Geological Characteristics and Metallogenic Epoch of Quartz vein type Tungsten (Tin) Deposit in Tangchun, Eastern Guangdong Province
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摘要: 塘唇钨（锡）矿是近年来新发现的一个具有大型规模找矿潜力的石英脉型矿床.矿床产于粤东龙窝花岗闪长岩岩体西部外接触带，赋矿地层为下侏罗统金鸡组碎屑岩，该层位是南岭及邻区石英脉型钨锡矿的最新赋矿地层.在详细的野外地质调查基础上，对矿床含钨石英脉中的白云母进行40Ar-39Ar测年，获得白云母40Ar-39Ar坪年龄为150±1 Ma，等时线年龄为149±2 Ma（MSWD=1.20），它们在误差范围内一致，为南岭地区燕山早期大规模成岩成矿作用高峰期的产物.塘唇钨（锡）矿的发现，不仅拓宽了石英脉型钨锡矿的找矿视野，还有助于完善石英脉型钨锡矿成矿规律和成矿模式，对区域下一步找矿具有重要指导意义.Abstract: The Tangchun tungsten(tin) deposit is a newly discovered quartz vein type deposit and the potential for prospecting is huge. The deposit occurs in the western outer contact zone of the Longwo granodiorite pluton in Eastern Guangdong Province. The ore-hosting strata are the clastic rocks of the Lower Jurassic Jinji formation, which are considered to be the youngest ore-hosting strata in the Nanling and its adjacent areas.On the basis of detailed field geological surveys, a muscovite 40Ar-39Ar plateau age of 150±1 Ma and an isochron age of 149±2 Ma (MSWD=1.20) have been obtained for a W-bearing quartz vein in the deposit, which are the same within the analytical uncertainties. Our 40Ar-39Ar dating results have shown that the Tangchun tungsten (tin) deposit was the product of early Yanshanian large scale petrogenesis and metallogenesis in the Nanling Range. The newly discovered Tangchun tungsten (tin) deposit is of great guiding significance in exploration since it not only broadens our mind in prospecting for quartz vein type tungsten-tin deposit, but also provides an opportunity to thoroughly unravel the metallogenic regularity as well as metallogenic models of the quartz vein type tungsten-tin deposit.
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图 2 塘唇钨(锡)矿地质简图
1.下侏罗统金鸡组下段；2.中侏罗世花岗闪长岩；3.辉石闪长岩脉；4.地质界线；5.断层及编号；6.勘探线及编号；7.钻孔及编号；8.矿带范围；9.钨矿化带及编号；10.锡矿化带及编号
Fig. 2. Geological sketch map of Tangchun tungsten (tin) deposit
图 3 塘唇钨(锡)矿8号勘探线地质剖面
1.第四系；2.下侏罗统金鸡组下段；3.剥土及编号；4.平硐及编号；5.钻孔及编号；6.地质界线；7.钨矿脉；8.锡矿脉；9.钨矿脉编号：厚度(m)/品位；10.锡矿脉编号：厚度(m)/品位
Fig. 3. Line No.8 geological section of the Tangchun Tungsten (Tin) deposit
图 4 塘唇钨(锡)矿地表及深部含钨石英脉
a.地表含钨石英细脉；b.深部含钨石英大脉；Apy.毒砂；Ms.白云母；Qtz.石英；Wf.黑钨矿；J1jna.下侏罗统金鸡组下段
Fig. 4. Photographs of W bearing quartz vein in Tangchun tungsten (tin) deposit
图 5 塘唇钨(锡)矿含钨石英脉中白云母40Ar-39Ar坪年龄(a)和等时线年龄(b)
Fig. 5. 40Ar-39Ar plateau age (a) and isochron age (b) for muscovite from W bearing quartz vein, Tangchun tungsten (tin) deposit
表 1 塘唇钨(锡)矿含钨石英脉中白云母40Ar-39Ar同位素年龄分析结果
Table 1. Analyzed 40Ar-39Ar isotopic result of muscovite from W bearing quartz vein, Tangchun tungsten (tin) deposit
加热阶段 T(℃) (40Ar/39Ar)m (36Ar/39Ar)m (37Ar/39Ar)m (38Ar/39Ar)m 40Ar(%) F 39Ar(10-14 mol) 39Ar累积(%) 年龄(Ma) ±1σ(Ma) 1 700 258.636 4 0.828 5 0.000 0 0.161 5 5.34 13.808 5 0.02 0.06 108.0 21.0 2 800 12.920 5 0.016 2 0.105 0 0.016 6 62.95 8.134 7 0.83 2.46 64.4 0.8 3 840 20.190 2 0.011 9 0.000 0 0.014 6 82.59 16.674 3 1.23 5.99 129.6 1.4 4 880 21.325 3 0.008 1 0.016 3 0.013 9 88.75 18.925 8 1.66 10.78 146.4 1.4 5 920 20.187 8 0.003 0 0.013 6 0.013 0 95.61 19.301 2 3.75 21.59 149.2 1.4 6 950 19.753 8 0.001 6 0.004 3 0.012 7 97.53 19.266 0 4.55 34.70 149.0 1.4 7 980 19.682 4 0.001 3 0.013 9 0.012 6 98.00 19.288 9 5.59 50.79 149.1 1.4 8 1 010 19.759 3 0.001 1 0.000 0 0.012 6 98.31 19.426 3 6.06 68.24 150.2 1.4 9 1 040 19.974 1 0.002 3 0.029 8 0.013 2 96.59 19.294 1 3.24 77.58 149.2 1.4 10 1 080 20.224 0 0.002 8 0.024 5 0.013 1 95.94 19.403 5 2.88 85.89 150.0 1.5 11 1 120 20.144 6 0.002 4 0.028 3 0.012 8 96.43 19.426 0 2.95 94.39 150.2 1.4 12 1 160 20.594 4 0.003 5 0.155 5 0.013 2 95.04 19.576 2 0.37 95.45 151.3 1.8 13 1 400 22.398 4 0.007 3 0.074 5 0.014 5 90.41 20.252 4 1.49 99.73 156.3 1.6 14 1 430 53.268 5 0.098 5 0.000 0 0.032 6 45.37 24.169 7 0.09 100.00 185.0 3.7 注：表中下标m代表样品中测定的同位素比值；F=40Ar*/39Ar，是指放射成因40Ar和39Ar的比值；样品重量W=14.50 mg，J=0.004 468. 
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表 2 赣南-粤北地区石英脉型钨锡矿成矿时代
Table 2. The ages of mineralization for quartz vein type Tungsten-Tin deposit in Southern Jiangxi Province and Northern Guangdong Province
地区 矿床 测年对象 测年方法 年龄(Ma) 参考文献 淘锡坑钨矿 辉钼矿 Re-Os 154±4 陈郑辉等(2006) 淘锡坑钨矿 白云母 Ar-Ar 153±2 郭春丽等(2008) 淘锡坑钨矿 白云母 Ar-Ar 153±1 郭春丽等(2008) 淘锡坑钨矿 白云母 Ar-Ar 155±1 郭春丽等(2008) 樟斗钨矿 辉钼矿 Re-Os 149±7 丰成友等(2007) 赣南 牛岭钨矿 辉钼矿 Re-Os 155±4 丰成友等(2007) 大吉山钨矿 辉钼矿 Re-Os 161±1 张思明等(2011) 九龙脑钨矿 辉钼矿 Re-Os 152+1 丰成友等(2011) 樟东坑钨矿 辉钼矿 Re-Os 151+2 丰成友等(2011) 樟东坑钨矿 辉钼矿 Re-Os 155+2 李光来等(2014) 樟东坑钨矿 辉钼矿 Re-Os 155+2 李光来等(2014) 石人嶂钨锡矿 辉钼矿 Re-Os 159±2 付建明等(2008) 师姑山钨锡矿 辉钼矿 Re-Os 154±3 付建明等(2008) 红岭钨矿 辉钼矿 Re-Os 159±2 王小飞等(2010) 红岭钨矿 辉钼矿 Re-Os 159±1 王小飞等(2010) 粤北 瑶岭钨矿 白云母 Ar-Ar 149±1 翟伟等(2011) 和尚田钨锡多金属矿 白云母 Ar-Ar 158±2 付建明等(2013a) 和尚田钨锡多金属矿 白云母 Ar-Ar 161±1 武国忠等(2014) 梅子窝钨矿 辉钼矿 Re-Os 151±1 武国忠等(2014) 梅子窝钨矿 黑云母 Ar-Ar 151±1 武国忠等(2014)
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