松辽盆地庆深气田天然气成因类型鉴别

杨春; 刘全有; 周庆华; 李剑; 冯子辉; 李志生

松辽盆地庆深气田天然气成因类型鉴别

杨春¹,
刘全有^2, ,,
周庆华³,
李剑⁴,
冯子辉⁵,
李志生⁴

1.
浙江大学地球科学系, 浙江杭州 310027
2.
中石化石油勘探开发研究院, 北京 100083
3.
中国石油勘探开发研究院, 北京 100083
4.
中国石油勘探开发研究院廊坊分院, 河北廊坊 065007
5.
中国石油大庆油田勘探开发院, 黑龙江大庆 163712

基金项目:

国家自然科学基金项目 40802028

国家基础研究“973”项目 2005CB422108

中国石油天然气股份有限公司科学研究与技术开发项目 07-01C-01-07

详细信息

作者简介:
杨春(1981-), 男, 博士, 主要从事天然气地质学及地球化学研究

通讯作者:
刘全有, E-mail: qyouliu@sohu.com

中图分类号: P618.13
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出版历程
- 收稿日期: 2009-02-20
- 刊出日期: 2009-09-25

Genetic Identification of Natural Gases in Qingshen Gas Field, Songliao Basin

1.
Department of Earth Sciences, Zhejiang University, Hangzhou 310027, China
2.
Exploration and Production Research Institute, SINOPEC, Beijing 100083, China
3.
Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China
4.
Langf ang Branch, Research Institute of Petroleum Exploration and Development, PetroChina, Langfang 065007, China
5.
Daqing Oil Company, PetroChina, Daqing 163712, China

摘要

摘要: 通过对松辽盆地徐家围子烃源岩和原油热模拟实验、烷烃气碳同位素组成分析, 认为在高演化阶段单一热力作用可以引起重烃气(δ¹³C₂ > δ¹³C₃ > δ¹³C₄) 碳同位素组成倒转, 但CH₄与C₂H₆(δ¹³C₁ > δ¹³C₂) 却很难发生倒转.庆深气田天然气重甲烷碳同位素组成、烷烃气碳同位素完全倒转、高稀有气体同位素组成(R/Ra > 1.0), 说明该气田天然气来源具有多样性.利用R/Ra与CO₂/³He和R/Ra与CH₄/³He关系对庆深气田天然气成因类型进行识别, 认为该气田烷烃气中甲烷有部分为无机成因, 重烃气则为有机成因.该地区高地温梯度导致有机成因重烃气碳同位素组成发生倒转, 而CH₄与C₂H₆碳同位素组成倒转主要与重碳同位素的无机甲烷混入有关.
- 庆深气田 /
- 热模拟实验 /
- 碳同位素组成 /
- 无机成因气 /
- 有机成因气
Abstract: According to measurement of carbon isotopes of gaseous alkanes thermally cracked from the hydrocarbon sources and oil under closed system pyrolysis, the results suggest that the reversal occurrence for carbon isotopes of heavy gaseous alkanses (δ¹³C₂ > δ¹³C₃ > δ¹³C₄) would be caused by single thermal dynamics, whereas the reversal trends of δ¹³C₁ and δ¹³C₂ (δ¹³C₁ > δ¹³C₂) could not be observed.The natural gases in the Qingshen gas field are characterized by the less negative δ¹³C₁ values, reversal series of carbon isotopes for gaseous alkanes and high R/Ra values (R/Ra > 1.0), indicating natural gases should have stemmed from multi-sources.Based on the correlation of R/Ra and CO₂/³He, R/Ra and CH₄/³He, the genesis of natural gases from the Qingshen gas field were identified.The hydrocarbon gases in the Qingshen gas field are a mixture of alkanes, in which the heavy gaseous alkanes were derived from the thermal decomposition of organic matters due to the high geothermal gradient, whereas mixing of inorganic methane into organic gas caused the reversal of the carbon isotopic trend of CH₄ and C₂H₆.
- Qingshen gas field /
- pyrolysis experiment /
- carbon isotope /
- inorganic gas /
- organic gas

HTML全文

图 1 庆深气田烷烃气碳同位素组成变化

Fig. 1. Plot of δ¹³C values of individual n-alkanes vs. carbon number for gas samples from the Qingshen gas field, Songliao basin

下载: 全尺寸图片幻灯片

图 2 庆深气田R/Ra与CO₂/³He (a)和R/Ra与CH₄/³He (b) 关系

Fig. 2. Plots of R/Ra ratios versus CO₂/³He (a) and CH₄/³He (b) two component mixing of CO₂ between crustal and mantle end-members

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表 1 松辽盆地徐家围子烃源岩与原油热模拟实验烷烃气碳同位素组成

Table 1. Carbon isotope compositions of alkane gases from possible source rocks and crude oils in the closed system pyrolysis

参考文献(49)

Ballentine, C. J., Schoell, M., Coleman, D., et al., 2001.300 Myr-old magmatic CO₂ in natural gas reservoirs of the West Texas Permian basin. Nature, 409 (6818): 327-331. doi: 10.1038/35053046
Basu, S., Stuart, F. M., Klemm, V., et al., 2006. Helium isotopes in ferromanganese crusts fromthe central PacificOcean. Geochimica et Cosmochimica Acta, 70 (15): 3996-4006. doi: 10.1016/j.gca.2006.05.015
Berndt, M. E., Allen, D. E., Seyfried, W. E., 1996. Reduction of CO₂ during serpentinization of olivine at 300℃ and 500 bar. Geology, 24 (4): 351-354. doi: 10.1130/0091-7613(1996)024<0351:ROCDSO>2.3.CO;2
Cai, C., Worden, R. H., Bottrell, S. H., et al., 2003. Thermochemical sulphate reduction and the generation of hydrogen sulphide and thiols (mercaptans) in Triassic carbonate reservoirs from the Sichuan basin, China. Chemical Geology, 202 (1-2): 39-57. doi: 10.1016/S0009-2541(03)00209-2
Chung, H. M., Gorml, J. R., Squires, R. M., 1988. Origin of gaseous hydrocarbons in subsurface environments: Theoretical considerations of carbon isotope distribution. Chemical Geology, 71 (1-3): 97-104. doi: 10.1016/0009-2541(88)90108-8
Craig, H., Lupton, J. E., 1976. Primordial neon, helium and hydrogen in oceanic basalts. Earth and Planetary Science Letters, 31 (3): 369-385. doi: 10.1016/0012-821X(76)90118-7
Cramer, B., Krooss, B. M., Littke, R., 1998. Modelling isotope fractionation during primary cracking of naturalgas: A reaction kinetic approach. Chemical Geology, 149 (3-4): 235-250. doi: 10.1016/S0009-2541(98)00042-4
Dai, J. X., Li, J., Luo, X., et al., 2005b. Stable carbon isotope compositions and source rock geochemistry of the giant gas accumulations in the Ordos basin, China. Organic Geochemistry, 36 (12): 1617-1635. doi: 10.1016/j.orggeochem.2005.08.017
Dai, J. X., Yang, S., Chen, H., et al., 2005a. Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins. Organic Geochemistry, 36 (12): 1664-1688. doi: 10.1016/j.orggeochem.2005.08.007
Dai, J. X., Xia, X., Qin, S., et al., 2004. Origins of partially reversed alkane δ¹³ C values for biogenic gases in China. Organic Geochemistry, 35 (4): 405-411. doi: 10.1016/j.orggeochem.2004.01.006
Dai, J. X., Yang, C., Hu, G. Y., et al., 2008. Coal-formed gas plays a significant role in the natural gas industry of China. Natural Gas Geoscience, 19 (6): 733-740 (inChinese with English abstract).
Des Marais, D. J., Donchin, J. H., Nehring, N. L., et al., 1981. Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons. Nature, 292 (5826): 826-828. doi: 10.1038/292826a0
Du, J., Jin, Z., Xie, H., et al., 2003. Stable carbon isotope compositions of gaseous hydrocarbons produced from high pressure and high temperature pyrolysis of lignite. Organic Geochemistry, 34 (1): 97-104. doi: 10.1016/S0146-6380(02)00158-4
Fu, G., Lu, Y. F., Yu, D., 2007. Major factors controlling formation of large and intermediate gas fields with high gas accumulation efficiency in different types of basinsin China. Earth Science—Journal of China University of Geosciences, 32 (1): 82-88 (in Chinese with English abstract).
Fu, G., Wang, Y. G., 2008. Time and space matching relation among accumulation essential factors of gas reservoirs in volcanic rock and its controlling to gas accumulation: A case study of deep strata of Xujiaweizi region. Earth Science—Journal of China University of Geosciences33 (3): 342-348 (in Chinese with English abstract). doi: 10.3799/dqkx.2008.045
Feng, Z. H., Chi, Y. L., Du, H. W., et al., 2002. Carbon isotopic composition and yield of gaseous hydrocarbon by oil hydrous pyrolysis in rock medium. Acta Sedimentologica Sinica, 20 (3): 505-509 (in Chinese with English abstract).
Fuex, A. N., 1977. The use of stable carbon isotopes in hydrocarbon exploration. Journal of Geochemical Exploration, 7 (2): 155-188.
Galimov, E. M., 1988. Sources and mechanisms of formation of gaseous hydrocarbons in sedimentary rocks. Chemical Geology, 71 (1-3): 77-95. doi: 10.1016/0009-2541(88)90107-6
Hiyagon, H., Kennedy, B. M., 1992. Noble gases in CH₄rich gas fields, Alberta, Canada. Geochimica et Cosmochimica Acta, 56 (4): 1569-1589. doi: 10.1016/0016-7037(92)90226-9
Hopp, J., Trieloff, M., 2005. Refining the noble gas record of the Réunion mantle plume source: Implications on mantle geochemistry. Earth and Planetary Science Letters, 240 (3-4): 573-588. doi: 10.1016/j.epsl.2005.09.036
Horita, J., Berndt, M. E., 1999. Abiogenic methane formation and isotopic fractionation under hydrothermal conditions. Science, 285 (5430): 1055-1057. doi: 10.1126/science.285.5430.1055
James, A. T., 1990. Correlation of reservoired gases using the carbon isotopic compositions of wet gas components. AAPG Bulletin, 74 (9): 1441-1458.
Janecky, D. R., Seyfried, W. E., 1986. Hydrothermal serpentinization of peridotite within the oceanic crust: Experimental investigations of mineralogy and major element chemistry. Geochimica et Cosmochimica Acta, 50 (7): 1357-1378. doi: 10.1016/0016-7037(86)90311-X
Lancet, M. S., Anders, E., 1970. Carbonisotope fractionation in the Fischer-Tropsch synthesis and in methane. Science, 170 (3961): 980-982. doi: 10.1126/science.170.3961.980
Liu, Q., Dai, J., Zhang, T., et al., 2007. Genetic types of natural gas and their distribution in Tarim basin, NW China. Journal of Nature Science and Sustainable Technology, 1 (4): 603-620.
Oxburgh, E. R., O'Nions, R. K., Hill, R. I., 1986. Helium isotopes in sedimentary basin. Nature, 324 (6089): 632-635.
Poreda, R., Craig, H., 1989. Helium isotope ratios in circum Pacific volcainc arcs. Nature, 338 (6215): 473-478. doi: 10.1038/338473a0
Poreda, R. J., Jenden, P. D., Kaplan, I. R., et al., 1986. Mantle helium in Sacramento basin natural gas wells. Geochimica et Cosmochimica Acta, 50 (12): 2847-2853. doi: 10.1016/0016-7037(86)90231-0
Prinzhofer, A., Battani, A., 2003. Gas isotopes tracing: An important tool for hydrocarbons exploration. Oil & Gas Science and Technology, 58 (2): 299-311.
Schoell, M., 1980. The hydrogen and carbon isotopic composition of methane from natural gases of various origins. Geochimica et Cosmochimica Acta, 44 (5): 649-661. doi: 10.1016/0016-7037(80)90155-6
Schoell, M., 1983. Genetic characterization of natural gases. AAPG Bulletin, 67 (12): 2225-2238.
Sherwood, L. B., Ballentine, C. J., O'Nions, R. K., 1997. The fate of mantle-derived carbon in a continental sedimentary basin: Integration of C/He relationships and stable isotope signatures. Geochimica et Cosmochimica Acta, 62 (11): 2295-2307.
Sherwood, L, B., Westgate, T. D., Ward, J. A., et al., 2002. Abiogenic formation of alkanes in the earth's crust as a minor source for global hydrocarbon reservoirs. Nature, 416 (6880): 522-524. doi: 10.1038/416522a
Tang, Y., Huang, Y., Ellis, G. S., et al., 2005. A kinetic model for thermally induced hydrogen and carbon isotope fractionation of individual n-alkanes in crude oil. Geochimica et Cosmochimica Acta, 69 (18): 4505-4520. doi: 10.1016/j.gca.2004.12.026
Wakita, H., Sano, Y., 1983. ³He/⁴He ratios in CH₄-rich natural gases suggest magmatic origin. Nature, 305 (5937): 792-794. doi: 10.1038/305792a0
Wang, X., Li, C., Chen, J., et al., 1997. On abiogenic natural gas. Chinese Science Bulletin, 42 (16): 1327-1336. doi: 10.1007/BF02882859
Welhan, J. A., 1988. Origins of methane in hydrothermal system. Chemical Geology, 71 (1-3): 183-198. doi: 10.1016/0009-2541(88)90114-3
Xu, S., Nakai, S. I., Wakita H., et al., 1995b. Mantle-derived noble gases in natural gases from Songliao basin, China. Geochimica et Cosmochimica Acta, 59 (22): 4675-4683. doi: 10.1016/0016-7037(95)00301-0
Xu, S., Nakai, S., Wakita, H., et al., 1995a. Helium isotope compositions in sedimentary basins in China. Applied Geochemistry, 10 (6): 643-656. doi: 10.1016/0883-2927(95)00033-X
Xu, Y. C., Shen, P., 1996. A study of natural gas origins in China. AAPG Bulletin, 80 (10): 1604-1614.
Xu, Y. C., Liu, W., Shen, P., et al., 2006. Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, China. Science in China (Ser. D), 49 (9): 938-946. doi: 10.1007/s11430-006-0938-8
Xu, Y. C., Shen, P., Liu, W. H., et al., 1998. Noble gas geochemistry of natural gases. Science Press, Beijing, 231 (in Chinese).
Yang, C., Luo, X., Li, J., et al., 2008. Geochemical characteristics of pyrolysis gas from epimetamorphic rocks in the northern basement of Songliao basin, NE China. Science in China (Ser. D), 51 (Suppl. Ⅰ): 140-147.
Zhou, Q., Feng, Z., Men, G., 2008. Present geotemperature and its suggestion to natural gas generation in Xujiaweizi fault-depression of the northern Songliao basin. Science in China (Ser. D), 51 (Suppl. Ⅰ): 207-220.
戴金星, 杨春, 胡国艺, 等, 2008. 煤成气是中国天然气工业的主角. 天然气地球科学, 19 (6): 733-740. doi: 10.11764/j.issn.1672-1926.2008.06.733
付广, 吕延防, 于丹, 2007. 我国不同类型盆地高效大中型气田形成的主控因素. 地球科学——中国地质大学学报, 32 (1): 82-88. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200701011.htm
付广, 王有功, 2008. 火山岩天然气成藏要素时空匹配及对成藏的控制作用: 以徐家围子地区深层为例. 地球科学——中国地质大学学报, 33 (3): 342-348. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200803008.htm
冯子辉, 迟元林, 杜洪文, 等, 2002. 原油在储层介质中的加水裂解生气模拟实验. 沉积学报, 20 (3): 505-509. doi: 10.3969/j.issn.1000-0550.2002.03.023
徐永昌, 沈平, 刘文汇, 等, 1998. 天然气中稀有气体地球化学. 北京: 科学出版社, 231.