徐淮早白垩世埃达克质岩中含橄榄石单斜辉石岩的成因及其岩石学意义

周群君; 许文良; 王清海; 杨德彬; 裴福萍; 于洋

doi:10.3799/dqkx.2014.014

徐淮早白垩世埃达克质岩中含橄榄石单斜辉石岩的成因及其岩石学意义

doi: 10.3799/dqkx.2014.014

1.
吉林大学地球科学学院, 吉林长春 130061
2.
吉林大学东北亚国际地学研究与教学中心, 吉林长春 130026

基金项目:

科技部"973"项目 2009CB825005

国家自然科学基金项目 90814003

详细信息

作者简介:
周群君(1986-), 女, 博士研究生, 从事矿物学、岩石学、矿床学研究

通讯作者:
许文良, E-mail: xuwl@jlu.edu.cn

中图分类号: P581
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出版历程
- 收稿日期: 2013-04-28
- 刊出日期: 2014-02-01

Petrogenesis of Olivine-Bearing Clinopyroxenite Xenolith in Early Cretaceous Adakitic Rocks from Xuhuai Area in Eastern China and Its Petrologic Implication

1.
College of Earth Sciences, Jilin University, Changchun 130061, China
2.
International Centre for Geoscience Research and Education in Northeast Asia, Jilin University, Changchun 130026, China

摘要

摘要: 报道了徐淮地区早白垩世埃达克质岩中首次发现的含橄榄石单斜辉石岩捕虏体的岩相学与矿物化学资料, 该类捕虏体显示堆积结构、块状构造, 主要由单斜辉石(~80%)、斜方辉石(~5%)、橄榄石(~5%)和普通角闪石(~10%)组成.橄榄石外侧发育有斜方辉石反应边, 角闪石沿辉石粒间分布, 呈嵌晶结构.矿物化学分析结果表明: 橄榄石的镁橄榄石分子值(Fo)=77.7~79.3, Ni=623×10^-6~773×10^-6; 斜方辉石的Mg^#=75.6~80.2, Cr=161×10^-6~684×10^-6, Ni=79×10^-6~708×10^-6; 单斜辉石的Mg^#=84.5~86.4, CaO=21.59%~23.13%, Al₂O₃=1.72%~2.44%.上述矿物与中、新生代玄武岩中橄榄石、斜方辉石和单斜辉石斑晶以及堆积成因辉石岩中的斜方辉石和单斜辉石成分类似.此外, 单斜辉石的稀土配分型式以相对富含中稀土元素的上凸型为特征, 稀土元素含量较低(∑REE=10.14×10^-6~12.71×10^-6), 无明显的铕异常(δEu=0.90~1.16), 类似于新生代玄武岩中单斜辉石斑晶.捕虏体中的普通角闪石的Mg^#=74.0~80.4、SiO₂=43.2%~44.5%、Na₂O=2.04%~2.29%, 稀土元素分馏不明显, 显示亏损高场强元素(HFSEs, 如Nb、Ta、Zr、Hf), 富集Sr、Rb、Ba的特征, 与新生代玄武岩中角闪石捕虏晶成分不同.结合其嵌晶结构, 普通角闪石应是寄主岩浆贯入结晶的产物.综合上述特征, 可以看出含橄榄石单斜辉石捕虏体为镁铁质岩浆高压堆晶成因.结合华北克拉通东部早白垩世双峰式火山岩组合的出现, 推断含橄榄石单斜辉石岩捕虏体可能是早白垩世基性岩浆底侵的产物.
- 早白垩世 /
- 埃达克质岩石 /
- 含橄榄石单斜辉石岩捕虏体 /
- 岩石成因 /
- 岩石学 /
- 徐淮地区
Abstract: The petrography and mineral chemical data of olivine-bearing clinopyroxenite xenolith entrained by the Early Cretaceous adakitic rocks in Xuhuai area, eastern China are reported in this paper. Olivine-bearing clinopyroxenite consists of clinopyroxene (~80%), orthopyroxene (~5%), olivine (~5%), and hornblende (~10%) and displays cumulate texture and massive structure. The orthopyroxene reaction rim can be found around olivine. The hornblendes occur among pyroxenes, and display poikilitic texture. The mineral chemical data indicate that olivines have forsterite (Fo)=77.7-79.3 and Ni=623×10^-6-773×10^-6, that orthopyroxenes have Mg^#=75.6-80.2, Cr=161×10^-6-684 ×10^-6, and Ni=79×10^-6-708×10^-6, and that clinopyroxenes have Mg^#=84.5-86.4, CaO=21.59%-23.13%, Al₂O₃=1.72%-2.44%. Chemically, these minerals are similar to the olivine, orthopyroxene, and clinopyroxene phenocrysts from the Mesozoic and Cenozoic basalts and those from the pyroxenites with cumulate origin. Additionally, the clinopyroxenes from the xenolith are characterized by convex upward rare earth element (REE) distribution patterns, low REE contents (∑REE=10.14×10^-6-12.71×10^-6), and no Eu anomalies (δEu=0.90-1.16), similar to the clinopyroxene phenocrysts in the Cenozoic basalts. Hornblendes in this xenolith have Mg^#=74.0-80.4, SiO₂=43.2%-44.5%, Na₂O=2.04%-2.29%, and display flat REE patterns and depletion in high field strength elements (HFSEs, Nb, Ta, Zr and Hf) and Th as well as enrichment in Sr, Rb and Ba, different from those hornblende xenocrysts from Cenozoic basalts. Combined with its poikilitic texture, it is suggested that these hornblendes could be formed by injection of the host magma. Taken together, we conclude that the olivine-bearing clinopyroxenite xenolith could be formed by the high-pressure accumulation of basaltic melt. Combined with Early Cretaceous bimodal magmatism in eastern China, it is suggested that the olivine-bearing clinopyroxenite could be generated by the underplating of mantle-derived basaltic magma.
- Early Cretaceous /
- adakitic rock /
- olivine-bearing clinopyroxenite xenolith /
- petrogenesis /
- petrology /
- Xuhuai area

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图 1 徐淮地区中生代侵入杂岩体分布(据Xu et al., 2006a)

Fig. 1. Distribution map of the Mesozoic intrusions in Xuhuai area

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图 2 含橄榄石单斜辉石捕虏体的岩相学

a.含橄榄石单斜辉石岩捕虏体堆积结构，块状构造(单偏光)；b.单斜辉石岩中的斜方辉石与普通角闪石(单偏光)；Cpx.单斜辉石；Hb.普通角闪石；Ol.橄榄石；Opx.斜方辉石

Fig. 2. Photomicrographs showing textures of olivine-bearing clinopyroxenite xenolith

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图 3 橄榄石的Fo值与Ni(a)、Mn(b)含量的变异图解

橄榄岩中橄榄石数据引自Xu et al.(2010)；含橄榄石的单斜辉石岩中橄榄石的成分引自Zhang et al.(2010)；含橄榄石的二辉石岩中橄榄石的数据引自Xu et al.(2013)；橄榄石斑晶数据王微(2008)

Fig. 3. Plots of Fo vs. Ni(a) and Mn(b) contents for olivines from olivine clinopyroxenite xenolith

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图 5 单斜辉石的球粒陨石标准化稀土元素型式(a)和原始地幔标准化微量元素蛛网图(b)

球粒陨石标准化数据引自Boynton(1984)；原始地幔标准化数据引自Sun and McDonough(1989)；二辉橄榄岩数据王微(2008)；含橄榄石的二辉石岩数据引自Xu et al.(2013)；单斜辉石斑晶数据路思明(2012a)

Fig. 5. Chondrite-normalized REE patterns (a) and primitive mantle-normalized trace element spider diagram (b) of clinopyroxenes from the olivine clinopyroxenite xenolith

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图 6 普通角闪石的球粒陨石标准化稀土元素型式(a)和原始地幔标准化微量元素蛛网图(b)

球粒陨石标准化数据引自Boynton(1984)；原始地幔标准化数据引自Sun and McDonough(1989)；普通角闪石捕掳晶数据未发表

Fig. 6. Chondrite-normalized REE patterns (a) and primitive mantle-normalized trace element spider diagram (b) of hornblendes from the olivine clinopyroxenite xenolith

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图 4 单斜辉石的Mg^#与TiO₂(a)、Al₂O₃(b)、Na₂O(c)、CaO(d)变异图解

橄榄岩数据王微(2008)，Xu et al.(2008)；单斜辉石斑晶数据引自Xu et al.(2003)，裴福萍等(2004)；路思明(2012a)；辉石岩(Ⅰ)数据王冬艳等(2004)；Zhang et al.(2010)；辉石岩(Ⅱ)数据引自Xu et al.(2013)；辉石岩(Ⅲ)数据引自Yu et al.(2010)

Fig. 4. Plots of Mg^# vs. TiO₂(a), Al₂O₃(b), CaO(c), and Na₂O (d) for clinopyroxenes from olivine-bearing clinopyroxenite xenolith

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图 7 与含橄榄石单斜辉石岩中单斜辉石平衡的熔体的球粒陨石标准化稀土元素形式

球粒陨石标准化数据引自Boynton(1984)；分配系数引自Lemarchand et al.(1987)；二长闪长斑岩数据来自王清海(2003)；玄武岩数据来自Zhang et al.(2002)和裴福萍等(2004)

Fig. 7. Chondrite-normalized REE patterns of melts in equilibrium with the clinopyroxenes in the olivine clinopyroxenite

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表 1 含橄榄石单斜辉石岩捕虏体中橄榄石的主量元素(%)和痕量元素(10^-6)分析结果

Table 1. Major (%) and trace element contents (10^-6) of olivines from olivine-bearing clinopyroxenite xenolith

样品编号	SiO₂	Cr₂O₃	FeO	MnO	MgO	CaO	NiO	Total	Fo	Sc	V	Cr	Co	Ni
JG12-1	37.9	0.04	20.1	0.32	41.3	0.02	0.03	99.6	78.6
JG12-2	38.2	0.00	20.1	0.30	40.9	0.15	0.05	99.8	78.5
JG12-4	38.8	0.06	20.9	0.24	40.6	0.08	0.09	100.8	77.7
JG12-5	37.9	0.00	20.0	0.28	41.8	0.03	0.09	100.2	78.8
JG12-6	37.3	0.05	19.4	0.30	41.3	0.09	0.12	98.6	79.2
JG12-8	38.1		19.8	0.30	41.0	0.02	0.03	99.2	78.7
JG12-9	37.7		20.1	0.27	40.7	0.01	0.13	99.0	78.3
JG12-10	38.0		19.4	0.29	41.6	0.02	0.17	99.5	79.3
JG12-11	37.9		19.8	0.31	41.4	0.01	0.08	99.5	78.9
JG12-1*	37.9		20.8	0.29	40.8	0.02			77.8	3.87	1.36	28.9	202	645
JG12-2*	37.2		20.8	0.29	41.5	0.07			78.1	3.94	2.61	36.9	213	694
JG12-3*	37.5		20.5	0.30	41.4	0.03			78.3	2.18	0.55	2.53	242	773
注：*为LA-ICP-MS分析，其他为电子探针分析.

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表 2 含橄榄石单斜辉石岩捕虏体中斜方辉石, 单斜辉石和角闪石的主量元素(%)分析结果

Table 2. Major (%) element contents of orthopyroxenes, clinopyroxenes and hornblendes from olivine-bearing clinopyroxenite xenolith

样品编号	SiO₂	TiO₂	Al₂O₃	Cr₂O₃	FeO	MnO	MgO	CaO	Na₂O	K₂O	NiO	Total	Mg^#	Cr	Ni	Wo	En	Fs
斜方辉石
JG12-1	53.4	0.11	2.37	0.03	12.9	0.25	28.4	0.97	0.040		0.09	98.6	79.8			1.91	77.9	20.2
JG12-2	53.9	0.07	2.36	0.10	13.5	0.32	28.9	0.57	0.010		0.00	99.6	79.3			1.11	78.0	20.9
JG12-3	54.1	0.13	2.50	0.07	12.8	0.25	29.0	0.94	0.000		0.05	99.7	80.2			1.83	78.4	19.7
JG12-4	53.8	0.14	2.54	0.05	13.1	0.30	29.2	0.97	0.050		0.05	100.1	79.9			1.86	78.1	20.1
JG12-5	54.4	0.15	2.28	0.04	13.7	0.31	29.0	0.95	0.060		0.04	100.9	79.1			1.82	77.2	21.0
JG12-6	54.3	0.08	2.28	0.05	13.7	0.31	28.7	0.82	0.090	0.01	0.01	100.3	78.9			1.59	77.2	21.2
JG12-1*	52.5	0.11	2.84		15.7	0.31	27.3	1.14	0.034	0.00		99.9	75.6	202	211	2.21	73.6	24.2
JG12-2*	53.4	0.08	1.54		15.3	0.31	28.2	1.08	0.031	0.00		99.9	76.8	161	194	2.06	74.7	23.2
JG12-3*	53.0	0.10	2.57		14.9	0.31	28.0	0.97	0.030	0.01		99.8	77.0	341	209	1.87	75.2	22.9
JG12-4*	53.5	0.09	2.28		14.0	0.30	28.8	0.93	0.025	0.00		99.9	78.7	304	202	1.78	76.8	21.4
JG12-5*	53.5	0.08	1.92		14.5	0.31	28.5	0.99	0.026	0.00		99.9	77.8	205	197	1.90	76.0	22.1
单斜辉石
JG12-1	52.4	0.19	2.25	0.68	4.84	0.17	16.5	21.6	0.41	0.02	0.00	99.0	85.9			44.6	47.3	8.08
JG12-2	52.3	0.24	2.26	0.32	5.31	0.08	16.3	22.1	0.40	0.00	0.07	99.3	84.5			45.2	46.2	8.61
JG12-3	52.4	0.28	2.14	0.11	4.86	0.13	16.3	22.1	0.36	0.00	0.03	98.6	85.7			45.5	46.5	8.01
JG12-4	52.5	0.20	2.15	0.53	4.63	0.12	16.5	21.8	0.40	0.02	0.06	98.8	86.4			45.0	47.3	7.66
JG12-5	52.5	0.19	1.54	0.18	5.40	0.19	16.2	22.4	0.36	0.02	0.00	99.0	84.3			45.4	45.7	8.87
JG12-6	52.9	0.25	1.72	0.38	4.95	0.12	16.3	22.7	0.39	0.01	0.00	99.8	85.5			46.0	46.0	8.01
JG12-7	52.7	0.22	2.21	0.45	4.97	0.14	16.5	21.8	0.44	0.01	0.05	99.5	85.6			44.7	47.1	8.18
JG12-1*	50.7	0.20	2.44		5.57	0.14	17.3	22.6	0.46	0.06		99.4	84.7	3 274	49.5	44.2	47.0	8.73
JG12-2*	50.8	0.19	2.22		5.10	0.13	17.4	23.1	0.37			99.3	85.9	4 176	74.0	44.9	47.1	7.95
JG12-3*	51.4	0.19	1.99		5.34	0.14	17.2	23.1	0.36			99.7	85.2	1 738	18.8	45.1	46.6	8.34
JG12-4*	51.2	0.20	2.10		5.41	0.14	17.3	22.9	0.35			99.7	85.1	1 646	36.7	44.6	46.9	8.44
JG12-5*	50.8	0.19	2.30		5.47	0.15	17.4	22.6	0.38			99.3	85.0	4 293	94.8	44.2	47.3	8.58
JG12-6*	50.8	0.19	2.33		5.38	0.15	17.3	22.8	0.39			99.3	85.2	4 302	100	44.5	47.1	8.44
JG12-7*	50.7	0.19	2.40		5.21	0.15	17.6	22.7	0.38			99.3	85.8	4 044	96.0	44.3	47.6	8.16
JG12-8*	50.6	0.19	2.34		5.10	0.14	17.7	22.9	0.38			99.3	86.1	4 226	71.4	44.4	47.7	7.94
普通角闪石
JG12-1	43.7	0.81	11.2	0.42	7.67	0.10	17.6	11.3	2.04	1.11	0.04	96.0	80.4
JG12-2	43.2	0.75	12.1	0.21	9.19	0.13	16.1	11.0	2.27	1.14	0.03	96.2	75.8
JG12-3	43.9	0.68	11.9	0.24	8.86	0.10	16.2	11.4	2.07	1.10	0.03	96.5	76.5
JG12-4	43.8	1.06	12.0	0.19	9.22	0.11	16.0	10.7	2.10	1.38	0.02	96.5	75.6
JG12-1*	44.5	0.73	12.1		10.30	0.15	16.9	11.7	2.21	1.17			74.6	536	259
JG12-2*	44.4	0.96	12.2		10.50	0.16	16.8	11.4	2.25	1.10			74.0	991	304
JG12-3*	43.9	0.97	12.9		9.37	0.12	16.7	11.9	2.29	1.46			76.2	1413	246
JG12-4*	44.2	0.89	12.5		10.40	0.16	16.7	11.5	2.23	1.16			74.1	802	278
注：*为LA-ICP-MS分析, 其他为电子探针分析，Mg^#=Mg/(Mg+Fe²⁺).

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表 3 含橄榄石单斜辉石岩捕虏体中单斜辉石和普通角闪石的痕量元素(10^-6)分析结果

Table 3. Trace element contents (10^-6) of clinopyroxenes and hornblendes from olivine-bearing clinopyroxenite xenolith

样品编号	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	∑REE	(La/Yb)_N	δEu
单斜辉石
JG12-1*	1.02	3.08	0.55	2.83	1.04	0.3	0.98	0.23	1.21	0.23	0.66	0.07	0.41	0.08	12.7	1.66	0.9
JG12-2*	0.63	2.16	0.43	2.52	0.97	0.33	0.87	0.15	1.12	0.23	0.78	0.07	0.49	0.06	10.8	0.87	1.08
JG12-3*	0.86	2.43	0.45	2.29	0.96	0.27	1.02	0.15	1.13	0.19	0.61	0.07	0.48	0.06	11.0	1.19	0.83
JG12-4*	0.67	2.28	0.42	2.49	0.65	0.26	0.89	0.18	0.96	0.20	0.60	0.07	0.41	0.06	10.2	1.09	1.06
JG12-5*	0.56	1.84	0.33	1.92	0.69	0.34	1.22	0.16	1.43	0.27	0.68	0.09	0.52	0.08	10.1	0.73	1.13
JG12-6*	0.54	1.95	0.39	2.41	0.84	0.31	0.75	0.22	1.24	0.25	0.72	0.07	0.47	0.05	10.2	0.78	1.16
JG12-7*	0.50	1.65	0.39	2.52	0.75	0.30	0.9	0.21	1.18	0.26	0.77	0.09	0.51	0.09	10.1	0.66	1.10
JG12-8*	0.58	2.13	0.40	2.19	0.96	0.34	1.26	0.16	1.40	0.27	0.71	0.08	0.55	0.07	11.1	0.72	0.94
普通角闪石
JG12-1*	3.08	10.6	1.89	8.97	2.59	1.06	3.37	0.54	3.30	0.68	2.25	0.25	1.81	0.26	40.6
JG12-2*	1.53	6.34	1.17	7.7	2.56	0.86	2.95	0.60	4.26	0.78	2.45	0.23	1.75	0.31	33.5
JG12-3*	1.90	7.57	1.45	7.32	2.59	1.07	3.26	0.53	3.80	0.70	2.31	0.23	2.04	0.22	35.0
JG12-4*	2.23	7.99	1.48	9.17	2.89	0.83	3.17	0.58	4.12	0.71	2.23	0.23	1.98	0.30	37.9

样品编号	Rb	Sr	Ba	Nb	Ta	Zr	Hf	Th	Y	Ti	Sc	V	Cr	Co	Ni	U	Ti/Eu
单斜辉石
JG12-1*	2.52	102	66.2	0.16	0.01	5.07	0.25	0.15	5.94	1 210	62.8	161	3 274	33.2	49.5	0.03	4 004
JG12-2*	0.03	75	0.23		0.00	2.13	0.15	0.01	5.34	1 154	62.4	159	4 176	31.7	74.0	0.05	3 502
JG12-3*	0.03	82	0.06		0.01	2.98	0.21	0.03	5.21	1 121	68.4	174	1 738	30.9	18.8	0.01	4 115
JG12-4*	0.02	74	0.12			2.31	0.11	0.02	5.56	1 210	66.7	176	1 646	32.2	36.7	0.01	4 572
JG12-5*	0.10	52	0.40			1.85	0.16	0.01	6.50	1 117	67.0	168	4 293	32.9	94.8	0.05	3 266
JG12-6*	0.05	57	0.12	0.01	0.01	2.30	0.11	0.01	6.04	1 140	63.9	171	4302	31.7	100.0		3 711
JG12-7*	0.05	57	0.08			1.83	0.13	0.01	6.22	1 109	66.8	165	4 044	31.6	96.0	0.15	3 731
JG12-8*	0.17	67	0.90	0.04	0.01	2.95	0.13	0.05	6.49	1141	66.7	157	4 226	31.7	71.4	0.01	3 354
普通角闪石
JG12-1*	15.3	317	318	1.36	0.10	22.9	1.16	0.05	18.8	3 921	30.8	140	536	71.8	259	0.02
JG12-2*	13.2	207	175	0.54	0.04	17.0	0.85	0.02	22.3	5 174	56.6	217	991	76.8	304	0.02
JG12-3*	10.2	244	273	1.07	0.05	16.0	0.71	0.04	20.5	5 198	45.1	267	1413	62.0	246	0.03
JG12-4*	14.4	250	226	0.68	0.06	20.1	0.96	0.04	20.1	4 758	45.3	187	802	79.4	278	0.03
注：*为LA-ICP-MS分析，(La/Yb)_N=(La/0.310)/(Yb/0.209)；δEu=2×(Eu/0.0735)/((Sm/0.195)+(Gd/0.259))；(La/Yb)_N球粒陨石标准化数据采用Boynton(1987).

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