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    郯庐断裂带晚白垩世金成矿作用: 来自龙泉站金矿床黄铁矿Rb-Sr年代学证据

    石文杰 魏俊浩 谭俊 李艳军 付乐兵 李欢 赵少卿 田宁

    石文杰, 魏俊浩, 谭俊, 李艳军, 付乐兵, 李欢, 赵少卿, 田宁, 2014. 郯庐断裂带晚白垩世金成矿作用: 来自龙泉站金矿床黄铁矿Rb-Sr年代学证据. 地球科学, 39(3): 325-340. doi: 10.3799/dqkx.2014.031
    引用本文: 石文杰, 魏俊浩, 谭俊, 李艳军, 付乐兵, 李欢, 赵少卿, 田宁, 2014. 郯庐断裂带晚白垩世金成矿作用: 来自龙泉站金矿床黄铁矿Rb-Sr年代学证据. 地球科学, 39(3): 325-340. doi: 10.3799/dqkx.2014.031
    Shi Wenjie, Wei Junhao, Tan Jun, Li Yanjun, Fu Lebing, Li Huan, Zhao Shaoqing, Tian Ning, 2014. Late Early Cretaceous Gold Mineralization in Tan-Lu Fault Zone: Evidence from Rb-Sr Isotopic Dating of Pyrite from Longquanzhan Gold Deposit. Earth Science, 39(3): 325-340. doi: 10.3799/dqkx.2014.031
    Citation: Shi Wenjie, Wei Junhao, Tan Jun, Li Yanjun, Fu Lebing, Li Huan, Zhao Shaoqing, Tian Ning, 2014. Late Early Cretaceous Gold Mineralization in Tan-Lu Fault Zone: Evidence from Rb-Sr Isotopic Dating of Pyrite from Longquanzhan Gold Deposit. Earth Science, 39(3): 325-340. doi: 10.3799/dqkx.2014.031

    郯庐断裂带晚白垩世金成矿作用: 来自龙泉站金矿床黄铁矿Rb-Sr年代学证据

    doi: 10.3799/dqkx.2014.031
    基金项目: 

    中国地质大学(武汉)高等学校博士学科点专项科研基金 20120145110004

    中央高校基本科研业务费专项资金 CUG120702

    中央高校基本科研业务费专项资金 CUG120842

    中国博士后科学基金 2012M521493

    详细信息
      作者简介:

      石文杰(1985-), 男, 博士研究生, 主要从事矿床地球化学研究工作.E-mail: swjhaoo@126.com

    • 中图分类号: P597

    Late Early Cretaceous Gold Mineralization in Tan-Lu Fault Zone: Evidence from Rb-Sr Isotopic Dating of Pyrite from Longquanzhan Gold Deposit

    • 摘要: 龙泉站金矿床位于郯庐断裂带山东段内中段, 为沂沭断裂金成矿带的重要组成部分, 同时也是目前沂沭断裂带内发现的唯一一个碎裂蚀变岩型金矿, 矿体主要产于沂水-汤头断裂内的破碎带以及下盘变质岩系中.应用Rb-Sr同位素定年方法对该矿床10件黄铁矿样品进行了成矿时代测定, 获得黄铁矿Rb-Sr同位素等时线年龄为96±2 Ma(MSWD=1.2), 该年龄与断裂带内及附近目前发现的早白垩世晚期至晚白垩世早期岩浆活动时限(106~96 Ma)相吻合.同时结合近些年来山东省成岩成矿的高精度年代学以及矿产勘查成果资料, 表明华北克拉通东南缘亦存在晚白垩世金成矿作用.成矿构造背景与该时期沂沭断裂带不断引张及减压环境有关.伸展机制可能导致断裂带内及附近软流圈不断抬升, 等温线升高, 其进而诱发的强烈壳幔作用为金成矿提供了物质和流体来源.龙泉站晚白垩世金成矿事件的确定, 也为郯庐断裂带内及其两侧矿床成因对比和找矿实践提供了参考.

       

    • 图  1  华北克拉通大地构造位置(a)和山东省地质矿产简图(b)

      a.据Santosh et al.(2010)Li et al.(2012)修改;b.据徐贵忠等(2002)修改

      Fig.  1.  The tectonic setting of North China Craton and the geology (a) and major mineral deposits of Shandong Province (b)

      图  2  山东省龙泉站金矿床矿区地质图以及A-A′B-B′地质剖面图

      图 2据山东省地质调查院山东省沂南县龙泉站矿区金矿普查报告(2009)修编;1.地质界线;2.断裂;3.矿体;4.花岗糜棱岩质碎裂岩带;5.碎裂岩;6.钻孔;Ar31-2gnγδob.新太古代早期泰山岩套望府山条带状细粒英云闪长岩;Ar33-3bηγm.新太古代傲徕山超单元条花峪二长花岗岩;K1ml.白垩系大盛群马朗沟组紫红色长石细砂岩夹黄绿色粉砂岩;γπ.燕山晚期花岗斑岩;χ.煌斑岩脉;δμ.闪长岩脉;βμ.辉绿岩脉;v53.辉长岩;Ⅰ、Ⅱ.代表矿化蚀变带

      Fig.  2.  The geological map of the Longquanzhan gold deposit and the geological profile of A-A′ and B-B′

      图  3  龙泉站金矿床野外地质现象、矿石类型以及矿化特征

      a.沂水-汤头断裂带;b.接触带位置大盛群马朗沟组紫红色含砾长石砂岩角砾被后期石英、碳酸盐、重晶石以及萤石等矿物胶结;c.网脉状花岗质碎裂岩型矿石,根据穿插关系可分3个成矿阶段;d.黄铁绢英岩化糜棱岩质碎裂岩,矿石中局部可见残留的二长花岗岩

      Fig.  3.  Geology ore type and mineralization features of the Longquanzhan gold deposit

      图  4  龙泉站金矿床矿石与蚀变围岩镜下照片

      a.早期自形-半自形黄铁矿(Py1)破碎,并被中细粒黄铁矿(Py2)以及硅酸盐细脉穿插交代;b.细粒黄铁矿(Py3)硅酸盐脉穿插于中粒黄铁矿(Py2)硅酸盐脉和黄铁矿之间相互绕行,无明显穿插交代关系;c.自然金以晶隙金与包体金形式赋存于黄铁矿中;d.花岗质碎裂岩发育硅化、绢云母化、黄铁矿化,多个矿物颗粒构成的碎斑周边常发育细脉状绢云母,并伴随着少量的自形粒状黄铁矿;e.围岩花岗质岩石中的斜长石是发生破碎、位错等应力作用的产物,局部被后期石英穿插与交代,颗粒内部有一组明显的斜列式破裂面,有不均匀消光和波状消光的现象,碎斑的成分主要由石英、斜长石和钾长石等构成;f.穿插于早期硅化、绢云母化蚀变岩的石英-黄铁矿细脉;Py1.第1阶段黄铁矿;Py2.第2阶段黄铁矿;Py3.第3阶段黄铁矿;Q.石英;Pl.斜长石;Ser.绢云母;Au.自然金;Kf.钾长石

      Fig.  4.  Photomicrographs of selected ores and wall rock with hydrothermal alterations from the Longquanzhan gold deposit

      图  5  龙泉站金矿床黄铁矿Rb-Sr等时线年龄

      Fig.  5.  Rb-Sr isochron for pyrite samples from Longquanzhan gold deposit

      图  6  龙泉站金矿床黄铁矿1/Sr-87Sr/86Sr和1/Rb-87Rr/86Sr关系

      Fig.  6.  Relation of 1/Sr-87Sr/86Sr and 1/Rb-87Rb/86Sr of pyrites from the Longquanzhan gold deposit

      图  7  山东省金矿成矿年龄概率密度图(n=49)

      ①代表晚侏罗世(150 Ma左右)金矿成矿作用;②代表早白垩世(106~130 Ma)金矿成矿爆发期;③代表早白垩世晚期-晚白垩世早期金成矿作用.数据骆万成和吴勤生, 1987; 李华芹等, 1993; 吕古贤和孔庆存, 1993; 张振海等, 1994; 孙丰月等, 1995; 张德全等, 1995; Yang and Zhou, 2001; 李厚民等, 2002, 2003; 张连昌, 2002; Li et al., 2003, 2006; Zhang et al., 2003a, 2003b; 胡芳芳等, 2004, 2010; 侯明兰等, 2006; 李红梅等, 2010; 蔡亚春等, 2011; 姜晓辉等, 2011; 丁正江等, 2012; 本文参考文献中成矿年龄的测试对象、测试方法等详见表 2

      Fig.  7.  Age probability diagram for gold deposits Shandong Province, eastern China (n=49)

      表  1  山东省龙泉站金矿床10件黄铁矿样品Rb-Sr同位素比值及含量测定结果

      Table  1.   The Rb-Sr isotopic data of 10 pyrites from the Longquanzhan gold deposit

      样品号 Rb(μg/g) Sr(μg/g) 87Rb/86Sr 87Sr/86Sr 误差(2σ)
      N-1 17.810 10.190 5.156 0 0.721 248 0.000 007
      N-2 15.430 18.260 2.491 0 0.717 374 0.000 009
      N-4 12.980 17.810 2.152 0 0.717 136 0.000 008
      N-6 19.860 7.494 7.812 0 0.724 637 0.000 011
      N-8 11.530 10.020 3.403 0 0.718 853 0.000 010
      N-9 12.610 12.470 2.984 0 0.718 064 0.000 009
      N-10 13.480 14.960 2.659 0 0.717 815 0.000 012
      N-20 6.019 27.170 0.653 2 0.714 868 0.000 008
      N-21 5.346 31.390 0.502 5 0.714 793 0.000 011
      N-22 3.984 24.410 0.481 7 0.714 736 0.000 009
      下载: 导出CSV

      表  2  山东省金矿成矿年龄统计

      Table  2.   Mineralization ages of gold deposits from Shandong Province

      地区 金矿 测试对象 测试方法 成矿时代(Ma) 资料来源
      胶东 蓬家夼 绢云母 Ar-Ar 120.9±0.4~119.1±0.2 Li et al., 2006
      蓬家夼 石英 Ar-Ar 115.2±1.0
      蓬家夼 石英 Ar-Ar 117±0.1 张连昌, 2002
      蓬家夼 石英 Ar-Ar 116±0.4
      蓬家夼 矿石 Rb-Sr 128±7
      蓬家夼 石英、黑云母 Ar-Ar 117.5±0.3~118.4±0.3 Zhang et al., 2003a
      蓬家夼 绢云母 K-Ar 100.5±1.9 孙丰月等, 1995
      乳山 蚀变岩 Rb-Sr 121.3±0.5
      乳山 蚀变岩 Rb-Sr 113.3±4.4 张振海等, 1994
      乳山 蚀变岩 Rb-Sr 101.7±4.8
      乳山 蚀变岩 Rb-Sr 112.3±3.3
      乳山 热液锆石 SHRIMP U-Pb 117±3 胡芳芳等, 2004
      乳山 绢云母 Ar-Ar 109.3±0.3~107.7±0.5 Li et al., 2006
      东季 钾长石 Ar-Ar 116.3±0.8 李厚民等, 2003
      东季 石英 Ar-Ar 114.4±0.2 李厚民等, 2003
      玲珑 黄铁矿 Rb-Sr 122~123 Yang and Zhou, 2001
      玲珑 绢云母 Rb-Sr 100.7±3.5 张振海等, 1994
      玲珑 绢云母 Rb-Sr 111.3±2.8 张振海等, 1994
      玲珑 绢云母 Rb-Sr 126.5±5.7 李华芹等, 1993
      玲珑 绢云母 Rb-Sr 100.2±3.7 骆万成和吴勤生, 1987
      玲珑 绢云母 Rb-Sr 112±2 骆万成和吴勤生, 1987
      金城 长石 Ar-Ar 116.3±13 李厚民等, 2002
      金城 石英 Ar-Ar 114.4±0.9 李厚民等, 2002
      大庄子 石英 Ar-Ar 115.6±1 Zhang et al., 2003a
      发云夼 黄铁矿 Rb-Sr 128.2±7 Zhang et al., 2003a
      仓上 绢云母 Ar-Ar 121.3±0.2 Zhang et al., 2003b
      下雨村 绢云母 K-Ar 124.6±2.5 孙丰月等, 1995
      胡八庄 绢云母 Rb-Sr 126.5±5.6 蔡亚春等, 2011
      马家窑 黄铁矿 Rb-Sr 106.1±4.9 张振海等, 1994
      马家窑 石英 Rb-Sr 137.6±7.1 李华芹等, 1993
      马家窑 绢云母 Rb-Sr 135.1±5.2 张振海等, 1994
      河西 黄铁矿 Rb-Sr 122.3±3.1 侯明兰等, 2006
      黑岚沟与大柳行 黄铁矿 Rb-Sr 117.8±6.5 侯明兰等, 2006
      焦家 绢云母/白云母 Ar-Ar 120.5±0.6~119.2±0.2 Li et al., 2003
      焦家 石英 Rb-Sr 134±8 李华芹等, 1993
      焦家 长石 K-Ar 100
      焦家 蚀变岩 Rb-Sr 115±5 吕古贤和孔庆存, 1993
      焦家 绢云母 Rb-Sr 105±7
      焦家 绢云母 K-Ar 106±2 骆万成和吴勤生, 1987
      新城 黄铁绢英岩全岩 Rb-Sr 116±5 杨进辉等, 2000
      新城 绢云母/白云母 Ar-Ar 120.7±0.2~120.2±0.3 Li et al., 2003
      望儿山 绢云母/白云母 Ar-Ar 121.0±0.4~119.4±0.2 Li et al., 2003
      邓格庄 绢云母 Rb-Sr 118±9 张德全等, 1995
      灵山沟 蚀变水白云母 Rb-Sr 115±5 骆万成和吴勤生, 1987
      土堆-沙旺 石英 Rb-Sr 119±10 李红梅等, 2010
      邢家山钼钨矿床 辉钼矿 Re-Os 158.70±2.06 丁正江等, 2012
      胶东留村 黄铁矿 Rb-Sr 151±2.7 姜晓辉等, 2011
      鲁西 沂南 黑云母 Rb-Sr 133±6~128±2 胡芳芳等, 2010
      沂沭断裂带 龙泉站 黄铁矿 Rb-Sr 96±2 本文
      下载: 导出CSV
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