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    吉林省兰家金矿南泉眼闪长岩U-Pb年代学和地球化学特征

    闻爽 李碧乐 李立宝 王斌

    闻爽, 李碧乐, 李立宝, 王斌, 2013. 吉林省兰家金矿南泉眼闪长岩U-Pb年代学和地球化学特征. 地球科学, 38(2): 305-316. doi: 10.3799/dqkx.2013.030
    引用本文: 闻爽, 李碧乐, 李立宝, 王斌, 2013. 吉林省兰家金矿南泉眼闪长岩U-Pb年代学和地球化学特征. 地球科学, 38(2): 305-316. doi: 10.3799/dqkx.2013.030
    WEN Shuang, LI Bi-le, LI Li-bao, WANG Bin, 2013. Zircon U-Pb Age and Geochemistry of Nanquanyan Diorite in the Lanjia Gold Deposit, Jilin Province. Earth Science, 38(2): 305-316. doi: 10.3799/dqkx.2013.030
    Citation: WEN Shuang, LI Bi-le, LI Li-bao, WANG Bin, 2013. Zircon U-Pb Age and Geochemistry of Nanquanyan Diorite in the Lanjia Gold Deposit, Jilin Province. Earth Science, 38(2): 305-316. doi: 10.3799/dqkx.2013.030

    吉林省兰家金矿南泉眼闪长岩U-Pb年代学和地球化学特征

    doi: 10.3799/dqkx.2013.030
    基金项目: 

    吉林省科技发展计划重点项目 20100445

    国家自然科学基金项目 41272093

    详细信息
      作者简介:

      闻爽(1988-),女,硕士研究生,主要从事热液矿床预测方面研究.E-mail: wenshuang10@mails.jlu.edu.cn

      通讯作者:

      李碧乐,E-mail: lbl66@sina.com

    • 中图分类号: P597

    Zircon U-Pb Age and Geochemistry of Nanquanyan Diorite in the Lanjia Gold Deposit, Jilin Province

    • 摘要: 南泉眼闪长岩是兰家矽卡岩型金矿的成矿岩体,研究程度极低.通过岩石地球化学和LA-ICP-MS U-Pb年代学研究,讨论了岩石成因、来源和构造背景.研究表明,南泉眼闪长岩为准铝质的钙碱性岩石;岩石明显富集大离子亲石元素(如Rb、K、Sr)、活泼的不相容元素(如Th、U)和轻稀土元素,相对亏损高场强元素(如Nb、Ta、Ti、P)和重稀土元素,具有明显的负Eu异常,Nb/Ta、La/Nb、Th/La比值显示岩石具壳源特征,Al2O3+MgO+FeOt图解显示岩浆具弧型活动大陆边缘特征.闪长岩岩浆锆石LA-ICP-MS U-Pb加权平均年龄为170.21±0.73 Ma(MSWD=0.14);谐和年龄值为170.21±0.39 Ma(MSWD=0.018),为中侏罗世.成岩构造背景为燕山早期太平洋板块俯冲引起大陆弧伸展和岩石圈减薄,软流圈物质上涌、底侵提供热动力,不成熟下地壳物质部分熔融形成南泉眼闪长岩.

       

    • 图  1  东北地区区域地质简图(据Li and Shen, 2012)

      Fig.  1.  Geological sketch map of Northeast China

      图  2  兰家金矿矿区地质简图

      1.第四系;2.二叠系范家屯组;3.早燕山闪长岩;4.隐爆角砾岩;5.金矿体;6.断层;7.向斜;8.倒转背斜

      Fig.  2.  Geological sketchmap of the Lanjia gold deposit

      图  3  兰家金矿南泉眼闪长岩锆石CL图像(圆圈数字代表U-Pb分析点)

      Fig.  3.  CL images of zircons from Nanquanyan diorite in the Lanjia gold deposit

      图  4  南泉眼闪长岩锆石加权平均年龄与U-Pb年龄谐和图

      Fig.  4.  Zircon U-Pb concordia diagram and weighted average ages from Nanquanyan diorite in the Lanjia gold deposit

      图  5  兰家金矿南泉眼闪长岩的A/CNK-A/NK(a)和K2O-SiO2(b)图解

      Fig.  5.  A/CNK-A/NK (a) and K2O-SiO2 (b) diagram of Nanquanyan diorite in the Lanjia gold deposit

      图  6  兰家金矿南泉眼闪长岩的Harker图解

      Fig.  6.  Harker diagram of Nanquanyan diorite in the Lanjia gold deposit

      图  7  兰家金矿南泉眼闪长岩的稀土元素球粒陨石标准化配分曲线图(a) (球粒陨石标准化值引自Boynton, 1984)和原始地幔标准化蛛网图(b) (原始地幔值引自Sun and McDonough, 1989)

      Fig.  7.  Chondrite-normalized REE patterns (a) and primitive mantle-normalized trace element spider diagams (b) of Nanquanyan diorite in the Lanjia gold deposit

      图  8  兰家金矿南泉眼闪长岩的Al2O3-MgO-FeOt图解

      Fig.  8.  Al2O3-MgO-FeOt diagram of Nanquanyan diorite in the Lanjia gold deposit

      表  1  兰家金矿南泉眼闪长岩锆石LA-ICP-MS U-Pb定年结果

      Table  1.   LA-ICP-MS zircon U-Pb data of Nanquanyan diorite in the Lanjia gold deposit

      点号 238U(10-6) 232Th(10-6) 207Pb/206Pb 207Pb/235U 206Pb/238U 206Pb/238U
      比值 误差 比值 误差 比值 误差 年龄(Ma) 误差
      LJ-N1-01 919.18 651.81 0.049 87 0.001 70 0.183 90 0.006 44 0.026 67 0.000 24 169.7 1.5
      LJ-N1-02 983.69 924.68 0.049 38 0.001 32 0.182 60 0.004 98 0.026 72 0.000 19 170.0 1.2
      LJ-N1-03 783.07 645.88 0.049 40 0.002 40 0.182 95 0.008 93 0.026 80 0.000 36 170.5 2.2
      LJ-N1-04 523.12 294.37 0.049 52 0.004 36 0.179 88 0.015 39 0.026 51 0.000 61 168.7 3.8
      LJ-N1-07 868.49 613.83 0.049 53 0.003 87 0.182 57 0.014 11 0.026 68 0.000 40 169.7 2.5
      LJ-N1-08 1 262.49 1 321.77 0.049 37 0.002 05 0.183 10 0.007 44 0.026 86 0.000 29 170.8 1.8
      LJ-N1-10 1 020.14 765.69 0.050 09 0.003 14 0.183 18 0.011 01 0.026 68 0.000 43 169.7 2.7
      LJ-N1-11 556.23 428.77 0.049 71 0.001 66 0.182 50 0.006 02 0.026 73 0.000 27 170.1 1.7
      LJ-N1-12 1 075.90 884.23 0.049 27 0.002 80 0.183 45 0.011 65 0.026 82 0.000 40 170.6 2.5
      LJ-N1-13 1 291.93 1 372.54 0.049 48 0.001 30 0.182 76 0.004 88 0.026 74 0.000 23 170.1 1.4
      LJ-N1-14 766.38 396.49 0.049 48 0.001 52 0.182 59 0.005 84 0.026 75 0.000 30 170.2 1.9
      LJ-N1-15 1 400.61 1 512.29 0.049 37 0.001 69 0.182 54 0.006 40 0.026 74 0.000 23 170.1 1.5
      LJ-N1-18 953.91 438.58 0.049 80 0.003 01 0.183 61 0.009 94 0.026 85 0.000 41 170.8 2.6
      LJ-N1-21 1 045.74 971.17 0.049 37 0.001 86 0.184 25 0.007 16 0.026 99 0.000 27 171.7 1.7
      LJ-N1-22 658.53 412.11 0.049 06 0.001 61 0.182 32 0.006 00 0.027 00 0.000 31 171.8 1.9
      LJ-N1-23 1 469.43 1 475.00 0.049 82 0.003 35 0.181 74 0.009 53 0.026 63 0.000 61 169.4 3.9
      LJ-N1-24 747.25 340.75 0.049 34 0.003 61 0.182 12 0.013 11 0.026 83 0.000 55 170.7 3.5
      LJ-N1-26 974.65 743.62 0.049 59 0.001 35 0.182 32 0.004 95 0.026 73 0.000 24 170.0 1.5
      LJ-N1-27 752.28 411.95 0.049 86 0.001 47 0.182 96 0.005 61 0.026 63 0.000 28 169.4 1.7
      LJ-N1-28 947.15 616.39 0.049 69 0.001 31 0.182 86 0.004 82 0.026 79 0.000 24 170.4 1.5
      LJ-N1-29 1 177.17 963.36 0.048 91 0.002 40 0.181 26 0.008 99 0.026 92 0.000 77 171.2 4.8
      LJ-N1-30 790.35 611.81 0.050 15 0.002 52 0.182 70 0.008 16 0.026 66 0.000 35 169.6 2.2
          测试单位:西北大学大陆动力学国家重点实验室,2011;1σ为误差;普通Pb用测量的204Pb校正.
      下载: 导出CSV

      表  2  兰家金矿南泉眼闪长岩主量元素(%)和微量元素含量(10-6)

      Table  2.   Contents of major elements (%) and trace elements (10-6) of acid intrusive rocks of Nanquanyan diorite in the Lanjia gold deposit

      样品 LJ-1 LJ-2 LJ-3 LJ-4 LJ-5 LJ-6 LJ-7 LJ-8 LJ-9 LJ-10 LJ-11 LJ-12 LJ-13
      SiO2 59.26 56.29 59.22 59.24 57.37 58.17 61.55 54.04 59.48 57.60 58.28 58.03 56.69
      Al2O3 14.86 14.52 14.81 14.45 15.59 13.97 15.38 15.30 14.81 15.09 15.20 13.86 13.89
      FeOt 7.45 7.19 7.21 7.79 8.18 6.67 5.09 7.46 6.94 8.13 7.44 8.96 7.76
      CaO 5.84 9.99 6.61 6.49 6.77 8.81 7.51 11.01 5.79 7.04 6.32 5.86 9.67
      MgO 3.44 4.09 3.52 3.86 3.92 3.71 2.57 3.44 3.17 4.01 3.65 4.21 3.47
      Na2O 3.10 1.97 3.06 2.95 3.02 3.01 3.25 2.62 3.14 3.14 3.14 2.74 2.13
      K2O 2.13 0.58 1.46 1.54 1.88 1.17 1.23 0.89 2.09 1.09 1.74 1.52 0.57
      TiO2 1.10 1.15 1.06 1.14 1.14 1.11 0.88 1.09 1.03 1.10 0.96 1.27 1.12
      MnO 0.21 0.29 0.21 0.22 0.16 0.29 0.22 0.29 0.21 0.20 0.15 0.26 0.37
      P2O5 0.260 0.295 0.296 0.314 0.291 0.266 0.222 0.274 0.250 0.297 0.277 0.315 0.241
      SrO 0.05 0.07 0.05 0.05 0.05 0.05 0.05 0.06 0.05 0.05 0.05 0.04 0.06
      BaO 0.04 0.00 0.05 0.04 0.03 0.05 0.05 0.02 0.04 0.02 0.03 0.03 0.00
      LOI 1.34 3.29 1.50 1.47 1.30 2.40 1.59 2.27 1.30 2.12 1.40 1.47 2.54
      Total 99.08 99.72 99.04 99.54 99.70 99.66 99.58 98.76 98.29 99.88 98.63 98.56 98.50
      Ba 518 108 519 469 389 553 596 324 503 289 408 399 136
      Ce 46.0 46.6 50.1 51.1 46.0 42.0 39.9 45.4 48.1 50.0 48.4 54.4 53.0
      Cr 50 50 40 40 40 40 30 40 40 40 40 40 30
      Cs 8.41 14.55 6.69 6.64 4.10 9.54 9.86 6.51 9.55 5.06 5.38 6.85 19.05
      Dy 4.71 4.08 5.11 5.08 4.71 4.32 4.11 5.18 4.79 5.45 4.46 4.78 4.72
      Er 2.66 2.29 2.82 2.90 2.61 2.44 2.41 2.75 2.79 3.01 2.49 2.71 2.58
      Eu 1.10 1.19 1.06 1.07 1.26 1.07 1.09 1.32 1.05 1.24 1.25 1.11 1.13
      Ga 18.5 15.9 17.6 17.7 19.7 16.0 16.7 18.9 17.6 18.9 19.4 16.6 15.5
      Gd 5.18 4.64 5.55 5.70 5.47 4.74 4.43 6.17 5.38 6.14 5.07 5.13 4.86
      Hf 4.9 5.5 5.1 5.3 4.7 4.5 4.2 4.5 4.9 4.7 4.7 5.4 5.0
      Ho 0.99 0.85 1.04 1.06 0.97 0.89 0.85 1.05 1.02 1.11 0.91 0.95 0.93
      La 22.6 22.4 24.1 24.3 21.9 18.4 19.0 21.0 23.4 23.1 23.9 25.9 25.8
      Lu 0.40 0.36 0.43 0.44 0.37 0.37 0.36 0.36 0.42 0.42 0.37 0.42 0.41
      Nb 8.0 8.4 8.0 8.8 7.9 8.0 7.2 7.3 7.2 7.8 6.9 8.8 8.0
      Nd 23.6 23.3 25.8 26.6 24.7 22.5 20.2 26.4 24.3 27.8 24.5 27.0 25.7
      Pr 5.77 5.75 6.34 6.42 5.82 5.49 5.00 6.02 5.96 6.55 5.98 6.77 6.47
      Rb 76.3 34.5 48.5 55.6 68.9 39.7 42.0 24.8 70.1 32.7 60.1 56.3 28.0
      Sm 5.13 4.86 5.58 5.73 5.37 4.84 4.40 6.04 5.35 6.12 5.08 5.71 5.50
      Sn 2 2 1 1 2 1 1 1 1 1 1 1 2
      Sr 400 654 390 382 432 450 474 529 403 418 427 379 582
      Ta 0.7 0.7 0.6 0.7 1.1 0.7 0.6 0.6 0.7 0.6 0.5 0.8 0.7
      Tb 0.81 0.72 0.86 0.88 0.82 0.74 0.70 0.91 0.82 0.92 0.77 0.78 0.76
      Th 11.30 13.50 11.40 12.65 7.88 12.30 11.05 9.26 11.80 10.40 11.90 12.50 11.95
      Tm 0.38 0.34 0.41 0.42 0.37 0.36 0.35 0.39 0.40 0.42 0.36 0.40 0.39
      U 2.89 3.66 3.31 3.52 4.09 4.20 4.50 2.74 3.54 3.38 2.98 3.61 4.48
      V 226 251 223 250 251 233 157 223 214 254 223 189 153
      W 2 3 2 2 1 3 3 3 2 2 1 2 3
      Y 26.0 23.6 28.3 29.0 26.5 24.4 24.3 28.9 27.9 30.8 25.4 30.5 29.6
      Yb 2.54 2.27 2.66 2.81 2.46 2.39 2.35 2.39 2.72 2.73 2.41 2.68 2.50
      Zr 167 188 171 184 167 139 129 138 163 139 150 190 168
      ANK 2.01 3.75 2.24 2.21 2.22 2.25 2.30 2.90 1.99 2.38 2.15 2.25 3.37
      ACNK 0.82 0.66 0.79 0.79 0.81 0.63 0.76 0.60 0.82 0.79 0.82 0.82 0.64
      (La/Yb)N 6.38 7.08 6.50 6.20 6.39 5.52 5.80 6.30 6.17 6.07 7.11 6.93 7.40
      Zr/Y 6.42 7.97 6.04 6.34 6.30 5.70 5.31 4.78 5.84 4.51 5.91 6.23 5.68
      La/Nb 2.8 2.7 3.0 2.8 2.8 2.3 2.6 2.9 3.3 3.0 3.5 2.9 3.2
      Nb/Ta 11.4 12.0 13.3 12.6 7.2 11.4 12.0 12.2 10.3 13.0 13.8 11.0 11.4
      Th/Nb 0.48 0.58 0.44 0.48 0.32 0.55 0.55 0.35 0.49 0.37 0.49 0.46 0.46
      Th/La 0.50 0.60 0.47 0.52 0.36 0.67 0.58 0.44 0.50 0.45 0.50 0.48 0.46
      下载: 导出CSV
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