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    东天山小热泉子矿床流体包裹体及矿床成因

    张文东 吴湘滨 邓小华 毛启贵 张会琼 杨利亚 陈曦 许骏 张岩 王洋

    张文东, 吴湘滨, 邓小华, 毛启贵, 张会琼, 杨利亚, 陈曦, 许骏, 张岩, 王洋, 2018. 东天山小热泉子矿床流体包裹体及矿床成因. 地球科学, 43(9): 3036-3048. doi: 10.3799/dqkx.2018.150
    引用本文: 张文东, 吴湘滨, 邓小华, 毛启贵, 张会琼, 杨利亚, 陈曦, 许骏, 张岩, 王洋, 2018. 东天山小热泉子矿床流体包裹体及矿床成因. 地球科学, 43(9): 3036-3048. doi: 10.3799/dqkx.2018.150
    Zhang Wendong, Wu Xiangbin, Deng Xiaohua, Mao Qigui, Zhang Huiqiong, Yang Liya, Chen Xi, Xu Jun, Zhang Yan, Wang Yang, 2018. Fluid Inclusions Constraints on the Origin of the Xiaorequanzi Deposit in Eastern Tianshan. Earth Science, 43(9): 3036-3048. doi: 10.3799/dqkx.2018.150
    Citation: Zhang Wendong, Wu Xiangbin, Deng Xiaohua, Mao Qigui, Zhang Huiqiong, Yang Liya, Chen Xi, Xu Jun, Zhang Yan, Wang Yang, 2018. Fluid Inclusions Constraints on the Origin of the Xiaorequanzi Deposit in Eastern Tianshan. Earth Science, 43(9): 3036-3048. doi: 10.3799/dqkx.2018.150

    东天山小热泉子矿床流体包裹体及矿床成因

    doi: 10.3799/dqkx.2018.150
    基金项目: 

    国土资源部公益性行业科研专项 201411026

    中国地质调查局项目 1212011140056

    国家自然科学基金项目 41572077

    国家重点基础研究发展计划(973计划)项目 2014CB440803

    中国地质调查局项目 12120114081701

    中国地质调查局项目 DD20160071

    详细信息
      作者简介:

      张文东(1992-), 男, 硕士研究生, 主要从事矿产普查与勘探方面的研究.E-mail:1198807031@qq.com

      通讯作者:

      邓小华, E-mail:dxh198411@126.com

    • 中图分类号: P611

    Fluid Inclusions Constraints on the Origin of the Xiaorequanzi Deposit in Eastern Tianshan

    • 摘要: 小热泉子铜矿是东天山最早发现的铜矿床之一,但其成矿流体性质、演化,以及矿床成因尚不明确.通过对不同成矿期次流体包裹体开展显微测温和激光拉曼分析,结果表明小热泉子成矿可分为VMS成矿期(包含黄铁矿、黄铜矿-闪锌矿阶段)、热液叠加期(包含石英-硫化物、碳酸盐阶段)和表生期.VMS成矿期包裹体以水溶液型为主,少量含CO2包裹体,其均一温度为234~392 ℃,盐度为3.5%~13.3% NaCleqv;热液叠加期包裹体为水溶液型,在122~296 ℃达到均一,盐度为1.4%~12.1% NaCleqv.激光拉曼分析显示包裹体成分以H2O为主,含少量CO2和SO2.小热泉子铜矿早期高温-中高盐度的VMS成矿系统叠加了后期低温-中低盐度的热液系统,其成因类型应为典型的叠加型成矿系统.

       

    • 图  1  中亚造山带构造简图(a)和东天山区域地质及矿床分布(b)

      王京彬等(2006)修改

      Fig.  1.  Tectonic sketch of the Central Asian orogenic belt (a) and regional geological sketch in the East Tianshan, showing deposit distribution (b)

      图  2  小热泉子地区地层柱状图

      Fig.  2.  Stratigraphic histogram of Xiaorequanzi region

      图  3  小热泉子矿区地质简图

      李凤鸣等(2002)刘申态等(2012)修改

      Fig.  3.  Geological sketch of the Xiaorequanzi deposit

      图  4  (a) 小热泉子矿区地质图;(b)小热泉子Ⅰ号矿床7勘探线纵剖面

      李凤鸣等(2002)刘申态等(2012)修改

      Fig.  4.  (a) Geological sketch of Xiaorequanzi deposit; (b) the profile of No.7 exploration line in Xiaorequanzi deposit

      图  5  小热泉子矿床矿石和矿物特征

      a.VMS成矿期的块状铜矿石;b.VMS成矿期的下盘支脉系统中的网脉状铜矿石;c.VMS成矿期的块状锌矿石被热液叠加期的石英-黄铜矿-黄铁矿脉切穿;d.VMS成矿期的黄铁矿阶段,黄铁矿常被黄铜矿交代呈交代残余结构;e.VMS成矿期的黄铜矿-闪锌矿阶段,闪锌矿出溶黄铜矿呈固溶体分离结构;f.VMS成矿期支脉系统中的绢云母化、碳酸盐化等蚀变;g.黄铜矿-闪锌矿阶段发生绿泥石化,后被热液叠加期石英-黄铜矿脉切穿;h.VMS成矿期的浸染状闪锌矿被热液叠加期的方解石脉切穿;i.表生氧化期的铜蓝,交代早期黄铜矿

      Fig.  5.  Photographs showing the geological characteristics of the Xiaorequanzi deposit

      图  6  小热泉子Ⅰ号矿床成矿阶段划分及矿物生成顺序

      Fig.  6.  Mineral paragenesis and ore-forming stages of the Xiaorequanzi deposit

      图  7  小热泉子矿床流体包裹体镜下照片

      a.Ⅰ号矿床VMS成矿期黄铜矿-闪锌矿阶段石英中的W型和C型包裹体共生;b.黄铜矿-闪锌矿阶段石英中的W型包裹体;c.黄铜矿-闪锌矿阶段石英中的富液相W型包裹体(左)和富气相W型包裹体(右)共存;d.黄铜矿-闪锌矿阶段的富气相W型包裹体(临界均一);e.Ⅰ号矿床热液叠加成矿期石英-硫化物阶段石英中的W型包裹体

      Fig.  7.  Photomicrographs of fluid inclusions in Xiaorequanzi deposit

      图  8  小热泉子矿床流体包裹体均一温度-盐度直方图

      Fig.  8.  Histograms of homogenization temperatures and salinities of fluid inclusions of the Xiaorequanzi deposit

      图  9  小热泉子矿床激光拉曼(LRM)图谱

      Fig.  9.  Laser Raman (LRM) atlas from the fluid inclusions of the Xiaorequanzi deposit

      图  10  小热泉子矿床压力估算结果

      底图据Driesner and Heinrich(2007)

      Fig.  10.  Evolution of pressure and salinity in each metallogenic period in Xiaorequanzi deposit

      图  11  小热泉子矿床盐度-温度散点图

      Fig.  11.  The homogenization temperature vs. salinity plot of the Xiaorequanzi deposit

      表  1  小热泉子矿床流体包裹体显微测温数据表

      Table  1.   Microthermometric data of the Xiaorequanzi deposit

      成矿期 成矿阶段 类型 数量
      (个)
      直径
      (μm)
      气液体积比
      (%)
      Tm-CO2
      (℃)
      Tm-cl
      (℃)
      Th-CO2
      (℃)
      Tm-ice
      (℃)
      Th
      (℃)
      盐度(%NaCleqv)
      VMS成矿期 黄铜矿-闪锌矿阶段 W 56 4~6 30~45 -9.7~-2.1 234~392 3.5~13.3
      C 1 5 70 -57.2 5.4 25.1 297 8.5
      热液叠加成矿期 石英-硫化物阶段 W 61 3~7 15~25 -8.3~-0.8 122~296 1.4~12.1
      注:Tm-CO2为固相CO2初熔温度;Tm-cl为笼合物熔化温度;Tm-ice为冰点温度;Th为完全均一温度.
      下载: 导出CSV

      表  2  小热泉子矿床压力和深度估算表

      Table  2.   Data for Pressure and Depth of Xiaorequanzi Deposit

      成矿期次 密度(g/cm3) 压力(MPa) 深度(km)
      VMS成矿期 0.60~0.80 10~20 1.0~2.0
      后期热液叠加期 0.75~0.86 1.5~6.0 0.2~0.6
      下载: 导出CSV

      表  3  小热泉子矿床和典型VMS矿床温度、盐度数据

      Table  3.   Temperature and salinity data from the Xiaorequanzi deposit and VMS deposits

      矿床名 矿石构造 寄主矿物 均一温度(℃) 盐度(%NaCleqv) 文献来源
      小热泉子Ⅰ号矿床 块状矿 石英 234~392 3.5~13.3 本文
      青海玉树尕龙格玛 块状和网脉状 石英、重晶石 176~263 1.1~6.3 王键等,2017
      浙江平水矿床 块状矿 石英 217~328 3.2~5.7 Chen et al., 2015
      新疆阿舍勒矿床 含铜石英脉 石英 191~307 2.7~8.5 Zheng et al., 2013
      四川呷村矿床 块状矿 石英 153~350 1.1~7.2 党院等,2014
      日本小坂矿床 块状矿 石英 225~310 2.5~8.3 Urabe and Sato, 1978
      伊比利亚黄铁矿带块状硫化物矿床 块状矿和网脉状矿 石英 120~380 0.4~12.0 Toscano et al., 1997
      东太平洋海隆14°N海底硫化物矿床 块状矿 石英 160~350 3.2~4.8 Vanko et al., 1991
      下载: 导出CSV
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    • 收稿日期:  2018-01-13
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