantle xenoliths, Changle

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图 8 昌乐方山新碱性玄武岩与地幔岩单斜辉石(Sm/Yb)_N-(Ce/Nd)_N图解

据Rivalenti et al.(1996), 原始地幔数据引自Hofmann(1998)

Fig. 8. (Sm/Yb)_N-(Ce/Nd)_N diagram for clinopyroxenes from the Fangshan alkali basalt and mantle xenoliths, Changle

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