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    福建龙海牛头山新生代玄武岩橄榄岩包体的水

    王蓉 张保民

    王蓉, 张保民, 2011. 福建龙海牛头山新生代玄武岩橄榄岩包体的水. 地球科学, 36(4): 635-642. doi: 10.3799/dqkx.2011.065
    引用本文: 王蓉, 张保民, 2011. 福建龙海牛头山新生代玄武岩橄榄岩包体的水. 地球科学, 36(4): 635-642. doi: 10.3799/dqkx.2011.065
    WANG Rong, ZHANG Bao-min, 2011. Water in Peridotite Xenoliths from Niutoushan, Longhai, Fujian. Earth Science, 36(4): 635-642. doi: 10.3799/dqkx.2011.065
    Citation: WANG Rong, ZHANG Bao-min, 2011. Water in Peridotite Xenoliths from Niutoushan, Longhai, Fujian. Earth Science, 36(4): 635-642. doi: 10.3799/dqkx.2011.065

    福建龙海牛头山新生代玄武岩橄榄岩包体的水

    doi: 10.3799/dqkx.2011.065
    基金项目: 

    国家自然科学基金项目 40372027

    国家自然科学基金项目 40872040

    详细信息
      作者简介:

      王蓉(1976-),女,博士,主要从事矿物学、岩石学、矿床学专业研究.E-mail: joangemm@yahoo.com.cn

    • 中图分类号: P588.12

    Water in Peridotite Xenoliths from Niutoushan, Longhai, Fujian

    • 摘要: 对福建龙海牛头山新生代玄武岩中橄榄岩包体进行了傅利叶变换红外光谱(FTIR)分析,结果显示,二辉橄榄岩中的辉石包体含有结构水,均以OH的形式存在,结构水含量分别如下: 单斜辉石为(151~845)×10-6,斜方辉石为(40~710)×10-6,全岩为(25~90)×10-6.无论是辉石中的水含量还是全岩中的水含量,福建牛头山地区均高于华北克拉通的安徽女山、河北汉诺坝和苏北盆地,而与同是华北克拉通的河北阳原地区水含量相当.实验证明辉石是牛头山地区上地幔重要的水储库.初步推断福建牛头山经历了洋壳俯冲作用及底侵作用.

       

    • 图  1  辉石中Mg#与各元素相关关系

      Fig.  1.  Correlations between major elements and Mg# of pyroxene

      图  2  单斜辉石(a)和斜方辉石(b)代表性IR光谱

      Fig.  2.  The representative infrared spectrum of Cpx (a) and Opx (b)

      图  3  包体中单斜辉石与斜方辉石结构水含量相关关系

      Fig.  3.  Correlations of the water content between Cpx and Opx

      表  1  包体中单斜辉石、斜方辉石的电子探针分析

      Table  1.   Electron microprobe of Cpx and Opx

      Cpx(%) Opx(%)
      FLN1 FLN2 FLN3 FLN4 FLN5 FLN1 FLN2 FLN3 FLN4 FLN5
      SiO2 50.50 50.58 50.34 50.47 50.36 53.34 54.04 53.96 53.78 53.69
      TiO2 0.39 0.36 0.61 0.45 0.38 0.03 0.03 0.12 0.06 0.05
      Al2O3 6.12 6.04 4.35 5.50 5.91 4.66 4.44 4.95 4.68 4.75
      FeO 2.98 3.03 2.75 2.92 2.82 6.64 6.84 6.79 6.76 6.82
      MnO 0.00 0.00 0.03 0.01 0.00 0.00 0.10 0.00 0.03 0.01
      MgO 15.08 15.90 17.21 16.06 16.31 33.41 33.87 33.84 33.70 34.02
      CaO 21.90 21.43 23.18 22.17 21.06 0.53 0.58 0.55 0.55 0.56
      Na2O 1.58 1.67 0.34 1.20 1.64 0.04 0.04 0.03 0.04 0.03
      Cr2O3 0.92 0.73 0.76 0.80 0.78 0.22 0.28 0.29 0.27 0.26
      Total 99.46 99.74 99.55 99.59 99.26 98.87 100.21 100.54 99.87 100.19
      Si 1.86 1.85 1.85 1.85 1.85 1.87 1.87 1.86 1.87 1.86
      Ti 0.01 0.01 0.02 0.01 0.01 0.00 0.00 0.00 0.00 0.00
      Al 0.27 0.26 0.19 0.24 0.26 0.19 0.18 0.20 0.19 0.19
      Fe 0.09 0.09 0.08 0.09 0.09 0.19 0.20 0.20 0.20 0.20
      Mn 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
      Mg 0.83 0.87 0.94 0.88 0.89 1.75 1.75 1.74 1.75 1.76
      Ca 0.86 0.84 0.91 0.87 0.83 0.02 0.02 0.02 0.02 0.02
      Na 0.11 0.12 0.02 0.09 0.12 0.00 0.00 0.00 0.00 0.00
      Cr 0.03 0.02 0.02 0.02 0.02 0.01 0.01 0.01 0.01 0.01
      Total 4.06 4.07 4.05 4.06 4.07 4.03 4.04 4.03 4.04 4.04
      Mg# 90.22 90.63 92.16 90.72 91.16 90.21 89.74 89.69 89.74 89.89
      下载: 导出CSV

      表  2  福建牛头山橄榄岩中辉石结构水含量

      Table  2.   Water content of pyroxene of peridotite xenoliths from Niutoushan, Fujian

      样品号 体积分数(%) 水含量(10-6)
      Cpx Opx Ol Cpx Opx WR
      FLN1 7 16 77 376 75 49
      FLN2 6 18 76 404 189 68
      FLN3 5 13 82 239 87 29
      FLN4 4 5 91 845 710 90
      FLN5 10 16 74 151 40 25
      下载: 导出CSV

      表  3  安徽女山、河北汉诺坝、苏北盆地、河北阳原和福建牛头山Cpx、Opx Al含量与Mg#值对比

      Table  3.   Comparison of Al and Mg# among Nüshan, Hannuoba, Subei basin, Yangyuan, Niutoushan

      地区 Cpx Opx
      Al2O3(%) Mg# Al2O3(%) Mg#
      安徽女山 6.12~8.07 87.40~90.90 3.10~6.19 88.10~91.40
      河北汉诺坝 2.65~6.44 90.45~92.39 2.72~4.15 89.26~91.40
      苏北盆地 2.11~7.94 89.06~93.72 1.77~6.33 89.77~92.34
      河北阳原 3.82~7.39 89.97~91.87 3.00~4.64 90.71~91.87
      福建牛头山 4.35~6.12 90.22~92.16 4.44~4.95 89.69~90.21
      下载: 导出CSV

      表  4  安徽女山、河北汉诺坝、苏北盆地、河北阳原和福建牛头山Cpx、Opx结构OH的特征吸收谱带

      Table  4.   Absorption bands of OH in Cpx and Opx at Nüshan, Hannuoba, Subei basin, Yangyuan, Niutoushan

      地区 IR光谱OH特征峰(cm-1)
      Cpx Opx
      安徽女山 3 620 520 440主特征峰3 620 3 580 510 410 310主特征峰3 580
      河北汉诺坝 3 620 540 460主特征峰3 620 3 580 510 410 290主特征峰3 580
      苏北盆地 3 620 520 440主特征峰3 620 3 580 510 410 310主特征峰3 580
      河北阳原 3 634\ 主特征峰3 634 3 589 523 421主特征峰3 589
      福建牛头山 3 633 600 514 461主特征峰3 633 3 580 518 408\ 3 302 200 053主特征峰3 580
      下载: 导出CSV
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    • 收稿日期:  2010-11-22
    • 刊出日期:  2011-07-01

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