湖相富有机质泥质白云岩生排烃模拟及其对页岩油勘探的启示

李志明; 郑伦举; 蒋启贵; 马中良; 陶国亮; 徐二社; 钱门辉; 刘鹏; 曹婷婷

doi:10.3799/dqkx.2018.025

湖相富有机质泥质白云岩生排烃模拟及其对页岩油勘探的启示

doi: 10.3799/dqkx.2018.025

李志明^1,2,3,4,,
郑伦举^1,2,3,4,
蒋启贵^1,2,3,4,
马中良^1,2,3,4,
陶国亮^1,2,3,4,
徐二社^1,2,3,4,
钱门辉^1,2,3,4,
刘鹏^1,2,3,4,
曹婷婷^1,2,3,4

1.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
2.
页岩油气富集机理与有效开发国家重点实验室, 江苏无锡 214126
3.
国家能源页岩油研发中心, 江苏无锡 214126
4.
中国石化油气成藏重点实验室, 江苏无锡 214126

基金项目:

国家重点基础研究发展计划（"973"计划）项目 2014CB239101

中国石油化工股份有限公司科技开发部项目 P14157

详细信息

作者简介:
李志明(1968-), 男, 研究员, 博士, 主要从事油气地球化学、页岩油气地质方面的研究

中图分类号: P618.13
计量
- 文章访问数: 3361
- HTML全文浏览量: 2299
- PDF下载量: 53
- 被引次数: 0
出版历程
- 收稿日期: 2017-07-14
- 刊出日期: 2018-02-15

Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration

Li Zhiming^{1,2,3,4
,},
Zheng Lunju^1,2,3,4,
Jiang Qigui^1,2,3,4,
Ma Zhongliang^1,2,3,4,
Tao Guoliang^1,2,3,4,
Xu Ershe^1,2,3,4,
Qian Menhui^1,2,3,4,
Liu Peng^1,2,3,4,
Cao Tingting^1,2,3,4

1.
Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi 214126, China
2.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Wuxi 214126, China
3.
State Energy Center for Shale Oil Research and Development, Wuxi 214126, China
4.
Key Laboratory of Petroleum Accumulation Mechanisms, SINOPEC, Wuxi 214126, China

摘要

摘要: 富有机质湖相白云质泥岩、泥质白云岩及其贫有机质粉砂岩、白云岩夹层是我国陆相盆地页岩油勘探的重要领域，但目前针对湖相富有机质白云质泥岩或泥质白云岩在近地质条件下的生排烃一体化模拟研究尚属空白.以典型低熟富有机质泥质白云岩为例，开展了近地质条件下的生排烃一体化模拟实验，揭示了其呈现四阶段生排烃演化模式.结果表明，R_o ≤ 0.74%时为缓慢生油伴生烃气、排油能力有限阶段，0.74% < R_o ≤ 0.84%时为快速生油伴生烃气、排油能力逐渐增高阶段，0.84% < R_o ≤ 1.28%≈1.30%时为生烃气伴生油与油初始裂解、高效排油阶段，1.30% < R_o ≤ 2.00%时为油裂解烃气兼干酪根生烃气阶段；同时，R_o < 0.68%时滞留油主要以有机质吸附态赋存，而0.68% ≤ R_o ≤ 2.00%时滞留油主要以游离态赋存于矿物基质微-纳米级孔缝系统内.综合分析提出湖相泥质白云岩烃源层系有利页岩油勘探的成熟度范围为0.84%~1.30%.
- 湖相 /
- 富有机质泥质白云岩 /
- 生排烃模拟 /
- 赋存方式 /
- 成熟度 /
- 石油地质
Abstract: The organic-rich lacustrine dolomitic mudstone, argillaceous dolomite, organic-poor siltstone and dolomite interlayer are important areas for shale oil exploration in terrestrial basins in China. However, the research on the integration of hydrocarbon generation, expulsion and hydrocarbon accumulation in the lacustrine organic-rich dolomitic mudstone or argillaceous dolomite under near geological conditions is still blank. An integrate experiment of hydrocarbon generation and expulsion simulation from argillaceous dolomite rich in organic matter under near geological condition in confined systems, has been carried out with typical lower mature organic-rich argillaceous dolomite. The four-stage of hydrocarbon generation and expulsion evolution model is revealed. The results show that the first stage is characterized by relatively slow oil generation associated hydrocarbon gases and by limited ability of oil expulsion when R_o is ≤ 0.74%. The second stage is characterized by rapid oil generation associated hydrocarbon gases and with incremental ability of oil expulsion when R_o is in the range of 0.74%-0.84%. The third stage is characterized by hydrocarbon gas generation associated oil and oil initial cracking, and by oil expulsion effectively at 0.84% < R_o ≤ 1.28%≈1.30%. The fourth stage is characterized by oil cracking into hydrocarbon gas associated hydrocarbon gases generation from kerogen when R_o is > 1.30%. And the retained oil is mainly occurred as adsorption phase with organic matter at R_o < 0.68%, and mainly occurred as free phase within micron to nano-scale pores and microfractures in mineral matrix of argillaceous dolomite at 0.68% ≤ R_o ≤ 2.00%. The range of thermal maturity for favorable shale oil exploration within lacustrine dolomite measures, is proposed at 0.84%-1.30%, on the basis of the results of simulation of hydrocarbon generation and expulsion for lacustrine organic-rich argillaceous dolomite, integrated with geological conditions and exploring economic benefit.
- lacustrine /
- organic-rich argillaceous dolomite /
- simulation of hydrocarbon generation and expulsion /
- occurrence /
- maturity /
- petroleum geology

HTML全文

图 1 富有机质泥质白云岩生排烃模拟实验流程

Fig. 1. The simulation experimental flow of hydrocarbon generation and expulsion for organic-rich argillaceous dolomite

下载: 全尺寸图片幻灯片

图 2 富有机质泥质白云岩生排烃模拟结果

Fig. 2. The simulation results of hydrocarbon generation and expulsion for organic-rich argillaceous dolomite

下载: 全尺寸图片幻灯片

图 3 泥质白云岩不同热演化阶段滞留烃含量与残余有机碳含量

Fig. 3. The contents of retained hydrocarbons and residual organic carbon in argillaceous dolomite at different thermal maturity stages

下载: 全尺寸图片幻灯片

表 1 富有机质泥质白云岩生排烃模拟实验方案与具体条件

Table 1. The plan and concrete conditions of hydrocarbon generation and expulsion simulation for organic-rich argillaceous dolomite

模拟温度 (℃)	升温速率 (℃/min)	恒温时间 (h)	流体压力 (MPa)	排烃压力 (MPa)	上覆压力 (MPa)	泥质白云岩重量(g)	上砂岩重量(g)	下砂岩重量(g)
250	1	48	25.0	20.0	36.8	60.98	20.14	20.60
275	1	48	26.5	21.5	39.1	60.10	20.54	20.39
300	1	48	28.8	23.8	43.7	60.75	20.90	20.11
310	1	48	30.0	25.0	46.0	60.55	20.70	20.39
320	1	48	32.5	27.5	50.6	59.14	20.19	20.41
335	1	48	35.0	30.0	55.2	58.28	20.72	20.36
350	1	48	37.5	32.5	59.8	59.85	20.27	20.15
360	1	48	40.0	35.0	64.4	59.48	20.21	20.56
370	1	48	45.0	40.0	73.6	58.60	20.96	20.55
380	1	48	48.8	43.8	80.5	60.32	20.78	20.71
400	1	48	55.0	50.0	92.0	60.49	20.48	20.36

下载: 导出CSV

表 2 富有机质泥质白云岩生排烃模拟结果

Table 2. The simulation results of hydrocarbon generation and expulsion for organic-rich argillaceous dolomite

模拟温度 (℃)	成熟度R_o (%)	流体压力 (MPa)	排烃压力 (MPa)	上覆压力 (MPa)	烃气总产率 (kg/tc)	排出油1 产率(kg/tc)
250	0.59	25.0	20.0	36.8	0.79	3.74
275	0.64	26.5	21.5	39.1	0.92	5.23
300	0.68	28.8	23.8	43.7	2.82	10.2
310	0.70	30.0	25.0	46.0	3.08	12.85
320	0.74	32.5	27.5	50.6	3.68	13.15
335	0.80	35.0	30.0	55.2	8.08	29.17
350	0.84	37.5	32.5	59.8	17.59	33.79
360	0.90	40.0	35.0	64.4	23.47	36.95
370	1.12	45.0	40.0	73.6	38.75	101.46
380	1.28	48.8	43.8	80.5	57.76	167.18
400	2.00	55.0	50.0	92.0	149.36	207.33

排出油2 产率(kg/tc)	排出油3 产率(kg/tc)	排出油4 产率(kg/tc)	总排出油产率(kg/tc)	残留油产率(kg/tc)	总油产率 (kg/tc)	总烃产率 (kg/tc)
1.56	1.61	0.66	7.57	83.51	91.08	91.87
1.77	2.82	0.22	10.04	126.75	136.79	137.71
1.18	1.83	1.91	15.12	160.20	175.32	178.14
0.86	2.17	1.65	17.54	206.35	223.89	226.97
1.74	4.50	1.23	20.62	225.16	245.78	249.46
11.13	3.44	2.69	46.44	349.60	396.04	404.12
5.88	34.19	70.89	144.75	372.23	516.98	534.57
8.32	89.95	51.95	187.17	335.73	522.90	546.38
11.27	116.89	64.88	294.49	224.54	519.03	557.78
39.37	78.42	120.82	405.79	110.90	516.69	574.45
79.47	18.23	36.48	341.51	21.64	363.15	512.50

下载: 导出CSV

表 3 富有机质泥质白云岩生排烃模拟过程中烃气组分产率

Table 3. The yield of hydrocarbon gas compositions for organic-rich argillaceous dolomite during the process of hydrocarbon generation and expulsion

模拟温度 (℃)	成熟度 R_o(%)	烃气组分产率(kg/tc)									烃气总产率 (kg/tc)
模拟温度 (℃)	成熟度 R_o(%)	CH₄	C₂H₆	C₃H₈	C₃H₆	iC₄H₁₀	nC₄H₁₀	C₄H₈	iC₅H₁₂	nC₅H₁₂	烃气总产率 (kg/tc)
250	0.59	0.46	0.11	0.1	0.05	0.00	0.07	0.00	0.00	0.00	0.79
275	0.64	0.68	0.11	0.08	0.00	0.00	0.05	0.00	0.00	0.00	0.92
300	0.68	1.69	0.43	0.37	0.02	0.1	0.13	0.00	0.04	0.04	2.82
310	0.70	1.78	0.52	0.41	0.03	0.12	0.12	0.00	0.05	0.05	3.08
320	0.74	2.07	0.65	0.51	0.03	0.13	0.17	0.00	0.06	0.06	3.68
335	0.80	3.79	1.66	1.42	0.07	0.29	0.43	0.00	0.24	0.18	8.08
350	0.84	7.28	3.89	3.46	0.10	0.7	1.12	0.00	0.52	0.52	17.59
360	0.90	8.69	5.18	4.80	0.20	1.09	1.71	0.00	0.90	0.90	23.47
370	1.12	12.81	8.44	8.44	0.27	1.77	3.29	0.12	1.73	1.88	38.75
380	1.28	16.97	12.42	13.36	0.39	2.93	5.6	0.13	2.81	3.15	57.76
400	2.00	37.1	34.13	39.69	0.75	8.06	16.34	0.2	6.42	6.67	149.36

下载: 导出CSV

表 4 富有机质泥质白云岩阶段生烃产率

Table 4. The hydrocarbon generation yield of different stages for organic-rich argillaceous dolomite

阶段温度 (℃)	阶段成熟度 R_o(%)	阶段烃气产率 (kg/tc)	阶段烃气产率占总烃气产率百分比(%)	阶段油产率 (kg/tc)	阶段油产率占总油产率百分比(%)
250	0.59	0.79	0.53	91.08	17.42
250~275	0.59~0.64	0.13	0.09	45.71	8.74
275~300	0.64~0.68	1.90	1.27	38.53	7.37
300~310	0.68~0.70	0.26	0.17	48.57	9.29
310~320	0.70~0.74	0.60	0.40	21.89	4.19
320~335	0.74~0.80	4.40	2.95	150.26	28.74
335~350	0.80~0.84	9.51	6.37	120.94	23.13
350~360	0.84~0.90	5.88	3.94	5.98	1.14
360~370	0.90~1.12	15.28	10.23	-3.87	-0.74
370~380	1.12~1.28	19.01	12.73	-2.34	-0.45
380~400	1.28~2.00	91.60	61.33	-153.54	-29.36

下载: 导出CSV

表 5 泥质白云岩不同热演化阶段滞留烃含量与残余有机碳含量

Table 5. The contents of retained hydrocarbons and residual organic carbon in argillaceous dolomite at different thermal maturity stages

模拟温度(℃)	成熟度R_o(%)	滞留油(mg/g Rock)	残余有机质(%)	滞留油(mg/g TOC)	备注
250	0.59	2.94	3.34	88	滞留油值是假设滞留油全部与有机质呈吸附态赋存时的含量
275	0.64	4.52	3.33	136
300	0.68	5.78	3.28	175
310	0.70	7.33	2.91	252
320	0.74	8.17	2.67	306
335	0.80	12.57	2.4	522
350	0.84	13.6	1.65	826
360	0.90	12.44	1.61	775
370	1.12	8.34	1.57	532
380	1.28	4.43	1.40	317
400	2.00	0.82	1.35	61

下载: 导出CSV

参考文献(68)

Chen, J.J., Cheng, K.M., Xiong, Y., et al., 2005.Hydrocarbon Generation of Laminar Algal Limestone of Lower Cretaceous in the Jiuxi Depression, NW China.Petroleum Exploration and Development, 32(6):61-65 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-SKYK200506013.htm
Fu, W.D., Chen, X., Sun, F.H., et al., 2002.Hydrocarbon Reserving Performance and Exploration Potential of Lake Facies Dolomite in Biyang Depression.Journal of Jianghan Petroleum Institute, 24(1):8-10 (in Chinese with English abstract). https://www.researchgate.net/publication/290992178_The_research_on_the_fractured_dolomite_oil_and_gas_reservoir_in_Biyang_Depression
Guan, D.F., Xu, X.H., Li, Z.M., et al., 2014.Hydrocarbon Generation Theory of Source Rocks in Confined System and Application.Petroleum Industry Press, Beijing, 49-63 (in Chinese). https://www.sciencedirect.com/science/article/pii/S0920410598000618
Jarvie, D. M., 2012. Shale Resource Systems for Oil and Gas: Part 2-Shale-Oil Resource Systems. In: Breyer, J. A., ed., Shale Reservoirs-Giant Resources for the 21st Century. AAPG Memoir, 97: 89-119. [DOI: 10.1306/13321447m973489]
Jiang, F.H., Liu, X.L., Xu, S.T., 1998.Early Cretaceous Charophyte Fossils and Their Time Significance from Bayan Qagan Sag, Eren Basin.Acta Micropalaeontologica Sinica, 15(1):85-90 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-GSWX199104008.htm
Larter, S.R., Huang, H.P., Snowdon, L., et al., 2012.What We do not Know about Self Sourced Oil Reservoirs:Challenges and Potential Solutions.SPE Canadian Unconventional Resources Conference, Calgary. https://doi.org/10.2118/162777-ms
Leythaeuser, D., Poelchau, H.S., 1991.Expulsion of Petroleum from Type Ⅲ Kerogen Source Rocks in Gaseous Solution:Modelling of Solubility Fractionation.Geological Society, London, Special Publications, 59(1):33-46. https://doi.org/10.1144/gsl.sp.1991.059.01.03
Li, J.J., Shi, Y.L., Zhang, X.W., et al., 2014.Control Factors of Enrichment and Producibility of Shale Oil:A Case Study of Biyang Depression.Earth Science, 39(7):848-857 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2014.079
Li, L., Xu, G.S., Wang, W., et al., 2007.Accumulation Patterns of the Oil Reservoirs in the Daerqi Area, Baiyinchagan Sag, Inner Mongol, China.Journal of Chengdu University of Technology (Science & Technology Edition), 34(3):277-284 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CCDZ201202007.htm
Li, M.W., Li, Z.M., Li, Z., et al., 2015.Formation and Occurrence Mechanism of Continental Shale Oil.Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi (in Chinese). https://www.sciencedirect.com/science/article/pii/B9780080217352500628
Li, Z.M., Zheng, L.J., Ma, Z.L., et al., 2011.Simulation of Source Rock for Hydrocarbon Generation and Expulsion in Finite Space and Its Significance.Petroleum Geology & Experiment, 33(5):447-451, 459 (in Chinese with English abstract). doi: 10.1080/10916466.2016.1277239
Lu, S.F., Huang, W.B., Chen, F.W., et al, 2012.Classification and Evaluation Criteria of Shale Oil and Gas Resources:Discussion and Application.Petroleum Exploration and Development, 39(2):249-256 (in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S1876380412600421
Ma, S.P., Luo, C.S., Tian, C.T., et al., 2012.Hydrocarbon-Generating Characteristics of Lacustrine Carbonate Rocks.Journal of Chengdu University of Technology (Science & Technology Edition), 39(6):583-587(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CDLG201206004.htm
Ma, S.P., Sun, D., Zhang, X.B., et al., 2011.The Study of Hydrocarbon Generation Kinetics in Lower Cretaceous Lacustrine Source Rocks, Qingxi Depression, Jiuxi Basin.Natural Gas Geoscience, 22(2):219-223(in Chinese with English abstract). doi: 10.1007/s12182-014-0348-z
Ma, Z.L., Zheng, L.J., Li, Z.M., 2012.The Thermocompression Simulation Experiment of Source Rock Hydrocarbon Generation and Expulsion in Formation Porosity.Acta Sedimentologica Sinica, 30(5):955-963(in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S2096249517301035
Ma, Z.L., Zheng, L.J., Qin, J.Z., et al., 2011.Hydrocarbon Generation and Expulsion Caused by Pressure Difference between Source Rock and Reservoir during Basin Subsiding and Uplifting.Petroleum Geology & Experiment, 33(4):402-407(in Chinese with English abstract). doi: 10.1007/978-981-10-2407-8_3/fulltext.html
Pang, X.Q., 1995.Theory and Application of the Hydrocarbon Expulsion Threshold Controlling Petroleum Distribution.Petroleum Industry Press, Beijing, 34-56(in Chinese). doi: 10.1260/014459805775992735
Pepper, A.S., Corvi, P.J., 1995.Simple Kinetic Models of Petroleum Formation.Part I:Oil and Gas Generation from Kerogen.Marine and Petroleum Geology, 12(3):291-319. https://doi.org/10.1016/0264-8172(95)98381-e
Que, Y.Q., Zheng, L.J., Cheng, Q.Q., et al., 2015.Vitrinite Reflectance Correction of Residues in Organic Matter Pyrolysis Simulation Experiments.Petroleum Geology & Experiment, 37(4):506-511, 517(in Chinese with English abstract).
Ritter, U., 2003.Solubility of Petroleum Compounds in Kerogen:Implications for Petroleum Expulsion.Organic Geochemistry, 34(3):319-326. https://doi.org/10.1016/s0146-6380(02)00245-0
Shao, H.S., Huang, X.Z., Yan, C.F., et al., 2002.Conditions for the Formation of Immature Oil in Lacustrine Carbonate Rocks in Biyang Depression.Geochimica, 31(3):266-272(in Chinese with English abstract). doi: 10.1360/04yd0111
Stainforth, J.G., 2009.Practical Kinetic Modeling of Petroleum Generation and Expulsion.Marine and Petroleum Geology, 26(4):552-572. https://doi.org/10.1016/j.marpetgeo.2009.01.006
Tan, Y.M., Feng, J.H., Jin, G.X., et al., 2003.Geochemical Characteristics and Physical Features of Daerqi Oilfield, Baiyinchagan Depression.Geochimica, 32(3):271-281(in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S0146638007001416
Tu, J.Q., Chen, J.P., Zhang, D.J., et al., 2012.A Petrographic Classification of Macerals in Lacustrine Carbonate Source Rocks and Their Organic Petrological Characteristics:A Case Study on Jiuxi Basin, NW China.Acta Petrologica Sinica, 28(3):917-926(in Chinese with English abstract). http://d.wanfangdata.com.cn/Periodical_ysxb98201203020.aspx
Wang, G.L., Wang, T.G., Zhang, L.Y., 2007.Hydrocarbon Generation Characteristics for Lacustrine Carbonate Source Rocks in Bonan Sag of Jiyang Depression.Acta Petrolei Sinica, 28(2):62-68(in Chinese with English abstract). https://www.researchgate.net/profile/Guangli_Wang2/publication/279903124_Hydrocarbon-generation_characteristics_for_lacustrine_carbonate_source_rocks_in_Bonan_Sag_of_Jiyang_Depression/links/5653aae208ae1ef929762ebe.pdf?origin=publication_detail
Wu, S.Q., Tang, X.S., Du, X.J., et al., 2013.Geologic Characteristics of Continental Shale Oil in the Qianjiang Depression, Jianghan Salt Lake Basin.Journal of East China Institute of Technology (Natural Science), 36(3):282-286(in Chinese with English abstract).
Xiong, Y., Cheng, K.M., Ma, L.Y., 2006.Hydrocarbon Generation of Lower Cretaceous Lacustrine Carbonate in Jiuxi Depression.Petroleum Exploration and Development, 33(6):687-691(in Chinese with English abstract). http://d.wanfangdata.com.cn/Periodical_syktykf200606009.aspx
Yan, Y.H., Zou, Y.R., Qu, Z.Y., et al., 2015.Experimental Study on Hydrocarbon Retention-Expulsion of Es₄ Formation Source Rock in the Dongying Depression.Geochimica, 44(1):79-86(in Chinese with English abstract). https://es.scribd.com/doc/74594711/1st-International-Geosciences-Student-Conferince-2010-Abstract-Kit
Yang, Z.M., Wang, Q., Shi, J.A., et al., 2003.Controls on the Enrichment of Oil Pools in Qingxi Sag, Jiuxi Basin.Acta Sedimentologica Sinica, 21(4):695-701(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-CJXB200304023.htm
Yao, Y., Wang, G., Li, L., et al., 2017.The Reservoir Heterogeneity Characteristics and Affecting Factors of Tight Lacustrine Dolomite Reservoirs.Earth Science, 42(12):2327-2335 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2017.145
Zhang, J.C., Lin, L.M., Li, Y.X., et al., 2012.Classification and Evaluation of Shale Oil.Earth Science Frontiers, 19(5):322-331(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXQY201205032.htm
Zhang, Y.M., Zhang, F.D., 2010.Reservoir-Forming Characteristics of Baiyinchagan Sag in Erlian Basin.Petroleum Exploration and Development, 37(1):32-37(in Chinese with English abstract). doi: 10.1016/S1876-3804(10)60012-2
Zhang, Z.P., Lin, C.M., Xu, S.M., et al., 2010.Sedimentary Characteristics and Evolution of Lower Cretaceous Duhongmu Formation in Baiyinchagan Sag, Erlian Basin in Inner Mongolia.Journal of Stratigraphy, 34(3):303-311(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DCXZ201003012.htm
Zheng, L.J., Guan, D.F., Guo, X.W., et al., 2015.Key Geological Conditions Affecting Pyrolysis Experiments of Marine Source Rocks for Hydrocarbon Generation.Earth Science, 40(5):909-917(in Chinese with English abstract).https://doi.org/https://doi.org/10.3799/dqkx.2015.075 https://www.researchgate.net/publication/281687728_Key_geological_conditions_affecting_pyrolysis_experiments_of_marine_source_rocks_for_hydrocarbon_generation
Zheng, L.J., He, S., Qin, J.Z., et al., 2011.Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion.Earth Science, 36(1):83-92(in Chinese with English abstract). https://doi.org/10.3799/dqkx.2011.009
Zheng, L.J., Wang, Q., Qin, J.Z., et al., 2008.Hydrocarbon-Regeneration Capability of Marine Paleo-Reservoir and Soluble Organic Matter.Petroleum Geology & Experiment, 30(4):390-395(in Chinese with English abstract). doi: 10.3969/j.issn.1673-8926.2017.06.004
Zou, C.N, Yang, Z., Cui, J.W., et al., 2013.Formation Mechanism, Geological Characteristics and Development Strategy of Nonmarine Shale Oil in China.Petroleum Exploration and Development, 40(1):14-26(in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S1876380413600026
陈建军, 程克明, 熊英, 等, 2005.酒西坳陷下白垩统藻纹层灰岩生烃特征.石油勘探与开发, 32(6):61-65. doi: 10.3321/j.issn:1000-0747.2005.06.014
伏卫东, 陈祥, 孙凤华, 等, 2002.泌阳凹陷湖相白云岩油气储集性能及勘探潜力.江汉石油学院学报, 24(1):8-10. http://d.wanfangdata.com.cn/Periodical_jhsyxyxb200201003.aspx
关德范, 徐旭辉, 李志明, 等, 2014.烃源岩有限空间生烃理论与应用.北京:石油工业出版社, 49-63.
蒋飞虎, 刘晓丽, 许书堂, 1998.二连盆地白音查干凹陷早白垩世轮藻化石及其时代意义.微体古生物学报, 15(1):85-90. http://d.wanfangdata.com.cn/Periodical_dqsydzykf200303005.aspx
李吉君, 史颖琳, 章新文, 等, 2014.页岩油富集可采主控因素分析:以泌阳凹陷为例.地球科学, 39(7):848-857. https://doi.org/10.3799/dqkx.2014.079
李莉, 徐国盛, 王威, 等, 2007.白音查干凹陷达尔其油田油气成藏规律.成都理工大学学报(自然科学版), 34(3):277-284. http://d.old.wanfangdata.com.cn/Periodical/cdlgxyxb200703010
黎茂稳, 李志明, 李政, 等, 2015.陆相页岩油形成演化与赋存机理.中国石化石油勘探开发研究院无锡石油地质研究所, 无锡. http://industry.wanfangdata.com.cn/dl/Detail/Conference?id=Conference_8177107
李志明, 郑伦举, 马中良, 等, 2011.烃源岩有限空间油气生排模拟及其意义.石油实验地质, 33(5):447-451, 459. doi: 10.11781/sysydz201105447
卢双舫, 黄文彪, 陈方文, 等, 2012.页岩油气资源分级评价标准探讨.石油勘探与开发, 39(2):249-256. https://www.wenkuxiazai.com/doc/ee4adf3883c4bb4cf7ecd1ea.html
马素萍, 罗春树, 田春桃, 等, 2012.湖相碳酸盐烃源岩热解生烃特征.成都理工大学学报(自然科学版), 39(6):583-587. http://d.wanfangdata.com.cn/Periodical_cdlgxyxb201206003.aspx
马素萍, 孙东, 张晓宝, 等, 2011.酒西盆地青西凹陷下白垩统湖相烃源岩生烃动力学研究.天然气地球科学, 22(2):219-223. http://www.cqvip.com/QK/97226X/201102/37582014.html
马中良, 郑伦举, 李志明, 2012.烃源岩有限空间温压共控生排烃模拟实验研究.沉积学报, 30(5):955-963. https://www.researchgate.net/profile/Zhongliang_Ma/publication/274899289_The_Thermocompression_Simulation_Experiment_of_Source_Rock_Hydrocarbon_Generation_and_Expulsion_in_Formation_Porosity/links/552c86140cf29b22c9c45e57.pdf?origin=publication_list
马中良, 郑伦举, 秦建中, 等, 2011.盆地沉降、抬升过程中源储压差的生排烃效应.石油实验地质, 33(4):402-407. doi: 10.11781/sysydz201104402
庞雄奇, 1995.排烃门限控油气理论与应用.北京:石油工业出版社, 34-56.
阙永泉, 郑伦举, 承秋泉, 等, 2015.有机质热解模拟实验残留物镜质体反射率校正研究.石油实验地质, 37(4):506-511, 517. doi: 10.11781/sysydz201504506
邵宏舜, 黄杏珍, 闫存凤, 等, 2002.泌阳凹陷湖相碳酸盐岩未成熟石油的形成条件.地球化学, 31(3):266-272. http://www.cnki.com.cn/Article/CJFDTotal-CJXB6S1.007.htm
谈玉明, 冯建辉, 靳广兴, 等, 2003.白音查干凹陷达尔其油田原油地球化学与物性特征.地球化学, 32(3):271-281. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqhx200303009
涂建琪, 陈建平, 张大江, 等, 2012.湖相碳酸盐岩烃源岩有机显微组分分类及其岩石学特征——以酒西盆地为例.岩石学报, 28(3):917-926. http://d.wanfangdata.com.cn/Periodical_ysxb98201203020.aspx
王广利, 王铁冠, 张林晔, 2007.济阳坳陷渤南洼陷湖相碳酸盐岩成烃特征.石油学报, 28(2):62-68. doi: 10.7623/syxb200702011
吴世强, 唐小山, 杜小绢, 等, 2013.江汉盆地潜江凹陷陆相页岩油地质特征.东华理工大学学报(自然科学版), 36(3):282-286. http://bianke.cnki.net/Web/Article/GDLX201305013.html
熊英, 程克明, 马立元, 2006.酒西坳陷下白垩统湖相碳酸盐岩生烃研究.石油勘探与开发, 33(6):687-691. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syktykf200606009
颜永何, 邹艳荣, 屈振亚, 等, 2015.东营凹陷沙四段烃源岩留-排烃量的实验研究.地球化学, 44(1):79-86. https://core.ac.uk/display/71730927
杨智明, 王琪, 史基安, 等, 2003.酒西坳陷青西凹陷富油的地质-地球化学因素分析.沉积学报, 21(4):695-701. http://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200103003.htm
姚悦, 王刚, 李乐, 等, 2017.湖相致密白云岩不均一油藏特征及主控因素.地球科学, 42(12):2327-2335. https://doi.org/10.3799/dqkx.2017.145
张金川, 林腊梅, 李玉喜, 等, 2012.页岩油分类与评价.地学前缘, 19(5):322-331. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=dxqy201205032&dbname=CJFD&dbcode=CJFQ
张亚敏, 张放东, 2010.二连盆地白音查干凹陷成藏特征.石油勘探与开发, 37(1):32-37. https://mall.cnki.net/lunwen-2008068656.html
张志萍, 林春明, 徐深谋, 等, 2010.二连盆地白音查干凹陷下白垩统都红木组沉积特征及演化.地层学杂志, 34(3):303-311. https://www.wenkuxiazai.com/doc/98e621f4f61fb7360b4c6527-4.html
郑伦举, 关德范, 郭小文, 等, 2015.影响海相烃源岩热解生烃过程的地质条件.地球科学, 40(5):909-917. https://doi.org/10.3799/dqkx.2015.075
郑伦举, 何生, 秦建中, 等, 2011.近临界特性的地层水及其对烃源岩生排烃过程的影响.地球科学, 36(1):83-92. https://doi.org/10.3799/dqkx.2011.009
郑伦举, 王强, 秦建中, 等, 2008.海相古油藏及可溶有机质再生烃气能力研究.石油实验地质, 30(4):390-395. doi: 10.11781/sysydz200804390
邹才能, 杨智, 崔景伟, 等, 2013.页岩油形成机制、地质特征及发展对策.石油勘探与开发, 40(1):14-26. https://www.wenkuxiazai.com/doc/cc9d54400722192e4536f6f4.html