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    我国3种绿色图章石中白云母的矿物学特征

    陈涛 韩文 李甜 皱倩

    陈涛, 韩文, 李甜, 皱倩, 2012. 我国3种绿色图章石中白云母的矿物学特征. 地球科学, 37(5): 981-988. doi: 10.3799/dqkx.2012.106
    引用本文: 陈涛, 韩文, 李甜, 皱倩, 2012. 我国3种绿色图章石中白云母的矿物学特征. 地球科学, 37(5): 981-988. doi: 10.3799/dqkx.2012.106
    CHEN Tao, HAN Wen, LI Tian, Zhou Qian, 2012. Mineralogy Characterization of Muscovite in Three Kinds of Green Sealed Stones from China. Earth Science, 37(5): 981-988. doi: 10.3799/dqkx.2012.106
    Citation: CHEN Tao, HAN Wen, LI Tian, Zhou Qian, 2012. Mineralogy Characterization of Muscovite in Three Kinds of Green Sealed Stones from China. Earth Science, 37(5): 981-988. doi: 10.3799/dqkx.2012.106

    我国3种绿色图章石中白云母的矿物学特征

    doi: 10.3799/dqkx.2012.106
    基金项目: 

    国家自然科学基金 41172050

    国家自然科学基金 40702007

    中国博士后面上基金 20100480925

    详细信息
      作者简介:

      陈涛(1979-), 女, 博士, 副教授, 主要从事矿物学研究工作.E-mail: summerjewelry@163.com

    • 中图分类号: P575

    Mineralogy Characterization of Muscovite in Three Kinds of Green Sealed Stones from China

    • 摘要: 对我国浙江青田山炮绿、福建寿山月尾绿以及西安绿3种绿色图章石分别利用X射线衍射、电子探针、环境扫描电镜以及能谱分析对其矿物成分、化学成分、微形貌特征以及颜色成因等方面进行了研究.研究发现, 3种图章石的绿色部分均由具二八面体结构的2M1型多硅白云母组成, 属于云母型图章石; 它们的次要矿物组成中山炮绿含有白云石、黄铁矿和磷灰石, 月尾绿含有高岭石, 西安绿含有白云石, 次要矿物组成对绿色图章石的产地鉴定具有一定意义.3种白云母的微形貌特征揭示了西安绿中白云母结晶程度高于月尾绿中白云母, 而山炮绿中白云母经历热液蚀变后晶形不完整重结晶程度不高.另外, 白云母八面体层中杂质离子的化学成分分析表明, 月尾绿和西安绿中白云母的绿色是由Fe3+和Ti4+离子形成, 而山炮绿的翠绿颜色主要由白云母中Cr3+离子以及Fe3+、Ti4+离子共同作用形成.

       

    • 图  1  3种绿色图章石的X射线粉晶衍射

      Fig.  1.  X-ray powder diffraction pattern of three different green sealed stones

      图  2  3种图章石中白云母的形貌像

      a.山炮绿中白云母,b.月尾绿中白云母,c.西安绿中白云母

      Fig.  2.  Morphology of muscovites in three different green sealed stones

      表  1  3种绿色图章石的主要粉晶衍射数据

      Table  1.   The main data of X-ray powder diffraction of three different green sealed stones

      SPL YWL XAL
      2θ(°) d(Å) I/I0 Min hkl 2θ(°) d(Å) I/I0 Min hkl 2θ(°) d(Å) I/I0 Min hkl
      8.8917 9.9372 93 M 002 8.896 7 9.931 2 100 M 002 8.925 1 9.900 1 99 M 002
      17.798 8 4.979 3 38 M 004 12.443 8 7.107 2 14 K 001 17.882 4 4.956 2 52 M 004
      19.971 3 4.442 3 18 M 111 17.789 3 4.981 8 25 M 004 19.904 4 4.457 1 12 M 111
      20.756 7 4.275 9 8 M 111 19.927 5 4.451 8 12 M 111 20.673 2 4.293 0 5 M 111
      21.692 6 4.093 5 7 M 022 22.995 0 3.864 4 4 M 113 21.659 1 4.099 8 5 M 022
      22.996 0 3.864 4 16 M 113 23.884 2 3.722 5 5 M 023 22.962 6 3.869 9 10 M 113
      23.898 4 3.720 5 19 M 023 24.963 3 3.564 0 8 K 002 23.865 0 3.725 6 12 M 023
      25.569 6 3.481 0 19 M 114 25.562 8 3.481 7 5 M 114 25.586 3 3.478 7 17 M 114
      26.806 2 3.323 1 71 M 006 26.811 8 3.322 3 60 M 006 26.939 9 3.306 9 100 M 006
      27.925 9 3.192 4 20 M 114 27.900 9 3.195 0 7 M 114 27.942 6 3.190 5 21 M 114
      29.931 2 2.982 9 22 M 025 29.249 8 3.050 7 6 M 025 29.964 6 2.979 6 25 M 025
      30.984 0 2.883 9 100 D 104 29.919 2 2.984 0 5 M 025 31.351 7 2.850 9 17 M 115
      31.318 2 2.853 9 18 M 115 31.308 0 2.854 7 7 M 115 32.187 2 2.778 8 14 M 116
      32.087 0 2.787 2 14 M 116 35.084 9 2.555 5 10 M 131 34.576 9 2.592 0 7 M 131
      33.089 6 2.705 0 16 P 200 35.944 2 2.496 4 6 M 008 35.011 4 2.560 8 17 M 131
      34.710 6 2.582 3 10 M 131 36.633 6 2.451 0 3 M 008 36.164 5 2.481 8 8 M 008
      35.145 1 2.551 4 21 M 131 37.852 6 2.374 8 2 M 133 37.785 5 2.379 0 4 M 133
      35.980 7 2.494 0 21 D 110 40.250 6 2.238 7 3 M 220 42.464 7 2.127 0 7 M 135
      37.117 1 2.420 2 10 P 210 42.518 7 2.124 4 3 M 135 45.639 8 1.986 40 M 10(10)
      41.177 9 2.190 5 15 D/M 113/042 45.356 3 1.997 8 16 M 00(10) 53.042 9 1.725 1 3 M 139
      42.514 8 2.124 6 11 M 135 55.847 6 1.644 8 3 M 139 55.415 9 1.656 7 6 M 20(10)
      45.422 6 1.995 1 10 M/D 136/10(10) 61.912 5 1.497 5 5 M 060 55.933 9 1.642 6 10 M 139
      50.552 9 1.804 0 16 D 018 60.930 6 1.519 3 5 M 245
      51.104 4 1.785 9 14 D 116 1.716 0 1.501 8 5 M 060
      55.850 4 1.644 8 10 M 139
      56.318 3 1.632 3 14 P 311
      60.813 6 1.521 9 7 M 245
      61.966 7 1.496 3 10 M 060
      Min.矿物成分;M.白云母;D.白云石;P.黄铁矿;K.高岭石.
      下载: 导出CSV

      表  2  3种绿色图章石中白云母的晶胞参数数据

      Table  2.   Lattice parameters of muscovites in three different green sealed stones

      晶系 a(Å) b(Å) c(Å) β(°) V3)
      SPL 单斜 晶胞参数 5.169 4 8.988 4 20.053 9 96°2′ 926.634 8
      SPL 单斜 标准差 0.001 8 0.004 5 0.006 1 2′ 0.432 0
      YWL 单斜 晶胞参数 5.180 9 8.956 6 20.074 5 96°1′ 926.398 9
      YWL 单斜 标准差 0.003 9 0.010 6 0.013 1 4′ 0.980 9
      XAL 单斜 晶胞参数 5.182 2 9.028 2 19.975 3 95°46′ 929.849 0
      XAL 单斜 标准差 0.002 2 0.004 1 0.003 9 1′ 0.427 4
      下载: 导出CSV

      表  3  3种绿色图章石中主要矿物的化学成分(%)

      Table  3.   Chemical data of main minerals in three different green sealed stones

      Element SPL-1 SPL-2 SPL-3 SPL-4 YWL-1 YWL-2 YWL-3 XAL-1 XAL-2 XAL-4
      Na2O 0.287 0.282 0.068 - 0.071 0.121 0.108 0.098 0.131 -
      K2O 10.506 10.123 - - 9.352 9.718 10.115 10.906 10.923 -
      Cr2O3 0.067 0.027 - - - - - - - -
      MgO 0.324 0.247 0.046 17.943 0.093 0.067 0.086 4.916 5.392 22.047
      CaO 0.108 - 56.208 29.418 0.134 0.081 0.030 0.055 0.055 29.634
      MnO - - 0.130 0.116 - - - - 0.006 0.006
      Al2O3 36.734 34.607 0.007 0.065 33.677 34.390 35.051 25.159 25.300 0.033
      TiO2 0.222 0.261 0.060 0.078 0.050 0.026 0.034 0.124 0.229 0.019
      Fe2O3 0.282 0.218 0.054 4.520 1.797 1.663 1.544 0.012 0.028 0.051
      SiO2 48.207 46.506 0.077 0.048 50.508 48.739 47.825 52.520 52.551 0.017
      P2O5 - - 42.123 - - - - - - -
      Total 96.737 92.271 98.773 52.188 95.682 94.805 94.793 93.790 94.615 51.807
      Minerals 白云母 白云母 磷灰石 白云石 白云母 白云母 白云母 白云母 白云母 白云石
      下载: 导出CSV

      表  4  3种绿色图章石中白云母的化学分子式

      Table  4.   Chemical formula of muscovites in three different green sealed stones

      SPL-1 SPL-2 YWL-1 YWL-2 YWL-3 XAL-1 XAL-2
      Si 3.126 3.159 3.288 3.216 3.167 3.519 3.495
      [Ⅵ]Al 0.874 0.841 0.712 0.784 0.833 0.481 0.505
      [Ⅵ]Al 1.932 1.929 1.872 1.891 1.902 1.506 1.478
      Cr3+ 0.003 0.001 0.000 0.000 0.000 0.000 0.000
      Fe3+ 0.014 0.011 0.088 0.083 0.077 0.001 0.001
      Mg 0.031 0.025 0.009 0.007 0.008 0.491 0.535
      Ti 0.011 0.013 0.002 0.001 0.002 0.006 0.011
      Mn 0.000 0.000 0.000 0.000 0.000 0.000 0.000
      K 0.868 0.877 0.776 0.818 0.854 0.932 0.926
      Na 0.036 0.037 0.009 0.015 0.014 0.013 0.017
      Ca 0.008 0.000 0.009 0.006 0.002 0.004 0.004
      Cht 0.874 0.841 0.712 0.784 0.833 0.481 0.505
      Cho 0.045 0.072 0.092 0.061 0.039 0.472 0.446
      Chi 0.919 0.914 0.804 0.845 0.872 0.952 0.951
      vac(o) 1.008 1.020 1.028 1.019 1.011 0.996 0.974
      [Ⅵ]R2+/([Ⅵ]R2++[Ⅵ]R3+) 0.016 0.013 0.005 0.003 0.004 0.246 0.266
      [Ⅵ]Al/([Ⅵ]Al+[Ⅵ]Fe3+) 0.993 0.994 0.955 0.958 0.961 1.000 0.999
      Cht.四面体层总电荷;Cho.八面体层总电荷;Chi.层间总电荷;vac(o).八面体空位;[Ⅵ]R2+[Ⅵ]R3+分别表示八面体中二价阳离子和三价阳离子数.
      下载: 导出CSV

      表  5  3种绿色图章石中矿物的化学成分(%)

      Table  5.   Chemical data of minerals in three different green sealed stones

      O Na Mg Al Si Ca Fe K
      Fig 4a-SPL 51.01 0.89 0.98 18.97 21.21 - - 6.95
      Fig 4b-YWL 46.85 - - 19.18 24.31 - 1.45 8.21
      Fig 4c-XAL 42.45 - 4.66 12.96 30.41 - - 8.99
      下载: 导出CSV
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    • 收稿日期:  2012-01-16
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