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    漠河地区黑云母花岗闪长岩地球化学、Hf同位素特征及其成因

    李良 孙丰月 李碧乐 陈广俊 许庆林 张雅静 钱烨 王琳琳

    李良, 孙丰月, 李碧乐, 陈广俊, 许庆林, 张雅静, 钱烨, 王琳琳, 2018. 漠河地区黑云母花岗闪长岩地球化学、Hf同位素特征及其成因. 地球科学, 43(2): 417-435. doi: 10.3799/dqkx.2018.022
    引用本文: 李良, 孙丰月, 李碧乐, 陈广俊, 许庆林, 张雅静, 钱烨, 王琳琳, 2018. 漠河地区黑云母花岗闪长岩地球化学、Hf同位素特征及其成因. 地球科学, 43(2): 417-435. doi: 10.3799/dqkx.2018.022
    Li Liang, Sun Fengyue, Li Bile, Chen Guangjun, Xu Qinglin, Zhang Yajing, Qian Ye, Wang Linlin, 2018. Geochemistry, Hf Isotopes and Petrogenesis of Biotite Granodiorites in the Mohe Area. Earth Science, 43(2): 417-435. doi: 10.3799/dqkx.2018.022
    Citation: Li Liang, Sun Fengyue, Li Bile, Chen Guangjun, Xu Qinglin, Zhang Yajing, Qian Ye, Wang Linlin, 2018. Geochemistry, Hf Isotopes and Petrogenesis of Biotite Granodiorites in the Mohe Area. Earth Science, 43(2): 417-435. doi: 10.3799/dqkx.2018.022

    漠河地区黑云母花岗闪长岩地球化学、Hf同位素特征及其成因

    doi: 10.3799/dqkx.2018.022
    基金项目: 

    中国地质调查局项目 1212011085485

    国家自然科学基金项目 41272093

    详细信息
      作者简介:

      李良(1986-), 男, 博士研究生, 主要从事矿床成矿理论与预测方面的研究

      通讯作者:

      孙丰月

    • 中图分类号: P581;P591.1

    Geochemistry, Hf Isotopes and Petrogenesis of Biotite Granodiorites in the Mohe Area

    • 摘要: 以往学者的研究多集中在印支期出露于漠河县城南的黑云母花岗闪长岩,而对该地区燕山早期构造演化的研究相对薄弱.运用LA-ICP-MS锆石U-Pb年代学、全岩地球化学与Hf同位素分析的方法确定其形成时代、岩浆源区性质及成岩构造背景.结果表明:该岩石的加权平均年龄分别为185±2 Ma和182±2 Ma,表明其形成于早侏罗世;岩石属于高钾钙碱性系列,A/CNK介于0.90~1.03,Mg#值为42~48,具有高Sr(489×10-6~653×10-6)低Yb(1.33×10-6~1.99×10-6)的特征,判定其属于埃达克岩类;岩石具有弧岩浆的微量元素特征,轻重稀土元素分馏明显((La/Yb)N=8.36~15.6),较弱的Eu负异常(Eu/Eu*=0.79~0.95),富集Rb、K等大离子亲石元素,明显亏损Nb、Ta、Ti等高场强元素;岩石的εHft)值为-3.26~-1.46,二阶段模式年龄介于1.25~1.59 Ga,结合该时期的地幔特征认为该岩石岩浆起源于中元古代亏损地幔新增生的下地壳部分熔融.综合认为岩石形成于蒙古-鄂霍茨克洋板块向南俯冲的活动大陆边缘环境.

       

    • 图  1  中国东北地区构造分区图(a)和漠河地区地质简图(b)

      图a中主要断裂:①牡丹江断裂,②敦化—密山断裂,③伊通—伊兰断裂,④索伦—西拉木伦—长春断裂,⑤贺根山—黑河断裂,⑥喜桂图—塔源断裂,⑦蒙古—鄂霍茨克缝合带;图b:1.中生代沉积岩, 2.古生代沉积岩, 3.前寒武纪基底, 4.中生代火山岩, 5.中生代花岗岩, 6.中生代花岗闪长岩, 7.时代不明的花岗岩, 8.主要断裂, 9.采样地点;图a据Wu et al.(2007),图b据黑龙江省地质矿产局(1993)李良等(2015)改编

      Fig.  1.  Simplified geological map of NE China, showing the main tectonic subdivisions (a) and detailed geological map of the Mohe area, Heilongjiang province (b)

      图  2  研究区黑云母花岗闪长岩手标本(a,b)和显微镜下照片(c~f)

      Aln.褐帘石;Ap.磷灰石;Bi.黑云母;Or.正长石;Pl.斜长石;Pth.条纹长石;Q.石英;Spn.榍石

      Fig.  2.  Hand specimen photographs (a, b) and micrographs (c-f) of the biotite granodiorites in the study area

      图  3  黑云母花岗闪长岩部分锆石阴极发光图像

      实线圆圈代表U-Pb分析点,虚线圆圈代表相应的Hf同位素分析点;MH-N3样品的锆石图中第一排数值为二阶段模式年龄,第二排数值为锆石U-Pb表面年龄

      Fig.  3.  CL images of zircons selected for analysis from biotite granodiorites

      图  4  漠河县城南黑云母花岗闪长岩样品锆石U-Pb年龄谐和图

      Fig.  4.  Zircon U-Pb concordia diagrams for biotite granodiorites in southern Mohe county

      图  5  黑云母花岗闪长岩QAP图解(a)、SiO2-K2O图解(b)和A/CNK-A/NK图解(c)

      图a底图据Streckeisen(1976);图b底图据Peccerillo and Taylor(1976);图c底图据Maniar and Piccoli(1989)

      Fig.  5.  QAP (a), SiO2 vs. K2O (b) and A/CNK vs. A/NK (c) diagrams of biotite granodiorites

      图  6  黑云母花岗闪长岩稀土元素球粒陨石标准化配分图(a)和微量元素原始地幔标准化蛛网图(b)

      图a底图据Boynton (1984);图b底图据Sun and McDonough (1989)

      Fig.  6.  Chondrite-normalized REE patterns (a) and primitive mantle-normalized trace element spider diagrams (b) for biotite granodiorites

      图  7  黑云母花岗闪长岩锆石Hf同位素特征

      兴-蒙造山带东段与燕山褶皱带Hf同位素组成引自Yang et al.(2006);额尔古纳地块早中生代花岗质岩石的Hf同位素组成引自Tang et al.(2016)

      Fig.  7.  Hf isotopic compositions of zircons from biotite granodiorites

      图  8  黑云母花岗闪长岩YbN-(La/Yb)N判别图解

      底图据Defant and Drummond (1990)

      Fig.  8.  YbN vs. (La/Yb)N diagram for biotite granodiorites

      图  9  黑云母花岗闪长岩Sr/Y-(La/Yb)N(a)、Sr-10Y-Zr(b)和Y/Yb-Sr/Y-La/Yb(c)判别图解

      图a底图据Liu et al.(2010);图b和c的底图据朱弟成等(2002)

      Fig.  9.  The discrimination diagrams of Sr/Y-(La/Yb)N (a), Sr-10Y-Zr (b) and Y/Yb-Sr/Y-La/Yb (c) for biotite granodiorites

      图  10  黑云母花岗闪长岩源区判别图解

      底图据Patiño(1999)

      Fig.  10.  Discriminant diagrams of source regions for biotite granodiorites

      图  11  黑云母花岗闪长岩(Yb+Ta)-Rb(a)、(Y+Nb)-Rb(b)和R1-R2(c)构造判别图解

      图a和b底图据Pearce et al.(1984);图c底图据Batchelor and Bowden(1985)

      Fig.  11.  Tectonic discrimination diagrams of (Yb+Ta)-Rb (a), (Y+Nb)-Rb (b) and R1-R2 (c) for biotite granodiorites

      表  1  漠河县城南黑云母花岗闪长岩锆石LA-ICP-MS U-Pb同位素分析结果

      Table  1.   Zircon LA-ICP-MS U-Pb dating results for biotite granodiorites in southern Mohe county

      分析点 含量(10-6) Th/U 同位素比值 同位素年龄(Ma)
      Pb Th U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ
      MH-N3-01 17.3 406 473 0.86 0.052 4 0.002 3 0.207 7 0.007 1 0.028 8 0.000 4 0.008 9 0.000 2 301 52 192 6 183 3 180 3
      MH-N3-02 9.32 67.4 262 0.26 0.054 0 0.003 9 0.216 5 0.014 2 0.029 1 0.000 6 0.010 5 0.000 6 370 112 199 12 185 4 210 11
      MH-N3-03 12.5 176 372 0.47 0.050 9 0.002 4 0.203 0 0.009 2 0.028 9 0.000 4 0.009 1 0.000 1 237 111 188 8 184 3 183 2
      MH-N3-04 10.7 177 304 0.58 0.050 1 0.002 4 0.200 2 0.007 5 0.029 0 0.000 4 0.008 4 0.000 2 199 60 185 6 184 3 169 3
      MH-N3-05 22.6 49.5 595 0.08 0.049 9 0.001 9 0.199 8 0.006 9 0.029 0 0.000 4 0.009 2 0.000 1 190 88 185 6 185 3 184 2
      MH-N3-06 9.23 77 269 0.29 0.051 3 0.002 6 0.204 6 0.008 4 0.028 9 0.000 4 0.010 5 0.000 3 256 66 189 7 184 3 211 6
      MH-N3-07 8.96 78.1 225 0.35 0.052 0 0.002 8 0.207 5 0.009 5 0.028 9 0.000 5 0.009 7 0.000 3 287 76 191 8 184 3 196 6
      MH-N3-08 7.52 93.8 220 0.43 0.053 8 0.002 7 0.215 9 0.009 0 0.029 1 0.000 4 0.010 3 0.000 3 363 66 199 7 185 3 207 5
      MH-N3-09 12.7 95.2 356 0.27 0.050 8 0.002 7 0.204 7 0.009 2 0.029 2 0.000 5 0.009 9 0.000 3 231 75 189 8 186 3 199 6
      MH-N3-10 12.8 125 369 0.34 0.051 9 0.002 8 0.211 5 0.009 6 0.029 6 0.000 5 0.008 9 0.000 3 279 74 195 8 188 3 179 5
      MH-N3-11 16.7 370 459 0.81 0.050 3 0.002 0 0.202 9 0.005 7 0.029 3 0.000 4 0.008 6 0.000 1 209 40 188 5 186 3 172 3
      MH-N3-12 8.73 68.8 270 0.25 0.053 3 0.002 9 0.213 1 0.009 8 0.029 0 0.000 5 0.009 2 0.000 3 342 74 196 8 184 3 185 6
      MH-N3-13 14.7 252 430 0.59 0.051 1 0.002 4 0.203 8 0.007 4 0.028 9 0.000 4 0.009 1 0.000 2 245 56 188 6 184 3 184 4
      MH-N3-14 18.7 207 525 0.39 0.053 2 0.002 3 0.212 1 0.006 8 0.028 9 0.000 4 0.009 3 0.000 2 337 47 195 6 184 3 188 4
      MH-N3-15 16.4 248 432 0.57 0.051 6 0.003 1 0.207 5 0.012 1 0.029 2 0.000 5 0.009 2 0.000 1 268 141 191 10 185 3 185 2
      MH-N3-16 96.4 643 1144 0.56 0.057 6 0.001 8 0.579 5 0.008 5 0.072 9 0.000 9 0.020 5 0.000 2 516 15 464 5 454 5 410 5
      MH-N3-17 51.5 146 630 0.23 0.063 1 0.002 1 0.634 9 0.011 6 0.073 0 0.001 0 0.031 4 0.000 5 710 19 499 7 454 6 625 9
      MH-N3-18 8.96 78.1 225 0.35 0.055 8 0.002 2 0.403 6 0.011 5 0.052 5 0.000 7 0.025 8 0.000 7 443 39 344 8 330 5 515 13
      MH-N3-19 39.7 173 725 0.24 0.058 0 0.002 1 0.420 2 0.009 5 0.052 5 0.000 7 0.021 9 0.000 4 530 27 356 7 330 4 437 8
      MH-N3-20 24.5 205 442 0.46 0.057 2 0.002 1 0.412 0 0.009 8 0.052 2 0.000 7 0.012 2 0.000 2 500 30 350 7 328 4 245 4
      MH-N4-01 10.2 55.5 291 0.19 0.051 8 0.002 9 0.197 3 0.010 0 0.027 6 0.000 6 0.010 3 0.000 4 275 79 183 8 176 4 206 9
      MH-N4-02 7.61 47.5 213 0.22 0.050 2 0.002 4 0.198 5 0.007 9 0.028 7 0.000 5 0.008 9 0.000 3 204 59 184 7 182 3 179 6
      MH-N4-03 15.7 312 449 0.70 0.052 0 0.006 1 0.200 6 0.022 5 0.028 0 0.000 9 0.007 9 0.000 5 286 194 186 19 178 6 159 11
      MH-N4-04 11.4 166 311 0.53 0.050 6 0.002 1 0.201 1 0.006 7 0.028 9 0.000 5 0.008 9 0.000 2 220 45 186 6 183 3 179 4
      MH-N4-05 10.2 152 281 0.54 0.054 5 0.004 7 0.215 0 0.017 6 0.028 6 0.000 7 0.009 2 0.000 5 390 138 198 15 182 5 185 10
      MH-N4-06 11 158 305 0.52 0.051 0 0.002 3 0.202 8 0.007 4 0.028 8 0.000 5 0.007 8 0.000 2 240 51 187 6 183 3 158 4
      MH-N4-07 15.8 48.3 470 0.10 0.052 2 0.002 1 0.210 5 0.006 5 0.029 2 0.000 5 0.012 9 0.000 5 294 39 194 5 186 3 258 9
      MH-N4-08 11.8 166 330 0.50 0.049 8 0.002 1 0.196 9 0.006 5 0.028 7 0.000 5 0.008 6 0.000 2 186 45 183 6 182 3 173 4
      MH-N4-09 11.3 154 269 0.57 0.055 7 0.004 8 0.225 8 0.018 1 0.029 4 0.000 8 0.009 5 0.000 5 440 133 207 15 187 5 192 9
      MH-N4-10 10.1 127 282 0.45 0.051 5 0.002 5 0.205 8 0.008 6 0.029 0 0.000 5 0.008 4 0.000 2 264 62 190 7 184 3 168 5
      MH-N4-11 8.04 124 193 0.64 0.050 6 0.005 7 0.198 2 0.021 3 0.028 4 0.000 9 0.009 3 0.000 5 223 186 184 18 181 5 187 10
      MH-N4-12 14.6 366 360 1.02 0.050 0 0.004 8 0.189 7 0.017 8 0.027 5 0.000 6 0.008 7 0.000 1 197 219 176 15 175 4 175 3
      MH-N4-13 11.9 177 323 0.55 0.055 3 0.003 1 0.218 8 0.010 6 0.028 7 0.000 6 0.009 2 0.000 3 424 73 201 9 182 4 186 5
      MH-N4-14 29.7 915 704 1.30 0.051 5 0.002 1 0.203 3 0.006 3 0.028 6 0.000 5 0.008 3 0.000 1 262 40 188 5 182 3 167 3
      MH-N4-15 19.8 381 519 0.73 0.052 1 0.002 5 0.207 8 0.008 2 0.028 9 0.000 5 0.009 3 0.000 2 289 56 192 7 184 3 188 4
      MH-N4-16 13.9 154 394 0.39 0.054 7 0.004 4 0.215 0 0.016 1 0.028 5 0.000 7 0.011 8 0.000 7 400 125 198 13 181 4 238 13
      MH-N4-17 12.4 32 371 0.09 0.051 4 0.002 3 0.204 2 0.007 4 0.028 8 0.000 5 0.011 8 0.000 5 258 51 189 6 183 3 237 10
      MH-N4-18 58.5 193 843 0.23 0.060 6 0.002 3 0.599 6 0.014 9 0.071 7 0.001 0 0.018 9 0.000 4 625 31 477 9 447 6 378 8
      MH-N4-19 55.9 97.8 841 0.12 0.054 9 0.001 8 0.483 6 0.008 1 0.063 9 0.000 8 0.022 0 0.000 4 406 18 401 6 399 5 440 8
      下载: 导出CSV

      表  2  漠河县城南黑云母花岗闪长岩主量(%)、微量元素(10-6)分析结果

      Table  2.   Major elements (%) and trace elements (10-6) compositions for biotite granodiorites in southern Mohe county

      样品号 MH-N3-B1 MH-N3-B2 MH-N3-B3 MH-N3-B4 MH-N4-B1 MH-N4-B2 MH-N4-B3
      SiO2 65.00 64.38 64.56 63.56 63.82 63.90 66.32
      TiO2 0.73 0.66 0.64 0.55 0.80 0.76 0.63
      Al2O3 16.82 16.58 16.96 16.76 17.10 17.34 16.63
      FeOT 3.90 4.05 4.11 3.87 3.75 3.53 2.96
      MnO 0.06 0.12 0.10 0.10 0.05 0.04 0.04
      MgO 1.98 1.70 1.81 1.96 1.58 1.54 1.22
      CaO 3.54 3.97 3.89 3.95 3.80 3.93 3.35
      Na2O 4.13 4.40 3.96 4.68 4.15 4.29 4.02
      K2O 2.89 2.68 2.71 3.39 2.98 2.74 3.13
      P2O5 0.21 0.21 0.23 0.18 0.22 0.21 0.17
      LOI 0.53 0.55 0.30 0.22 0.43 0.44 0.39
      Total 99.91 99.40 99.40 99.40 99.28 99.27 99.34
      ALK 7.02 7.08 6.67 8.07 7.14 7.03 7.15
      Na2O/K2O 1.43 1.64 1.46 1.38 1.39 1.57 1.29
      A/CNK 1.03 0.96 1.03 0.90 1.01 1.01 1.03
      Mg# 48 43 44 47 43 44 42
      La 17.5 19.2 27.1 15.5 41.0 38.2 25.4
      Ce 46.6 53.0 61.2 41.8 83.7 75.6 62.4
      Pr 5.71 5.84 7.07 4.74 10.8 9.74 7.98
      Nd 24.9 25.3 30.4 21.0 39.7 36.3 30.7
      Sm 4.50 4.60 5.42 3.95 6.55 6.13 5.92
      Eu 1.16 1.23 1.39 0.96 1.81 1.67 1.43
      Gd 3.48 3.58 4.28 3.41 5.20 4.92 5.13
      Tb 0.45 0.45 0.54 0.47 0.66 0.62 0.71
      Dy 2.49 2.40 2.80 2.70 3.25 3.11 3.85
      Ho 0.45 0.43 0.49 0.48 0.65 0.59 0.75
      Er 1.37 1.29 1.51 1.47 1.82 1.67 2.10
      Tm 0.20 0.19 0.23 0.21 0.28 0.26 0.30
      Yb 1.39 1.35 1.58 1.33 1.99 1.76 1.83
      Lu 0.20 0.21 0.24 0.19 0.31 0.29 0.27
      ΣREE 111 119 144 98.1 198 181 149
      HREE 10.0 9.89 11.7 10.3 14.2 13.2 14.9
      (La/Yb)N 9.08 10.2 12.3 8.36 14.8 15.6 10.0
      Eu/Eu* 0.90 0.92 0.88 0.80 0.95 0.93 0.79
      V 82.3 76.9 81.5 58.9 85.0 79.0 69.0
      Cr 6.24 7.63 9.01 7.06 6.56 8.34 7.83
      Co 8.15 7.88 8.70 6.51 6.87 6.65 8.22
      Ni 7.00 6.16 6.08 4.89 6.52 5.37 6.21
      Sn 2.64 2.51 2.69 2.76 3.00 3.00 3.00
      Cs 2.88 2.45 2.42 3.22 3.00 2.74 4.11
      Rb 47.0 41.4 50.0 59.3 114 100 118
      Sr 541 504 563 489 653 622 587
      Y 11.3 12.6 15.3 11.9 19.4 17.3 21.7
      Ba 649 604 620 614 987 823 943
      Zr 204 88.2 261 43.9 250 220 210
      Nb 12.8 12.1 13.1 12.2 16.5 14.5 15.1
      Hf 3.52 1.81 4.53 1.03 6.60 6.10 5.30
      Ta 0.94 0.92 1.01 0.94 1.50 1.40 1.40
      Ga 28.2 26.5 27.8 26.4 27.9 26.3 26.4
      Pb 14.4 14.2 14.8 15.4 18.6 17.3 20.7
      Th 5.26 4.84 6.24 4.60 8.77 8.46 8.24
      U 2.01 1.97 2.25 1.92 2.59 2.17 2.03
      下载: 导出CSV

      表  3  漠河县城南黑云母花岗闪长岩锆石Hf同位素分析结果

      Table  3.   Zircon Lu-Hf isotopic data for biotite granodiorites in southern Mohe county

      分析点 t(Ma) 176Yb/177Hf 2σ 176Lu/177Hf 2σ 176Hf/177Hf 2σ εHf(0) εHf(t) 2σ tDM1(Hf) tDM2(Hf) fLu/Hf
      MH-N3-1 183 0.019 292 0.000 218 0.000 582 0.000 004 0.282 592 0.000 014 -6.36 -2.41 0.50 924 1 378 -0.98
      MH-N3-2 185 0.013 751 0.000 062 0.000 434 0.000 002 0.282 582 0.000 014 -6.71 -2.70 0.49 934 1 398 -0.99
      MH-N3-3 184 0.025 231 0.000 089 0.000 723 0.000 001 0.282 595 0.000 015 -6.26 -2.31 0.53 923 1 372 -0.98
      MH-N3-4 184 0.011 502 0.000 151 0.000 376 0.000 003 0.282 574 0.000 015 -6.98 -2.99 0.52 943 1 416 -0.99
      MH-N3-5 185 0.014 551 0.000 385 0.000 452 0.000 010 0.282 605 0.000 015 -5.92 -1.91 0.53 903 1 348 -0.99
      MH-N3-6 184 0.022 926 0.000 311 0.000 697 0.000 013 0.282 613 0.000 016 -5.61 -1.65 0.56 897 1 331 -0.98
      MH-N3-7 184 0.042 380 0.001 638 0.001 156 0.000 044 0.282 610 0.000 018 -5.74 -1.85 0.63 913 1 343 -0.97
      MH-N3-8 185 0.028 355 0.000 905 0.000 768 0.000 021 0.282 618 0.000 018 -5.43 -1.46 0.63 891 1 319 -0.98
      MH-N3-9 186 0.057 628 0.000 663 0.001 457 0.000 022 0.282 607 0.000 018 -5.85 -1.94 0.63 925 1 351 -0.96
      MH-N3-10 188 0.025 143 0.000 246 0.000 757 0.000 008 0.282 592 0.000 013 -6.35 -2.32 0.46 928 1 376 -0.98
      MH-N3-11 186 0.013 000 0.000 183 0.000 391 0.000 002 0.282 571 0.000 015 -7.12 -3.09 0.52 949 1 423 -0.99
      MH-N3-12 184 0.022 687 0.000 141 0.000 679 0.000 004 0.282 617 0.000 017 -5.49 -1.53 0.60 892 1 323 -0.98
      MH-N3-13 184 0.007 467 0.000 080 0.000 283 0.000 001 0.282 567 0.000 015 -7.26 -3.26 0.54 952 1 433 -0.99
      MH-N3-14 184 0.020 418 0.000 221 0.000 590 0.000 005 0.282 617 0.000 016 -5.49 -1.52 0.57 889 1 322 -0.98
      MH-N3-15 185 0.016 438 0.000 132 0.000 493 0.000 004 0.282 577 0.000 017 -6.88 -2.88 0.60 942 1 410 -0.99
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