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    洋中脊热液系统中的锇及其同位素

    黄威 陶春辉 李军 孙治雷 邓希光 崔汝勇

    黄威, 陶春辉, 李军, 孙治雷, 邓希光, 崔汝勇, 2016. 洋中脊热液系统中的锇及其同位素. 地球科学, 41(3): 441-451. doi: 10.3799/dqkx.2016.036
    引用本文: 黄威, 陶春辉, 李军, 孙治雷, 邓希光, 崔汝勇, 2016. 洋中脊热液系统中的锇及其同位素. 地球科学, 41(3): 441-451. doi: 10.3799/dqkx.2016.036
    Huang Wei, Tao Chunhui, Li jun, Sun Zhilei, Deng Xiguang, Cui Ruyong, 2016. Osmium Isotopic Compositions and Osmium Distribution in the Mid-Ocean Ridge Hydrothermal System. Earth Science, 41(3): 441-451. doi: 10.3799/dqkx.2016.036
    Citation: Huang Wei, Tao Chunhui, Li jun, Sun Zhilei, Deng Xiguang, Cui Ruyong, 2016. Osmium Isotopic Compositions and Osmium Distribution in the Mid-Ocean Ridge Hydrothermal System. Earth Science, 41(3): 441-451. doi: 10.3799/dqkx.2016.036

    洋中脊热液系统中的锇及其同位素

    doi: 10.3799/dqkx.2016.036
    基金项目: 

    中国科学院海洋地质与环境重点实验室开放基金 MGE2012KG06

    国土资源部海洋油气资源与环境地质重点实验室开放基金 MRE-201235

    国际海域资源调查与开发“十二五”课题 DY125-11-R-06

    国家自然科学基金项目 41506074

    国土资源部海底矿产资源重点实验室开放基金 KLMMR-2013-B-01

    详细信息
      作者简介:

      黄威(1981-),助理研究员,博士,从事现代海底热液系统的贵金属成矿作用研究. E-mail: qimg_huangwei@sina.com

      通讯作者:

      陶春辉, E-mail: taochunhuimail@163.com

    • 中图分类号: P736.4

    Osmium Isotopic Compositions and Osmium Distribution in the Mid-Ocean Ridge Hydrothermal System

    • 摘要: 洋中脊热液系统是将相对富集在深部的Os运移到海底表面的重要媒介,同时该过程也是全球Os循环的重要组成部分.在归纳总结洋中脊热液系统各物源组分和产物中Os的化学形态、含量及其同位素组成特征的基础上,探讨了Os在洋中脊热液活动各阶段中的分布演化规律及物源贡献特征.在缺乏沉积物覆盖的洋中脊区域,热液系统中的Os及其同位素组成特征主要受控于海水和不同构造环境下洋壳组分特征的差异以及这两种物源组分混合比例的不同.经历了海底之下的水岩反应后,围岩会将下渗海水中的部分放射性成因Os固定,而将自身富集的非放射性成因Os释放进入热液流体中.堆积在海底之上的各种热液产物中的Os大多来自海水,而海底之下的热液产物则因为海水下渗深度以及海水与热液流体混合程度的差异而体现出宽泛的Os含量和187Os/188Os比值变化范围.

       

    • 图  1  Os在洋中脊热液系统中的循环过程

      底图改编自美国国家海洋和大气管理局网站(http://oceanexplorer.noaa.gov/explorations/02fire/background/vent_chem/media/chemistry.html),圆括号中从左到右依次标注的是热液系统各端元和产物的Os同位素组成特征及Os含量的平均值(单位为10-12),方括号中标注的是其可能的组成形态,数据出处见下文

      Fig.  1.  The cycle process of Os in the mid-ocean ridge hydrothermal system

      图  2  高温和低温热液流体的Os含量的倒数与Os同位素组成之间的关系

      高温和低温热液流体数据引自Sharma et al.(2000, 2007);海水的数据引自Levasseur(1998)Woodhouse et al.(1999)Chen and Sharma(2009);洋壳的数据引自Peucker-Ehrenbrink et al.(2012)

      Fig.  2.  Os contents versus 187Os/188Os plots for the high temperature and low temperature fluids

      图  3  热液硫化物的Os含量与Os同位素组成之间的关系

      表层硫化物数据引自Ravizza et al.(1996)Zeng et al.(2014);深部硫化物数据引自Brügmann et al.(1998);海水的数据引自Levasseur(1998)Woodhouse et al.(1999)Chen and Sharma(2009);洋壳的数据引自Peucker-Ehrenbrink et al.(2012)

      Fig.  3.  Os concentrations versus 187Os/188Os plots for the hydrothermal massive sulfide

    • Alt, J.C., 1995.Subseafloor Processes in Mid-ocean Ridge Hydrothermal Systems.In:Humphris S.E., Zierenberg R.A., Mullineaux L.S., eds., Geophysical Monograph Series 91, Seafloor Hydrothermal Systems:Physical, Chemical, Biological, and Geological Interactions.American Geophysical Union, Washington D.C., 85-114.doi:10.1029/GM091p0085
      Alt, J.C., Teagle, D.A.H., 2003.Hydrothermal Alteration of Upper Oceanic Crust Formed at a Fast-Spreading Ridge:Mineral, Chemical, and Isotopic Evidence from ODP Site 801.Chemical Geology, 201(3-4):191-211.doi: 10.1016/s0009-2541(03)00201-8
      Baioumy, H.M., Eglinton, L.B., Peucker-Ehrenbrink, B., 2011.Rhenium-Osmium Isotope and Platinum Group Element Systematics of Marine Vs.Non-Marine Organic-Rich Sediments and Coals from Egypt.Chemical Geology, 285(1-4):70-81.doi: 10.1016/j.chemgeo.2011.02.026
      Baker, J.A., Jensen, K.K., 2004.Coupled 186Os-187Os Enrichments in the Earth s Mantle-Core-mantle Interaction or Recycling of Ferromanganese Crusts and Nodules?Earth and Planetary Science Letters, 220(3-4):277-286.doi: 10.1016/s0012-821x(04)00059-7
      Berglund, M., Wieser, M.E., 2011.Isotopic Compositions of the Elements 2009 (IUPAC Technical Report).Pure and Applied Chemistry, 83(2):397-410.doi: 10.1351/pac-rep-10-06-02
      Brügmann, G.E., Birck, J.L., Herzig, P.M., et al., 1998.Os Isotopic Composition and Os and Re Distribution in the Active Mound of the TAG Hydrothermal System, Mid-Atlantic Ridge.Proceedings of the Ocean Drilling Program, 92-100.doi: 10.2973/odp.proc.sr.158.209.1998
      Burton, K.W., Gannoun, A., Birck, J.L., et al., 2002.The Compatibility of Rhenium and Osmium in Natural Olivine and their Behaviour during Mantle Melting and Basalt Genesis.Earth and Planetary Science Letters, 198(1-2):63-76.doi: 10.1016/s0012-821x(02)00518-6
      Cave, R.R., German, C.R., Thomson, J., et al., 2002.Fluxes to Sediments Underlying the Rainbow Hydrothermal Plume at 36°14′N on the Mid-Atlantic Ridge.Geochimica et Cosmochimica Acta, 66(11):1905-1923.doi: 10.1016/s0016-7037(02)00823-2
      Cave, R.R., Ravizza, G.E., German, C.R., et al., 2003.Deposition of Osmium and other Platinum-Group Elements beneath the Ultramafic-Hosted Rainbow Hydrothermal Plume.Earth and Planetary Science Letters, 210(1-2):65-79.doi: 10.1016/s0012-821x(03)00135-3
      Chen, C., Sedwick, P.N., Sharma, M., 2009.Anthropogenic Osmium in Rain and Snow Reveals Global-Scale Atmospheric Contamination.Proceedings of the National Academy of Sciences, 106(19):7724-7728.doi: 10.1073/pnas.0811803106
      Chen, C., Sharma, M., 2009.High Precision and High Sensitivity Measurements of Osmium in Seawater.Analytical Chemistry, 81(13):5400-5406.doi: 10.1021/ac900600e
      Colodner, D., Sachs, J., Ravizza, G., et al., 1993.The Geochemical Cycle of Rhenium:A Reconnaissance.Earth and Planetary Science Letters, 117(1-2):205-221.doi: 10.1016/0012-821x(93)90127-u
      Dill, H.G., 2010.The "Chessboard" Classification Scheme of Mineral Deposits:Mineralogy and Geology from Aluminum to Zirconium.Earth-Science Reviews, 100(1-4):1-420.doi: 10.1016/j.earscirev.2009.10.011
      Escrig, S., Capmas, F., Dupré, B., et al., 2004.Osmium Isotopic Constraints on the Nature of the DUPAL Anomaly from Indian Mid-Ocean-Ridge Basalts.Nature, 431(7004):59-63.doi: 10.1038/nature02904
      Escrig, S., Schiano, P., Schilling, J.G., et al., 2005.Rhenium-osmium Isotope Systematics in MORB from the Southern Mid-Atlantic Ridge (40°-50° S).Earth and Planetary Science Letters, 235(3-4):528-548.doi: 10.1016/j.epsl.2005.04.035
      Gannoun, A., 2004.Osmium Isotope Heterogeneity in the Constituent Phases of Mid-Ocean Ridge Basalts.Science, 303(5654):70-72.doi: 10.1126/science.1090266
      Gannoun, A., Burton, K.W., Parkinson, I.J., et al., 2007.The Scale and Origin of the Osmium Isotope Variations in Mid-Ocean Ridge Basalts.Earth and Planetary Science Letters, 259(3-4):541-556.doi: 10.1016/j.epsl.2007.05.014
      Georg, R.B., West, A.J., Vance, D., et al., 2013.Is the Marine Osmium Isotope Record a Probe for CO2 Release from Sedimentary Rocks?Earth and Planetary Science Letters, 367:28-38.doi: 10.1016/j.epsl.2013.02.018
      German, C.R., Higgs, N.C., Thomson, J., et al., 1993.A Geochemical Study of Metalliferous Sediment from the TAG Hydrothermal Mound, 26°08′N, Mid-Atlantic Ridge.Journal of Geophysical Research, 98(B6):9683.doi: 10.1029/92jb01705
      German, C.R., Seyfried, W.E., 2014.Hydrothermal Processes.In:Holland, H., Turekian, K., eds., Treatise on Geochemistry (Second Edition).Elsevier, Oxford, 191-233.doi:10.1016/B978-0-08-095975-7.00607-0
      Hannington, M., Jamieson, J., Monecke, T., et al., 2011.The Abundance of Seafloor Massive Sulfide Deposits.Geology, 39(12):1155-1158.doi: 10.1130/g32468.1
      Helgeson, H.C., Kirkham, D.H., Flowers, G.C., 1981.Theoretical Prediction of the Thermodynamic Behavior of Aqueous Electrolytes at High Pressures and Temperatures:Ⅳ.Calculation of Activity Coefficients, Osmotic Coefficients, and Apparent Molal and Standard and Relative Partial Molal Properties to 600 ℃ and 5 kBar.American Journal of Science, 281:1249-1516.doi: 10.2475/ajs.281.10.1249
      Humphris, S.E., Herzig, P.M., Miller, D.J., et al., 1995.The Internal Structure of an Active Sea-Floor Massive Sulphide Deposit.Nature, 377(6551):713-716.doi: 10.1038/377713a0
      Koide, M., Hodge, V.F., Yang, J.S., et al., 1986.Some Comparative Marine Chemistries of Rhenium, Gold, Silver and Molybdenum.Applied Geochemistry, 1(6):705-714.doi: 10.1016/0883-2927(86)90092-2
      Koide, M., Goldberg, E.D., Niemeyer, S., et al., 1991.Osmium in Marine Sediments.Geochimica et Cosmochimica Acta, 55(6):1641-1648.doi: 10.1016/0016-7037(91)90135-r
      Lassiter, ,J..C, 2003.Rhenium Volatility in Subaerial Lavas:Constraints from Subaerial and Submarine Portions of the HSDP-2 Mauna Kea Drillcore.Earth and Planetary Science Letters, 214(1-2):311-325.doi: 10.1016/s0012-821x(03)00385-6
      Levasseur, S., 1998.Direct Measurement of Femtomoles of Osmium and the 187Os/186Os Ratio in Seawater.Science, 282(5387):272-274.doi: 10.1126/science.282.5387.272
      Li, J., Sun, Z.L., Huang, W., et al., 2014.Modern Seafloor Hydrothevinal Processes and Mineralization.Earth Science, 39(3):312-324 (in Chinese with English abstract).
      Mills, R., Elderfield, H., Thomson, J., 1993.A Dual Origin for the Hydrothermal Component in a Metalliferous Sediment Core from the Mid-Atlantic Ridge.Journal of Geophysical Research, 98(B6):9671.doi: 10.1029/92jb01414
      Pester, N.J., Rough, M., Ding, K., et al., 2011.A New Fe/Mn Geothermometer for Hydrothermal Systems:Implications for High-Salinity Fluids at 13°N on the East Pacific Rise.Geochimica et Cosmochimica Acta, 75(24):7881-7892.doi: 10.1016/j.gca.2011.08.043
      Peucker-Ehrenbrink, B., Ravizza, G., 2000.The Marine Osmium Isotope Record.Terra Nova, 12(5):205-219.doi: 10.1046/j.1365-3121.2000.00295.x
      Peucker-Ehrenbrink, B., Bach, W., Hart, S.R., et al., 2003.Rhenium-Osmium Isotope Systematics and Platinum Group Element Concentrations in Oceanic Crust from DSDP/ODP Sites 504 and 417/418.Geochemistry, Geophysics, Geosystems, 4(7):253.doi: 10.1029/2002gc000414
      Peucker-Ehrenbrink, B., Ravizza, G., 2012.Osmium Isotope Stratigraphy.In:Gradstein, F.M., Ogg, J.G., Schmitz, M.D., eds., The Geologic Time Scale.Elsevier, Boston, 145-166.doi:10.1016/B978-0-444-59425-9.00008-1
      Peucker-Ehrenbrink, B., Hanghoj, K., Atwood, T., et al., 2012.Rhenium-Osmium Isotope Systematics and Platinum Group Element Concentrations in Oceanic Crust.Geology, 40(3):199-202.doi: 10.1130/g32431.1
      Ravizza, G., McMurtry, G.M., 1993.Osmium Isotopic Variations in Metalliferous Sediments from the East Pacific Rise and the Bauer Basin.Geochimica et Cosmochimica Acta, 57(17):4301-4310.doi: 10.1016/0016-7037(93)90324-p
      Ravizza, G., Martin, C.E., German, C.R., et al., 1996.Os Isotopes as Tracers in Seafloor Hydrothermal Systems:Metalliferous Deposits from the TAG Hydrothermal Area, 26°N Mid-Atlantic Ridge.Earth and Planetary Science Letters, 138(1-4):105-119.doi: 10.1016/0012-821x(95)00216-y
      Ravizza, G., Blusztajn, J., Prichard, H.M., 2001.Re-Os Systematics and Platinum-Group Element Distribution in Metalliferous Sediments from the Troodos Ophiolite.Earth and Planetary Science Letters, 188(3-4):369-381.doi: 10.1016/s0012-821x(01)00337-5
      Reisberg, L., Rouxel, O., Ludden, J., et al., 2008.Re-Os Results from ODP Site 801:Evidence for Extensive Re Uptake during Alteration of Oceanic Crust.Chemical Geology, 248(3-4):256-271.doi: 10.1016/j.chemgeo.2007.07.013
      Rona, P.A., Scott, S.D., 1993.A Special Issue on Sea-Floor Hydrothermal Mineralization; New Perspectives; Preface.Economic Geology, 88(8):1935-1976.doi: 10.2113/gsecongeo.88.8.1935
      Rouxel, O., Dobbek, N., Ludden, J., et al., 2003.Iron Isotope Fractionation during Oceanic Crust Alteration.Chemical Geology, 202:155-182.doi: 10.1016/j.chemgeo.2003.08.011
      Roy-Barman, M., Allègre, C.J., 1994.187Os/186Os Ratios of Mid-ocean Ridge Basalts and Abyssal Peridotites.Geochimica et Cosmochimica Acta, 58(22):5043-5054.doi: 10.1016/0016-7037(94)90230-5
      Roy-Barman, M., Wasserburg, G.J., Papanastassiou, D.A., et al., 1998.Osmium Isotopic Compositions and Re-Os Concentrations in Sulfide Globules from Basaltic Glasses.Earth and Planetary Science Letters, 154(1-4):331-347.doi: 10.1016/s0012-821x(97)00180-5
      Seewald, J.S., Seyfried, W.E., 1990.The Effect of Temperature on Metal Mobility in Subseafloor Hydrothermal Systems:Constraints from Basalt Alteration Experiments.Earth and Planetary Science Letters, 101(2-4):388-403.doi: 10.1016/0012-821x(90)90168-w
      Seyfried, W.E., Shanks, W.C., 2004.Alteration and Mass Transport in Mid-ocean Ridge Hydrothermal Systems:Controls on the Chemical and Isotopic Evolution of High-temperature Crustal Fluids.In:Davis, E.E., Elderfield, H., eds., The Hydrogeology of the Oceanic Lithosphere.Cambridge University Press, Cambridge, 451-494.
      Sharma, M., Papanastassiou, D.A., Wasserburg, G.J., 1997.The Concentration and Isotopic Composition of Osmium in the Oceans.Geochimica et Cosmochimica Acta, 61(16):3287-3299.doi: 10.1016/s0016-7037(97)00210-x
      Sharma, M., Wasserburg, G.J., Hofmann, A.W., et al., 2000.Osmium Isotopes in Hydrothermal Fluids from the Juan de Fuca Ridge.Earth and Planetary Science Letters, 179(1):139-152.doi: 10.1016/s0012-821x(00)00099-6
      Sharma, M., Rosenberg, E.J., Butterfield, D.A., 2007.Search for the Proverbial Mantle Osmium Sources to the Oceans:Hydrothermal Alteration of Mid-Ocean Ridge Basalt.Geochimica et Cosmochimica Acta, 71(19):4655-4667.doi: 10.1016/j.gca.2007.06.062
      Sharma, M., 2011.Applications of Osmium and Iridium as Biogeochemical Tracers in the Environment.In:Baskaran, M., Handbook of Environmental Isotope Geochemistry, Advances in Isotope Geochemistry.Springer, Berlin, 205-227.doi:10.1007/978-3-642-10637-8_11
      Stein, H.J., Sundblad, K., Markey, R.J., et al., 1998.Re-Os Ages for Archean Molybdenite and Pyrite, Kuittila-Kivisuo, Finland and Proterozoic Molybdenite, Kabeliai, Lithuania:Testing the Chronometer in a Metamorphic and Metasomatic Setting.Mineralium Deposita, 33(4):329-345.doi: 10.1007/s001260050153
      Tivey, M., 2007.Generation of Seafloor Hydrothermal Vent Fluids and Associated Mineral Deposits.Oceanography, 20(1):50-65.doi: 10.5670/oceanog.2007.80
      Tolstoy, M., Waldhauser, F., Bohnenstiehl, D.R., et al., 2008.Seismic Identification of Along-Axis Hydrothermal Flow on the East Pacific Rise.Nature, 451(7175):181-184.doi: 10.1038/nature06424
      Woodhouse, O.B., Ravizza, G., Falkner, K.K., et al., 1999.Osmium in Seawater:Vertical Profiles of Concentration and Isotopic Composition in the Eastern Pacific Ocean.Earth and Planetary Science Letters, 173(3):223-233.doi: 10.1016/s0012-821x(99)00233-2
      Yamashita, Y., Takahashi, Y., Haba, H., et al., 2007.Comparison of Reductive Accumulation of Re and Os in Seawater-sediment Systems.Geochimica et Cosmochimica Acta, 71(14):3458-3475.doi: 10.1016/j.gca.2007.05.003
      Yang, A.Y., Zhao, T.P., Zhou, M.F., et al., 2013.Os Isotopic Compositions of MORBs from the Ultra-Slow Spreading Southwest Indian Ridge:Constraints on the Assimilation and Fractional Crystallization (AFC) Processes.Lithos, 179:28-35.doi: 10.1016/j.lithos.2013.07.020
      Zeng, Z.G., Chen, S., Selby, D., et al., 2014.Rhenium-osmium Abundance and Isotopic Compositions of Massive Sulfides from Modern Deep-Sea Hydrothermal Systems:Implications for Vent Associated Ore Forming Processes.Earth and Planetary Science Letters, 396:223-234.doi: 10.1016/j.epsl.2014.04.017
      Zierenberg, R.A., Fouquet, Y., Miller, D.J., et al., 1998.The Deep Structure of a Sea-floor Hydrothermal Deposit.Nature, 392:485-488.doi: 10.1038/33126
      李军, 孙治雷, 黄威, 等, 2014.现代海底热液过程及成矿.地球科学, 39(3): 312-324. http://earth-science.net/WebPage/Article.aspx?id=2841
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