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    不同成因类型煤型气地球化学特征及其判识意义

    鲍园 韦重韬 王超勇

    鲍园, 韦重韬, 王超勇, 2013. 不同成因类型煤型气地球化学特征及其判识意义. 地球科学, 38(5): 1037-1046. doi: 10.3799/dqkx.2013.101
    引用本文: 鲍园, 韦重韬, 王超勇, 2013. 不同成因类型煤型气地球化学特征及其判识意义. 地球科学, 38(5): 1037-1046. doi: 10.3799/dqkx.2013.101
    BAO Yuan, WEI Chong-tao, WANG Chao-yong, 2013. Geochemical Characteristics and Identification Significance of Coal Type Gas in Various Geneses. Earth Science, 38(5): 1037-1046. doi: 10.3799/dqkx.2013.101
    Citation: BAO Yuan, WEI Chong-tao, WANG Chao-yong, 2013. Geochemical Characteristics and Identification Significance of Coal Type Gas in Various Geneses. Earth Science, 38(5): 1037-1046. doi: 10.3799/dqkx.2013.101

    不同成因类型煤型气地球化学特征及其判识意义

    doi: 10.3799/dqkx.2013.101
    基金项目: 

    国家自然科学基金重点项目 41030422

    国家科技重大专项 2011ZX05060-005

    详细信息
      作者简介:

      鲍园(1983-), 男, 博士后, 主要从事煤层气地质与成藏研究.E-mail: baoyuan8384@163.com

    • 中图分类号: P597

    Geochemical Characteristics and Identification Significance of Coal Type Gas in Various Geneses

    • 摘要: 通过数理统计前人公开发表的国内外21个盆地或地区的324组煤型气地化数据, 分析不同成因类型煤型气地层分布和稳定碳、氢同位素组成及空间分布特征, 提出多个煤型气成因类型判识图版, 并以实例论证这些图版的可行性.研究结果表明: 与煤层相关的生物成因气不同于常规生物气, 最显著区别在于前者δ13C(CH4)上限值低, 即生物成因气δ13C(CH4)<-60‰, 热成因气δ13C(CH4)>-40‰, 混合成因气δ13C(CH4)介于二者之间.随着有机质演化程度增强, 从生物成因气至热成因气, δ13C(CH4)、δ13C(CO2-CH4)、δ13C(C2H6-CH4)及CH4/(C2H6+C3H8)具有变重趋势且相关性明显, δ13C(CH4)与δ13C(CO2-CH4)、δ13C(CH4)与δ13C(C2H6-CH4)及δ13C(CH4)与CH4/(C2H6+C3H8)是划分煤型气成因类型最可靠的图版.

       

    • 图  1  δ13C(CH4)与δD(CH4)关系(据Whiticar,1996)

      A为陆相沉积环境;B为海相沉积环境

      Fig.  1.  Carbon and hydrogen isotopic compositions of methane

      图  2  δ13C(CH4)与δ13C(CO2)关系

      a.δ13C(CH4)与δ13C(CO2)关系;b.δ13C(CH4)与δ13C(CO2-CH4)关系

      Fig.  2.  The relationship of δ13C(CH4) versus δ13C(CO2) in coal type gases

      图  3  δ13C(CH4)与δ13C(C2H6)关系

      a.δ13C(CH4)与δ13C(C2H6)关系;b.δ13C(CH4)与δ13C(C2H6-CH4)关系

      Fig.  3.  The relationships of δ13C(CH4) versus δ13C(C2H6) in coal type gases

      图  4  δ13C(CH4)与δ13C(C3H8)关系

      Fig.  4.  The relationships of δ13C(CH4) versus δ13C(C3H8) in coal type gases

      图  5  δ13C(CH4)与CH4/(C2H6+C3H8)关系

      Fig.  5.  The relationships of δ13C(CH4) versus CH4/(C2H6+C3H8) in coal type gases

      表  1  国内、外不同盆地煤型气地层分布与碳、氢同位素组成数据

      Table  1.   The date of stratigraphic distribution and carbon and hydrogen isotopic compositions of coal type gas from different basins all over the world

      盆地或地区 储层 δ13C(CH4) δ13C(C2H6) δ13C(C3H8) δD(CH4) δ13C(CO2) C1/C2+3 类型 数据来源
      柴达木 E-Q -73.6~-62.9/-66.6(69) -50.6~-22.0/-43.9(43) -35.4~-23.3/-32.5(38) -268.0~-210.0/-230.6(44) -21.5~-3.2/-12.1(14) 235.9~2 499.0/1 054.3(47) 生物成因气 戴金星等,1996张晓宝等,2003赵东升等,2006贾星亮等,2008刘文汇等,2009张英等,2009沈平等,2010
      陆良 N2 -73.3~-71.8/-72.5(8) -66.0~-61.2/-63.0(4) / -242.0~-234.0/-236.2(4) / 1 600.8~3 274.0/1 936.5(7) 生物成因气 王大悦和罗槐章,2000徐永昌等,2005沈平等,2010
      保山 E2-N2 -63.6~-59.0/-62.6(21) -53.0~-46.1/-49.1(10) / -267.0~-252.0/-258.5(11) -12.5~-9.3/-11.1(8) 375.2~9 910.0/1 748.7(14) 生物成因气 刘树根等,1998徐永昌等,2005沈平等,2010;党红艳等,2010
      百色 E2-N2 -69.7~-64.9/-67.8(7) -64.5~-45.2/-54.8(7) -50.1~-35.5/-42.2(5) / / 293.1~9 814.0/2 094.9(6) 生物成因气 罗毅等,2003
      T2-E2 -61.1~-58.4/-59.2(4) -38.5~-36.1/-37.3(2) -33.4(1) -237.9(1) / 2.3~28.1/11.2(4) 混合成因气 戴金星等,1996罗毅等,2003
      渤海湾 Es1 -57.5(1) / / / / 202.7 生物成因气 王振升等,2010
      Es1-Em -59.3~-55.6/-57.2(5) -48.5~-31.2/-41.2(3) / / / 68.5~2 422.3/853.9(3) 混合成因气 王振升等,2010
      C-Ed2 -37.6~-28/-34.4(28) -33.7~-13.9/-26.9(28) -32.9~-12.8/-24.8(28) / / 3.9~80.7/17.4(13) 热成因气 赵青芳,2005徐耀辉等,2005
      鄂尔多斯 O1m-J -37.9~-23.7/-31.2(41) -26.6~-7.7/-22.5(37) -26.3~-19.4/-23.8(23) -380.0~-117.0/-267.7(23) -24.5~-21.8/-23.0(23) 2.4~1 166.6/98.3(23) 热成因气 陈安定,2002贺建桥,2004帅燕华等,2005
      塔里木 O-N1 -38.5~-22.6/-31.7(75) -37.7~-18.0/-24.5(60) -34.6~-13.2/-23.1(56) -191.0~-127.0/-166.4(37) -23.3~-5.4/-18.8(35) 3.7~119.5/28.9(64) 热成因气 刘全有,2001刘文汇等,2003刘全有等,2007
      敦化 Q -34.5~-26.9/-30.8(5) -28.9~-18.8/-25.4(4) -28.7~-24.2/-27.0(3) -228.0~-144.0/-188.2(5) -17.9~-15.4/-16.7(5) / 热成因气 段毅等,2011
      淮南 C3-P1 -59.4~-51.1/-56(9) -23.7~-18.8/-20.7(9) -25.3~-7.7/-19.5(6) -243.0~-219.0/-231.0(2) -32.0~-12.6/-21.5(7) 359.3~394.4/376.8(2) 混合成因气 陶明信等,2005;张弘等,2005
      恩洪 P2 -54.5~-47.9/-51.3(4) / / -206.0~-196.0/-201.0(2) / 117.9~128.1/123.0(3) 混合成因气 陶明信等,2005
      霍州 P1 -61.7(1) -21.5(1) / -229.5(1) / 5 240.6(1) 生物成因气 陶明信等,2005
      P1 -36.3(1) / / / / 1.2(1) 热成因气 张小军等,2009
      海拉尔 -73.2(1) / / / / 557.7(1) 生物成因气 张小军等,2009
      苏北 E1 -53.3(1) -36.5(1) / / / 48.0(1) 混合成因气 郑绍贵等,2000
      莺歌海 Q -63.3(1) / / -152.0(1) / / 生物成因气 沈平等,2010
      启东 Q -70.5(1) / / -158.0(1) / / 生物成因气 沈平等,2010
      沁水 -31.2(1) / / / / 14 137.1(1) 热成因气 张小军等,2009
      靖远 -43.4(1) / / / / 360.9(1) 热成因气 张小军等,2009
      悉尼和鲍恩 P -38.8~-34.4/-36.7(3) / / / -21.9~-19.3/-20.9(3) 15.1~16.9/15.8(3) 热成因气 Smith and Palasser, 1996
      上西里西亚 C3 -74.0~-61.6/-69.5(12) / / -184.0~-157.0/-169.6(11) -27.2~-13.1/-16.9(4) 449.3~9 840.0/5 405.3(6) 生物成因气 Kotarba, 2001
      C3 -54.2~-44.5/-49.1(8) -22.3(1) / -202.0~-153.0/-183.9(8) -17.1~-2.8/-10(8) 130.6~5 405.3/1 444.9(9) 混合成因气 Kotarba, 2001
      卢布林 C3 -67.3(1) / / -201.0(1) -11.9(1) / 生物成因气 Kotarba, 2001
      C3 -52.5(1) / / / -13.7(1) / 混合成因气 Kotarba, 2001
      宗古尔达克 C3 -51.1~-48.3/-49.7(13) -37.9~-25.2/-29.2(12) -26.3~-19.2/-21.7(9) -190.1~-177.7/-183.2(13) -29.4~-13.2/-18.6(10) 76.0~752.0/251.2(13) 混合成因气 Hakan et al., 2002
        注:表中数据为最小值~最大值/平均值(测试数据组数).
      下载: 导出CSV
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    • 收稿日期:  2012-08-22
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