环氧树脂/沸石纳米复合材料的制备及表征

陈艳玲; 袁军华; 范畴; 叶立庭

环氧树脂/沸石纳米复合材料的制备及表征

中国地质大学材料科学与化学工程学院, 湖北武汉 430074

详细信息

作者简介:
陈艳玲(1955 -), 女, 副教授, 1982年毕业于武汉大学, 获学士学位, 2001年毕业于中国地质大学(武汉), 获博士学位, 现从事分析化学﹑油田化学﹑材料化学的研究工作

中图分类号: O633
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出版历程
- 收稿日期: 2002-04-23
- 刊出日期: 2002-07-25

Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite

Faculty of Material Sciences and Chemistry Engineering, China University of Geosciences, Wuhan 430074, China

摘要

摘要: 提出了一种用原位插入法制取环氧树脂/沸石纳米复合材料的新方法, 详细探讨了钠化、有机化、环氧树脂插入、固化及制备环氧树脂/沸石纳米复合材料的条件, 在实验的基础上确定了最佳条件, 制成了纳米复合材料, 并用XRD和TEM对其结构进行了表征, 发现纳米复合材料的平均粒径在5 0~ 6 0nm之间, 同时力学性能有明显提高, 可用于高性能的工程塑料和高品质的粘合剂.
- 纳米复合材料 /
- 沸石 /
- 环氧树脂 /
- 插入 /
- 固化
Abstract: This paper proposes a new method to synthesize the epoxy resin/zeolite nanocomposite. In this method, zeolite was previously treated with sodium nitrate, and organized with ceyltrimethyl ammonium bromide. Epoxy resin was interposed in the cavity of zeolite and polymerized in situ. Then, the polymer mixtures were solidified by pp' diaphenyl methane to prepare for nanocomposite. The synthesis condition such as mixing temperature, mixing time and concentrations are discussed extensively, and the epoxy resin/zeolite nanocomposite was characterized by XRD and TEM. This composite is found to be formed by the nanometer aggregated particles, ranging from 50 to 60 nm in diameter based on the analysis of the TEM image. The epoxy resin/zeolite nanocomposite exhibits dramatic increases in their mechanical properties, which can be used in engineering plastic and high quality adhesive.
- nanocomposite /
- zeolite /
- epoxy resin /
- interpose /
- solidify

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图 1 沸石(a) 及有机化沸石(b) 的X衍射图

Fig. 1. XRD pattern of zeolite (a) and organo zeolite (b)

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图 2 环氧树脂/有机沸石的X衍射图

a.直接法; b.间接法

Fig. 2. XRD pattern of epoxy resin/organozeolite synthesized by direct method (a) and indirect method (b)

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图 3 环氧树脂/有机沸石96%在不同混合时间、温度的衍射峰位置

Fig. 3. XRD peaks of epoxy resin/organozeolite 96% in different mixing times and different temperatures

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图 4 环氧树脂/有机沸石固化后的X衍射图

Fig. 4. XRD pattern of cured epoxy resin/organozeolite

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图 5 环氧树脂/有机沸石复合材料的扫描电镜(×2 700)

Fig. 5. TEM photograph of cured epoxy resin/organozeolite nanocomposite

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表 1 温度、浓度、时间对有机化的影响

Table 1. Influence of temperature, concentration and mixing time on zeolite organizing

表 2 不同含量沸石固化后的XRD分析

Table 2. Relation between peaks and organozeolite concentration

表 3 不同的固化温度所需的固化时间

Table 3. Relation between cured temperature and cured time

参考文献(14)

[1]	严东生. 纳米材料的合成和制备[J]. 无机材料学报, 1995, 1(10) : 1. https://www.cnki.com.cn/Article/CJFDTOTAL-WGCL501.000.htm YAN D S. Sy nthesis and fabrication of nanostructured materials[J]. Journal of Inorganic M aterials, 1995, 1(10) : 1. https://www.cnki.com.cn/Article/CJFDTOTAL-WGCL501.000.htm
[2]	汪信, 陆路德. 纳米金属氧化物的制备及应用的若干进展[J]. 无机化学学报, 2000, 2(16) : 14. https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200002006.htm WANG X, LU L D. Progress of preparation and applications of metal ox ide nanocry stallines[J]. Chinese Journal of Inorganic Chemistry, 2000, 2(16) : 14. https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200002006.htm
[3]	Theng B K G. The chemistry of clay-org anic reactions [M]. London: Adam Hilger, 1979.
[4]	Theng B K G. Formation and proper ties of clay-polymer complexes[M]. A msterdam : Elsevier, 1979.
[5]	刘晓辉, 范家起, 李强, 等. 聚丙烯/蒙脱土纳米复合材料I. 制备、表征及动态力学[J]. 高分子学报, 2000, 5: 563. doi: 10.3321/j.issn:1000-3304.2000.05.009 LIU X H, FAN J Q, LI Q, et al. Polypropylene/ montmo rillonite nanoco mposites preparation characterisation and dy namic methnical propertites[J]. A cta Poly merica Sinica, 2000, 5: 563. doi: 10.3321/j.issn:1000-3304.2000.05.009
[6]	徐卫兵, 何平笙. A rrami法研究环氧树脂/ 蒙脱土/ 咪唑纳米复合材料的固化动力学[J]. 功能高分子学报, 2001, 14(1) : 66. https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF200101015.htm XU W B, HE P S. Study on cure kinetics of epoxy resin/ montmorillonite/midazole nanocomposite by A rrami equation[J]. Journal of Functional Polymers, 2001, 14(1) : 66. https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF200101015.htm
[7]	陈光明, 毛永梅, 漆宗能. 甲苯-2, 4 -二异氰酸酯修饰蒙脱土及聚苯乙烯/ 蒙脱土纳米复合材料的制备与表征[J]. 高分子学报, 2000, 10(5) : 599. doi: 10.3321/j.issn:1000-3304.2000.05.017 CHEN G M, MAO Y M, QI Z N. M odification of montmo rillonite with toluene-2, 4-di -isocy anate and preparatio n and characterization of polysty rene/montmorillonite nanocomposite[J]. A cta Polymerica Sinica, 2000, 10(5) : 599. doi: 10.3321/j.issn:1000-3304.2000.05.017
[8]	刘立敏, 朱晓光, 漆宗能. 尼龙6/ 蒙脱土纳米复合材料的等温结晶动力学研究[J]. 高分子学报, 1997, (5) : 519. doi: 10.3321/j.issn:1000-3304.1997.05.002 LIU I M, ZHU X G, QI Z N. Kinetics of iso thermal crystallizatio n for nylo n 6/montmorillonite nano composites[J]. Acta Polymerica Sinica, 1997, (5) : 519. doi: 10.3321/j.issn:1000-3304.1997.05.002
[9]	赵竹第, 李强, 欧玉春, 等. 尼龙6/蒙脱土纳米复合材料的制备、结构与力学性能的研究[J]. 高分子学报, 1999, 71 : 1133. https://www.cnki.com.cn/Article/CJFDTOTAL-GFXB705.001.htm ZHAO Z D, LI Q, OU Y C, et al. Sy nthesis, structure and mechanical proper ties o f nylon 6/montmorillonite nanocompo sites[J]. Acta Poly merica Sinica, 1999, 71 : 1133. https://www.cnki.com.cn/Article/CJFDTOTAL-GFXB705.001.htm
[10]	中国科学院地质研究所. 沸石矿物与应用研究论文集[M]. 北京: 科学出版社, 1979. Geology Institute of Chinese Academy of Sciences. The research paper series of zeolite and its application[M]. Beijing: Science Press, 1979.
[11]	Akane O, Masaya K, Toshio, et al. Synthesis and characterization of a nilon 6-clay hybrid[J]. Polymer P reprints, 1987, 28(2) : 447-451.
[12]	Philip B M, Emmanuel P, Giannelis E. Synthesis and barrier properties of poly (ε-caprolactone)-layered silicate naocomposites[J]. Journal of Polymer Science, 1995, 33 (5) : 1047-1051.
[13]	Kelly P, Akelah A, Qutubuddin S, et al. Reduction of residual stress in montmorillonite/ epoxy compounds[J]. Journal M aterials Science, 1994, 29 : 2274-2278.
[14]	Luca B, Mauro A R, Francesco C. Functionalization of montmorillonite by methyl methacrylate polymers containing side-chain ammonium cations[J]. Polymer, 1994, 35(15) : 3296 -3301. doi: 10.1016/0032-3861(94)90138-4