Characteristics and Metallogenic Significance of Melt-Fluid Inclusions of Shanshenfu Granite in the Hongyan Area, Inner Mongolia
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摘要: 通过内蒙古红彦镇地区山神府花岗岩的包裹体研究来探讨岩浆-热液过渡阶段的流体特征和成矿潜力.研究表明，山神府花岗岩包裹体类型可分为熔融包裹体、熔-流包裹体和流体包裹体3大类.熔-流包裹体的存在表明花岗岩经历岩浆-热液过渡阶段，而岩体中心相-边缘相流体包裹体均一温度从281 ℃变化到大于550 ℃，盐度从1.1% NaCl eqv变化到大于66.8% NaCl eqv同样指示了这一特征.根据不同温度、盐度包裹体等容线和水饱和花岗质岩浆固相线相交法可计算岩浆出溶流体温压范围，结合CO2三相包裹体对岩体最小侵位压力有较好限制，估算出山神府花岗岩最小侵位深度为7.6~9.5 km，出溶温度为580~700 ℃，出溶深度集中在6.0~14.9 km.包裹体拉曼特征表明，熔-流包裹体固相成分含有重晶石、蓝铜矿和赤铁矿等强氧化性物质，说明岩浆-热液体系具有高氧逸度，而在高温高压高盐条件下非常有利于岩浆中Cu等金属向出溶流体中富集，结合野外矿化蚀变特征，分析得出山神府地区具有较好寻找岩浆热液型Cu矿床的成矿潜力.Abstract: This study investigates the characteristics of the fluid and its mineralization potential in magmatic-hydrothermal phase by the inclusions study of the Shanshenfu granite located in the Hongyan area, Inner Mongolia. The study shows that the inclusions of the Shanshenfu granite can be divideddevided into three types includingof melt inclusions, melt-fluid inclusions and fluid inclusions. The presence of melt-fluid inclusions indicates that granitic magma has experiencedgot through magmatic-hydrothermal transition stage, which is confirmed by the large changes in homogenization temperatures (from 281 ℃ to > 550 ℃) and the salinities(from 1.1% NaCl eqv to > 66.8% NaCl eqv) from rock center lithofaciesphase to edge lithofaciesphase. We use inclusion isochors of different homogenization temperatures and salinitiesy together with water-saturated solidus of granitic magma to estimate the temperatures and pressures of exsolved fluids. Considering that the three-phase inclusions containing CO2 have a good limitation to the smallest emplacement pressure, we estimate that the smallest emplacement depth of Shanshenfu granite of range 7.6-9.5 km, exsolution temperature and depth of range 580-700 ℃ and 6.0-14.9 km, respectively. Laser-Raman characteristics of inclusions show that the solid phases of melt-fluid inclusions contain strong oxidation substances such as barite, azurite and hematite, which indicates the strong oxidation in magmatic-hydrothermal system that is very beneficial for Cu enriched in the exsolved fluids under the conditions of high-pressure, high-temperature and high-salinity. Combined with the wild in situ mineralized alteration characteristics, we conclude that the Shanshenfu area has good mineralization potential to form magmatic-hydrothermal deposit of Cu.
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图 1 红彦镇山神府地区地质简图
据陈俊等(2013)修编
Fig. 1. Sketch geological map of the Shanshenfu region in the Hongyan area
图 2 山神府碱长花岗岩野外及镜下特征
a.碱长花岗岩呈脉状侵入围岩中；b.钾长石绢云母化
Fig. 2. The wild and microscopic characteristics of Shanshenfu alkali feldspar granite
图 3 山神府碱长花岗岩石英中不同类型包裹体
a.岩体中心相结晶质熔融包裹体；b.岩体边缘相含两个气泡的玻璃质熔融包裹体(上)与富液相包裹体(下)共生；c.岩体中心相结晶质熔-流包裹体；d.岩体过渡相结晶质熔-流包裹体(上)与富液相包裹体(下)共生；e.岩体中心相含石盐子矿物包裹体；f.岩体过渡相含石盐和赤铁矿子矿物包裹体；g.岩体中心相含CO2三相包裹体；h.岩体过渡相纯液相包裹体(上)、富气包裹体(中)与富液包裹体(下)共生；i.岩体边缘相纯液相包裹体(左)、富液相包裹体(中)和纯气相包裹体(右)共生；L.液相；V.气相；S.结晶质；G.玻璃质；Hal.石盐；Hm.赤铁矿
Fig. 3. Different inclusion type in quartz from Shanshenfu alkali feldspar granite
图 4 山神府碱长花岗岩石英中熔-流包裹体和流体包裹体激光拉曼分析
Fig. 4. Laser-Raman spectrum of melt-fluid and fluid inclusions in quartz from Shanshenfu alkali feldspar granite
图 5 山神府碱长花岗岩中心相-边缘相流体包裹体均一温度直方图
a.中心相；b.过渡相；c.边缘相
Fig. 5. Histogram of homogenization temperature data of fluid inclusion from center phase to edge phase of Shanshenfu alkali feldspar granite
图 6 山神府碱长花岗岩中心相-边缘相流体包裹体T-ω-ρ相
底图据Bodar(1983)
Fig. 6. T-ω-ρ phase diagram of fluid inclusion from center phase to edge phase of Shanshenfu alkali feldspar granite
图 7 山神府碱长花岗岩流体包裹体+H2O饱和花岗岩质岩浆固相线法计算出溶流体温压条件
Fig. 7. Diagram of the method of fluid inclusion together with water-saturated solidus of granitic magma illustrating the temperature and pressure of exsolved fluid from Shanshenfu alkali feldspar granite
表 1 山神府碱长花岗岩中心相-边缘相流体包裹体特征及参数
Table 1. Characteristics and parameters of fluid iclusions from center phase to edge phase of Shanshenfu alkali feldspar granite
样号 类型 大小
(μm)气液比
(%)Φ(CO2)
(%)Φ(CO2)气
(%)测次 Tm(ice)
(℃)Tm(cla)
(℃)Ts
(℃)均一温度
(℃)盐度
(%NaCl eqv)密度
(g/cm3)压力(MPa) 深度(km) 方法一 方法二 方法一 方法二 Zx-1 Ⅲ-1 6~10 15~40 13 2.8~-20.5 369~＞550 4.6~25.6 0.6~0.8 150~325 5.5~11.8 Ⅲ-2 7~12 60~70 11 5.4~-19.3 357~＞551 8.4~26.2 0.6~0.9 150~355 5.5~12.9 Ⅲ-3 7~12 11 397~＞550 445~＞552 47.1~＞66.8 165~225 6.0~8.2 Zx-2 Ⅲ-4 6~10 35~90 20~50 4 6.6~8.1 350~400 3.7~6.4 0.47~0.68 210~260 7.6~9.5 Gd-1 Ⅲ-1 6~20 20~45 14 1.0~-15.1 310~512 1.7~18.7 0.57~0.83 160~490 5.8~17.8 Ⅲ-2 7~22 70~80 13 0.6~-17.4 315~414 1.1~20.5 0.65~0.87 165~500 6.0~18.2 Gd-2 Ⅲ-3 6~10 7 302~426 311~426 38.4~50.1 270~450 9.8~16.4 By-1 Ⅲ-1 6~16 20~40 15 1.5~-8.4 292~429 2.6~12.2 0.55~0.80 160~355 6.0~12.9 Ⅲ-2 8~20 70~80 13 1.3~-5.4 287~410 2.2~8.4 0.55~0.76 160~360 5.8~13.1 By-2 Ⅲ-3 6~10 9 285~456 281~464 37.1~54.0 240~580 8.9~21.1 注：Φ(CO2).CO2占包裹体总体积的百分数；Φ(CO2)气.气相CO2占CO2相总体积的百分数；Tm(ice).冰点温度；Tm(cla).CO2笼合物熔化温度；TS.子晶消失温度. 
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