Geochemical, Boron Isotope Characteristics and Geological Significance of Tourmaline from Tangyin Granitic Pegmatite in Yihuang, Jiangxi Province
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摘要: 江西宜黄地区花岗伟晶岩极为发育，电气石广泛赋存于花岗伟晶岩及其围岩（黑云母二长花岗岩）中.在江西宜黄棠阴发现了三种类型的电气石，分别为黑云母二长花岗岩中随机浸染状的电气石（Tur-G型）、花岗伟晶岩中的未分带电气石（Tur-PU型）和分带电气石（Tur-PZ型）.但是，电气石的类型、成因及其对花岗伟晶岩成因的指示意义并不清楚.利用电子探针（EMPA）和LA-（MC）-ICP-MS分别对电气石开展了主量、微量元素和硼同位素分析.从Tur-G型→Tur-PU型→Tur-PZ电气石核部（Core）→边部（Rim），呈现出Al、Fe含量先升再降，Mg、Na、Ca、Ti、Sc、V、Cr、Co、Ni、Sr、Ga、REE含量先降再升的规律.Tur-G、Tur-PU、Tur-PZ-Core、Tur-PZ-Rim电气石δ11B分别为-10.77‰~-8.87‰、-10.59‰~-8.73‰、-11.07‰~-10.09‰、-11.05‰~-8.95‰.研究表明，所有电气石属碱性电气石中的铁电气石‒镁电气石系列，均为岩浆成因.Tur-G、Tur-PU、Tur-PZ型电气石分别结晶于花岗岩熔体晚期阶段、花岗伟晶岩熔体早期阶段和晚期岩浆‒热液阶段，电气石Fe3+/Fe2+比值和V含量变化揭示了各阶段岩浆熔体中氧逸度表现为先降低再升高，电气石中Mg、Na、Ca、Ti、Sc、V、Cr、Co、Ni、Sr、Ga含量反映了熔体中元素含量的变化.棠阴花岗伟晶岩和黑云母二长花岗岩电气石具有集中且相似的硼同位素组成（-11.07‰~-8.73‰），指示两者具有一致的岩浆源区，初始岩浆来源于大陆地壳（贫钙富铝的变质泥岩、变质砂岩）的部分熔融.Abstract: Granitic pegmatite is extensively developed in the Yihuang area of Jiangxi Province, and tourmaline is commonly found within granitic pegmatite and its surrounding rocks (biotite monzogranite). Three distinct types of tourmalines have been identified in Tangyin area: randomly disseminated tourmaline (Tur-G) in biotite monzogranite, unzoned tourmaline (Tur-PU) and zoned tourmaline (Tur-PZ) in granitic pegmatite. However, the classification and origin of tourmaline, as well as its implications for the genesis of granitic pegmatite, remain unclear. This study analyzed the major, trace elements, and boron isotopic compositions using EPMA and LA-(MC)-ICP-MS. From Tur-G type→Tur-PU type→Tur-PZ tourmalines core to rim, the concentrations of Al and Fe initially increase and subsequently decrease, whereas the concentrations of Mg, Na, Ca, Ti, Sc, V, Cr, Co, Ni, Sr, Ga, and rare earth elements exhibit an opposite trend, decreasing first and then increasing. The δ11B values for Tur-G, Tur-PU, Tur-PZ type tourmalines core and rim are -10.77‰--8.87‰, -10.59‰--8.73‰, -11.07‰--10.09‰, and -11.05‰- -8.95‰, respectively. It is believed that all tourmalines belong to the iron-magnesium tourmaline series within the alkaline tourmaline group and are of magmatic origin. Specifically, Tur-G, Tur-PU, and Tur-PZ tourmalines crystallized during the late granite melt, the early granitic pegmatite melt, and the late magma-hydrothermal stages, respectively. The changes in the Fe3+/Fe2+ ratio and V content of the tourmaline revealed that the oxygen fugacity of the magma melt exhibit a trend of initially decreasing and subsequently increasing. The concentrations of Mg, Na, Ca, Ti, Sc, V, Cr, Co, Ni, Sr, and Ga in the tourmaline reflect variations in elemental composition within the melt. The tourmaline found in both the Tangyin granitic pegmatite and biotite monzogranite exhibits a concentrated and comparable boron isotope composition, ranging from -11.07‰ to -8.73‰. This similarity suggests that both rock types originated from the same magma source, with the initial magma being derived from the partial melting of the continental crust, specifically calcium-poor and aluminum-rich metamorphic mudstone and sandstone.
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Key words:
- tourmaline /
- granitic pegmatite /
- geochemistry /
- boron /
- isotope /
- magmatic evolution /
- magma source /
- Tangyin /
- Jiangxi Province
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图 1 华南加里东期花岗岩分布（a）、江西宜黄地区大地构造位置（b）和区域地质简图（c）
a.据郭春丽和刘泽坤（2021）修改；b，c.据袁晶等（2024）修改. 1.古近系新余组；2.白垩系莲荷组；3.白垩系塘边组；4.白垩系河口组；5.白垩系周田组；6.侏罗系水北组；7.三叠系安源组；8.寒武系外管坑组；9.南华‒震旦系洪山组；10.南华系万源岩组；11.青白口系周潭岩组；12.中侏罗世白云母花岗岩；13.晚志留世二长花岗岩；14.早志留世二长花岗岩；15.早志留世花岗闪长岩；16.地质界线；17.平行不整合界线；18.角度不整合界线；19.一般实测断层；20.重要实测断层；21.棠阴矿区位置
Fig. 1. Distribution map of Caledonian granite in South China (a), tectonic location (b) and regional geology schematic map (c) of Tangyin area
图 2 棠阴矿区地质矿产简图
据袁晶等（2024）修改.1.第四系联圩组；2.第四系莲塘组；3.南华系‒震旦系洪山组；4.志留纪黑云母二长花岗岩；5.花岗伟晶岩及编号；6.地质界线；7.花岗伟晶岩脉；8.槽探及编号；9.钻孔及编号；10.勘探线及编号
Fig. 2. Sketch map of geology and mineral in Tangyin mine lot
图 3 棠阴矿区7号勘探线剖面
Fig. 3. Geological profile of exploration line No. 7 in Tangyin mine lot
图 4 棠阴花岗伟晶岩和黑云母二长花岗岩电气石岩相学特征
Tur.电气石；Grt.石榴子石；Bt.黑云母
Fig. 4. Petrographic characteristics of tourmalines from Tangyin granitic pegmatite and biotite monzogranite
图 5 棠阴花岗伟晶岩和黑云母二长花岗岩中电气石分类图解(底图据Henry et al., 2011)
Fig. 5. Classification diagrams of tourmalines from Tangyin granitic pegmatite and biotite monzogranite (after Henry et al., 2011)
图 6 棠阴花岗伟晶岩和黑云母二长花岗岩中电气石成分Al-Fe-Mg(a)和Ca-Fe-Mg(b)三角图(据Henry and Guidotti, 1985)
1.富Li花岗岩及相关的花岗伟晶岩、细晶岩；2.贫Li花岗岩及相关的花岗伟晶岩、细晶岩；3.富Fe3+石英‒电气石岩（热液蚀变花岗岩）；4.与Al饱和相共存的变质泥岩、变质砂岩；5.与Al饱和相不共存的变质泥岩、变质砂岩；6.富Fe3+石英‒电气石岩，钙硅酸盐及变质泥岩；7.低Ca变铁镁质岩和富Cr、V变质沉积岩；8.变质碳酸盐岩和变质灰岩；9.富Ca变质泥岩，变质砂岩及钙硅酸盐；10.贫Ca变质泥岩、变质砂岩和石英电气石岩；11.变质碳酸盐岩；12.变超铁镁质岩
Fig. 6. Ternary Al-Fe-Mg (a) and Ca-Fe-Mg (b) diagrams showing tourmaline compositions from Tangyin granitic pegmatite and biotite monzogranite (after Henry and Guidotti, 1985)
图 7 棠阴花岗伟晶岩和黑云母二长花岗岩中电气石主微量元素箱线图
Fig. 7. Box and whisker plots showing comparisons of representative major and trace elements of tourmalines from Tangyin granitic pegmatite and biotite monzogranite
图 8 棠阴花岗伟晶岩和黑云母二长花岗岩电气石球粒陨石标准化稀土元素配分图（标准化值据Sun and McDonough, 1989）
Fig. 8. Chondrite-normalized REE diagrams of tourmalines from Tangyin granitic pegmatite and biotite monzogranite(normalization values after Sun and McDonough, 1989)
图 9 棠阴花岗伟晶岩和黑云母二长花岗岩电气石硼同位素组成
Fig. 9. Histograms of boron isotope compositions of tourmalines from Tangyin granitic pegmatite and biotite monzogranite
图 10 棠阴花岗伟晶岩中Tur-PZ型电气石分带特征及化学成分变化
a，b.显微镜下照片；c，d.背散射图像；e，f.电子探针剖面
Fig. 10. Zonation characteristics and chemical composition changes of Tur-PZ tourmalines from Tangyin granitic pegmatite
图 11 棠阴花岗伟晶岩和黑云母二长花岗岩电气石Zn-Li/Si (a), Mn-Li/Si (b), Cr-Li/Si (c)和V-Li/Si (d)图解（底图据 Harlaux et al.，2020）
Fig. 11. Plots of Zn-Li/Si (a), Mn-Li/Si (b), Cr-Li/Si (c), and V-Li/Si (d) of tourmalines from Tangyin granitic pegmatite and biotite monzogranite (after Harlaux et al., 2020)
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