海南抱伦金矿含金石英脉流体包裹体特征及其意义

王朝文; 洪汉烈; 钟增球; 张小文; 王婧; 李方林; 徐亚军

doi:10.3799/dqkx.2011.107

海南抱伦金矿含金石英脉流体包裹体特征及其意义

doi: 10.3799/dqkx.2011.107

王朝文¹,
洪汉烈^1, ,,
钟增球¹,
张小文^{1, 2},
王婧¹,
李方林¹,
徐亚军¹

1.
中国地质大学地球科学学院, 湖北武汉 430074
2.
海南大维矿产资源开发有限公司, 海南海口 570206

基金项目:

国家自然科学基金项目 40872038

国家自然科学基金项目 41072030

详细信息

作者简介:
王朝文(1986-), 男, 博士, 岩石学、矿物学、矿床学专业

通讯作者:
洪汉烈, E-mail: honghl8311@yahoo.com.cn

中图分类号: P61;P57
计量
- 文章访问数: 396
- HTML全文浏览量: 595
- PDF下载量: 15
- 被引次数: 0
出版历程
- 收稿日期: 2011-06-11
- 网络出版日期: 2021-11-10
- 刊出日期: 2011-06-15

The Characteristics of Fluid Inclusions in Gold-Bearing Quartze and Their Source Indicator of Baolun Gold Deposit, Hainan

1.
Faulty of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
Dawei Company of Mine Resources Development in Hainan, Haikou 570206, China

摘要

摘要: 为了了解抱伦金矿的成因条件, 利用岩相学和拉曼光谱分析方法对不同期次含金石英脉中流体包裹体进行系统、深入的研究.结果表明, 石英中流体包裹体可分为2种类型, 即CO₂-H₂O包裹体和H₂O溶液包裹体.CO₂-H₂O包裹体以CO₂为主, 含有CH₄, 主要存在于成矿期金-石英脉和金-多金属硫化物脉中, 多为原生包裹体, 孤立分布或成群分布, 气液比变化大, 显示不混溶流体包裹体组合特征.H₂O溶液包裹体, 主要存在于石英-碳酸盐脉中.显微测温结果显示, 成矿期Ⅰ和成矿期Ⅱ包裹体的均一温度范围分别为248~376℃和213~320℃, 成矿后流体包裹体的均一温度为140~244℃.成矿流体主要为CO₂-H₂O-NaCl热液体系, 在成矿期Ⅰ和成矿期Ⅱ主要为中、低盐度(0.80%~16.05%NaCl equiv), 并且富含挥发分(密度0.21~0.85g/cm³); 在成矿期后, 温度、盐度和CO₂含量都相对降低; 成矿晚期, 方解石碳、氧同位素δ¹³C(PBD, ‰)和δ¹⁸O(PBD, ‰)分别在-6.86~-13.14和-10.64~-14.51之间, 均指示流体主要以深源岩浆为特征, 流体在运移过程中发生了水岩反应、蚀变, 同时受到围岩有机质的混染.这种水岩反应以及由温度和压力降低所导致的不混溶作用可能是金矿金沉淀的主要因素.
- 金 /
- 流体包裹体 /
- 拉曼 /
- 石英脉 /
- 金矿床
Abstract: To better understand the formation of Baolun gold deposit and provide information for further exploration, fluid inclusions of quartz in gold-bearing quartz veins were investigated using Raman method. Our results showed that there were mainly two types of inclusion, i. e., CO₂-H₂O and H₂O, respectively. The former contained mainly CO₂, with minor CH₄, formed in the mineralization stage of gold-bearing quartz veins and gold multi-metal sulfide veins. These inclusions occurred in isolation or group with varied volume, and were the primary inclusion, exhibiting the characteristics of immiscible fluid inclusion. The later occurred mainly in quantz-calcite veins, containing pure H₂O. The results of micro-thermometric measurement showed that the homogenization temperatures of mineralization periods Ⅰ and Ⅱ were 248-376℃ and 213-320℃, respectively. The homogenization temperature of the post-mineralization period fluid inclusion was 140-244℃. Ore-forming fluid was the CO₂-H₂O-NaCl hydrothermal system, mineralization periods Ⅰ and Ⅱ were dominantly mid-low salinities (0.8%-16.05% NaCl equiv) and rich in volatile component (density 0.21-0.85g/cm³). Temperature, salinity, and CO₂ concentration all decreased in the late mineralization period. The calcite δ¹³C(PBD, ‰) and δ¹⁸O(PBD, ‰) values of the late stage veins were -6.86 to -13.14 and -10.64 to -14.51, respectively, indicating a magma origin in combination with fluid-rock reactions and organic mixing from the country rocks during the migration and transportation processes. Immiscibility due to water/rock reactions and decrease in fluid temperature and pressure was probably responsible for the gold deposition.
- gold /
- fluid inclusions /
- Raman /
- quartz vein /
- gold deposit

HTML全文

图 1 海南尖峰岭岩体(a)及抱伦金矿矿区(b)地质简图(据丁式江等，2001；谢才富等，2006修改)

1.中元古代花岗岩；2.晚二叠世二长花岗岩；3.尖峰岭单元；4.黑岭单元；5.金鸡岭单元；6.瘦岭单元；7.辉长辉绿岩；8.晚燕山石英闪长岩；9.晚燕山花岗岩；10.抱伦金矿；11.岩脉；12.断层；13.抱板群戈枕村组；14.抱板群峨文岭组；15.奥陶系南碧沟组；16.志留系陀烈组；17.石炭-二叠；18.白垩系；19.第四系；20.破碎构造带；21.热液石英脉和含金石英脉；F₁.九所-陵水断裂；F₂.王五-文教断裂

Fig. 1. Regional geological sketch map of Jianfengling batholith (a) and Baolun gold deposit (b), Hainan

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图 2 抱伦金矿流体包裹体照片(标尺30μm)

a.乳白色石英脉，Ia型三相包裹体与Ic型包裹体共存，Ia型三相包裹体小群状分布，近负晶形，15μm×7μm，为原生-假次生；b.乳白色石英脉，Ia型两相包裹体与Ic型包裹体共存，Ia型两相包裹体孤立分布，负晶形，10μm×8μm，为原生-假次生；c.烟灰色石英脉，Ib型三相包裹体与Ic型包裹体共存，Ib型三相包裹体，气液比变化较大，5μm~14μm；d.烟灰色石英脉，Ic型包裹体呈群状分布，气相CO₂所占总体积比例＜30%；e.烟灰色石英脉，晚期石英充填在早期石英间隙中，为水溶液包裹体，8μm×4μm，原生；f.烟灰色石英脉，晚期充填石英中包裹体呈线状分布

Fig. 2. Micrographs of fluid inclusions of the Baolun gold deposit

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图 3 抱伦金矿各类型流体包裹体拉曼光谱

Fig. 3. Laser Raman spectra of the typical CO₂-H₂O and H₂O fluid inclusions of the Baolun gold deposit

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图 4 抱伦金矿不同成矿阶段流体包裹体均一温度直方图

Fig. 4. Histogram showing the total homogenization temperature of CO₂-H₂O and H₂O fluid inclusions of the Baolun gold deposit

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图 5 抱伦金矿不同成矿阶段流体包裹体盐度-均一温度图解(据Wilkinson, 2001)

Fig. 5. Salinity-temperature diagram of mineralization stages of the Baolun gold deposit

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图 6 各阶段富水流体包裹体密度-均一温度图解

Fig. 6. Density-temperature diagram of mineralization stages of the Baolun gold deposit

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图 7 抱伦金矿成矿期CO₂-H₂O±CH₄部分完全均一温度对CO₂摩尔分数关系图(底图据Bower and Helgeson, 1983)

T_h(l).均一至液相；T_h(g).均一至气相；T_decr.爆裂温度

Fig. 7. Total homogenization temperature (T_h) versus calculated equivalent mole fraction CO₂ of CO₂-H₂O±CH₄ inclusion in Baolun gold deposit

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表 1 抱伦金矿流体包裹体显微测温结果

Table 1. Microthermometric results of fluid inclusions in Baolun gold deposit

成矿阶段	包裹体类型	T_{m, CO₂}(℃)	T_{m, ice}(℃)	T_{h, CO₂}(℃)	T_{m, clath}(℃)	T_{h, TOT}(℃)	均一方式	盐度(% equiv)	流体密度(g/cm^-3)
金-石英脉(成矿期Ⅰ)	Ⅰa型包裹体	-57.1~-58.5		22.7~30.0	7.4~9.6	300~358	T_h(g)	0.82~5.41	0.21~0.34
	Ⅰa型包裹体	-57.3~-58.9		18.1~29.0	6.4~8.3	298~330	T_h(l)	2.81~6.81	0.61~0.71
	Ⅰc型包裹体		-0.9~-10.6			248~376	T_h(l)	1.57~14.57	0.52~0.79
金-多金属硫化物(成矿期Ⅱ)	Ⅰb型包裹体	-66.2~-68.4		24.2~31.2	7.9~8.7	268~320	T_h(l)	2.62~4.14	0.29-0.71
金-多金属硫化物(成矿期Ⅱ)	Ic型包裹体		-2.3~-12.1			213~311	T_h(l)	2.9~16.05	0.64~0.85
石英-碳酸盐(成矿后)	Ⅱ型包裹体		-1.0~-9.6			140~244	T_h(l)	0.7~13.51	0.76~0.94
注：T_{m, CO₂}.固相CO₂熔化温度；T_{m, ice}.冰点温度；T_{h, CO₂}.CO₂部分均一温度；T_{m, clath}.笼形水合物熔化温度；T_{h, TOT}.完全均一温度；T_h(g).均一至气相；T_h(l).均一至液相.

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表 2 抱伦金矿方解石碳、氧同位素

Table 2. Calcite δ¹³C and δ¹⁸O of the Baolun gold deposit

样号	δ¹³C(PBD，‰)	δ¹⁸O(PBD，‰)	δ¹⁸O(SMOW，‰)
248-2	-8.24	-14.51	15.96
248-6	-13.14	-10.64	19.95
248-DW-1	-11.06	-13.66	16.83
248-DW-2	-9.87	-13.59	16.91
BL-D-7	-6.86	-13.13	17.38

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