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    内蒙古赵井沟铌钽矿床燕山期成矿:来自LA-MC-ICP-MS独居石、锆石U-Pb和黑云母40Ar-39Ar年龄的证据

    李志丹 李效广 崔玉荣 李国占 张佳 郭虎 刘文刚 张超 俞礽安 谢瑜 王佳营

    李志丹, 李效广, 崔玉荣, 李国占, 张佳, 郭虎, 刘文刚, 张超, 俞礽安, 谢瑜, 王佳营, 2019. 内蒙古赵井沟铌钽矿床燕山期成矿:来自LA-MC-ICP-MS独居石、锆石U-Pb和黑云母40Ar-39Ar年龄的证据. 地球科学, 44(1): 234-247. doi: 10.3799/dqkx.2018.100
    引用本文: 李志丹, 李效广, 崔玉荣, 李国占, 张佳, 郭虎, 刘文刚, 张超, 俞礽安, 谢瑜, 王佳营, 2019. 内蒙古赵井沟铌钽矿床燕山期成矿:来自LA-MC-ICP-MS独居石、锆石U-Pb和黑云母40Ar-39Ar年龄的证据. 地球科学, 44(1): 234-247. doi: 10.3799/dqkx.2018.100
    Li Zhidan, Li Xiaoguang, Cui Yurong, Li Guozhan, Zhang Jia, Guo Hu, Liu Wengang, Zhang Chao, Yu Reng'an, Xie Yu, Wang Jiaying, 2019. Yanshanian Mineralization of Zhaojinggou Nb-Ta Deposit, Inner Mongolia: Evidences from the Monazite and Zircon LA-MC-ICP-MS U-Pb and Biotite 40Ar-39Ar Geochronology. Earth Science, 44(1): 234-247. doi: 10.3799/dqkx.2018.100
    Citation: Li Zhidan, Li Xiaoguang, Cui Yurong, Li Guozhan, Zhang Jia, Guo Hu, Liu Wengang, Zhang Chao, Yu Reng'an, Xie Yu, Wang Jiaying, 2019. Yanshanian Mineralization of Zhaojinggou Nb-Ta Deposit, Inner Mongolia: Evidences from the Monazite and Zircon LA-MC-ICP-MS U-Pb and Biotite 40Ar-39Ar Geochronology. Earth Science, 44(1): 234-247. doi: 10.3799/dqkx.2018.100

    内蒙古赵井沟铌钽矿床燕山期成矿:来自LA-MC-ICP-MS独居石、锆石U-Pb和黑云母40Ar-39Ar年龄的证据

    doi: 10.3799/dqkx.2018.100
    基金项目: 

    国家自然科学基金项目 41502082

    中国地质调查局项目 DD20160129

    中国地质调查局项目 DD20160039

    中国地质调查局项目 DD20160014

    中国地质调查局项目 12120113057300

    详细信息
      作者简介:

      李志丹(1986-), 男, 工程师, 从事矿床学研究工作

    • 中图分类号: P618.7

    Yanshanian Mineralization of Zhaojinggou Nb-Ta Deposit, Inner Mongolia: Evidences from the Monazite and Zircon LA-MC-ICP-MS U-Pb and Biotite 40Ar-39Ar Geochronology

    • 摘要: 内蒙古武川县赵井沟铌钽矿是新近取得勘查突破的一例大型铌钽矿床.矿体赋存岩石为含天河石钠长花岗岩,其次为花岗细晶岩、云英岩及天河石花岗伟晶岩.运用LA-MC-ICP-MS法对矿区钠长花岗(细晶)岩脉、正长花岗岩中的独居石、锆石进行了U-Pb同位素年龄测定,同时对石英-黑云母脉中的黑云母进行了40Ar-39Ar定年.4件独居石的LA-MC-ICP-MS U-Pb年龄分别为124±2 Ma(MSWD=2.9,n=27)、124±3 Ma(MSWD=2.0,n=46)、121±1 Ma(MSWD=3.3,n=43)和124±2 Ma(MSWD=3.2,n=12),1件锆石的LA-MC-ICP-MS U-Pb年龄为125±1 Ma(MSWD=1.6,n=18);黑云母40Ar-39Ar坪年龄为133.84±0.79 Ma(MSWD=3.31),40Ar/36Ar-39Ar/36Ar等时线年龄为134.55±0.79 Ma(MSWD=1.93),反等时线年龄为134.58±0.80 Ma(MSWD=1.99),这些年龄限定赵井沟铌钽矿形成于早白垩世.综合分析表明,燕山期是内蒙古地区重要的铌钽成矿期,赵井沟铌钽矿是燕山期伸展体制下构造岩浆活动的产物.

       

    • 图  1  内蒙古乌拉山-大青山一带地质矿产简图

      图a据Zhao and Cawood(2012)修改;图b据王梁等(2015)修改

      Fig.  1.  Simplified geological map of the Wulashan-Daqingshan region, Inner Mongolia

      图  2  内蒙古赵井沟铌钽矿区域地质简图

      据内蒙古自治区第一地质矿产勘查开发院, 2013, 内蒙古自治区武川县赵井沟矿区铌钽矿详查报告修改

      Fig.  2.  Regional geological map of Zhaojinggou Nb-Ta deposit, Inner Mongolia

      图  3  内蒙古赵井沟铌钽矿区地质图

      据内蒙古自治区第一地质矿产勘查开发院, 2013, 内蒙古自治区武川县赵井沟矿区铌钽矿详查报告修改

      Fig.  3.  Geological map of Zhaojinggou Nb-Ta deposit, Inner Mongolia

      图  4  赵井沟铌钽矿Ⅰ号勘探线剖面

      据内蒙古自治区第一地质矿产勘查开发院, 2013, 内蒙古自治区武川县赵井沟矿区铌钽矿详查报告修改

      Fig.  4.  No.1 cross section of Zhaojinggou Nb-Ta deposit

      图  5  赵井沟铌钽矿区代表性岩矿石照片

      a.矿化钠长花岗岩;b.矿化钠长花岗细晶岩;c.矿化天河石伟晶岩;d.角砾岩;e.栓马庄组砂岩;f.栓马庄组砾岩;g.矿化钠长花岗岩中的石英-黑云母细脉和石英-天河石-白云母细脉;h.含黑钨矿石英脉;i.白垩纪正长花岗岩

      Fig.  5.  Photos of representative rocks and ores in the Zhaojinggou Nb-Ta deposit, Inner Mongolia

      图  6  内蒙古赵井沟铌钽矿稀有稀土矿物显微照片

      a.产于钠长花岗岩中的铌钽铁矿,边部被锆石浸蚀交代;b.钠长花岗岩中产于萤石边部的铌钽铁矿与磷钇矿呈共生关系;c.钠长石中铌钽铁矿交代锆石呈交代残余结构;d.产于石英脉中的粒状钽锡石;e.产于萤石中的独居石呈包含结构;f.产于钾长石内部和边部的氟碳铈矿与锆石、萤石呈共生关系;图中照片通过岛津EPMA-1600电子探针仪观测得到

      Fig.  6.  Micrographs of rare and REE minerals of Zhaojinggou Nb-Ta deposit, Inner Mongolia

      图  7  赵井沟铌钽矿代表性独居石背散射图像(BSE)和锆石CL图像

      Fig.  7.  Representative BSE images of monazites and CL images of zircons from the Zhaojinggou Nb-Ta deposit

      图  8  赵井沟铌钽矿独居石U-Pb年龄Tera-Wasserburg谐和图

      Fig.  8.  Tera-Wasserburg concordia diagrams for monazites from the Zhaojinggou Nb-Ta deposit

      图  9  赵井沟铌钽矿钠长花岗岩样品锆石U-Pb年龄谐和图

      Fig.  9.  Zircon U-Pb concordia plots of the albite granite sample from the Zhaojinggou Nb-Ta deposit

      图  10  赵井沟铌钽矿黑云母阶段升温年龄图谱

      Fig.  10.  40Ar/39Ar age spectrum of biotite in the Zhaojinggou Nb-Ta deposit

      图  11  赵井沟铌钽矿黑云母40Ar-39Ar等时线(a)和反等时线(b)年龄

      Fig.  11.  40Ar/39Ar age isochron (a) and inverse isochron (b) diagrams of biotite in the Zhaojinggou Nb-Ta deposit

      图  12  内蒙古中东部地区重要矿床燕山期成岩成矿年龄

      Fig.  12.  Diagenetic and metallogenic age of main ore deposits during Yanshanian Period in central-eastern Inner Mongolia

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