桂东大瑶山南缘社山花岗闪长岩的锆石U-Pb年龄及Hf同位素特征: 对区内加里东期成岩成矿作用的制约

李巍; 毕诗健; 杨振; 梁培; 唐克非

doi:10.3799/dqkx.2015.002

桂东大瑶山南缘社山花岗闪长岩的锆石U-Pb年龄及Hf同位素特征: 对区内加里东期成岩成矿作用的制约

doi: 10.3799/dqkx.2015.002

李巍^1,,
毕诗健^{2, 3, ,},
杨振³,
梁培⁴,
唐克非^{2, 3}

1.
广西壮族自治区地球物理勘察院, 广西柳州 545005
2.
中国地质大学地质过程与矿产资源国家重点实验室, 湖北武汉 430074
3.
中国地质大学资源学院, 湖北武汉 430074
4.
中国科学院广州地球化学研究所, 广东广州 510640

基金项目:

国家自然科学基金项目 41202052

中央高校基本科研业务费专项资金 CUG120102

广西壮族自治区地质矿产开发局科研项目 2012026193

详细信息

作者简介:
李巍(1969-), 男, 高级工程师, 主要从事矿产勘查方面的研究工作.E-mail: liwei6909@163.com

通讯作者:
毕诗健, E-mail: Shijianbi_1982@163.com

中图分类号: P581
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- 被引次数: 0
出版历程
- 收稿日期: 2014-06-19
- 刊出日期: 2015-01-15

Zircon U-Pb Age and Hf Isotope Characterization of Sheshan Granodiorite in Southern Edge of Dayaoshan, Guidong: Constraints on Caledonian Diagenesis and Mineralization

Li Wei^1
,,
Bi Shijian^{2, 3
, ,},
Yang Zhen³,
Liang Pei⁴,
Tang Kefei^{2, 3}

1.
Geophysical Exploration Institute of Guangxi, Liuzhou 545005, China
2.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China
3.
Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, China
4.
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China

摘要

摘要: 利用激光剥蚀(MC)-ICP-MS方法对桂东大瑶山南缘的社垌钨钼矿床中的花岗岩类进行研究, 精确限定社山黑云母花岗闪长岩(SD256)中锆石的²⁰⁶Pb/²³⁸U加权平均年龄为438.7±3.0 Ma(MSWD=0.22), 侵位于平头背石英砂岩的花岗闪长(斑)岩脉(SD190)形成于438.1±2.6 Ma(MSWD=0.28);花岗岩中新生岩浆锆石的Hf同位素特征较为一致, ¹⁷⁶Hf/¹⁷⁷Hf比值分布于0.282 406~0.282 518, 对应的ε_Hf(438 Ma)值变化于-3.7~0, 两阶段Hf模式年龄(T_DM2)集中在1 226~1 417 Ma之间.这表明大瑶山地区社山花岗闪长岩类的形成时间在438 Ma左右(加里东期), 成岩成矿作用可能与中元古代新生地壳物质(1.2~1.4 Ga)的部分熔融密切相关.结合区域内已有可靠年龄进行分析, 认为华南加里东期成岩成矿作用应该不是呈简单的北东向分布, 而是呈面状展布, 且该期构造-岩浆-成矿运动可能是引起华南地区在印支期、燕山早期发生大规模的岩浆作用和金属成矿作用的关键原因之一.
- 社垌W-Mo矿床 /
- 地球化学 /
- 加里东期 /
- 成岩成矿作用 /
- 大瑶山
Abstract: In this paper, we present laser ablation (MC)-ICP-MS U-Pb dating and Hf isotopic compositions of zircons from two representative granitoid samples collected from Shedong W-Mo deposit in the southern edge of the Dayaoshan. Highly precise U-Pb results indicate that zircons from Sheshan biotite granodiorite (SD256) and granodiorite-(porphyry) (SD190) which emplaced in the Pingtoubei quartz sandstone yields weighted mean ²⁰⁶Pb/²³⁸U age of 438.7±3.0 Ma (MSWD=0.22) and 438.1±2.6 Ma (MSWD=0.28), respectively. And the zircons crystallized in the Kwangsian granites yield ¹⁷⁶Hf/¹⁷⁷Hf ratios of 0.282 406 to 0.282 518, ε_Hf(438 Ma) values ranging from -3.7 to 0 and Hf model ages (T_DM2) of 1 226 to 1 417 Ma. Our U-Pb and Hf isotopic data can be interpreted as the crystallization time of granites, and indicate that it was formed in the ~438 Ma (Caledonian) and may have been formed by reworking of Mesoproterozoic juvenile crust (1.2-1.4 Ga) closely related to partial melting. Together with other published geochronological data, it is proposed that the late Early Paleozoic granites predominantly have a similar formation age and exhibit a planar-shaped distribution, rather than a north-east-striking-distribution pattern in the hinterland of the South China. Moreover, the Caledonian tectonic-magmatic-metallogenic movement may be the one of key reasons for the large-scale magmatism and metal mineralization in the following tectonic episodes, such as Indosinian and Yanshanian in the South China.
- Shedong W-Mo deposit /
- geochemistry /
- Caledonian /
- diagenesis and mineralization /
- Dayaoshan

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图 1 钦杭成矿带大瑶山地区区域地质图及社垌W-Mo矿等矿床分布

a.华南钦杭成矿带地质略图；b.大瑶山隆起构造单元示意图；c.钦杭成矿带大瑶山地区区域地质图及矿床分布

Fig. 1. Regional geologic map of the Dayaoshan showing the location of the Shedong W-Mo district and other ore deposits

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图 2 大瑶山社垌钨钼矿床区域地质简图

Fig. 2. Simplified geologic map of Sheshan district, Dayaoshan, showing the location of Sheshan biotite granodiorite in the Shedong W-Mo deposit

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图 3 社山黑云母花岗闪长岩中矿物组成

Qtz.石英；Bt.黑云母；Pl.斜长石；Am.角闪石；Ser.绢云母；Chl.绿泥石；Cb.碳酸盐矿物；Spn.榍石；Zrn.锆石

Fig. 3. Microphotographs of Sheshan biotite granodiorite

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图 4 社垌钨钼矿床黑云母花岗闪长岩(SD256)中锆石阴极发光(CL)图像

圆圈标准为分析点位置及²⁰⁶Pb/²³⁸U年龄，圆圈直径为32 μm

Fig. 4. Representative cathodoluminescence (CL) images of zircons for biotite granodiorite in the Shedong W-Mo deposit

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图 5 社垌地区花岗闪长岩(SD256)、花岗闪长(斑)岩脉(SD190)中锆石U-Pb谐和曲线

Fig. 5. Concordia diagrams of LA-ICPMS zircons U-Pb data from biotite granodiorite (SD-256) and biotite (porphyry) granodiorite (SD190) in the Shedong W-Mo deposit

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图 6 华南早古生代早期花岗岩体锆石U-Pb年龄的概率分布曲线

数据主要来源于舒良树等，2008；Wang et al., 2011；Chen et al., 2012；Zhang et al., 2012及本文

Fig. 6. Frequency of zircon U-Pb ages for the Early Paleozoic granites in the South China block

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表 1 社垌花岗闪长岩(SD190和SD256) 锆石的LA-ICP-MS锆石U-Pb分析结果

Table 1. LA-ICP-MS U-Pb data for zircons (SD190 and SD256) from the Shedong granodiorite

测试点号	含量(μg/g)			U-Th-Pb同位素比值						年龄(Ma)
测试点号	Th	U	Th/U	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ
SD190
SD190-1	1 395	2 727	0.5	0.059 4	0.001 7	0.582 6	0.015 6	0.071 0	0.001 1	583	61	466	10	442	6
SD190-2	2 586	4 848	0.5	0.056 0	0.002 1	0.543 6	0.020 8	0.070 0	0.001 0	454	118	441	14	436	6
SD190-3	821	943	0.9	0.068 6	0.001 6	1.445 8	0.034 5	0.152 3	0.001 7	888	49	908	14	914	10
SD190-4	1 621	3 325	0.5	0.055 1	0.001 4	0.540 2	0.014 1	0.070 4	0.000 6	417	53	439	9	439	4
SD190-5	929	1 523	0.6	0.057 7	0.002 3	0.563 5	0.020 2	0.071 0	0.001 1	520	90	454	13	442	7
SD190-6	617	1 322	0.5	0.056 0	0.002 4	0.551 4	0.023 7	0.071 0	0.000 9	450	98	446	16	442	6
SD190-7	534	1 008	0.5	0.055 5	0.002 0	0.535 7	0.018 6	0.070 2	0.000 9	432	80	436	12	438	5
SD190-8	1 499	2 034	0.7	0.056 9	0.001 4	0.554 5	0.013 4	0.070 6	0.000 7	487	56	448	9	440	4
SD190-9	3 886	6 830	0.6	0.058 4	0.001 4	0.568 6	0.014 4	0.070 0	0.000 6	546	49	457	9	436	4
SD190-10	698	2 429	0.3	0.066 1	0.001 8	0.647 9	0.020 4	0.070 6	0.001 2	809	57	507	13	440	7
SD190-11	699	2 267	0.3	0.179 2	0.003 5	12.580 7	0.272 6	0.506 5	0.006 1	2 656	32	2 649	20	2 642	26
SD190-12	280	1 087	0.3	0.074 7	0.001 7	2.062 5	0.045 9	0.199 5	0.001 8	1 061	46	1 136	15	1 173	10
SD190-13	4 106	10 072	0.4	0.056 1	0.001 2	0.542 4	0.011 7	0.069 6	0.000 7	457	44	440	8	434	4
SD190-14	2 586	3 211	0.8	0.054 7	0.001 6	0.526 5	0.015 6	0.070 4	0.001 7	398	67	429	10	439	10
SD190-15	1 145	1 792	0.6	0.056 1	0.001 7	0.544 8	0.014 8	0.070 8	0.000 9	457	65	442	10	441	5
SD190-16	296	387	0.8	0.056 0	0.004 2	0.542 2	0.040 6	0.070 6	0.001 6	450	170	440	27	440	9
SD190-17	388	497	0.8	0.055 6	0.003 1	0.542 7	0.031 1	0.070 7	0.001 2	435	124	440	20	440	7
SD190-18	1 359	2 562	0.5	0.066 9	0.006 9	0.611 2	0.029 7	0.071 0	0.001 8	835	216	484	19	442	11
SD190-19	1 262	5 343	0.2	0.066 7	0.002 0	0.649 8	0.021 3	0.070 0	0.001 2	828	69	508	13	436	8
SD190-20	834	1 609	0.5	0.055 7	0.001 8	0.533 5	0.015 6	0.069 7	0.000 8	443	77	434	10	434	5
SD256
SD256-1	297	458	0.6	0.053 3	0.002 4	0.516 9	0.024 7	0.070 0	0.000 8	343	104	423	17	436	5
SD256-2	394	679	0.6	0.053 2	0.002 4	0.520 4	0.023 2	0.071 0	0.001 2	345	100	425	15	442	7
SD256-3	333	588	0.6	0.060 8	0.002 1	0.593 6	0.020 5	0.070 8	0.000 8	632	76	473	13	441	5
SD256-4	441	655	0.7	0.055 7	0.002 0	0.540 4	0.018 4	0.070 4	0.000 9	443	80	439	12	438	5
SD256-5	307	375	0.8	0.060 5	0.003 6	0.592 3	0.036 5	0.070 6	0.001 4	620	130	472	23	440	8
SD256-6	274	405	0.7	0.058 1	0.002 6	0.563 3	0.024 6	0.070 2	0.001 0	532	98	454	16	437	6
SD256-7	569	597	1.0	0.056 3	0.002 2	0.543 4	0.020 1	0.070 7	0.001 0	465	85	441	13	441	6
SD256-8	233	322	0.7	0.055 9	0.002 5	0.540 9	0.026 0	0.070 5	0.001 0	456	102	439	17	439	6
SD256-9	285	534	0.5	0.065 7	0.003 3	0.622 8	0.032 7	0.068 0	0.000 9	798	107	492	20	424	6
SD256-10	275	1 143	0.2	0.072 0	0.001 5	1.547 1	0.035 2	0.155 2	0.001 9	985	43	949	14	930	10
SD256-11	116	191	0.6	0.070 7	0.002 5	1.505 0	0.051 6	0.154 3	0.001 8	950	72	932	21	925	10
SD256-12	236	336	0.7	0.056 2	0.003 3	0.546 5	0.030 3	0.071 7	0.001 5	457	130	443	20	447	9
SD256-13	1 522	1 134	1.3	0.052 8	0.001 7	0.512 3	0.016 9	0.070 6	0.001 4	320	74	420	11	440	9
SD256-14	402	483	0.8	0.054 7	0.002 0	0.529 2	0.018 8	0.070 2	0.000 8	398	81	431	13	437	5
SD256-15	250	1 562	0.2	0.056 2	0.001 5	0.546 8	0.015 0	0.070 0	0.000 7	457	61	443	10	436	4
SD256-16	282	379	0.7	0.055 4	0.002 3	0.541 3	0.021 7	0.070 7	0.000 9	428	93	439	14	441	5
SD256-17	488	1 036	0.5	0.091 4	0.002 0	2.965 0	0.063 2	0.232 3	0.002 1	1 457	42	1 399	16	1 347	11
SD256-18	256	375	0.7	0.064 0	0.003 2	0.609 8	0.028 3	0.070 0	0.001 1	743	112	483	18	436	6

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表 2 社垌花岗闪长岩(SD190和SD256)锆石的LA-ICPMS锆石Hf同位素分析结果

Table 2. Hafnium isotope analyses of zircons (SD190 and SD256) from the Shedong granodiorite

点号	¹⁷⁶Yb/¹⁷⁷Hf	¹⁷⁶Lu/¹⁷⁷Hf	¹⁷⁶Hf/¹⁷⁷Hf	±(2σ)	年龄(Ma)	ε_Hf(0)	ε_Hf(t)	±(2σ)	T_DM1(Ma)	±(2σ)	f_Lu/Hf	T_DM2(Ma)	±(2σ)
SD190
SD190-1	0.044 935 52	0.001 324 30	0.282 406 11	0.000 015	438	-12.9	-3.7	0.5	1 207	41	-0.96	1 417	65
SD190-2	0.040 712 57	0.001 230 67	0.282 456 70	0.000 008	438	-11.2	-1.9	0.3	1 132	24	-0.96	1 324	38
SD190-3	0.053 265 91	0.001 579 14	0.282 463 86	0.000 008	438	-10.9	-1.7	0.3	1 133	22	-0.95	1 316	35
SD190-4	0.048 118 83	0.001 172 81	0.281 799 21	0.000 009	1 800	-34.4	4.3	0.3	2 050	24	-0.96	2 119	38
SD190-5	0.036 316 18	0.001 056 90	0.282 455 20	0.000 008	438	-11.2	-1.9	0.3	1 129	22	-0.97	1 324	34
SD190-6	0.032 305 30	0.000 823 22	0.282 342 14	0.000 019	914	-15.2	4.5	0.7	1 280	54	-0.98	1 386	86
SD190-7	0.068 240 39	0.001 739 39	0.282 454 79	0.000 008	438	-11.2	-2.1	0.3	1 151	24	-0.95	1 335	37
SD190-8	0.036 433 23	0.000 991 43	0.282 475 99	0.000 010	438	-10.5	-1.1	0.3	1 098	27	-0.97	1 286	43
SD190-9	0.037 868 21	0.001 101 48	0.282 486 88	0.000 010	438	-10.1	-0.8	0.4	1 086	29	-0.97	1 268	46
SD190-10	0.067 226 42	0.001 897 32	0.282 472 59	0.000 010	438	-10.6	-1.5	0.3	1 130	27	-0.94	1 305	42
SD190-11	0.065 442 61	0.001 823 17	0.282 501 99	0.000 008	438	-9.5	-0.4	0.3	1 085	23	-0.95	1 251	36
SD190-12	0.043 078 66	0.001 246 56	0.282 460 48	0.000 008	438	-11.0	-1.7	0.3	1 127	22	-0.96	1 317	35
SD190-13	0.030 755 78	0.000 759 26	0.280 991 24	0.000 008	2 642	-63.0	-5.1	0.3	3 125	21	-0.98	3 266	34
SD190-14	0.033 015 37	0.000 913 23	0.282 476 82	0.000 008	438	-10.4	-1.1	0.3	1 095	22	-0.97	1 283	34
SD190-15	0.047 833 10	0.001 402 05	0.282 484 15	0.000 007	438	-10.2	-1.0	0.3	1 099	21	-0.96	1 277	33
SD190-16	0.034 894 80	0.001 043 74	0.282 458 40	0.000 007	438	-11.1	-1.8	0.2	1 124	19	-0.97	1 318	29
SD190-17	0.023 063 44	0.000 576 34	0.282 431 17	0.000 008	438	-12.1	-2.6	0.3	1 148	23	-0.98	1 360	38
SD190-18	0.029 836 34	0.000 863 23	0.282 465 79	0.000 008	438	-10.8	-1.5	0.3	1 109	23	-0.97	1 302	36
SD256
SD256-1	0.046 444 63	0.001 173 92	0.282 472 11	0.000 007	438	-10.6	-1.3	0.2	1 109	19	-0.96	1 295	30
SD256-2	0.037 723 07	0.000 969 01	0.282 467 68	0.000 008	438	-10.8	-1.4	0.3	1 109	22	-0.97	1 300	34
SD256-3	0.032 043 59	0.000 822 65	0.282 430 11	0.000 007	438	-12.1	-2.7	0.3	1 157	20	-0.98	1 366	32
SD256-4	0.035 601 91	0.000 906 33	0.282 451 52	0.000 006	438	-11.3	-2.0	0.2	1 130	18	-0.97	1 329	29
SD256-5	0.042 877 74	0.001 138 94	0.282 541 23	0.000 007	438	-8.2	1.1	0.2	1 010	19	-0.97	1 170	30
SD256-6	0.027 126 83	0.000 650 53	0.282 028 91	0.000 009	1350	-26.3	3.1	0.3	1 707	23	-0.98	1 813	38
SD256-7	0.045 593 09	0.001 130 31	0.282 472 26	0.000 007	438	-10.6	-1.3	0.3	1 107	20	-0.97	1 295	32
SD256-8	0.048 209 95	0.001 299 46	0.282 483 81	0.000 007	438	-10.2	-0.9	0.3	1 096	20	-0.96	1 276	32
SD256-9	0.040 046 41	0.000 990 62	0.282 470 67	0.000 007	438	-10.7	-1.3	0.2	1 106	19	-0.97	1 295	30
SD256-10	0.021 988 48	0.000 555 98	0.282 441 11	0.000 008	438	-11.7	-2.2	0.3	1 134	22	-0.98	1 342	36
SD256-11	0.055 172 58	0.001 442 48	0.282 439 77	0.000 007	438	-11.7	-2.5	0.3	1 163	21	-0.96	1 358	32
SD256-12	0.089 617 62	0.002 156 19	0.282 518 35	0.000 008	438	-9.0	0.0	0.3	1 072	22	-0.94	1 226	34
SD256-13	0.048 509 61	0.001 244 39	0.282 463 14	0.000 007	438	-10.9	-1.7	0.3	1 124	20	-0.96	1 313	32
SD256-14	0.050 665 35	0.001 276 48	0.282 460 51	0.000 009	438	-11.0	-1.8	0.3	1 128	26	-0.96	1 318	40
SD256-15	0.033 574 02	0.000 858 93	0.282 299 32	0.000 008	925	-16.7	3.2	0.3	1 341	22	-0.97	1 461	36
SD256-16	0.036 693 87	0.000 913 54	0.282 456 14	0.000 008	438	-11.2	-1.8	0.3	1 124	23	-0.97	1 320	37
SD256-17	0.038 378 21	0.000 931 29	0.282 016 34	0.000 007	1350	-26.7	2.4	0.2	1 737	19	-0.97	1 848	31
SD256-18	0.023 497 64	0.000 601 59	0.282 482 43	0.000 006	438	-10.2	-0.8	0.2	1 078	18	-0.98	1 268	28
SD256-19	0.028 049 05	0.000 712 34	0.282 463 74	0.000 007	438	-10.9	-1.5	0.2	1 107	20	-0.98	1 304	32

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参考文献(131)

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