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    天津蓟县长城系串岭沟组混层粘土矿物

    陈涛 王河锦

    陈涛, 王河锦, 2008. 天津蓟县长城系串岭沟组混层粘土矿物. 地球科学, 33(5): 716-722.
    引用本文: 陈涛, 王河锦, 2008. 天津蓟县长城系串岭沟组混层粘土矿物. 地球科学, 33(5): 716-722.
    CHEN Tao, WANG He-jin, 2008. Mix-layer Clay Minerals from Chuanlinggou Formation of Changcheng System in Jixian County, Tianjin City. Earth Science, 33(5): 716-722.
    Citation: CHEN Tao, WANG He-jin, 2008. Mix-layer Clay Minerals from Chuanlinggou Formation of Changcheng System in Jixian County, Tianjin City. Earth Science, 33(5): 716-722.

    天津蓟县长城系串岭沟组混层粘土矿物

    基金项目: 

    国家自然科学基金面上项目 40702007

    中国地质大学(武汉) 第四批优秀青年教师资助计划 CUGQNL0710

    详细信息
      作者简介:

      陈涛(1979-), 女, 博士, 讲师, 主要从事粘土矿物学研究. E-mail: chentao@cug.edu.en

    • 中图分类号: P57

    Mix-layer Clay Minerals from Chuanlinggou Formation of Changcheng System in Jixian County, Tianjin City

    • 摘要: 为了解天津蓟县长城系串岭沟组地层中混层粘土矿物的组成和结构特征, 利用X射线粉晶衍射(XRD) 和高分辨透射电镜(HRTEM) 对其进行了深入研究.通过对比该区粘土矿物的自然干燥片、Ca离子饱和片、Ca饱和的乙二醇膨胀片、加热到375℃和550℃的乙二醇膨胀片获取的XRD衍射峰, 确定该区混层粘土矿物为伊利石/蒙脱石(I/S) 不规则混层矿物和绿泥石/蒙脱石(Chl/S) 不规则混层矿物.从高分辨透射电镜观察到I/S规则及不规则混层的晶格条纹像以及Chl/S不规则混层的晶格条纹像, 揭示了该区I/S混层和Chl/S混层的层间堆跺结构特征.该研究为蓟县中元古界典型剖面提供了重要的混层粘土矿物的结构信息.

       

    • 图  1  样品的各种XRD衍射图谱

      绿泥石; S.smectite, 蒙脱石; I.illite, 伊利石; (?).还不能确定粘土矿物组成; A.自然干燥片; Ca.Ca离子饱和片; Ca-EG.Ca饱和的乙二醇膨胀片; 375.加热到375 ℃的乙二醇膨胀片; 550.加热到550 ℃的乙二醇膨胀片; Smectite-EG.乙二醇膨胀蒙脱石

      Fig.  1.  Different kinds of XRD pattern of the sample Chl.chlorite,

      图  2  I/S不规则(a) 和不规则(b) 混层粘土矿物的晶格像

      Fig.  2.  Lattice image of disorder I/S (a) and order I/S (b) mix-layer clay mineral

      图  3  Chl/S不规则混层粘土矿物的晶格像

      Fig.  3.  Lattice image of disorder Chl/S mix-layer clay miner

      表  1  具有混层粘土矿物判断意义的XRD衍射峰及其对应矿物

      Table  1.   Identification XRD diffraction peaks of mixed-layer clay minerals and their counterpart minerals

    • Ahn, J. H., Buseck, P. R., 1990. Layer-stacking sequences and structural disorder in mixed-layer illite/smectite: Image simulations and HRTEM imaging. American Mineralogist, 75: 267-275.
      Buseck, P. R., Iiji ma, S., 1974. High resolution electron microscopy of silicates. American Mineralogist, 59 (1-2): 1-21.
      Cai, X. C., Liang, S. X., Chen, S. Y., et al., 1992. EPR study of dickite-kaolinite interstratified mineral. Acta Miner-alogica Sinica, 12 (2): 152-158 (in Chinese with Eng-lish abstract).
      Chen, T., Chen, D. Z., Wang, H. J., 2005. Electron diffraction patterns of plesiot winning of Feillite. Acta Geologica Sinica, 79 (3): 332-335. doi: 10.1111/j.1755-6724.2005.tb00897.x
      Chen, T., Wang, H. J., 2007a. Microstructure characteristics of illite from Chuanlinggou Formation of Changcheng Systemin Jixian City, Tianjin City. Science in China (Ser. D), 50 (10): 1452-1458. doi: 10.1007/s11430-007-0090-0
      Chen, T., Wang, H. J., 2007b. Determination of layer stacking microstructures and intralayer transition of illitepolytypes by high-resolution transmission electron mi-croscopy (HRTEM). American Mineralogist, 92 (5-6): 926-932. doi: 10.2138/am.2007.2293
      Hong, H. L., Tie, L. Y., Bian, Q. J., et al., 2005. Study on the Zhongxiang rectorite by SEM and EPMA. Journal of Chinese Electron Microscopy Society, 24 (2): 124-128 (in Chinese with English abstract).
      Kogure, T., 2002. Investigation of micas using advancedTEM. In: Reviews in mineralogy (Vol. 46), Mineralog-ical Society of America, Washington, D. C., 281-312.
      Kogure, T., Murakami, T., 1996. Direct identification of bio-tite/vermiculitelayers in hydrobiotite using high-resolution TEM. Mineralogical Journal, 18 (4): 131-137. doi: 10.2465/minerj.18.131
      Kogure, T., Banfield, J. F., 2000. New insights into themechanism for chloritization of biotite using polytypeanalysis. American Mineralogist, 85: 1202-1208. doi: 10.2138/am-2000-8-913
      Lee, J. H., Peacor, D. R., 1983. Intralayer transitions in phyllosilicates of Martins burg shale. Nature, 303: 608-609. doi: 10.1038/303608a0
      Lu, Q., Lei, X. R., Liu, H. F., 1993a. Study of the stackingsequences of a kind of irregular mixed-layer illite-smectite (I/S) clay mineral—With a discussion of the existence of minerals with two-dimensional lattice and one-dimensional quasi-lattice. Acta Geological Sinica, 67 (2): 123-130 (in Chinese with English abstract).
      Lu, Q., Liu, H. F., Lei, X. R., 1993b. Si mulating quantitative analysis method—Quantitative analysis of clay mineral mixtures of mont morillonite, illite/smectite interst ratified clay minerals, illite, chlorite and some others. Acta Mineralogica Sinica, 13 (1): 12-20 (in Chinese withEnglish abstract).
      Méring, J., 1949. L′Intérference des Rayons X dans les systems à stratification désordonnée. Acta Crystallography, (2): 371-377.
      Moore, D. M., 1989. X-ray diffraction and the identification and analysis of clay minerals. Oxford University Press, New York, 332.
      Murakami, T., Sato, T., Inoue, A., 1999. HRTE Mevidence for the process and mechanism of saponite-to-chlorite conversion through corrensite. American Mineralogist 84: 1080-1087.
      Shi, Y. X., Dai, X. R., Song, Z. G., et al., 2005. Characteris-tics of clay mineral assemblages and their spatial distribution of chinese loess in different climatic zones. Acta Sedimentologica Sinica, 23 (4): 690-695 (in Chinesewith English abstract).
      Walker, G. F., 1957. On the differentiation of vermiculitesand smectites in clays. Clay Mineralogy Bulletin, 3: 239-246.
      Wang, H., Wang, H. J., Chen, T., et al., 2005. Study of two-dimensional nanometer illitein Jixian County, Tian-jin City. Geological Review, 51 (3): 319-324 (in Chinese with English abstract).
      Wang, H., Zhou, J., 2000. Data smoothing and distortion ofX-ray diffraction Peak (I: Theory). Journal of Applied Crystallography, 33: 1128-1135. doi: 10.1107/S0021889800006932
      Wang, Q. M., Zhang, L. F., 1992. Study on illite/chlorite bytransmission electron microscope. Chinese Science Bulletin, 37 (8): 727-730 (in Chinese). doi: 10.1360/csb1992-37-8-727
      Yang, X. Z., Ye, N. J., 2003. Gibbs free energies of formationfor mixed-layer illite-mont morillonite in the process ofmont morillonite illitization. Geology-Geochemistry, 31 (3): 20-25 (in Chinese with English abstract).
      Zhang, L. F., Wang, Q. M., Ren, L. F., 1992. Transformation of clay minerals in the buried metamorphic process of Triassic mudstone from Ordos basin in northern Shaanxi. Science in China (Ser. B), (7): 759-767 (inChinese).
      Zhang, Y., Chen, W., Chen, K. L., et al., 2006. Study on theAr-Ar Age spectrum of diagenetic I/S and the mecha-nism of 39Ar recoil loss—Examples fromthe clay min-erals of P-T boundaryin Changxing, Zhejiang Province. Geological Review, 52 (4): 556-561 (in Chinese withEnglish abstract).
      蔡秀成, 梁绍暹, 陈世悦, 等, 1992. 地开石-高岭石混层矿物的电子顺磁共振(EPR) 研究. 矿物学报, 12 (2): 152-158. https://www.cnki.com.cn/Article/CJFDTOTAL-KWXB201901002.htm
      洪汉烈, 铁丽云, 边秋娟, 等, 2005. 湖北钟祥累托石的电子显微研究. 电子显微学报, 24 (2): 124-128. doi: 10.3969/j.issn.1000-6281.2005.02.008
      陆琦, 雷新荣, 刘惠芳, 1993a. 一种不规则伊/蒙混层粘土矿物堆垛序列的研究——兼论具二维晶格一维准晶格的矿物的存在. 地质学报, 67 (2): 123-130. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE199302002.htm
      陆琦, 刘惠芳, 雷新荣, 1993b. 蒙脱石+伊/蒙混层+伊利石等粘土矿物混合物相X射线定量分析方法—模拟定量法. 矿物学报, 13 (1): 12-20. https://www.cnki.com.cn/Article/CJFDTOTAL-KWXB199301002.htm
      师育新, 戴雪荣, 宋之光, 等, 2005. 我国不同气候带黄土中粘土矿物组合特征分析. 沉积学报, 23 (4): 690-695. doi: 10.3969/j.issn.1000-0550.2005.04.019
      王欢, 王河锦, 陈涛, 等, 2005. 天津蓟县二维纳米级伊利石研究. 地质论评, 51: 319-324. doi: 10.3321/j.issn:0371-5736.2005.03.012
      王启明, 张立飞, 1992. 伊利石/绿泥石混层的电镜研究. 科学通报, 37 (8): 727-730. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199208017.htm
      杨献忠, 叶念军, 2003. 蒙脱石伊利石化过程中伊/蒙混层形成的Gibbs自由能. 地质地球化学, 31 (3): 20-25. doi: 10.3969/j.issn.1672-9250.2003.03.004
      张立飞, 王启明, 任磊夫, 1992. 陕北鄂尔多斯盆地三叠系泥岩中粘土矿物在埋藏变质过程中的转化. 中国科学(B辑), (7): 759-767.
      张彦, 陈文, 陈克龙, 等, 2006. 成岩混层(I/S) Ar-Ar年龄谱型及39Ar核反冲丢失机理研究——以浙江长兴地区P-T界线粘土岩为例. 地质论评, 52 (4): 556-561. doi: 10.3321/j.issn:0371-5736.2006.04.015
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    • 收稿日期:  2008-03-05
    • 刊出日期:  2008-09-25

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