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    全球海水剖面Fe同位素组成的不均一性及其影响因素

    王建强 李小虎 毕冬伟 伍锡昌 初凤友

    王建强, 李小虎, 毕冬伟, 伍锡昌, 初凤友, 2017. 全球海水剖面Fe同位素组成的不均一性及其影响因素. 地球科学, 42(9): 1519-1530. doi: 10.3799/dqkx.2017.533
    引用本文: 王建强, 李小虎, 毕冬伟, 伍锡昌, 初凤友, 2017. 全球海水剖面Fe同位素组成的不均一性及其影响因素. 地球科学, 42(9): 1519-1530. doi: 10.3799/dqkx.2017.533
    Wang Jianqiang, Li Xiaohu, Bi Dongwei, Wu Xichang, Chu Fengyou, 2017. Fe Isotopic Composition Heterogeneity of Seawater Profiles and Its Influence Factors. Earth Science, 42(9): 1519-1530. doi: 10.3799/dqkx.2017.533
    Citation: Wang Jianqiang, Li Xiaohu, Bi Dongwei, Wu Xichang, Chu Fengyou, 2017. Fe Isotopic Composition Heterogeneity of Seawater Profiles and Its Influence Factors. Earth Science, 42(9): 1519-1530. doi: 10.3799/dqkx.2017.533

    全球海水剖面Fe同位素组成的不均一性及其影响因素

    doi: 10.3799/dqkx.2017.533
    基金项目: 

    国家自然科学基金项目 41406066

    国家重点基础研究发展计划项目 2013CB429705

    浙江省自然科学基金项目 LY14D060005

    国家自然科学基金项目 41276055

    详细信息
      作者简介:

      王建强(1989-), 男, 硕士研究生, 主要从事海底热液硫化物成矿研究

      通讯作者:

      李小虎, E-mail:xhli@sio.org.cn

    • 中图分类号: P736.4

    Fe Isotopic Composition Heterogeneity of Seawater Profiles and Its Influence Factors

    • 摘要: 全球海水剖面Fe同位素组成存在显著不均一性.对大西洋洋中脊、大西洋近海岸带、东太平洋和西太平洋弧后扩张中心多个站位的海水剖面溶解Fe浓度和Fe同位素组成进行了综合分析,得出以下主要认识:(1)不同区域的海水剖面溶解Fe浓度和Fe同位素组成呈现不同的变化特征,海水Fe同位素的变化趋势与海水溶解氧浓度变化一致,而与海水溶解Fe浓度呈镜像变化关系;(2)不同深度的海水溶解Fe浓度和Fe同位素组成特征的主要控制因素不同.表层海水受到大气降尘、生物作用影响呈现富重Fe同位素特征,受河流的影响Fe同位素组成偏轻;深层海水主要受到深海沉积和海底热液活动的影响,其中沉积物中的非还原溶解Fe导致海水富集重Fe同位素,而受洋中脊热液流体影响的深部海水显著富集轻Fe同位素;(3)将目前已知海底热液溶解Fe通量最小值(0.5 Gmol/a)作为全球大洋的热液溶解Fe通量,利用不同来源的溶解Fe同位素与其通量间的关系估算海底热液对海洋的Fe循环的贡献为~5.5%.由于海底热液流体的Fe通量可能远大于0.5 Gmol/a,因此,海底热液活动对海洋溶解Fe的贡献可能远超过前人的估算结果(6.0%).

       

    • 图  1  海水剖面站位分布示意

      红色实心圆为海水剖面站位;橙色实心三角形为热液活动区

      Fig.  1.  Location of sea profile stations

      图  2  太平洋和大西洋不同站位海水剖面溶解Fe、溶解氧浓度和Fe同位素组成变化

      a.东太平洋SAFe站位引自(Conway and John, 2015);b.赤道太平洋14、28站位数据来自(Radic et al., 2011);c, d.北大西洋USGT站位数据来自(Resing et al., 2015);e.南大西洋5、7、9站位数据来自(Saito et al., 2013)

      Fig.  2.  Dissolved Fe, dissolved oxygen concentration and Fe isotope profiles from the Atlantic and Pacific oceans

      图  3  大西洋和太平洋表层海水溶解Fe浓度和Fe同位素组成

      a.北大西洋USGT-10航次站位;b.北大西洋USGT-11航次站位;c.东太平洋SAFe站位;溶解Fe浓度和Fe同位素数据来自(Conway and John, 2015; Resing et al., 2015),营养盐数据来自(Conway and John, 2015)

      Fig.  3.  Dissolved Fe concentrations and Fe isotopic compositions of surface waters from the Atlantic and Pacific oceans

      图  4  南大西洋、南太平洋和东南太平洋热液溶解Fe与3He的浓度关系

      南大西洋溶解Fe、3He浓度数据来自(Saito et al., 2013),南太平洋溶解Fe、3He浓度数据来自(Fitzsimmons et al., 2014),东南太平洋溶解Fe、3He浓度数据来自(Resing et al., 2015)

      Fig.  4.  Relationship between dissolved Fe and 3He of South Atlantic, South Pacific and southeast Pacific oceans

      图  5  大西洋、东太平洋热液流体对海水溶解Fe浓度、Fe同位素的响的水深剖面

      a.北大西洋USGT-11航次站位;b.南大西洋CoFeMUG航次站位;c.东太平洋SAFe站位;引自数据见图 2

      Fig.  5.  The influence of hydrothermal fluid of the Atlantic and eastern Pacific oceans on dissolved Fe concentration and Fe isotope

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