广东文光岭铅锌铜多金属矿花岗闪长岩LA-ICP-MS锆石U-Pb定年、地球化学特征及其成因

欧阳志侠; 楚克磊; 陈友良; 吴晓东; 杨胜虎; 汪汝澎; 刘东宏; 汪礼明

doi:10.3799/dqkx.2017.591

广东文光岭铅锌铜多金属矿花岗闪长岩LA-ICP-MS锆石U-Pb定年、地球化学特征及其成因

doi: 10.3799/dqkx.2017.591

1.
广东省有色金属地质局, 广东广州 510080
2.
中国地质科学院, 北京 100037
3.
成都理工大学地球科学学院, 四川成都 610059

基金项目:

中国地质调查局地质调查工作项目 12120114015801

中国地质调查局地质调查工作项目 1212011120826

详细信息

作者简介:
欧阳志侠(1984-), 男, 硕士, 高级工程师, 主要从事区域地质调查与矿产勘查等工作

通讯作者:
陈友良

中图分类号: P581;P597
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出版历程
- 收稿日期: 2017-12-05
- 刊出日期: 2019-04-15

Zircon U-Pb Dating, Geochemistry and Petrogenesis of Granodiorite from Wenguangling Pb-Zn-Cu Polymetallic Deposit in Guangdong Province

1.
Geology Bureau for Nonferrous Metals of Guangdong Province, Guangzhou 510080, China
2.
Chinese Academy of Geological Sciences, Beijing 100037, China
3.
College of Earth Sciences, Chengdu University of Technology, Chengdu 610059, China

摘要

摘要: 广东省文光岭矿床是云开地区近年来新发现的铅锌铜多金属矿.以文光岭花岗闪长岩作为研究对象，对其开展了LA-ICP-MS锆石U-Pb同位素定年和地球化学特征研究.获得其锆石²⁰⁶Pb/²³⁸U同位素加权平均年龄为165.7±1.9 Ma（n=18，MSWD=3.1）.花岗闪长岩属于准铝质Ⅰ型花岗岩，SiO₂含量在64.11%~66.64%之间，Al₂O₃含量为14.9%~15.57%，MgO含量在1.39%~1.61%之间，K₂O+Na₂O含量介于6.5%~7.21%，K₂O/Na₂O=1.25~2.74，铝饱和指数A/CNK=0.93~1.11.轻、重稀土元素分馏作用明显，（La/Yb）_N=13.03~17.83，具有弱的负铕异常（δEu为0.70~0.88），HFSE和LILE分异明显，富集Rb、Th、U、K等元素，亏损Nb、Ta、P和Ti等元素.结合区内已有资料，认为文光岭铅锌铜多金属矿床的形成与古太平洋板块的俯冲作用密切相关.
- 文光岭铅锌铜多金属矿 /
- LA-ICP-MS锆石U-Pb定年 /
- 地球化学 /
- 云开地区
Abstract: The recently discovered Wenguangling deposit is a Pb-Zn-Cu polymetallic deposit, located in the Yunkai area. It was firstly investigated of the granodiorites from the Wenguangling deposit by integrating in situ zircon U-Pb dating and geochemical analysis. Eighteen zircons from sample WGL-02 yield excellently concordant results with a weighted mean ²⁰⁶Pb/²³⁸U age of 165.7±1.9 Ma (n=18, MSWD=3.1). The Wenguangling granodiorites belong to metaluminous Ⅰ-type granite. Their SiO₂ and Al₂O₃ contents are 64.11%-66.64% and 14.9%-15.57%, respectively. The MgO contents are between 1.39% and 1.61%. The alkali (K₂O+Na₂O) contents range from 6.5% to 7.21%, with K₂O/Na₂O ratios from 1.25 to 2.74. Their aluminum indexes (A/CNK ratios) are 0.93-1.11. The granodiorites are also characterized by noteworthy fractionation between LREE and HREE ((La/Yb)_N=13.03-17.83), with weak negative Eu anomalies (δEu=0.70-0.88). The trace element analyses show clear fractionation between HFSE and LILE, and the granodiorites are strongly enriched in Rb, Th, U and K but depleted in Nb, Ta, P and Ti. Based on the geochemistry, zircon U-Pb dating of the Wenguangling granodiorite and regional tectonic evolution, it is infered that the formation of the Wenguangling Pb-Zn-Cu polymetallic deposit is closely associated with the subduction of the Paleo-Pacific plate.
- Wenguangling Pb-Zn-Cu polymetallic deposit /
- LA-ICP-MS zircon U-Pb dating /
- geochemistry /
- Yunkai area

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图 1 云开地区地质、矿产略图

改自毛景文等(2011)和楚克磊(2013)

Fig. 1. Geological and mineral sketch map of the Yunkai area

下载: 全尺寸图片幻灯片

图 2 广东省文光岭花岗闪长岩野外照片

Fig. 2. Field photos of the Wenguangling granodiorites in Guangdong Province

下载: 全尺寸图片幻灯片

图 3 广东省文光岭花岗闪长岩体LA-ICP-MS锆石U-Pb谐和图和²⁰⁶Pb/²³⁸U年龄谱图

Fig. 3. Zircon U-Pb concordia diagram and ²⁰⁶Pb/²³⁸U age spectra for the Wenguangling granodiorite in Guangdong Province

下载: 全尺寸图片幻灯片

图 4 广东省文光岭花岗闪长岩体的SiO₂-K₂O图解(a)及A/CNK-A/NK图解(b)

据Rickwood(1989)和Peccerillo and Taylor(1976)

Fig. 4. SiO₂ versus K₂O (a) and A/CNK versus A/NK (b) plots for the Wenguangling granodiorites in Guangdong Province

下载: 全尺寸图片幻灯片

图 5 广东省文光岭花岗闪长岩体微量元素原始地幔标准化蛛网图(a)及稀土元素球粒陨石标准化配分曲线图(b)

据Sun and McDonough (1989)

Fig. 5. Primitive mantle-normalized trace element patterns (a) and chondrite-normalized REE patterns (b) diagrams of the Wenguangling granodiorites in Guangdong Province

下载: 全尺寸图片幻灯片

图 6 广东省文光岭花岗闪长岩构造环境判别图

Syn-COLG.同碰撞花岗岩；WPG.板内花岗岩；VAG.岛弧花岗岩；ORG.洋中脊花岗岩.底图据Pearce et al.(1984)

Fig. 6. Tectonic setting discrimination diagram of Wenguangling granodiorites in Guangdong Province

下载: 全尺寸图片幻灯片

表 1 广东省文光岭花岗闪长岩体的主量(%)、微量和稀土元素(10^-6)组成

Table 1. Major (%), trace (10^-6) elements and REE (10^-6) compositions of the Wenguangling granodiorite in Guangdong Province

样品	YGL-01	YGL-02	HB-01	HB-02
SiO₂	66.25	64.11	66.28	66.64
TiO₂	0.46	0.50	0.55	0.50
Al₂O₃	15.42	15.57	14.90	14.94
Fe₂O₃	4.13	3.85	4.77	4.35
MnO	0.10	0.24	0.11	0.08
MgO	1.41	1.39	1.61	1.42
CaO	2.51	3.51	3.97	3.75
Na₂O	2.94	1.93	2.89	2.96
K₂O	4.15	5.28	3.61	4.03
P₂O₅	0.14	0.18	0.18	0.17
LOI	1.84	2.61	0.96	0.56
Total	99.43	99.25	99.90	99.48
Be	2.2	3.0	2.3	2.1
Sc	7	8	7	7
V	73	81	83	77
Cr	23	32	24	21
Co	8	8	8	8
Ni	4	5	5	5
Cu	< 1	4	< 1	1
Zn	37	73	46	34
Ga	19.0	17.7	18.6	17.7
As	5	6	9	9
Rb	218	351	187	202
Ba	613	656	521	627
Nb	10.5	10.8	12.5	11.1
Sr	420	292	468	453
Zr	155	151	173	140
Hf	4.4	4.2	5.1	3.9
Ti	2 757.7	2 997.5	3 297.3	2 997.5
La	46.1	52.7	46.9	40.5
Ce	66.4	83.3	79.2	69.3
Pr	7.08	8.67	8.34	7.45
Nd	24.3	29.2	29.3	25.3
Sm	4.40	5.13	5.51	4.82
Eu	1.23	1.14	1.29	1.24
Gd	3.94	4.63	4.51	3.76
Tb	0.58	0.69	0.72	0.58
Dy	3.49	3.82	3.96	3.31
Ho	0.65	0.78	0.74	0.75
Er	1.99	2.07	2.34	1.96
Tm	0.31	0.29	0.35	0.31
Yb	2.16	2.12	2.55	2.23
Lu	0.32	0.32	0.36	0.29
Y	17.5	20.9	21.4	19.6
K	34 450.4	43 830.9	29 967.7	33 454.2
Ta	0.9	1.0	1.1	0.9
P	611.04	785.63	785.63	741.98
Th	30	30	30	30
U	7.35	9.55	12.55	7.81

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