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    太平洋海山钴结壳资源量估算

    张富元 章伟艳 朱克超 张霄宇 倪建宇 赵宏樵 郑连福

    张富元, 章伟艳, 朱克超, 张霄宇, 倪建宇, 赵宏樵, 郑连福, 2011. 太平洋海山钴结壳资源量估算. 地球科学, 36(1): 1-11. doi: 10.3799/dqkx.2011.001
    引用本文: 张富元, 章伟艳, 朱克超, 张霄宇, 倪建宇, 赵宏樵, 郑连福, 2011. 太平洋海山钴结壳资源量估算. 地球科学, 36(1): 1-11. doi: 10.3799/dqkx.2011.001
    ZHANG Fu-yuan, ZHANG Wei-yan, ZHU Ke-chao, ZHANG Xiao-yu, NI Jian-yu, ZHAO Hong-qiao, ZHENG Lian-fu, 2011. Resource Estimation of Co-Rich Crusts of Seamounts in the Pacific. Earth Science, 36(1): 1-11. doi: 10.3799/dqkx.2011.001
    Citation: ZHANG Fu-yuan, ZHANG Wei-yan, ZHU Ke-chao, ZHANG Xiao-yu, NI Jian-yu, ZHAO Hong-qiao, ZHENG Lian-fu, 2011. Resource Estimation of Co-Rich Crusts of Seamounts in the Pacific. Earth Science, 36(1): 1-11. doi: 10.3799/dqkx.2011.001

    太平洋海山钴结壳资源量估算

    doi: 10.3799/dqkx.2011.001
    基金项目: 

    国家科学技术部项目 2004DIB3J086

    国家科学技术部项目 2006FY220400

    中国大洋协会 DYXM115-01-1-06

    中国科学院地球化学研究所矿床地球化学国家重点实验室开放课题资助 200809

    详细信息
      作者简介:

      张富元(1952-), 男, 研究员, 主要从事海洋地质研究和海洋矿产资源评价.E-mail: fyzhang2003@163.com

    • 中图分类号: P628;P744

    Resource Estimation of Co-Rich Crusts of Seamounts in the Pacific

    • 摘要: 为合理地估算出太平洋海山钴结壳资源量, 基于我国西太平洋海山钴结壳拖网采样调查资料以及对太平洋海山钴结壳资源分布规律和钴结壳矿区圈定参数指标的深入研究, 创造性地按海山不同高度、不同洋壳年龄赋予不同结壳厚度, 进而首次计算出太平洋海山干结壳资源量为(507.06~1 014.11)×108 t, 锰为(111.15~222.29)×108 t, 钴为(3.04~6.08)×108 t, 镍为(2.23~4.46)×108 t, 铜为(0.66~1.32)×108 t, 结壳分布面积为2 062 862 km2.通过Co通量与结壳Co沉积量、结壳厚度的相关分析表明, 赋予不同洋壳年龄段的结壳厚度是理论厚度的6.10%~12.20%, 这与Ku et al.得出"结壳生长时间只占其整个生命史4%"的认识非常相近, 说明所赋结壳厚度基本合理, 得出的结壳资源量基本正确.为整个大洋海盆内海山钴结壳资源量的估算提供了新方法.

       

    • 图  1  太平洋海山分布示意(据Muller et al., 1997修改)

      颜色表示洋壳年龄;黑点表示海山;数据来自http://www.mantleplumes.org

      Fig.  1.  Sketch of seamount distribution in the Pacific

      图  2  西太平洋最低含氧层水深分布(5个测站)

      Fig.  2.  The water depth distribution of oxygen minimum zone in the western Pacific

      图  3  钴结壳Co含量与水深关系(研究区指西太平洋,太平洋资料来自http://www.ngdc.noaa.gov)

      Fig.  3.  Relationship between Co contents of cobalt crusts and the water depth

      图  4  钴结壳厚度与年龄关系(数据见表 4)

      Fig.  4.  Relationship between crust thickness and age

      图  5  西太平洋洋壳年龄、海山年龄与经度关系(数据来自Clouard and Bonneville, 2001; Wessel, 2001)

      Fig.  5.  Relationship between ocean crust (seamount) age and longitude

      表  1  钴结壳厚度与洋壳(海山)沉降深度关系

      Table  1.   Relationship between cobalt crust thickness and depressed depth of the ocean crust (seamount)

      洋壳(海山)沉降深度(m) 结壳生长间隔深度(m) 结壳生长年龄(Ma) 结壳生长速率(mm/Ma) 结壳厚度(mm)
      500~1 000 500 2.04 1.1 2.24
      500~1 500 1 000 8.16 1.1 8.98
      500~2 000 1 500 18.36 1.1 20.20
      500~2 500 2 000 32.65 1.1 35.92
      500~3 000 2 500 51.02 1.1 56.12
      500~3 500 3 000 73.46 1.1 80.81
      500~4 000 3 500 100.00 1.1 110.00
      下载: 导出CSV

      表  2  太平洋海山钴结壳资源量计算(按海山高度)

      Table  2.   Estimation of cobalt crust resource amount on the seamount in the Pacific (based on seamount height)

      海山高度(m) 海山个数 洋壳平均年龄(Ma) 最小经度 最大经度 平均经度 最小纬度 最大纬度 平均纬度
      0~2 000 3 333 74.50 131.42 256.25 198.29 -64.92 58.70 -0.97
      2 000~3 000 3 334 89.04 131.52 256.98 192.98 -63.62 58.77 1.77
      3 000~4 000 924 112.55 131.28 252.48 186.50 -63.56 56.24 4.89
      4 000~5 000 281 111.46 140.98 252.87 186.17 -61.36 55.10 7.43
      5 000~6 000 75 111.18 140.22 248.88 187.56 -63.49 50.85 6.09
      6 000~8 000 75 107.63 147.02 244.42 190.07 -48.19 56.47 6.36
      海山高度(m) 海山平均高度(m) 海山平均半径(km) 海山面积(km2) 结壳平均厚度(cm) 结壳平均丰度(kg/m2) 结壳资源量(108 t) 结壳资源量*(108 t)
      0~2 000 1 831 10.13 1 243 043.37 1.00 18.00 223.75 447.50
      2 000~3 000 2 415 13.59 2 756 136.45 1.50 27.00 744.16 1 488.31
      3 000~4 000 3 477 18.07 1 881 715.03 2.00 36.00 677.42 1 354.83
      4 000~5 000 4 409 19.98 786 981.60 2.50 45.00 354.14 708.28
      5 000~6 000 5 528 18.12 131 235.13 3.00 54.00 70.87 141.73
      6 000~8 000 6 941 16.75 77 096.82 3.50 63.00 48.57 97.14
      平均/累计 2 436 12.96 6 876 208.00 1.71 30.78 2 118.90 4 237.80
      注:*钴结壳资源量按2倍丰度计算.
      下载: 导出CSV

      表  3  太平洋海山钴结壳资源量计算(按洋壳年龄)

      Table  3.   Estimation of cobalt crust resource amount on the seamount in the Pacific (based on ocean crust age)

      洋壳年龄(Ma) 海山个数 洋壳平均年龄(Ma) 最小经度 最大经度 平均经度 最小纬度 最大纬度 平均纬度
      0~30 1 355 13.83 136.08 256.98 236.94 -64.92 56.24 -6.19
      30~60 864 42.62 133.00 236.42 203.22 -62.99 58.19 -4.17
      60~90 695 77.11 167.92 222.78 206.00 -58.69 50.68 -11.63
      90~120 1 527 107.38 148.35 215.25 195.69 -50.86 46.70 10.40
      120~150 922 132.97 143.75 193.08 175.26 -6.18 43.79 15.75
      150~180 968 161.88 145.88 176.75 159.83 0.12 31.38 13.89
      无年龄 1 691 87.22 131.28 250.55 178.77 -63.62 58.77 -8.02
      洋壳年龄(Ma) 海山平均高度(m) 海山平均半径(km) 海山面积(km2) 结壳平均厚度(cm) 结壳平均丰度(kg/m2) 结壳资源量(108 t) 结壳资源量*(108 t)
      0~30 2 203 10.48 560 671 0.50 9.00 50.46 100.92
      30~60 2 258 11.43 429 638 1.00 18.00 77.33 154.67
      60~90 2 400 13.25 544 225 1.50 27.00 146.94 293.88
      90~120 2 538 15.65 1 681 634 2.00 36.00 605.39 1 210.78
      120~150 2 576 14.75 853 284 2.50 45.00 383.98 767.96
      150~180 2 843 19.48 1 576 789 3.00 54.00 851.47 1 702.93
      无年龄 2 327 13.13 1 229 966 2.08 37.44 460.50 921.00
      平均/累计 2 436 13.94 6 876 208 2.08 37.44 2 576.07 5 152.13
      注:*钴结壳资源量按2倍丰度计算.
      下载: 导出CSV

      表  4  世界大洋钴结壳厚度分布(拖网采样)

      Table  4.   Distribution of cobalt crust thickness on seamounts in the world-wide oceans (dredge haul samples)

      样品 位置 纬度 经度 水深(m) 厚度(cm) 年龄(Ma) 生长速率(mm/Ma) 文献
      OSM3 麦哲伦 10°50′N 157°40′E 1 772~1 950 19.0 Kim et al., 2005, 2006
      OSM4 麦哲伦 12°50′N 157°50′E 1 555~2 015 11.5 Kim et al., 2005, 2006
      OSM5 马绍尔 15°20′N 158°45′E 1 421~1 564 14.0 Kim et al., 2005, 2006
      OSM6 马绍尔 15°40′N 160°05′E 1 385~1 631 13.0 Kim et al., 2005, 2006
      KK84-RD50 Schumann海山 25°42′N 159°48′W 2 250~2 600 9.5 78.5 1.10 McMurtry et al., 1994
      CLD01 威克 21°45′00″N 160°44′24″E 2 210 8.0 81.8 0.98 Ling et al., 2005; Pan et al., 2002
      CB12 中太平洋 17°59′52″N 178°39′36″E 2 381 7.0 78.1 0.90 Ling et al., 2005; Pan et al., 2002
      CJ01 中太平洋 17°59′18″N 177°42′34″W 3 082 8.0 77.7 1.03 Ling et al., 2005; Pan et al., 2002
      CD29-2 太平洋 16°42′N 168°14′W 2 390~1 970 10.5 55.0 2.10 Ling et al., 2005; Pan et al., 2002
      D11-1 太平洋 11°39′N 161°41′E 1 870~1 690 14.7 58.0 2.53 Ling et al., 2005; Pan et al., 2002
      BM1969.05 大西洋 39°00′N 60°57′W 1 800 13.0 80.0 1.62 Frank et al., 1999
      ALV539 大西洋 35°00′N 59°00′W 2 700 8.0 41.0 2.37 Frank et al., 1999
      SS663 印度洋 12°57′S 76°06′E 5 250 6.7 26.0 2.80 Frank et al., 1999
      109D-C 印度洋 27°58′S 60°48′E 5 434 3.0 24.0 1.60 Frank et al., 1999
      89-D09 马绍尔群岛 11°45.10′N 161°33.60′W 2 530 5.4 14.0 2.00 Jeong et al., 2000
      89-D11 马绍尔群岛 11°37′N 161°40′W 1 870 10.4 47.0 3.00 Jeong et al., 2000
      90-D01 马绍尔群岛 10°27.29′N 156°41.80′W 2 180 8.5 33.0 3.00 Jeong et al., 2000
      91-D16 帕老群岛 8°33.49′N 135°36.79′W 3 400 1.5 8.0 2.00 Jeong et al., 2000
      下载: 导出CSV

      表  5  Co通量与钴结壳Co沉积量和厚度的相关分析

      Table  5.   Relationship between Co flux and Co deposited amount and thickness of cobalt crust

      海山洋壳年龄(Ma) Co通量(kg/m2) 赋予结壳厚度(cm) 丰度(kg/m2) Co沉积量(kg/m2) Co沉积量占Co通量百分数(Co沉积量/Co通量)×100 理论推测厚度(cm)
      1 0.0295 0.016 653 0.029 5 100.00 0.273
      30 0.885 0.5 9 0.054 6.10 8.2
      60 1.770 1.0 18 0.108 6.10 16.3
      90 2.655 1.5 27 0.162 6.10 24.5
      120 3.540 2.0 36 0.216 6.10 33.0
      150 4.425 2.5 45 0.270 6.10 41.0
      180 5.310 3.0 54 0.324 6.10 49.0
      下载: 导出CSV

      表  6  太平洋海山钴结壳资源量

      Table  6.   Amount of cobalt crust resource on the seamount in the Pacific

      金属元素 结壳金属元素含量(%) 结壳金属量(108t) 太平洋CC区结核金属量*(108 t) 陆地资源量*(108 t) 美国年需求量*(103 t)
      锰(Mn) 21.92 111.15~222.29 7.06~26.00 20.00 580
      钴(Co) 0.60 3.04~6.08 0.064~0.24 0.085 5.2
      镍(Ni) 0.44 2.23~4.46 0.35~1.31 0.540 132
      铜(Cu) 0.13 0.66~1.32 0.29~1.08 4.600 1 490
      太平洋海山面积 6 876 208 km2 结壳分布面积 2 062 862 km2 干结壳资源量 (507.05~1014.11)×108 t
      注: *Manheim, 1986.Marine Cobalt Resources.Science, 232:600~608.
      下载: 导出CSV
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    • 收稿日期:  2010-08-31
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