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    四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义

    张海强 周炼 王瑾 苏洁 曹菱 戴梦宁

    张海强, 周炼, 王瑾, 苏洁, 曹菱, 戴梦宁, 2011. 四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义. 地球科学, 36(6): 1053-1063. doi: 10.3799/dqkx.2011.111
    引用本文: 张海强, 周炼, 王瑾, 苏洁, 曹菱, 戴梦宁, 2011. 四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义. 地球科学, 36(6): 1053-1063. doi: 10.3799/dqkx.2011.111
    ZHANG Hai-qiang, ZHOU Lian, WANG Jin, SU Jie, CAO Ling, DAI Meng-ning, 2011. Molybdenum Isotopic Compositions and Significance of Bitumen at Different Geological Periods in Shangsi Section, Guangyuan, Sichuan. Earth Science, 36(6): 1053-1063. doi: 10.3799/dqkx.2011.111
    Citation: ZHANG Hai-qiang, ZHOU Lian, WANG Jin, SU Jie, CAO Ling, DAI Meng-ning, 2011. Molybdenum Isotopic Compositions and Significance of Bitumen at Different Geological Periods in Shangsi Section, Guangyuan, Sichuan. Earth Science, 36(6): 1053-1063. doi: 10.3799/dqkx.2011.111

    四川广元上寺剖面不同地史时期沥青的钼同位素组成及意义

    doi: 10.3799/dqkx.2011.111
    基金项目: 

    国家自然科学基金项目 40673020

    国家自然科学基金项目 90714010

    国家自然科学基金项目 40821061

    国家自然科学基金项目 40839903

    教育部创新团队项目 IRT0441

    教育部"111"创新引智计划 B07039

    详细信息
      作者简介:

      张海强(1985-), 男, 硕士研究生, 主要从事同位素地球化学研究.E-mail: lianzhou@cug.edu.cn

    • 中图分类号: P736.4

    Molybdenum Isotopic Compositions and Significance of Bitumen at Different Geological Periods in Shangsi Section, Guangyuan, Sichuan

    • 摘要: 对四川广元地区寒武纪、二叠纪和石炭纪部分海相碳酸盐岩地层中沥青的Mo同位素和微量元素进行了测定.结果表明, 该区不同时期沥青的δ98Mo有较大的变化范围(+0.34‰~+1.71‰), 总体上, 接近缺氧沉积岩δ98Mo的范围.寒武纪海相地层中沥青具有明显的δEu正异常(0.75~1.68), 其Mo、Ni、V等氧化还原敏感元素含量相对较高, 且具有明显偏重的δ98Mo(1.17‰~1.71‰), 特别是下寒武统筇竹寺组的一个样品(Hs-qzs)出现明显的δEu正异常(1.68), 可能与同期强烈的海底热液活动有关.热液喷发过程中产生的大量硫化氢, 导致偏重δ98Mo以及Mo、Ni、V等元素的富集.虽然该区不同时期的海相碳酸盐岩中沥青的TMVTMNi没有明显的相关性, 但是不同时期(寒武纪、二叠纪和石炭纪)沥青的δ98Mo与V/Ni比值的分布区域存在一定的差异, 有可能与来源不同有关, 暗示δ98Mo有可能仍然保存着部分源岩的性质, 特别是下寒武统筇竹寺组(Hs-qzs)的TMVTMNi相对偏高, 可能与海底热液作用及后期相对较强的降解作用有关.

       

    • 图  1  四川广元上寺剖面地质示意(据Isozaki et al., 2007修改)

      Fig.  1.  Geological map of Guangyuan Shangsi section, Sichuan

      图  2  四川广元上寺剖面部分沥青样品的赋存特征

      Fig.  2.  Characteristics of the deposit occurrence of bitumen in Guangyuan Shangsi section, Sichuan

      图  3  广元地区海相碳酸盐岩中沥青EFMoEFV关系(a)和EFVEFNi关系(b)

      Fig.  3.  EFMo and EFV (a) and EFVEFNi (b) plot of bitumen in marine carbonate rocks in Guangyuan area

      图  4  广元地区海相碳酸盐岩中沥青δ98Mo与V/Ni比值关系

      Fig.  4.  δ98Mo and V/Ni plot of bitumen in marine carbonate rocks in Guangyuan area

      图  5  广元地区海相碳酸盐岩中沥青的稀土元素分配曲线

      a.寒武纪沥青;b.二叠纪和石炭纪沥青

      Fig.  5.  REE patterns of bitumen in marine carbonate rocks in Guangyuan

      图  6  广元地区海相碳酸盐岩中沥青δ98Mo与TOC关系

      Fig.  6.  δ98Mo and TOC plot of bitumen in marine carbonate rocks in Guangyuan

      表  1  四川广元地区不同时期海相碳酸盐岩中沥青的δ98Mo、TOC和微量元素数据

      Table  1.   The δ98Mo, TOC and trace element data of the bitumen from marine carbonate rock in Guangyuan section

      样品编号 Pgy-wjp-100 Gy-qx-c Pgy-mo-43 Pgy-qx-22 Pgy-17 Pgy-mo-3 C2-fs-5 Hs-clp Hs-cl Hs-qzs
      时代 二叠纪 二叠纪 二叠纪 二叠纪 二叠纪 二叠纪 石炭纪 寒武纪 寒武纪 寒武纪
      样品描述 黑色泥质层 方解石脉与沥青共生 干沥青较多,选干沥青 黑色灰岩夹干沥青 泥质灰岩夹干沥青 干沥青 藻纹层沥青层共生 中粗粉砂岩夹沥青 粉砂岩中夹干沥青 沥青带,较厚
      V(μg/g) 759.7 698.0 918.8 140.6 319.0 274.3 57.27 83.81 438.0 132.6
      Co(μg/g) 42.72 3.64 20.65 2.23 3.08 5.06 6.20 0.85 14.98 1.90
      Ni(μg/g) 616.0 143.7 168.49 40.71 74.51 40.19 58.02 51.56 132.3 293.9
      Cu(μg/g) 185.8 51.42 68.19 17.55 10.52 39.68 36.91 7.22 3408 7.47
      Zn(μg/g) 727.3 86.18 104.1 92.20 64.21 50.52 18.34 13.20 77.12 20.20
      Ga(μg/g) 23.88 14.18 25.46 2.37 3.88 3.53 10.01 1.42 5.37 0.78
      Zr(μg/g) 352.6 147.0 227.9 23.08 34.65 29.28 114.3 18.09 82.92 6.25
      Mo(μg/g) 121.7 79.56 68.46 16.67 120.9 7.15 3.89 3.38 77.84 21.32
      La(μg/g) 34.06 11.13 22.92 2.57 5.20 6.33 9.47 2.84 11.11 1.30
      Ce(μg/g) 63.45 17.91 34.59 4.23 9.45 9.24 13.94 5.25 17.02 2.21
      Pr(μg/g) 9.10 2.07 3.86 0.51 1.16 1.32 1.49 0.68 2.26 0.28
      Nd(μg/g) 40.17 7.15 12.97 1.93 4.30 5.02 4.77 2.82 8.87 1.06
      Sm(μg/g) 9.46 1.26 2.13 0.44 0.90 1.16 0.81 0.77 1.79 0.23
      Eu(μg/g) 2.14 0.20 0.36 0.10 0.14 0.25 0.15 0.21 0.50 0.13
      Gd(μg/g) 9.71 1.02 1.71 0.52 0.78 1.34 0.74 0.99 1.89 0.22
      Tb(μg/g) 1.33 0.17 0.29 0.09 0.13 0.22 0.13 0.18 0.30 0.03
      Dy(μg/g) 7.03 1.18 1.75 0.61 0.78 1.23 0.83 1.10 1.83 0.18
      Ho(μg/g) 1.40 0.27 0.43 0.15 0.16 0.27 0.21 0.24 0.41 0.04
      Er(μg/g) 3.97 0.92 1.40 0.42 0.46 0.76 0.72 0.64 1.24 0.12
      Tm(μg/g) 0.60 0.16 0.26 0.07 0.08 0.12 0.13 0.09 0.20 0.02
      Yb(μg/g) 3.46 1.13 1.86 0.48 0.51 0.70 0.94 0.50 1.22 0.12
      Lu(μg/g) 0.49 0.18 0.29 0.07 0.07 0.11 0.14 0.07 0.19 0.02
      La/Sm 2.33 5.72 6.94 3.80 3.72 3.53 7.56 2.38 4.01 3.57
      Gd/Yb 2.32 0.74 0.76 0.91 1.26 1.58 0.65 1.65 1.29 1.52
      La/Yb 7.06 7.06 8.85 3.87 7.32 6.46 7.19 4.11 6.56 7.67
      ∑L/∑H 2.37 2.81 3.37 1.54 2.71 1.99 2.77 1.37 2.24 2.89
      ∑REE 750.8 169.4 313.5 52.49 91.97 117.9 131.3 73.52 199.4 24.33
      δCe(‰) 0.87 0.85 0.82 0.85 0.90 0.74 0.82 0.90 0.79 0.86
      δEu(‰) 0.68 0.51 0.56 0.63 0.51 0.62 0.57 0.75 0.83 1.68
      V/Ni 1.23 4.86 5.45 3.45 4.28 6.83 0.99 1.63 3.31 0.45
      δ98Mo(‰) 0.58 1.02 1.5 1.1 0.59 0.34 1.5 1.17 1.24 1.71
      TOC(%) 25.34 13.60 11.40 1.91 2.47 5.04 9.08 75.59 57.97 65.64
      EFV 3.02 6.65 5.64 8.53 12.89 13.11 0.70 6.49 7.39 29.69
      EFNi 6.67 3.73 2.82 6.73 8.21 5.24 1.94 10.88 6.09 179.4
      EFCu 2.21 1.47 1.26 3.19 1.27 5.69 1.36 1.68 172.6 5.02
      EFZn 5.10 1.45 1.13 9.87 4.58 4.26 0.40 1.80 2.30 7.98
      EFU 8.50 39.70 5.93 46.83 16.72 27.98 2.84 1.24 5.61 4.22
      EFMo 72.47 113.66 63.08 151.65 733.04 51.29 7.15 39.27 197.1 716.20
      EFCo 1.11 0.23 0.83 0.88 0.81 1.58 0.50 0.43 1.65 2.77
      注:δCe=2(Ce样品/Ce球粒陨石)/(La样品/La球粒陨石+Nd样品/Nd球粒陨石);δEu=2(Eu样品/Eu球粒陨石)/(Sm样品/Sm球粒陨石+Tb样品/Tb球粒陨石);EF为元素富集因子,TM为微量元素的浓度.EF=TM/Zr*=TM/Zrsample: TM/Zraverage shale,即利用锆扣除陆源碎屑影响(Wilde et al., 2004).平均页岩数据据Wedepohl(1971, 1991).
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    • 收稿日期:  2011-01-10
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