Characteristics of Pyrite Sulfur Isotope of Mn Deposit from Datangpo Formation in Songtao Area, East Guizhou Province and Its Geological Significance
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摘要: 黔东松桃地区是我国重要的锰矿富集区，其中大塘坡组中黄铁矿δ34S存在比较大的差异.通过CF-IRSM法对松桃李家湾、道坨、西溪堡矿区菱锰矿样品中黄铁矿硫同位素组成开展研究，结果显示出两个明显的特征：(1) 样品中黄铁矿普遍具有极高的δ34S值，为47.69‰~66.76‰；(2) 在同一成锰盆地中，水深相对较浅的李家湾矿区黄铁矿δ34S值(47.69‰~59.15‰)明显低于水深相对较深的道坨矿区的δ34S值(53.85‰~62.86‰)，且中心相δ34S的值(53.85‰~66.76‰)明显高于过渡相δ34S的值(47.69‰~59.15‰)，黄铁矿硫同位素组成表现出明显的深度梯度效应.大塘坡组含锰层位黄铁矿异常高的δ34S值及其明显的深度梯度特征表明，在新元古代Sturtian冰期刚刚结束的间冰期初期，海水硫酸盐浓度极低，海洋呈现显著的分层现象，这一时期深部海洋可能并没有完全氧化.Abstract: Songtao area, East Guizhou Province, is an important area rich in manganese ore deposit, of which there are relatively big differences between pyrite δ34S values. This paper focuses on the sulfur isotope composition of pyrite from dialogite samples in Lijiawan, Daotuo and Xixibao areas in Songtao. CF-IRSM results indicate two obvious characteristics: (1) the pyrites mostly have extremely high δ34S values, which vary between 47.69‰-66.76‰; (2) the δ34S values of pyrites in shallow water Lijiawan area (47.69‰-59.15‰) are obviously lower than those in deep water Daotuo area (53.85‰-62.86‰) in the same basin, and the δ34S values of pyrites in central facies (53.85‰-66.76‰) are obviously higher than those in transition facies (47.69‰-59.15‰), the sulfur isotope compositions of pyrites have distinctive depth gradient effect. The extremely high δ34S values and distinctive depth gradient features of pyrites in Mn deposit in Datangpo Formation indicate that the ocean has extremely low sulfate concentration and obvious stratified phenomenon. The deep ocean has not been completely oxidized at the beginning of interglacial period after Neoproterozoic sturtian glaciation.
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Key words:
- Mn deposit /
- S isotope /
- Datangpo Formation /
- Songtao /
- stratigraphy
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图 2 岩心中锰矿层照片(a)和草莓状黄铁矿扫描电镜照片(b)
Fig. 2. Mn-deposit photo in the drill core (a) and SEM image showing pyrite framboids (b)
图 3 李家湾-道坨地区(a)和西溪堡地区(b)含锰岩系等厚线
Fig. 3. Isopachous of Mn-bearing series of Lijiawan-Daotuo area (a) and Xixibao area (b)
图 4 松桃地区李家湾、道坨、西溪堡矿区菱锰矿样品δ34S值分布
Fig. 4. Distribution of δ34S values of dialogite samples in Lijiawan, Daotuo and Xixibao area
图 5 贵州松桃地区中心相、过渡相菱锰矿样品δ34S值分布
Fig. 5. Distribution of δ34S values for dialogite samples of centre facies and transition facies in Songtao, Guozhou Province
图 6 华南大塘坡组黄铁矿硫同位素组成(δ34S值)频数分布
数据来源于Li et al.(1999); Chu et al.(2003); Liu et al.(2006); Chen et al.(2008); Feng et al.(2010); Li et al.(2012)以及张飞飞等(2013c)
Fig. 6. Frequency distribution of sulfur isotopic composition (δ34S values) of pyrites from Datangpo Formation in Huanan area
表 1 李家湾、道坨、西溪堡矿区菱锰矿样品硫同位素测试结果
Table 1. Sulfur isotope analytical results for dialogite samples in Lijiawan, Daotuo and Xixibao area
采样地区 样品编号 钻孔号 δ34S(‰) 相带 李家湾 py-5 ZK807 47.69 过渡相 李家湾 py-7 ZK607 49.40 过渡相 李家湾 py-11 ZK209 57.72 中心相 李家湾 py-15 ZK107 59.15 过渡相 李家湾 py-16 ZK107 52.29 过渡相 李家湾 py-17 ZK107 51.81 过渡相 道坨 py-22 ZK303 57.75 中心相 道坨 py-23 ZK303 62.00 中心相 道坨 py-26 ZK308 61.07 中心相 道坨 py-27 ZK308 59.88 中心相 道坨 py-36 ZK306 56.71 中心相 道坨 py-48 ZK310 53.85 中心相 道坨 py-49 ZK310 59.22 中心相 道坨 py-51 ZK310 58.68 中心相 道坨 py-52 ZK310 62.34 中心相 道坨 py-53 ZK310 61.21 中心相 道坨 py-54 ZK310 62.86 中心相 西溪堡 py-39 ZK1003 59.25 中心相 西溪堡 py-42 ZK1010 55.53 中心相 西溪堡 py-43 ZK1010 66.76 中心相 西溪堡 py-44 ZK1010 59.83 中心相 西溪堡 py-45 ZK1010 56.62 中心相 
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Allen, P.A., Hoffman, P.F., 2005.Extreme Winds and Waves in the Aftermath of a Neoproterozoic Glaciation.Nature, 433(7022):123-127.doi: 10.1038/nature03176 Anbar, A.D., Knoll, A.H., 2002.Proterozoic Ocean Chemistry and Evolution:A Bioinorganic Bridge?Science, 297(5584):1137-1142.doi: 10.1126/science.1069651 Bottomley, D.J., Veizer, J., Nielsen, H., et al., 1992.Isotopic Composition of Disseminated Sulfur in Precambrian Sedimentary Rocks.Geochimica et Cosmochimica Acta, 56(8):3311-3322.doi: 10.1016/0016-7037(92)90307-5 Canfield, D.E., Farquhar, J., 2009.Animal Evolution, Bioturbation, and the Sulfate Concentration of the Oceans.Proceedings of the National Academy of Sciences, 106(20):8123-8127.doi: 10.1073/pnas.0902037106 Canfield, D.E., Poulton, S.W., Knoll, A.H., et al., 2008.Ferruginous Conditions Dominated Later Neoproterozoic Deep-Water Chemistry.Science, 321(5891):949-952.doi: 10.1126/science.1154499 Canfield, D.E., Poulton, S.W., Narbonne, G.M., 2007.Late-Neoproterozoic Deep-Ocean Oxygenation and the Rise of Animal Life.Science, 315(5808):92-95.doi: 10.1126/science.1135013 Canfield, D.E., Teske, A., 1996.Late Proterozoic Rise in Atmospheric Oxygen Concentration Inferred from Phylogenetic and Sulphur-Isotope Studies.Nature, 382(6587):127-132.doi: 10.1038/382127a0 Chen, X., Li, D., Ling, H.F., et al., 2008.Carbon and Sulfur Isotopic Compositions of Basal Datangpo Formation, Northeastern Guizhou, South China:Implications for Depositional Environment.Progress in Natural Science, 18(4):421-429.doi: 10.1016/j.pnsc.2007.10.008 Chu, X.L., Li, R.W., Zhang, T.G., et al., 2001.Implication of Ultra-high δ34S Values of Pyrite in Manganese Mineralization Beds of Datangpo Stage.Bulletin of Mineralogy, Petrology and Geochemistry, 20(4):320-322(in Chinese with English abstract). Chu, X.L., Zhang, Q.R., Zhang, T.G., et al., 2003.Sulfur and Carbon Isotopic Variations in Neoproterozoic Sedimentary Rocks from Southern China.Progress in Natural Science, 13(11):875-880.doi: 10.1080/10020070312331344580 Dalziel, I.W.D., 1991.Pacific Margins of Laurentia and East Antarctica-Australia as a Conjugate Rift Pair:Evidence and Implications for an Eocambrian Supercontinent.Geology, 19(6):598.doi:10.1130/0091-7613(1991)019<0598:pmolae>2.3.co;2 Evans, D.A.D., Li, Z.X., Kirschvink, J.L., et al., 2000.A High-Quality Mid-Neoproterozoic Paleomagnetic Pole from South China, with Implications for Ice Ages and the Breakup Configuration of Rodinia.Precambrian Research, 100(1-3):313-334.doi: 10.1016/s0301-9268(99)00079-0 Feng, L.J., Chu, X.L., Huang, J., et al., 2010.Reconstruction of Paleo-Redox Conditions and Early Sulfur Cycling during Deposition of the Cryogenian Datangpo Formation in South China.Gondwana Research, 18(4):632-637.doi: 10.1016/j.gr.2010.02.011 Gorjan, P., Veevers, J.J., Walter, M.R., 2000.Neoproterozoic Sulfur-Isotope Variation in Australia and Global Implications.Precambrian Research, 100(1-3):151-179.doi: 10.1016/s0301-9268(99)00073-x Gorjan, P., Walter, M.R., Swart, R., 2003.Global Neoproterozoic (Sturtian) Post-Glacial Sulfide-Sulfur Isotope Anomaly Recognised in Namibia.Journal of African Earth Sciences, 36(1-2):89-98.doi: 10.1016/s0899-5362(03)00002-2 Hayes, J.M., Lambert, I.B., Strauss, H., 1992.The Sulfur-Isotopic Record.In: Schopf, J.W., Klein, C., eds., The Proterozoic Biosphere:A Multidisciplinary Study.Cambridge University Press, Cambridge, 129-132. Hoffman, P.F., 1991.Did the Breakout of Laurentia Turn Gondwanaland Inside-Out?Science, 252(5011):1409-1412.doi: 10.1126/science.252.5011.1409 Hoffman, P.F., Kaufman, A.J., Halverson, G.P., et al., 1998.A Neoproterozoic Snowball Earth.Science, 281(5381):1342-1346. doi: 10.1126/science.281.5381.1342 Hoffman, P.F., Schrag, D.P., 2002.The Snowball Earth Hypothesis:Testing the Limits of Global Change.Terra Nova, 14(3):129-155.doi: 10.1046/j.1365-3121.2002.00408.x Hoffmann, K.H., Condon, D.J., Bowring, S.A., et al., 2004.U-Pb Zircon Date from the Neoproterozoic Ghaub Formation, Namibia:Constraints on Marinoan Glaciation.Geology, 32(9):817.doi: 10.1130/g20519.1 Hurtgen, M.T., Arthur, M.A., Halverson, G.P., 2005.Neoproterozoic Sulfur Isotopes, the Evolution of Microbial Sulfur Species, and the Burial Efficiency of Sulfide as Sedimentary Pyrite.Geology, 33(1):41.doi: 10.1130/g20923.1 Hurtgen, M.T., Arthur, M.A., Suits, N.S., et al., 2002.The Sulfur Isotopic Composition of Neoproterozoic Seawater Sulfate: Implications for a Snowball Earth?Earth and Planetary Science Letters, 203(1):413-429.doi: 10.1016/s0012-821x(02)00804-x Kasemann, S.A., Hawkesworth, C.J., Prave, A.R., et al., 2005.Boron and Calcium Isotope Composition in Neoproterozoic Carbonate Rocks from Namibia:Evidence for Extreme Environmental Change.Earth and Planetary Science Letters, 231(1-2):73-86.doi: 10.1016/j.epsl.2004.12.006 Kirschvink, J.L., 1992.Late Proterozoic Low-Latitude Global Glaciation:The Snowball Earth.In:Schopf, J.W., Klein, C., des Maris, D., eds., The Proterozoic Biosphere: A Multidisciplinary Study.Cambrige University Press, New York, 51-52. Lan, Z., Li, X., Zhu, M., et al., 2014.A Rapid and Synchronous Initiation of the Wide Spread Cryogenian Glaciations.Precambrian Research, 255(1):401-411. https://www.researchgate.net/profile/Qi-Rui_Zhang/publication/267455844_A_rapid_and_synchronous_initiation_of_the_wide_spread_Cryogenian_glaciations/links/546e89100cf2b5fc17607935.pdf?inViewer=true&disableCoverPage=true&origin=publication_detail Li, C., Love, G.D., Lyons, T.W., et al., 2012.Evidence for a Redox Stratified Cryogenian Marine Basin, Datangpo Formation, South China.Earth and Planetary Science Letters, 331:246-256.doi: 10.1016/j.epsl.2012.03.018 Li, R.W., Chen, J., Zhang, S., et al., 1999.Spatial and Temporal Variations in Carbon and Sulfur Isotopic Compositions of Sinian Sedimentary Rocks in the Yangtze Platform, South China.Precambrian Research, 97(1-2):59-75.doi: 10.1016/s0301-9268(99)00022-4 Li, R.W., Zhang, S.K., Lei, J.J., et al., 1996.Temporal and Spatial Variation in δ34S Values of Pyrite from Sinian Strata:Discussion on Relationship between Yangtze Block and the Late Proterozoic Supercontinent.Scientia Geologica Sinica, 31(3):209-217(in Chinese with English abstract). Liu, T.B., Maynard, J.B., Alten, J., 2006.Superheavy S Isotopes from Glacier-Associated Sediments of the Neoproterozoic of South China:Oceanic Anoxia or Sulfate Limitation?Geological Society of America Memoir, 198:205-222.doi: 10.1130/2006.1198(12) Liu, X.F., Wang, Q.S., Gao, X.J., 1989.Manganese Deposits of Guizhou, China.Guizhou People's Press, Guiyang (in Chinese). Logan, G.A., Hayes, J.M., Hieshima, G.B., et al., 1995.Terminal Proterozoic Reorganization of Biogeochemical Cycles.Nature, 376(6535):53-56.doi: 10.1038/376053a0 Macdonald, F.A., Schmitz, M.D., Crowley, J.L., et al., 2010.Calibrating the Cryogenian.Science, 327(5970):1241-1243.doi: 10.1126/science.1183325 Moores, E.M., 1991.Southwest U.S.-East Antarctic (SWEAT) Connection:A Hypothesis.Geology, 19(5):425.doi:10.1130/0091-7613(1991)019<0425:suseas>2.3.co;2 Qin, Y., Zhou, Q., Zhang, S., 2005.Elementary Properties of Manganese of Nh in the Northeastern Guizhou.Guizhou Geology, 22(4):246-251(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-GZDZ200504005.htm Ries, J.B., Fike, D.A., Pratt, L.M., et al., 2009.Superheavy Pyrite (δ34Spyr>δ34SCAS) in the Terminal Proterozoic Nama Group, Southern Namibia:A Consequence of Low Seawater Sulfate at the Dawn of Animal Life.Geology, 37(8):743-746. doi: 10.1130/G25775A.1 Schmidt, P.W., Williams, G.E., 1995.The Neoproterozoic Climatic Paradox:Equatorial Palaeolatitude for Marinoan Glaciation near Sea Level in South Australia.Earth and Planetary Science Letters, 134(1-2):107-124.doi: 10.1016/0012-821x(95)00106-m Shen, B., Xiao, S.H., Kaufman, A.J., et al., 2008.Stratification and Mixing of a Post-Glacial Neoproterozoic Ocean:Evidence from Carbon and Sulfur Isotopes in a Cap Dolostone from Northwest China.Earth and Planetary Science Letters, 265(1-2):209-228.doi: 10.1016/j.epsl.2007.10.005 Shen, Y., Knoll, A.H., Walter, M.R., 2003.Evidence for Low Sulphate and Anoxia in a Mid-Proterozoic Marine Basin.Nature, 423(6940):632-635.doi: 10.1038/nature01651 Sohl, L.E., Christie-Blick, N., Kent, D.V., 1999.Paleomagnetic Polarity Reversals in Marinoan (ca.600 Ma) Glacial Deposits of Australia:Implications for the Duration of Low-Latitude Glaciation in Neoproterozoic Time.Geological Society of America Bulletin, 111(8):1120-1139.doi:10.1130/0016-7606(1999)111<1120:pprimc>2.3.co;2 Strauss, H., Bengtson, S., Myrow, P.M., et al., 1992.Stable Isotope Geochemistry and Palynology of the Late Precambrian to Early Cambrian Sequence in Newfoundland.Canadian Journal of Earth Sciences, 29(8):1662-1673.doi: 10.1139/e92-131 Tang, S.Y., 1990.Isotope Geological Study of Manganese Deposit in Minle Area, Hunan Province.Acta Sedimentologica Sinica, 8(4):77-84(in Chinese with English abstract). https://www.researchgate.net/publication/282724648_The_mineralization_geological_characteristics_and_genesis_of_Minle_type_manganese_deposits_in_northwestern_of_Hunan_Province Trindade, R.I.F., Macouin, M., 2007.Palaeolatitude of Glacial Deposits and Palaeogeography of Neoproterozoic Ice Ages.Comptes Rendus Geoscience, 339(3-4):200-211.doi: 10.1016/j.crte.2007.02.006 Walter, M.R., Veevers, J.J., Calver, C.R., et al., 1995.Neoproterozoic Stratigraphy of the Centralian Superbasin, Australia.Precambrian Research, 73(1):173-195.doi: 10.1016/0301-9268(94)00077-5 Wang, J., 2000.Neoproterozoic Rifting History of South China:Significance to Rodinia Breakup.Geological Publishing House, Beijing (in Chinese). Wang, Y.G., Wang, L.X., Zhu, S.C., 1985.Sedimentary Environment and the Formation of Manganese Deposits of Datangpo Formation in Eastern Guizhou Province.Guizhou People's Press, Guiyang (in Chinese). Xiang, W.Q., Xiao, Y.K., 2013.Geological Characteristics and Metallogenic Regularity for Nanhuan Datangpo Manganese Deposits from Tongren-Songtao Region.Journal of Southwest University of Science and Technology, 28(4):31-38(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-XNGX201304006.htm Ye, L.J., et al., 1998.Mineralization and Its Background of Organic Matter.China Ocean Press, Beijing (in Chinese). Yu, W.C., Du, Y.S., Zhou, Q., et al., 2016.Provenance of Nanhuan Datangpo Formation Manganese Mn Deposit in Songtao Area, East Guizhou Province:Evidence from Sr Isotope.Earth Science, 41(7):1110-1120(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-DQKX201607003.htm Zhang, F.F., Peng, Q.Y., Zhu, X.K., et al., 2013a.Fe Isotope Characteristics of the Gucheng Manganese Ore Deposits in Hubei Province and Its Geological Implication.Acta Geologica Sinica, 87(9):1411-1418(in Chinese with English abstract). https://www.researchgate.net/publication/273766720_Fe_isotope_Characteristics_of_the_Gucheng_Manganese_Ore_Deposits_in_Hubei_Province_and_Its_Geological_Implication Zhang, F.F., Yan, B., Guo, Y.L., et al., 2013b.Precipitation Form of Manganese Ore Deposits in Gucheng, Hubei Province, and Its Paleoenvironment Implication.Acta Geologica Sinica, 87(2):245-258(in Chinese with English abstract). https://www.researchgate.net/publication/277583814_Precipitation_Form_of_Manganese_Ore_Deposits_in_Gucheng_Hubei_Province_and_Its_Paleoenvironment_Implication Zhang, F.F., Zhu, X.K., Gao, Z.F., et al., 2013c.Implication of the Precipitation Mode of Manganese and Ultra-High δ34S Values of Pyrite in Mn-Carbonate of Xixibao Mn Ore Deposit in Northeastern Guizhou Province.Geological Review, 59(2):274-286(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZLP201302012.htm Zhang, F.F., Zhu, X.K., Yan, B., et al., 2015.Oxygenation of a Cryogenian Ocean (Nanhua Basin, South China) Revealed by Pyrite Fe Isotope Compositions.Earth and Planetary Science Letters, 429(3-4):11-19.doi: 10.1016/j.epsl.2015.07.021 Zhang, S.H., Jiang, G.Q., Han, Y.G., 2008.The Age of the Nantuo Formation and Nantuo Glaciation in South China.Terra Nova, 20(4):289-294.doi: 10.1111/j.1365-3121.2008.00819.x Zhao, H.Y., Gong, A.R., Yin, H., et al., 2014.Substructural Transformation of Birnessite and Formation of Todorokite in Simulated Surface Environment.Earth Science, 39(2):227-239(in Chinese with English abstract). https://www.researchgate.net/publication/287262499_Substructural_transformation_of_birnessite_and_formation_of_todorokite_in_simulated_surface_environment Zhou, Q., 2008.Geological and Geochemical Characteristics of Cold Seep Carbonates of Neoproterozoic Nanhua Period and Their Significance for Manganese Ore Deposits in East Guizhou (Dissertation).China University of Geosciences, Wuhan (in Chinese with English abstract). Zhou, Q., Du, Y.S., 2012.Ancient Natural Gas Seepage and the Formation of Manganese Deposits-Taking the Datangpo-Type Manganese Deposit of Nanhua Period in East of Guizhou as an Example.Geological Publishing House, Beijing (in Chinese). Zhou, Q., Du, Y.S., Qin, Y., 2013.Ancient Natural Gas Seepage Sedimentary-Type Manganese Metallogenic System and Ore-Forming Model:A Case Study of 'Datangpo Type' Manganese Deposits Formed in Rift Basin of Nanhua Period along Guizhou-Hunan-Chongqing Border Area.Mineral Deposits, 32(3):457-466(in Chinese with English abstract). http://www.sciencedirect.com/science/article/pii/S0301926816302339 Zhou, Q., Du, Y.S., Wang, J.S., 2007a.Characteristics and Significance of the Cold Seep Carbonates from the Datangpo Formation of the Nanhua Series in the Northeast Guizhou.Earth Science, 32(3):339-346(in Chinese with English abstract). https://www.researchgate.net/publication/286944859_Characteristics_and_significance_of_the_cold_seep_carbonates_from_the_Datangpo_Formation_of_the_Nanhua_Series_in_the_Northeast_Guizhou Zhou, Q., Du, Y.S., Yan, J.X., et al., 2007b.Geological and Geochemical Characteristics of the Cold Seep Carbonates in the Early Nanhua System in Datangpo, Songtao, Guizhou Province.Earth Science, 32(6):845-852(in Chinese with English abstract). https://www.researchgate.net/publication/289986514_Geological_and_geochemical_characteristics_of_the_cold_seep_carbonates_in_the_early_Nanhua_system_in_Datangpo_Songtao_Guizhou_Province Zhou, Q., Du, Y.S., Yuan, L.J..et al., 2016.Provenance of Nanhuan Datangpo Formation Manganese Mn Deposit in Songtao Area, East Guizhou Provinle:Evidence from Sr Isotope.Earth Science, 41(2):177-188(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-DQKX201607003.htm 储雪蕾, 李任伟, 张同钢, 等, 2001.大塘坡期锰矿层中黄铁矿异常高的δ34S值的意义.矿物岩石地球化学通, 20(4): 320-322. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=kydh200104031&dbname=CJFD&dbcode=CJFQ 李任伟, 张淑坤, 雷加锦, 等, 1996.震旦纪地层黄铁矿硫同位素组成时-空变化特征及扬子地块与晚元古超大陆关系的论证.地质科学, 31(3): 209-217. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKX603.000.htm 刘巽锋, 王庆生, 高兴基, 1989.贵州锰矿地质.贵阳:贵州人民出版社. 覃英, 周琦, 张遂.2005.黔东北地区南华纪锰矿基本特征.贵州地质, 22(4): 246-251. http://www.cnki.com.cn/Article/CJFDTOTAL-YSJW201603020.htm 唐世瑜.1990.湖南花垣民乐震旦系锰矿床同位素地质研究.沉积学报, 8(4): 77-84. http://www.cnki.com.cn/Article/CJFDTOTAL-CJXB199004008.htm 王剑, 2000.华南新元古代裂谷盆地演化--兼论与Rodinia解体的关系.北京:地质出版社. 王砚耕, 王来兴, 朱顺才, 1985.贵州东部大塘坡组地层沉积环境和成锰作用.贵阳:贵州人民出版社. 向文勤, 肖永开, 2013.铜仁-松桃地区南华系大塘坡式锰矿地质特征及成矿规律探讨.西南科技大学学报, 28(4): 31-38. http://www.cnki.com.cn/Article/CJFDTOTAL-XNGX201304006.htm 叶连俊, 等, 1998.生物有机质成矿作用和成矿背景.北京:海洋出版社. 余文超, 杜远生, 周琦, 等, 2016.黔东松桃南华系大塘坡组锰矿层物源:来自Sr同位素的证据.地球科学, 41(7): 1110-1120. http://earth-science.net/WebPage/Article.aspx?id=3322 张飞飞, 彭乾云, 朱祥坤, 等, 2013a.湖北古城锰矿Fe同位素特征及其古环境意义.地质学报, 87(9): 1411-1418. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201309017.htm 张飞飞, 闫斌, 郭跃玲, 等, 2013b.湖北古城锰矿的沉淀形式及其古环境意义.地质学报, 87(2): 245-258. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201302011.htm 张飞飞, 朱祥坤, 高兆富, 等, 2013c.黔东北西溪堡锰矿的沉淀形式与含锰层位中黄铁矿异常高δ34S值的成因.地质论评, 59(2): 274-286. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=dzlp201302012&dbname=CJFD&dbcode=CJFQ 赵怀燕, 龚爱蓉, 殷辉, 等, 2014.模拟表生环境水钠锰矿亚结构转化及钙锰矿的形成.地球科学, 39(2): 227-239. doi: 10.11867/j.issn.1001-8166.2014.02-0227 周琦, 2008. 黔东新元古代南华纪早期冷泉碳酸盐岩地质地球化学特征及其对锰矿的控矿意义(博士学位论文). 武汉: 中国地质大学. http://cdmd.cnki.com.cn/Article/CDMD-10491-2008095605.htm 周琦, 杜远生, 2012.古天然气渗漏与锰矿成矿--以黔东地区南华纪"大塘坡式"锰矿为例.北京:地质出版社. 周琦, 杜远生, 覃英, 2013.古天然气渗漏沉积型锰矿床成矿系统与成矿模式--以黔湘渝毗邻区南华纪"大塘坡式"锰矿为例.矿床地质, 32(3): 457-466. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201303001.htm 周琦, 杜远生, 颜佳新, 等, 2007a.贵州松桃大塘坡地区南华纪早期冷泉碳酸盐岩地质地球化学特征.地球科学, 32(6): 845-852. http://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200706016.htm 周琦, 杜远生, 王家生, 等, 2007b.黔东北地区南华系大塘坡组冷泉碳酸盐岩及其意义.地球科学, 32(3): 339-346. http://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200703005.htm 周琦, 杜远生, 袁良军, 等, 2016.黔湘渝毗邻区南华纪武陵裂谷盆地结构及其对锰矿的控制作用.地球科学, 41(2): 177-188. http://earth-science.net/WebPage/qk.aspx?id=146 -
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