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    东昆仑马尼特地区片麻状花岗闪长岩锆石U-Pb年代学、地球化学及其构造背景

    赵菲菲 孙丰月 刘金龙

    赵菲菲, 孙丰月, 刘金龙, 2017. 东昆仑马尼特地区片麻状花岗闪长岩锆石U-Pb年代学、地球化学及其构造背景. 地球科学, 42(6): 927-940. doi: 10.3799/dqkx.2017.073
    引用本文: 赵菲菲, 孙丰月, 刘金龙, 2017. 东昆仑马尼特地区片麻状花岗闪长岩锆石U-Pb年代学、地球化学及其构造背景. 地球科学, 42(6): 927-940. doi: 10.3799/dqkx.2017.073
    Zhao Feifei, Sun Fengyue, Liu Jinlong, 2017. Zircon U-Pb Geochronology and Geochemistry of the Gneissic Granodiorite in Manite Area from East Kunlun, with Implications for Geodynamic Setting. Earth Science, 42(6): 927-940. doi: 10.3799/dqkx.2017.073
    Citation: Zhao Feifei, Sun Fengyue, Liu Jinlong, 2017. Zircon U-Pb Geochronology and Geochemistry of the Gneissic Granodiorite in Manite Area from East Kunlun, with Implications for Geodynamic Setting. Earth Science, 42(6): 927-940. doi: 10.3799/dqkx.2017.073

    东昆仑马尼特地区片麻状花岗闪长岩锆石U-Pb年代学、地球化学及其构造背景

    doi: 10.3799/dqkx.2017.073
    基金项目: 

    中国地质调查局地质大调查项目 12120111086020

    详细信息
      作者简介:

      赵菲菲(1982-),男,博士研究生,主要从事矿床学研究.ORCID:0000-0003-4133-6718.E-mail:terry__xp@163.com

      通讯作者:

      孙丰月,E-mail:sfy@jlu.edu.cn

    • 中图分类号: P581

    Zircon U-Pb Geochronology and Geochemistry of the Gneissic Granodiorite in Manite Area from East Kunlun, with Implications for Geodynamic Setting

    • 摘要: 为确定东昆仑马尼特地区片麻状花岗闪长岩的形成时代、源区性质和构造背景,对其进行了锆石U-Pb年代学、地球化学和锆石Hf同位素研究.本次测试的片麻状花岗闪长岩锆石LA-ICP-MS(laser ablation inductively coupled plasma mass spectrometry) U-Pb加权平均年龄为495.6±1.1 Ma(MSWD=0.13),属于晚寒武世.马尼特片麻状花岗闪长岩SiO2含量为61.47%~63.99%,Na2O、K2O和CaO含量分别为2.91%~3.64%、0.93%~2.31%和4.29%~6.52%,全碱ALK=3.92%~5.69%,铝饱和指数A/CNK=0.83~0.97,属准铝质钙碱性系列岩石.岩石具有富集大离子亲石元素(Rb、K)和不相容元素(Th、U),相对亏损Nb、Ta、Zr、Ti高场强元素的特征,Nb/Ta、La/Nb、Th/Nb、Th/La等比值显示出岩石具有壳源特征.岩石具有高的εHf(t)值(12.2~15.0),Hf两阶段模式年龄在506~662 Ma范围内,其岩浆源区初始物质主要来源于新生地壳.岩石在微量元素Rb-(Y+Nb)构造判别图落入火山弧花岗岩区域,在R1-R2构造判别图落入板块碰撞前消减区花岗岩区域.结合岩石成岩年龄、地球化学特征以及区域构造演化,推测其应形成于原特提斯洋俯冲的构造环境,属于大洋洋壳向南俯冲的产物,即柴达木地块和万宝沟大洋玄武岩高原之间的洋壳同时向南、北发生双向俯冲消减.

       

    • 图  1  马尼特地区地质简图

      1.第四系;2.中二叠世马尔争组板岩、千枚岩;3.中二叠世马尔争组砂岩、砾岩;4.华力西期花岗闪长岩;5.华力西期闪长玢岩脉;6.片麻状花岗闪长岩;7.正断层/逆断层;8.构造蚀变破碎带;9.研究区位置;10.岩体位置及取样位置;据青海省第三地质矿产勘查院,2013.青海省都兰县马尼特地区金矿普查2012年工作总结及2013年工作安排.青海

      Fig.  1.  The sketch geological map of the Manite area

      图  2  马尼特片麻状花岗闪长岩显微照片

      a.片麻状花岗闪长岩中定向的角闪石(单偏光);b.片麻状花岗闪长岩中角闪石的简单双晶及闪石式解理、石英、斜长石的聚片双晶(正交偏光).矿物代号缩写:Qtz.石英,Pl.斜长石,Hbl.角闪石,Al.碱性长石

      Fig.  2.  The micrographs of the Manite gneissic granodiorite

      图  3  马尼特片麻状花岗闪长岩锆石阴极发光图像

      Fig.  3.  Cathodoluminescence images of analyzed zircons of the Manite gneissic granodiorite

      图  4  马尼特片麻状花岗闪长岩锆石U-Pb年龄谐和图

      Fig.  4.  U-Pb concordia ages of the Manite gneissic granodiorite

      图  5  马尼特片麻状花岗闪长岩TAS、SiO2-K2O和A/CNK-A/NK

      a.据Irvine and Baragar(1971);b.据Peccerillo and Taylor(1976);c.据Maniar and Piccoli(1989)

      Fig.  5.  Total alkali versus SiO2, SiO2 versus K2O and A/CNK versus A/NK diagrams for the Manite gneissic granodiorite

      图  6  马尼特片麻状花岗闪长岩稀土元素配分模式和微量元素蛛网图

      a.球粒陨石值据Boynton(1984);b.原始地幔值据Sun and McDonough(1989)

      Fig.  6.  Chondrite-normalized REE patterns and primitive mantle-normalized trace element patterns for the Manite gneissic granodiorite

      图  7  马尼特片麻状花岗闪长岩锆石的εHf(t)-t图解

      Yang et al.(2006)

      Fig.  7.  εHf(t) versus t diagram of the Manite gneissic granodiorite

      图  8  马尼特片麻状闪长岩构造环境判别图解

      a.据Harris et al.(1986);b.据Pearce(1996)

      Fig.  8.  Tectonic setting discrimination diagrams of the Manite gneissic granodiorite

      图  9  柴达木地块和万宝沟大洋玄武岩高原之间的洋壳同时向南、北发生双向俯冲消减

      Sun et al.(2003)

      Fig.  9.  The crust between the Qaidam massif and Wanbaogou oceanic plateau occurred bidirectional subduction to the south and the north

      表  1  马尼特片麻状花岗闪长岩锆石LA-MC-ICP-MS U-Pb同位素定年数据

      Table  1.   LA-MC-ICP-MS zircon U-Pb isotope dating results of the Manite gneissic granodiorite

      测点号 质量百分含量(10-6) Th/U 同位素比率 同位素年龄(Ma)
      PbThU 207Pb/206Pb1σ207Pb/235U1σ206Pb/238U207Pb/206Pb1σ207Pb/235U1σ206Pb/238U1σ
      MNT-N4-143.992.12750.330.056 80.002 00.626 60.021 30.079 50.000 848381494134935
      MNT-N4-288.1196.05150.380.056 70.003 20.633 20.032 50.080 30.001 0480131498204986
      MNT-N4-339.879.92760.290.057 10.001 80.622 90.019 20.079 00.000 849470492124905
      MNT-N4-441.079.53000.270.055 80.001 80.615 60.018 80.080 10.000 744377487124964
      MNT-N4-527.957.41830.310.054 30.002 40.621 00.028 50.082 10.001 038398490185096
      MNT-N4-639.078.32960.260.057 00.001 90.622 70.019 50.079 40.000 950072492124935
      MNT-N4-758.4122.03780.320.056 70.001 50.627 80.019 90.080 00.001 248061495124967
      MNT-N4-870.3151.04240.360.057 00.001 60.630 20.018 40.080 00.000 750060496114964
      MNT-N4-939.073.22720.270.056 90.001 90.626 60.021 00.079 80.000 848774494134955
      MNT-N4-1097.0230.05290.430.056 40.001 60.623 80.018 00.080 10.000 647832492114974
      MNT-N4-1143.798.13150.310.056 90.001 90.631 30.022 40.080 10.001 148777497144977
      MNT-N4-12111.0246.07510.330.056 90.001 40.630 10.016 00.080 00.000 948752496104965
      MNT-N4-1390.0210.05770.360.057 30.001 40.631 20.015 10.079 50.000 65025249794934
      MNT-N4-1465.6156.03360.470.057 10.001 70.631 00.018 90.079 80.000 749467497124954
      MNT-N4-15113.0279.05600.500.056 20.001 60.622 30.016 90.080 10.000 745763491114964
      MNT-N4-1653.7121.03140.390.056 50.002 00.624 40.021 50.080 00.000 947878493134965
      MNT-N4-1742.093.82330.400.057 10.002 30.630 20.024 70.079 70.000 849461496154945
      MNT-N4-1845.5113.02280.490.056 90.002 00.631 20.021 50.080 20.000 848778497134975
      MNT-N4-1959.2121.04350.280.057 30.001 60.630 80.017 50.079 30.000 950261497114925
      MNT-N4-2067.2142.04760.300.056 80.001 60.628 90.018 00.079 60.000 848361495114935
      注:测试单位和测试时间:中国地质大学(武汉)地质过程与矿产资源国家重点实验室,2014.
      下载: 导出CSV

      表  2  马尼特片麻状花岗闪长岩锆石Lu-Hf同位素组成

      Table  2.   Zircon Lu-Hf isotopic compositions of the Manite gneissic granodiorite

      测点号 176Hf/177Hf 2σ 176Lu/177Hf 2σ 176Yb/177Hf 2σ εHf(0) εHf(t) 2σ tDM1(Ma) tDM2(Ma) fLu/Hf
      MNT-N4-1 0.282 821 0.000 021 0.001 279 0.000 035 0.034 368 0.000 971 1.7 12.2 0.9 615 662 -0.96
      MNT-N4-20.282 8700.000 0260.001 3710.000 0160.035 8800.000 6753.513.91.0547567-0.96
      MNT-N4-30.282 8620.000 0200.001 0150.000 0470.025 6040.001 0543.213.80.9553576-0.97
      MNT-N4-40.282 8890.000 0330.001 1360.000 0210.029 4920.000 5544.214.71.3516524-0.97
      MNT-N4-50.282 8460.000 0340.000 9160.000 0370.024 8770.001 1242.613.21.3574605-0.97
      MNT-N4-60.282 8310.000 0230.000 9170.000 0190.023 1600.000 3162.112.71.0596636-0.97
      MNT-N4-70.282 8850.000 0250.001 1160.000 0260.028 9860.000 7374.014.51.0522533-0.97
      MNT-N4-80.282 8830.000 0250.001 1030.000 0260.028 3730.000 5583.914.51.0524536-0.97
      MNT-N4-90.282 8570.000 0240.001 1260.000 0090.028 8750.000 1583.013.61.0562587-0.97
      MNT-N4-100.282 8440.000 0170.001 7380.000 0390.043 3940.001 1242.512.90.8590625-0.95
      MNT-N4-110.282 8300.000 0250.001 0030.000 0050.025 5020.000 0802.012.61.0598639-0.97
      MNT-N4-120.282 8630.000 0280.001 0460.000 0240.026 5220.000 6983.213.81.1553575-0.97
      MNT-N4-130.282 8980.000 0340.001 0270.000 0500.025 4910.001 3834.415.01.3503506-0.97
      MNT-N4-140.282 8910.000 0280.001 3720.000 0410.038 0840.001 1234.214.71.1517525-0.96
      MNT-N4-15 0.282 898 0.000 037 0.002 090 0.000 049 0.057 525 0.000 655 4.4 14.7 1.4 517 525 -0.94
      下载: 导出CSV

      表  3  马尼特片麻状花岗闪长岩主量元素(%)、稀土元素及微量元素(10-6)分析结果

      Table  3.   Major(%), REE and trace (10-6) element compositions of the Manite gneissic granodiorite

      样号MNT-1MNT-2MNT-3MNT-4MNT-5MNT-6MNT-7
      SiO262.6461.6761.8063.2863.1961.4763.99
      TiO20.380.390.380.360.360.390.39
      Al2O315.5214.8414.9914.6414.7914.8115.37
      Fe2O36.397.367.226.566.427.285.96
      MnO0.160.160.150.140.140.150.14
      MgO2.713.603.553.123.403.642.04
      CaO4.676.286.045.875.386.524.29
      Na2O3.642.932.913.353.292.993.38
      K2O1.941.081.161.021.310.932.31
      P2O50.110.090.090.100.100.090.11
      LOI1.741.521.621.491.551.651.94
      Total99.999.9299.9199.9399.9399.9299.92
      K2O/Na2O0.530.370.400.300.400.310.68
      A/CNK0.930.850.880.850.890.830.97
      A/NK1.922.482.482.212.162.501.91
      K2O+Na2O5.584.014.074.374.603.925.69
      V140162161148143172123
      Cr31.062.157.450.965.062.613.5
      Cs1.0800.7960.8390.7571.0800.7261.20
      Ga11.509.9410.009.4910.509.869.97
      Hf1.271.221.241.261.391.091.15
      Rb73.924.529.227.842.420.477.6
      Sr268269282269292259234
      Zr32.525.732.328.635.624.030.3
      Nb3.372.632.853.133.632.732.93
      Ba598426464299385292626
      Ta0.320.270.250.290.300.260.27
      Th7.843.263.544.265.393.265.64
      U1.431.511.481.51.441.481.22
      Y13.611.911.711.112.11210.3
      La21.711.810.914.015.011.414.2
      Ce36.921.121.124.427.520.624.9
      Pr4.032.452.402.783.112.382.77
      Nd14.709.649.5110.5011.909.6910.10
      Sm2.832.022.132.062.512.061.96
      Eu0.770.580.530.530.640.590.61
      Gd2.912.092.192.282.782.101.85
      Tb0.470.400.350.420.410.340.32
      Dy2.472.092.091.952.262.161.75
      Ho0.520.440.440.400.460.430.36
      Er1.621.401.431.311.441.391.12
      Tm0.260.220.230.230.230.220.20
      Yb1.811.531.451.511.641.501.29
      Lu0.290.240.230.230.250.230.22
      δEu0.820.850.740.750.730.850.97
      ΣREE91.2755.9954.9862.6070.1355.0961.64
      LREE80.9347.5946.5754.2760.6546.7254.54
      HREE10.348.408.428.339.478.377.10
      LREE/HREE7.835.675.536.526.405.587.68
      (La/Yb)N8.085.205.076.256.175.127.42
      Rb/Sr0.280.090.100.100.150.080.33
      Rb/Nb21.939.3210.258.8811.687.4726.48
      Nb/Ta10.609.8511.2610.9812.1410.7110.89
      La/Nb6.444.493.824.474.134.184.85
      Th/Nb2.331.241.241.361.481.191.92
      Th/La0.360.280.320.300.360.290.40
      注:LOI.烧失量;A/CNK=Al2O3/(CaO+Na2O+K2O)摩尔比;δEu=2×(Eu/0.0735)/(Gd/0.259+Sm/0.195);LREE=La+Ce+Pr+Nd+Sm+Eu;HREE=Gd+Tb+Dy+Ho+Er+Tm+Yb+Lu;(La/Yb)N=(La/0.310)/(Yb/0.209).
      下载: 导出CSV
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