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    塘沽地区沙河街组下部含云质泥岩主微量元素地球化学特征及地质意义

    李乐 姚光庆 刘永河 侯秀川 王刚 赵耀 高玉洁

    李乐, 姚光庆, 刘永河, 侯秀川, 王刚, 赵耀, 高玉洁, 2015. 塘沽地区沙河街组下部含云质泥岩主微量元素地球化学特征及地质意义. 地球科学, 40(9): 1480-1496. doi: 10.3799/dqkx.2015.133
    引用本文: 李乐, 姚光庆, 刘永河, 侯秀川, 王刚, 赵耀, 高玉洁, 2015. 塘沽地区沙河街组下部含云质泥岩主微量元素地球化学特征及地质意义. 地球科学, 40(9): 1480-1496. doi: 10.3799/dqkx.2015.133
    Li Le, Yao Guangqing, Liu Yonghe, Hou Xiuchuan, Wang Gang, Zhao Yao, Gao Yujie, 2015. Major and Trace Elements Geochemistry and Geological Implications of Dolomite-Bearing Mudstones in Lower Part of Shahejie Formation in Tanggu Area, Eastern China. Earth Science, 40(9): 1480-1496. doi: 10.3799/dqkx.2015.133
    Citation: Li Le, Yao Guangqing, Liu Yonghe, Hou Xiuchuan, Wang Gang, Zhao Yao, Gao Yujie, 2015. Major and Trace Elements Geochemistry and Geological Implications of Dolomite-Bearing Mudstones in Lower Part of Shahejie Formation in Tanggu Area, Eastern China. Earth Science, 40(9): 1480-1496. doi: 10.3799/dqkx.2015.133

    塘沽地区沙河街组下部含云质泥岩主微量元素地球化学特征及地质意义

    doi: 10.3799/dqkx.2015.133
    基金项目: 

    中国石油股份有限公司大港油田分公司重点项目 DGYT-2012-JS-566

    详细信息
      作者简介:

      李乐(1985-), 男, 博士研究生, 主要从事储层地质方面研究工作.E-mail: santali2005@gmail.com

      通讯作者:

      姚光庆(1964-), E-mail: gqyao@cug.edu.cn

    • 中图分类号: P595

    Major and Trace Elements Geochemistry and Geological Implications of Dolomite-Bearing Mudstones in Lower Part of Shahejie Formation in Tanggu Area, Eastern China

    • 摘要: 细粒泥岩记录并反映着源区及沉积区的重要地质信息.塘沽地区沙河街组下部发育一套湖相含云质泥岩, 为了解该地区的构造背景、沉积背景、风化程度以及物源属性, 对25块含云质泥岩的地球化学特征进行了全面的分析.经"去白云石"调整后, 各类元素地球地化参数及图解反映出了一致的地质信息.其中, 高∑REE值(154.0×10-6~219.3×10-6)、中等强度的负铕异常(0.64~0.73)以及包括K2O/Na2O-SiO2, SiO2/Al2O3-K2O/Na2O和判别函数几类双变量图解均指示塘沽地区具有主动大陆边缘(安第斯型)的构造背景; SiO2-(K2O+Na2O+Al2O3)图解指示岩石沉积期气候干旱, 相当B(200.17~313.21)指示沉积水体为咸水类型, 近似黄铁矿矿化度(approximate degree of pyritization, 简称DOPapx)(0.02~0.38)、自生铀(0.14~1.22)及U/Th(0.17~0.44)指示水体具备常氧属性; 化学蚀变指数(chemical index of alteration, 简称CIA)(51.26~65.74), 长石蚀变指数(plagioclase index of alteration, 简称PIA)(51.65~78.06), 修正成分变异指数(modified index of composition variation, 简称ICVm)(0.67~1.24)及A-CN-K图解反映了母岩经受了弱-中等强度的风化程度; 判别函数图解、K-Rb双变量判别图解、A-CN-K图解、Al2O3/TiO2指标(23.37~28.58)、与上地壳(upper continental crust, 简称UCC)相似的稀土配分模式及负铕异常则共同确定长英质岩石为含云质泥岩的母岩来源.在上述背景条件的约束下, 研究表明塘沽地区沙河街组含云质泥岩的物质来源应主要由燕山褶皱带提供.

       

    • 图  1  区域构造(a)和研究区古近系地层简图(b)

      图a底图据周立宏等(2011)修改

      Fig.  1.  Geological sketch of study area (a) and generalized paleogene stratigraphic of the study area (b)

      图  2  沙三段含云质泥岩典型岩心及薄片照片

      a.水平层理发育,富泥质纹层及富云质纹层纵向上交替出现,3 094.5 m;b.块状层理发育,难见纹层,3 111.8 m;c.纹层状含云质泥岩,泥晶级白云石及泥级碎屑颗粒(石英和长石)呈纹层状产出(正交偏光,放大5倍);d.块状含云质泥岩,粉砂级长石呈分散状赋存于岩石之中(单偏光,放大10倍)

      Fig.  2.  Typical photos of core and thin sections of Sha3 member dolomite-bearing mudstones

      图  3  沙三段含云质泥岩主量元素氧化物(a)、微量元素(b)UCC标准化模式

      UCC数据来自Rudnick and Gao(2003);DM.含云质泥岩(以下同)

      Fig.  3.  Distribution of UCC-nomalized major oxides (a) and trace elements (b) of Sha3 member dolomite-bearing mudstones

      图  4  沙三段含云质泥岩稀土元素配分模式

      球粒陨石、PAAS及UCC数据分别来自于Henderson(1984), Taylor and McLennan(1985)Rudnick and Gao(2003)

      Fig.  4.  Chondrite-normalized REE pattern of Sha3 member dolomite-bearing mudstones

      图  5  沙三段含云质泥岩构造背景判别

      a.K2O/Na2O-SiO2双变量判别图,据Roser and Korsch(1986);b.K2O/Na2O-SiO2双变量图解,所有样品均经过白云石及LOI修正处理;c.SiO2/Al2O3-K2O/Na2O双变量判别图解,据Maynard et al.(1982)Roser and Korsch(1986);d.判别函数双变量图解,据Bhatia(1983);OIA.大洋岛弧边缘;ACM.主动大陆边缘;PM.被动大陆边缘;A1.原始岛弧;A2.进化岛弧;CIA.大陆岛弧;判别函数1=0.303-0.0447×SiO2%-0.972×TiO2%+0.008×Al2O3%-0.267×Fe2O3%+0.208×FeO%-3.082×MnO%+0.140×MgO%+0.195×CaO%+0.719×Na2O%-0.032×K2O%+7.510×P2O5%;判别函数2=43.57-0.421×SiO2%+1.988×TiO2%-0.526×Al2O3%-0.551×Fe2O3%-1.610×FeO%+2.720×MnO%+0.881×MgO-0.907×CaO%-0.117×Na2O%-1.840×K2O%+7.244×P2O5%

      Fig.  5.  Tectonic setting discrimination diagrams for Sha3 member dolomite-bearing mudstones

      图  6  沙三段含云质泥岩古气候判别

      Suttner and Dutta(1986)

      Fig.  6.  SiO2-(Al2O3+K2O+Na2O) bivariate paleoclimate discrimination for Sha3 member dolomite-bearing mudstones

      图  7  沙三段含泥白云岩A-CN-K图解

      Ga.辉长岩;T.英闪岩;Gr.花岗闪长岩;A.石英二长岩;G.花岗岩;箭头1.含云质泥岩风化趋势线;箭头2.理想风化趋势线;据Nesbitt and Young(1984)

      Fig.  7.  A-CN-K diagram for Sha3 member dolomite-bearing mudstones

      图  8  沙三段含云质泥岩物源属性判别图解

      a.判别函数双变量图解,据Roser and Korsch(1988),判别函数1=-1.773×TiO2+0.607×Al2O3+0.760×TFe2O3-1.500×MgO+0.616×CaO+0.509×Na2O-1.224×K2O-9.090;判别函数2=0.445×TiO2+0.070×Al2O3-0.250×Fe2O3-1.142×MgO+0.438×CaO+1.475×Na2O+1.426×K2O-6.861;b.K-Rb双变量判别图解,据Floyd and Leveridge(1987)

      Fig.  8.  Provence discrimination diagrams for Sha3 member dolomite-bearing mudstones

      表  1  沙三段含云质泥岩主量、微量和稀土元素分析结果

      Table  1.   Major element, trace element and rare-earth element (REE) analyses of Sha3 member dolomite-bearing mudstones

      样品 Y1 Y2 Y3 Y4 Y5 Y6 Y7 Y8 Y9 Y10 Y11 Y12 Y13 Y14 Y15 Y16 Y17 Y18 Y19 Y20 Y21 Y22 Y23 Y24 Y25
      Na2O 2.12 2.01 2.77 1.96 2.03 2.18 2.13 2.43 2.22 1.93 1.97 1.77 1.87 2.00 2.12 2.07 1.60 1.95 1.54 1.96 2.41 2.28 2.54 1.46 2.76
      MgO 4.19 2.65 2.60 2.75 2.82 2.72 2.63 3.61 3.17 3.14 3.05 3.32 3.12 3.26 3.22 3.11 4.58 3.08 2.67 3.09 3.69 4.14 3.60 3.02 4.63
      Al2O3 14.57 16.80 15.68 16.05 15.96 15.77 16.41 14.31 15.23 14.74 14.76 14.97 15.51 14.64 14.84 15.85 13.20 14.34 13.72 14.92 13.58 13.37 13.91 14.36 12.62
      SiO2 47.54 52.99 50.82 49.50 50.29 51.60 51.43 43.90 48.65 48.03 48.99 47.92 48.82 46.87 48.86 51.60 42.57 49.29 47.83 48.13 44.82 44.08 46.84 46.98 41.76
      P2O5 0.17 0.21 0.24 0.27 0.22 0.20 0.21 0.67 0.29 0.37 0.26 0.21 0.17 0.35 0.20 0.12 0.35 0.21 0.21 0.16 0.18 0.23 0.18 0.20 0.21
      K2O 3.16 3.87 3.31 3.57 3.51 3.51 3.57 2.64 3.06 3.14 3.18 3.14 3.08 3.03 3.06 3.44 2.92 3.15 3.00 3.29 3.02 3.01 2.97 3.29 2.69
      CaO 6.46 5.08 5.80 6.09 5.95 6.31 5.38 8.08 5.57 6.21 6.20 6.65 5.94 7.13 6.60 4.09 9.46 7.04 9.68 6.42 8.08 8.39 8.03 8.28 9.59
      TiO2 0.57 0.70 0.67 0.65 0.65 0.66 0.69 0.52 0.60 0.57 0.58 0.57 0.60 0.57 0.58 0.64 0.53 0.59 0.48 0.57 0.54 0.53 0.57 0.55 0.54
      MnO 0.07 0.04 0.07 0.08 0.08 0.07 0.07 0.10 0.09 0.08 0.08 0.09 0.09 0.09 0.09 0.05 0.10 0.09 0.09 0.08 0.10 0.10 0.10 0.12 0.11
      Fe2O3 2.65 2.15 1.70 1.89 1.90 2.10 2.26 2.23 2.30 2.20 2.25 2.48 2.58 1.98 1.96 2.08 2.22 2.31 2.73 2.06 1.78 1.69 1.98 2.05 1.76
      FeO 2.30 2.15 3.30 3.45 3.55 2.55 2.95 4.05 3.65 3.50 2.80 3.10 3.15 3.55 2.65 2.20 3.10 3.00 2.12 3.40 3.50 3.65 2.65 3.75 4.30
      TFe2O3 5.21 4.54 5.37 5.72 5.85 4.93 5.54 6.73 6.36 6.09 5.36 5.93 6.08 5.93 4.90 4.52 5.67 5.64 5.09 5.84 5.67 5.75 4.92 6.22 6.54
      H2O+ 3.66 4.88 5.14 5.28 5.04 4.74 5.20 6.02 6.44 7.68 7.76 6.24 5.64 6.22 5.80 8.66 5.70 4.98 5.38 4.80 6.04 7.22 5.56 5.42 5.16
      H2O- 2.09 3.38 2.79 2.79 3.20 3.25 3.20 2.64 2.83 2.35 2.55 2.90 3.01 2.73 2.48 2.44 2.52 3.23 3.55 2.77 1.90 1.77 1.91 3.02 1.71
      LOI 15.59 10.90 12.47 13.11 12.35 11.84 11.65 16.84 14.54 15.44 15.32 15.18 14.47 15.88 15.28 14.18 18.73 14.37 15.42 15.31 17.64 17.86 16.05 15.26 18.40
      SUM 99.39 99.55 99.43 99.37 99.31 99.51 99.38 99.38 99.37 99.35 99.44 99.40 99.40 99.35 99.46 99.43 99.36 99.42 99.49 99.39 99.34 99.33 99.42 99.32 99.37
      ICV 1.46 1.08 1.27 1.26 1.27 1.25 1.18 1.65 1.34 1.40 1.34 1.40 1.30 1.46 1.35 1.09 1.84 1.46 1.61 1.39 1.69 1.77 1.59 1.56 2.09
      ICVm 0.80 0.74 0.91 0.88 0.88 0.87 0.83 1.07 0.88 0.92 0.88 0.90 0.85 0.96 0.86 0.67 1.04 0.98 1.17 0.92 1.07 1.06 1.01 1.08 1.24
      K2O/Al2O3 0.22 0.23 0.21 0.22 0.22 0.22 0.22 0.18 0.20 0.21 0.22 0.21 0.20 0.21 0.21 0.22 0.22 0.22 0.22 0.22 0.22 0.23 0.21 0.23 0.21
      CIA 65.74 63.88 57.67 60.86 60.85 58.95 62.21 57.06 64.62 62.09 60.63 61.86 63.61 59.73 59.41 71.33 61.02 59.32 62.24 59.83 54.79 55.39 54.57 63.17 51.26
      PIA 42.21 50.08 44.43 45.96 46.15 44.23 48.52 37.95 46.33 43.89 43.76 43.49 46.69 41.09 42.62 52.75 33.56 40.52 34.17 43.21 35.55 34.68 36.24 38.16 30.59
      Al2O3/TiO2 25.56 24.00 23.40 24.69 24.55 23.89 23.78 27.52 25.38 25.86 25.45 26.26 25.85 25.68 25.59 24.77 24.91 24.31 28.58 26.18 25.15 25.23 24.40 26.11 23.37
      B 123.95 162.92 113.11 116.06 111.03 103.48 140.49 96.50 91.55 100.73 101.27 100.89 110.55 106.79 100.44 129.64 109.83 103.11 106.08 143.62 92.51 111.17 90.75 109.36 83.14
      Ga 23.05 23.57 21.47 21.07 22.35 19.67 23.48 20.33 19.03 19.02 18.43 19.73 19.23 17.97 19.61 20.45 17.40 18.88 18.14 19.20 18.80 19.06 18.37 20.03 17.35
      Rb 102.70 108.00 85.56 84.70 102.20 100.70 110.70 85.61 81.66 88.28 88.23 88.12 85.14 79.04 82.99 94.40 79.71 93.94 93.62 94.95 92.59 78.89 88.94 92.42 76.85
      Th 11.53 11.00 9.30 9.56 10.52 9.96 11.03 9.88 8.72 9.28 9.05 9.48 9.33 8.92 9.60 9.57 8.98 9.16 9.30 9.40 10.00 9.05 9.99 10.27 8.60
      U 5.06 1.90 1.73 1.89 1.76 1.71 1.99 3.08 3.05 3.66 3.59 3.33 3.29 3.89 4.03 3.37 3.93 2.57 3.43 3.39 3.08 3.45 2.93 2.92 2.30
      Ba 616.51 484.65 494.22 592.81 429.70 417.92 397.60 734.55 508.70 736.46 569.91 554.52 467.90 532.80 520.11 1293.75 598.20 559.70 622.74 545.75 619.90 640.37 821.17 646.84 618.28
      Ni 38.77 40.23 34.89 43.09 33.93 40.73 38.69 39.19 39.66 35.95 38.62 34.53 41.38 34.12 28.95 43.42 31.24 33.15 45.34 38.57 27.53 34.16 28.37 25.40 27.81
      Sr 756.56 406.28 355.58 551.98 370.04 392.43 343.20 857.87 605.17 732.26 704.79 744.21 659.29 729.04 742.62 569.19 1032.75 725.53 863.10 612.90 763.58 834.26 776.89 687.98 670.93
      V 93.68 94.68 96.81 106.69 108.49 81.50 95.76 97.76 81.44 83.47 77.72 87.75 86.88 82.21 75.86 85.27 86.95 99.66 96.24 85.60 75.12 79.91 69.58 89.58 92.18
      相当B 267.85 313.21 237.47 233.06 225.13 209.82 282.12 235.44 201.97 218.56 217.97 218.90 242.85 237.10 221.58 265.97 249.91 223.27 237.07 302.65 205.84 247.90 204.17 230.45 200.17
      Sr/Ba 1.23 0.84 0.72 0.93 0.86 0.94 0.86 1.17 1.19 0.99 1.24 1.34 1.41 1.37 1.43 0.44 1.73 1.30 1.39 1.12 1.23 1.30 0.95 1.06 1.09
      Fepy-apx 2.29 - 0.74 0.88 0.44 0.38 0.16 1.84 0.78 0.86 0.72 1.04 1.04 1.46 1.51 - 2.39 1.21 1.55 1.90 2.47 1.89 2.02 1.53 2.82
      DOPapx 0.38 - 0.11 0.12 0.06 0.07 0.02 0.19 0.09 0.11 0.11 0.13 0.13 0.19 0.27 - 0.33 0.17 0.27 0.25 0.35 0.26 0.35 0.18 0.33
      自生U 1.22 - - - - - - - 0.14 0.56 0.58 0.17 0.18 0.92 0.83 0.18 0.93 - 0.33 0.25 - 0.43 - - -
      U/Th 0.44 0.17 0.19 0.20 0.17 0.17 0.18 0.31 0.35 0.39 0.40 0.35 0.35 0.44 0.42 0.35 0.44 0.28 0.37 0.36 0.31 0.38 0.29 0.28 0.27
      Ni/V 0.41 0.42 0.36 0.40 0.31 0.50 0.40 0.40 0.49 0.43 0.50 0.39 0.48 0.42 0.38 0.51 0.36 0.33 0.47 0.45 0.37 0.43 0.41 0.28 0.30
      La 39.45 44.76 49.14 45.83 43.76 41.14 47.86 35.45 40.08 37.14 36.48 36.16 40.53 38.48 38.52 34.15 37.50 40.33 34.14 38.65 36.93 37.84 34.44 41.09 38.83
      Ce 72.54 83.40 91.61 85.16 81.56 76.80 89.18 65.96 73.63 67.46 67.37 65.91 75.33 71.53 71.61 65.67 67.70 74.37 63.53 71.49 67.87 69.89 65.04 77.74 71.45
      Pr 9.14 10.51 11.34 10.48 10.01 9.48 11.01 8.44 9.40 8.72 8.56 8.38 9.32 8.93 9.01 8.33 8.61 9.49 7.96 9.05 8.66 8.84 8.31 9.86 9.22
      Nd 32.13 37.09 40.52 37.13 35.5 33.34 39.31 30.27 33.15 30.69 30.25 29.53 33.15 31.58 31.89 29.09 30.71 33.42 28.01 31.94 30.81 31.69 29.70 34.70 32.75
      Sm 5.90 6.83 7.42 6.83 6.54 6.06 7.21 5.76 6.23 5.83 5.75 5.56 6.36 5.97 6.06 5.27 6.01 6.23 5.40 5.96 5.81 5.95 5.61 6.65 6.00
      Eu 1.15 1.38 1.50 1.39 1.36 1.23 1.43 1.12 1.20 1.13 1.13 1.05 1.25 1.18 1.18 1.01 1.14 1.24 1.04 1.16 1.11 1.16 1.08 1.31 1.23
      Gd 4.61 5.30 5.74 5.50 5.35 4.60 5.43 4.71 4.86 4.74 4.48 4.42 5.02 4.82 4.8 4.06 4.85 4.88 4.17 4.76 4.55 4.75 4.41 5.10 4.44
      Tb 0.76 0.83 0.89 0.85 0.82 0.74 0.85 0.75 0.78 0.75 0.73 0.72 0.83 0.77 0.79 0.65 0.82 0.78 0.69 0.78 0.75 0.77 0.72 0.84 0.75
      Dy 4.04 4.26 4.64 4.43 4.26 3.77 4.33 4.02 4.00 3.95 3.86 3.72 4.35 4.14 4.16 3.48 4.29 4.00 3.59 4.21 4.03 4.08 3.81 4.47 3.84
      Ho 0.77 0.79 0.89 0.87 0.83 0.74 0.86 0.79 0.80 0.78 0.75 0.75 0.86 0.82 0.81 0.69 0.84 0.79 0.72 0.83 0.79 0.81 0.75 0.89 0.76
      Er 2.27 2.25 2.55 2.43 2.39 2.06 2.45 2.36 2.29 2.27 2.16 2.12 2.53 2.36 2.40 2.02 2.39 2.23 2.12 2.43 2.25 2.33 2.14 2.54 2.16
      Tm 0.36 0.36 0.39 0.39 0.38 0.32 0.39 0.38 0.38 0.37 0.34 0.35 0.41 0.37 0.38 0.33 0.39 0.35 0.34 0.38 0.36 0.37 0.35 0.41 0.35
      Yb 2.10 2.10 2.36 2.26 2.20 1.89 2.27 2.26 2.22 2.18 2.08 2.11 2.41 2.25 2.27 1.94 2.53 2.13 2.02 2.27 2.13 2.19 2.05 2.34 2.01
      Lu 0.33 0.31 0.34 0.35 0.33 0.29 0.34 0.35 0.34 0.34 0.31 0.31 0.36 0.34 0.34 0.29 0.35 0.31 0.30 0.35 0.33 0.34 0.31 0.37 0.31
      Y 21.24 21.74 23.98 22.58 21.90 19.95 22.20 21.62 21.56 20.90 20.11 19.74 23.47 22.25 21.57 17.68 21.22 21.16 19.12 22.38 20.71 21.78 19.99 24.51 20.14
      ∑REE 175.5 200.2 219.3 203.9 195.3 182.5 212.9 162.6 179.4 166.3 164.3 161.1 182.7 173.5 174.2 157 168.1 180.5 154 174.3 166.4 171 158.7 188.3 174.1
      LaN/YbN 12.65 14.38 14.06 13.64 13.43 14.71 14.23 10.59 12.19 11.50 11.83 11.53 11.33 11.51 11.43 11.90 10.01 12.78 11.42 11.47 11.67 11.63 11.34 11.84 13.03
      L/H 10.52 11.35 11.32 10.94 10.79 11.66 11.58 9.42 10.45 9.82 10.16 10.11 9.90 9.93 9.92 10.67 9.21 10.68 10.04 9.88 9.95 9.93 9.91 10.1 10.91
      δEu 0.67 0.70 0.70 0.69 0.70 0.71 0.70 0.66 0.66 0.66 0.68 0.65 0.68 0.67 0.67 0.67 0.64 0.69 0.67 0.66 0.66 0.67 0.67 0.69 0.73
      注:主量元素单位为%;微量元素单位为10-6;稀土元素单位为10-6.
      下载: 导出CSV

      表  2  沙三段含云质泥岩主量元素氧化物与微量元素皮尔逊积矩相关系数

      Table  2.   Pearson correlation coefficient of major and trace element in Sha3 member dolomite-bearing mudstones

      Na2O MgO Al2O3 SiO2 P2O5 K2O CaO TiO2 MnO Fe2O3 FeO H2O+ H2O- LOI B Ga Rb Th U Ba Ni Sr V
      Na2O 1.00
      MgO 0.23 1.00
      Al2O3 -0.09 -0.78 1.00
      SiO2 -0.14 -0.86 0.91 1.00
      P2O5 0.09 0.16 -0.16 -0.38 1.00
      K2O -0.23 -0.69 0.85 0.85 -0.43 1.00
      CaO -0.04 0.60 -0.89 -0.84 0.23 -0.71 1.00
      TiO2 0.18 -0.60 0.89 0.82 -0.28 0.84 -0.82 1.00
      MnO -0.03 0.50 -0.77 -0.80 0.24 -0.75 0.79 -0.74 1.00
      Fe2O3 -0.56 -0.12 0.09 0.16 0.02 -0.05 -0.06 -0.18 -0.14 1.00
      FeO 0.28 0.32 -0.35 -0.58 0.46 -0.45 0.33 -0.27 0.64 -0.47 1.00
      H2O+ -0.05 0.03 -0.08 -0.07 0.17 -0.17 -0.16 -0.16 -0.01 -0.13 0.07 1.00
      H2O- -0.54 -0.77 0.61 0.64 -0.01 0.54 -0.32 0.41 -0.35 0.44 -0.31 -0.29 1.00
      LOI 0.06 0.85 -0.93 -0.94 0.26 -0.87 0.76 -0.88 0.72 -0.09 0.41 0.26 -0.71 1.00
      B -0.26 -0.38 0.62 0.56 -0.27 0.74 -0.52 0.55 -0.72 0.11 -0.44 -0.21 0.40 -0.56 1.00
      Ga 0.06 -0.43 0.74 0.62 -0.12 0.71 -0.62 0.70 -0.64 0.06 -0.29 -0.36 0.34 -0.72 0.68 1.00
      Rb -0.17 -0.49 0.58 0.65 -0.34 0.71 -0.45 0.54 -0.61 0.29 -0.54 -0.38 0.49 -0.67 0.64 0.74 1.00
      Th -0.05 -0.21 0.45 0.40 -0.18 0.53 -0.31 0.41 -0.41 0.18 -0.40 -0.47 0.20 -0.47 0.54 0.83 0.83 1.00
      U -0.30 0.50 -0.46 -0.41 0.07 -0.50 0.22 -0.63 0.21 0.41 -0.16 0.25 -0.40 0.61 -0.14 -0.33 -0.30 -0.11 1.00
      Ba 0.05 0.22 -0.19 -0.13 0.00 -0.18 -0.03 -0.22 -0.07 -0.06 -0.16 0.60 -0.41 0.31 -0.06 -0.18 -0.15 -0.11 0.30 1.00
      Ni -0.21 -0.47 0.54 0.52 0.06 0.38 -0.48 0.31 -0.64 0.50 -0.43 0.08 0.48 -0.48 0.44 0.31 0.30 0.08 -0.07 0.06 1.00
      Sr -0.26 0.67 -0.81 -0.77 0.33 -0.78 0.70 -0.90 0.62 0.25 0.11 0.24 -0.43 0.87 -0.46 -0.66 -0.56 -0.38 0.74 0.31 -0.27 1.00
      V -0.14 -0.28 0.34 0.22 0.16 0.33 -0.11 0.30 -0.21 0.13 0.11 -0.43 0.51 -0.41 0.32 0.52 0.31 0.27 -0.45 -0.22 0.33 -0.36 1.00
      下载: 导出CSV
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    • 收稿日期:  2015-04-15
    • 刊出日期:  2015-09-15

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