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    大别山超高压硬玉石英岩中的水: 来自红外光谱的证据

    樊孝玉 吴秀玲 孟大维 刘卫平 汪新星 郑建平

    樊孝玉, 吴秀玲, 孟大维, 刘卫平, 汪新星, 郑建平, 2007. 大别山超高压硬玉石英岩中的水: 来自红外光谱的证据. 地球科学, 32(2): 167-174.
    引用本文: 樊孝玉, 吴秀玲, 孟大维, 刘卫平, 汪新星, 郑建平, 2007. 大别山超高压硬玉石英岩中的水: 来自红外光谱的证据. 地球科学, 32(2): 167-174.
    FAN Xiao-yu, WU Xiu-ling, MENG Da-wei, LIU Wei-ping, WANG Xin-xing, ZHENG Jian-ping, 2007. Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR. Earth Science, 32(2): 167-174.
    Citation: FAN Xiao-yu, WU Xiu-ling, MENG Da-wei, LIU Wei-ping, WANG Xin-xing, ZHENG Jian-ping, 2007. Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR. Earth Science, 32(2): 167-174.

    大别山超高压硬玉石英岩中的水: 来自红外光谱的证据

    基金项目: 

    国家自然科学基金项目 40572114

    国家自然科学基金项目 40572114

    国家杰出青年科学基金项目 40425002

    高等学校博士学科点专项科研基金项目 20060491504

    地质过程与矿产资源国家重点实验室开放基金项目 GPMR0521

    详细信息
      作者简介:

      樊孝玉(1978-), 女, 博士研究生, 主要从事矿物材料的微结构及其表征方面的研究.E-mail: dwmeng@cug.edu.cn

    • 中图分类号: P571

    Water in UHP Jadeite-Quartzites of Dabie Mountains: Evidence from Micro-FTIR

    • 摘要: 为了探讨大别山“名义上无水矿物”(NAMs)中结构水的分布特征, 研究相关的流体活动、矿物变形以及板块俯冲和折返动力学过程提供重要的微观信息.对大别山双河和碧溪岭地区超高压硬玉石英岩中的石英、硬玉、石榴石和金红石进行了傅立叶变换红外光谱(FTIR)分析, 研究结果显示这些矿物都含有以OH-或者H2O形式存在的氢, 硬玉中结构水平均含量在1000×10-6左右; 石榴石结构水含量在(900~1600)×10-6之间, 各样品颗粒结构水的分布不均匀; 副矿物金红石结构水含量在2000×10-6以上, 而石英结构中基本不含或仅含微量水(< 4×10-6).双河和碧溪岭地区的硬玉石英岩全岩含水量分别为(490~600)×10-6和545×10-6, 不同地区同一种NAMs中结构水含量基本相同.表明在高压-超高压变质岩的形成过程中, 地壳或原岩中的水可以通过这些超高压变质岩中的NAMs携带到地球深部.

       

    • 图  1  南大别部分地区地质简图和双河、碧溪岭的位置(据李旭平等, 2005)

      1.北大别角闪岩-麻粒岩变质带; 2.中大别UHP变质带; 3.南大别LT榴辉岩变质带; 4.宿松蓝片岩-角闪变质带; 5.晚中生代花岗岩; 6.主剪切带; 7.主断层

      Fig.  1.  Geological sketch map of the southern Dabie mountains and the position of Shuanghe and Bixiling

      图  2  大别山超高压硬玉石英岩矿物中OH-伸缩区红外光谱

      a.硬玉; b.石榴石; c.金红石; d.石英; “SH”和“BXL”表示红外光谱分别对应双河、碧溪岭地区的硬玉石英岩

      Fig.  2.  Representative spectra of the minerals in UHP jadeite-quartzites from Dabie mountains

      表  1  大别山硬玉石英岩硬玉中结构水的红外吸收特征和计算结果

      Table  1.   FTIR analysis of jadeites from the jadeite-quartzites at Dabie mountains

      表  2  大别山硬玉石英岩石榴石中水的红外吸收特征和计算结果

      Table  2.   FTIR analysis of garnets from the jadeite-quartzites at Dabie mountains

      表  3  大别山硬玉石英岩金红石中结构水的红外吸收特征和计算结果

      Table  3.   FTIR analysis of rutiles from the jadeite-quartzites at Dabie mountains

      表  4  大别山硬玉石英岩石英中结构水的红外吸收特征和计算结果

      Table  4.   FTIR analysis of quartzs from the jadeite-quartzites at Dabie mountains

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