四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义

张海强; 周炼; 王瑾; 苏洁; 曹菱; 戴梦宁

doi:10.3799/dqkx.2011.111

四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义

doi: 10.3799/dqkx.2011.111

张海强^1,,
周炼¹,
王瑾¹,
苏洁¹,
曹菱²,
戴梦宁³

1.
中国地质大学地质过程与矿产资源国家重点实验室, 湖北武汉 430074
2.
中国地质大学材料科学与化学工程学院, 湖北武汉 430074
3.
西北大学大陆动力学国家重点实验室, 陕西西安 710069

基金项目:

国家自然科学基金项目 40673020

国家自然科学基金项目 90714010

国家自然科学基金项目 40821061

国家自然科学基金项目 40839903

教育部创新团队项目 IRT0441

教育部"111"创新引智计划 B07039

详细信息

作者简介:
张海强(1985-), 男, 硕士研究生, 主要从事同位素地球化学研究.E-mail: lianzhou@cug.edu.cn

中图分类号: P736.4
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出版历程
- 收稿日期: 2011-01-10
- 网络出版日期: 2021-11-10
- 刊出日期: 2011-06-15

Molybdenum Isotopic Compositions and Significance of Bitumen at Different Geological Periods in Shangsi Section, Guangyuan, Sichuan

1.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China
2.
School of Materials Science and Chemical Engineering, China University of Geosciences, Wuhan 430074, China
3.
State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, China

摘要

摘要: 对四川广元地区寒武纪、二叠纪和石炭纪部分海相碳酸盐岩地层中沥青的Mo同位素和微量元素进行了测定.结果表明, 该区不同时期沥青的δ⁹⁸Mo有较大的变化范围(+0.34‰~+1.71‰), 总体上, 接近缺氧沉积岩δ⁹⁸Mo的范围.寒武纪海相地层中沥青具有明显的δEu正异常(0.75~1.68), 其Mo、Ni、V等氧化还原敏感元素含量相对较高, 且具有明显偏重的δ⁹⁸Mo(1.17‰~1.71‰), 特别是下寒武统筇竹寺组的一个样品(Hs-qzs)出现明显的δEu正异常(1.68), 可能与同期强烈的海底热液活动有关.热液喷发过程中产生的大量硫化氢, 导致偏重δ⁹⁸Mo以及Mo、Ni、V等元素的富集.虽然该区不同时期的海相碳酸盐岩中沥青的TM_V与TM_Ni没有明显的相关性, 但是不同时期(寒武纪、二叠纪和石炭纪)沥青的δ⁹⁸Mo与V/Ni比值的分布区域存在一定的差异, 有可能与来源不同有关, 暗示δ⁹⁸Mo有可能仍然保存着部分源岩的性质, 特别是下寒武统筇竹寺组(Hs-qzs)的TM_V与TM_Ni相对偏高, 可能与海底热液作用及后期相对较强的降解作用有关.
- Mo同位素 /
- 沥青 /
- 海相碳酸盐岩 /
- 地球化学
Abstract: In this research, new Molybdenum isotopic compositions of the bitumen, in the Gaungyuan section, Sichuan, as well as trace elements are determined. The results show that it has a large variation of δ⁹⁸Mo (+0.34‰~+1.71‰) in this region, reaching the range of anoxic sediments δ⁹⁸Mo in general. The slightly positive δEu anomaly has been shown in the Cambrian interval (0.75-1.68), specially, with a sample from Qiongzhusi Formation (Hs-qzs) with a significant positive δEu anomaly (1.68), corresponding to the enrichment of redox-sensitive trace elements (such as Mo, Ni, V), with the positive δ⁹⁸Mo (1.17‰-1.71‰). These characteristics might be related to local intense hydrothermal erupting, corresponding to the large quantity of H₂S and HS^- into the contemporaneous seawater. Introduction of these sulfide gases would cause MoO₄^2- to be transferred into MoS₄^2-, favoring the preferential deposition of the heavy Mo isotope as MoS₄^2- and thus leaving a positive Mo isotope value. Although no much good correlation between TM_V and TM_Ni has been shown in this area, the distinct fields from difference interval of bitumen is observed by the plot of δ⁹⁸Mo against V/Ni ratios, it implies the possible stability of δ⁹⁸Mo by local mobilization during diagenesis/early catagenesis.
- Molybdenum isotope /
- bitumen /
- marine sediment /
- geochemistry

HTML全文

图 1 四川广元上寺剖面地质示意(据Isozaki et al., 2007修改)

Fig. 1. Geological map of Guangyuan Shangsi section, Sichuan

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图 2 四川广元上寺剖面部分沥青样品的赋存特征

Fig. 2. Characteristics of the deposit occurrence of bitumen in Guangyuan Shangsi section, Sichuan

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图 3 广元地区海相碳酸盐岩中沥青EF_Mo与EF_V关系(a)和EF_V与EF_Ni关系(b)

Fig. 3. EF_Mo and EF_V (a) and EF_V与EF_Ni (b) plot of bitumen in marine carbonate rocks in Guangyuan area

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图 4 广元地区海相碳酸盐岩中沥青δ⁹⁸Mo与V/Ni比值关系

Fig. 4. δ⁹⁸Mo and V/Ni plot of bitumen in marine carbonate rocks in Guangyuan area

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图 5 广元地区海相碳酸盐岩中沥青的稀土元素分配曲线

a.寒武纪沥青；b.二叠纪和石炭纪沥青

Fig. 5. REE patterns of bitumen in marine carbonate rocks in Guangyuan

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图 6 广元地区海相碳酸盐岩中沥青δ⁹⁸Mo与TOC关系

Fig. 6. δ⁹⁸Mo and TOC plot of bitumen in marine carbonate rocks in Guangyuan

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表 1 四川广元地区不同时期海相碳酸盐岩中沥青的δ⁹⁸Mo、TOC和微量元素数据

Table 1. The δ⁹⁸Mo, TOC and trace element data of the bitumen from marine carbonate rock in Guangyuan section

样品编号	Pgy-wjp-100	Gy-qx-c	Pgy-mo-43	Pgy-qx-22	Pgy-17	Pgy-mo-3	C2-fs-5	Hs-clp	Hs-cl	Hs-qzs
时代	二叠纪	二叠纪	二叠纪	二叠纪	二叠纪	二叠纪	石炭纪	寒武纪	寒武纪	寒武纪
样品描述	黑色泥质层	方解石脉与沥青共生	干沥青较多，选干沥青	黑色灰岩夹干沥青	泥质灰岩夹干沥青	干沥青	藻纹层沥青层共生	中粗粉砂岩夹沥青	粉砂岩中夹干沥青	沥青带，较厚
V(μg/g)	759.7	698.0	918.8	140.6	319.0	274.3	57.27	83.81	438.0	132.6
Co(μg/g)	42.72	3.64	20.65	2.23	3.08	5.06	6.20	0.85	14.98	1.90
Ni(μg/g)	616.0	143.7	168.49	40.71	74.51	40.19	58.02	51.56	132.3	293.9
Cu(μg/g)	185.8	51.42	68.19	17.55	10.52	39.68	36.91	7.22	3408	7.47
Zn(μg/g)	727.3	86.18	104.1	92.20	64.21	50.52	18.34	13.20	77.12	20.20
Ga(μg/g)	23.88	14.18	25.46	2.37	3.88	3.53	10.01	1.42	5.37	0.78
Zr(μg/g)	352.6	147.0	227.9	23.08	34.65	29.28	114.3	18.09	82.92	6.25
Mo(μg/g)	121.7	79.56	68.46	16.67	120.9	7.15	3.89	3.38	77.84	21.32
La(μg/g)	34.06	11.13	22.92	2.57	5.20	6.33	9.47	2.84	11.11	1.30
Ce(μg/g)	63.45	17.91	34.59	4.23	9.45	9.24	13.94	5.25	17.02	2.21
Pr(μg/g)	9.10	2.07	3.86	0.51	1.16	1.32	1.49	0.68	2.26	0.28
Nd(μg/g)	40.17	7.15	12.97	1.93	4.30	5.02	4.77	2.82	8.87	1.06
Sm(μg/g)	9.46	1.26	2.13	0.44	0.90	1.16	0.81	0.77	1.79	0.23
Eu(μg/g)	2.14	0.20	0.36	0.10	0.14	0.25	0.15	0.21	0.50	0.13
Gd(μg/g)	9.71	1.02	1.71	0.52	0.78	1.34	0.74	0.99	1.89	0.22
Tb(μg/g)	1.33	0.17	0.29	0.09	0.13	0.22	0.13	0.18	0.30	0.03
Dy(μg/g)	7.03	1.18	1.75	0.61	0.78	1.23	0.83	1.10	1.83	0.18
Ho(μg/g)	1.40	0.27	0.43	0.15	0.16	0.27	0.21	0.24	0.41	0.04
Er(μg/g)	3.97	0.92	1.40	0.42	0.46	0.76	0.72	0.64	1.24	0.12
Tm(μg/g)	0.60	0.16	0.26	0.07	0.08	0.12	0.13	0.09	0.20	0.02
Yb(μg/g)	3.46	1.13	1.86	0.48	0.51	0.70	0.94	0.50	1.22	0.12
Lu(μg/g)	0.49	0.18	0.29	0.07	0.07	0.11	0.14	0.07	0.19	0.02
La/Sm	2.33	5.72	6.94	3.80	3.72	3.53	7.56	2.38	4.01	3.57
Gd/Yb	2.32	0.74	0.76	0.91	1.26	1.58	0.65	1.65	1.29	1.52
La/Yb	7.06	7.06	8.85	3.87	7.32	6.46	7.19	4.11	6.56	7.67
∑L/∑H	2.37	2.81	3.37	1.54	2.71	1.99	2.77	1.37	2.24	2.89
∑REE	750.8	169.4	313.5	52.49	91.97	117.9	131.3	73.52	199.4	24.33
δCe(‰)	0.87	0.85	0.82	0.85	0.90	0.74	0.82	0.90	0.79	0.86
δEu(‰)	0.68	0.51	0.56	0.63	0.51	0.62	0.57	0.75	0.83	1.68
V/Ni	1.23	4.86	5.45	3.45	4.28	6.83	0.99	1.63	3.31	0.45
δ⁹⁸Mo(‰)	0.58	1.02	1.5	1.1	0.59	0.34	1.5	1.17	1.24	1.71
TOC(%)	25.34	13.60	11.40	1.91	2.47	5.04	9.08	75.59	57.97	65.64
EF_V	3.02	6.65	5.64	8.53	12.89	13.11	0.70	6.49	7.39	29.69
EF_Ni	6.67	3.73	2.82	6.73	8.21	5.24	1.94	10.88	6.09	179.4
EF_Cu	2.21	1.47	1.26	3.19	1.27	5.69	1.36	1.68	172.6	5.02
EF_Zn	5.10	1.45	1.13	9.87	4.58	4.26	0.40	1.80	2.30	7.98
EF_U	8.50	39.70	5.93	46.83	16.72	27.98	2.84	1.24	5.61	4.22
EF_Mo	72.47	113.66	63.08	151.65	733.04	51.29	7.15	39.27	197.1	716.20
EF_Co	1.11	0.23	0.83	0.88	0.81	1.58	0.50	0.43	1.65	2.77
注：δCe=2(Ce_样品/Ce_球粒陨石)/(La_样品/La_球粒陨石+Nd_样品/Nd_球粒陨石)；δEu=2(Eu_样品/Eu_球粒陨石)/(Sm_样品/Sm_球粒陨石+Tb_样品/Tb_球粒陨石)；EF为元素富集因子，TM为微量元素的浓度.EF=TM/Zr^=TM/Zr_sample: TM/Zr_{average shale}，即利用锆扣除陆源碎屑影响(Wilde et al*., 2004).平均页岩数据据Wedepohl(1971, 1991).

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