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    新疆哈密小白石头钨钼矿床流体包裹体及矿床成因

    陈叙安 邓小华 张静 姜晓 郑震 吴艳爽 岳素伟

    陈叙安, 邓小华, 张静, 姜晓, 郑震, 吴艳爽, 岳素伟, 2018. 新疆哈密小白石头钨钼矿床流体包裹体及矿床成因. 地球科学, 43(9): 3086-3099. doi: 10.3799/dqkx.2018.171
    引用本文: 陈叙安, 邓小华, 张静, 姜晓, 郑震, 吴艳爽, 岳素伟, 2018. 新疆哈密小白石头钨钼矿床流体包裹体及矿床成因. 地球科学, 43(9): 3086-3099. doi: 10.3799/dqkx.2018.171
    Chen Shu'an, Deng Xiaohua, Zhang Jing, Jiang Xiao, Zheng Zhen, Wu Yanshuang, Yue Suwei, 2018. Fluid Inclusions Constraints on the Origin of the Xiaobaishitou W-Mo Deposit in Hami, Xinjiang, NW China. Earth Science, 43(9): 3086-3099. doi: 10.3799/dqkx.2018.171
    Citation: Chen Shu'an, Deng Xiaohua, Zhang Jing, Jiang Xiao, Zheng Zhen, Wu Yanshuang, Yue Suwei, 2018. Fluid Inclusions Constraints on the Origin of the Xiaobaishitou W-Mo Deposit in Hami, Xinjiang, NW China. Earth Science, 43(9): 3086-3099. doi: 10.3799/dqkx.2018.171

    新疆哈密小白石头钨钼矿床流体包裹体及矿床成因

    doi: 10.3799/dqkx.2018.171
    基金项目: 

    国家重点研发计划重点专项项目 2018YFC0604006

    国家重点基础研究发展计划(973计划)项目 2014CB440803

    国家自然科学基金项目 41572077

    中国地质调查局项目 1212011140056

    中国地质调查局项目 12120114081701

    详细信息
      作者简介:

      陈叙安(1994-), 男, 硕士研究生, 主要从事矿石学、岩石学、矿床学方面的研究

      通讯作者:

      邓小华

    • 中图分类号: P611

    Fluid Inclusions Constraints on the Origin of the Xiaobaishitou W-Mo Deposit in Hami, Xinjiang, NW China

    • 摘要: 新疆哈密小白石头钨钼矿床位于中天山地块,是北疆代表性的钨钼矿床,但人们对其成矿流体性质和矿床成因类型了解得很少.矿床地质研究表明,矿体主要产于三叠纪黑云母花岗岩与蓟县系卡瓦布拉克群碳酸盐岩接触带,根据穿插关系和矿物组合,成矿阶段可划分为干矽卡岩、湿矽卡岩、氧化物、硫化物和碳酸盐5个阶段,白钨矿和辉钼矿分别形成于氧化物和硫化物阶段.流体包裹体显微测温结果表明,成矿早期(干矽卡岩阶段)流体为中高温、中高盐度的NaCl-H2O-CO2体系,成矿晚期(碳酸盐阶段)演变为低温、低盐度的NaCl-H2O体系.小白石头矿床为矽卡岩型钨钼矿床,流体包裹体特征指示流体混合及降温可能是矿质沉淀的主要机制.

       

    • 图  1  中亚造山带构造简图(a)和东天山区域地质及矿床分布(b)

      Deng et al.(2017)修改

      Fig.  1.  Tectonic sketch of the Central Asian orogenic belt (a) and regional geological sketch in the East Tianshan, showing deposit distribution (b)

      图  2  小白石头矿区地质简图

      Deng et al.(2017)修改

      Fig.  2.  Geological sketch of Xiaobaishitou deposit

      图  3  小白石头钨矿床1矿段No.8勘探线剖面

      Deng et al.(2017)修改

      Fig.  3.  The profile of No.8 exploration line in Xiaobaishitou tungsten deposit

      图  4  小白石头矿床野外照片

      a.围岩矽卡岩化,被石英脉充填;b.石榴石矽卡岩被萤石交代;c.石榴石矽卡岩贯入炭质灰岩中;d.干矽卡岩阶段石榴石被绿帘石交代,二者被更晚的石英交代;e.围岩中发育石榴石包体;f.绿泥石、绿帘石交代早期石榴石

      Fig.  4.  Photos showing the geological characteristics of Xiaobaishitou deposit

      图  5  小白石头钨钼矿床成矿阶段划分及矿物生成顺序

      Fig.  5.  Mineral paragenesis and ore-forming stages of Xiaobaishitou W-Mo deposit

      图  6  小白石头矿床矿石及显微照片

      a.石榴石矽卡岩中浸染状辉钼矿;b石英-黄铁矿-黄铜矿脉;c.湿矽卡岩阶段绿帘石环带;d.氧化物阶段白钨矿交代绿帘石

      Fig.  6.  Ore samples and microphotographs of Xiaobaishitou deposit

      图  7  小白石头矿床流体包裹体显微照片

      a.干矽卡岩阶段的S型包裹体;b.干矽卡岩阶段W型包裹体;c.湿矽卡岩阶段W型包裹体群;d.氧化物阶段含NaCl子晶包裹体;e.氧化物阶段含KCl子晶包裹体;f.氧化物阶段不同气液比W型包裹体;g.硫化物阶段C型包裹体;h.硫化物阶段局部不同气液比的C型、W型包裹体共存,反映包裹体群沸腾的特征;i.碳酸盐阶段W型包裹体

      Fig.  7.  Photomicrographs showing fluid inclusions of the Xiaobaishitou deposit

      图  8  小白石头床流体包裹体均一温度、盐度直方图

      Fig.  8.  Histogram of homogenization temperatures and salinities of fluid inclusions of the Xiaobaishitou deposit

      图  9  小白石头钨钼矿床均一温度-盐度散点图

      Fig.  9.  The homogenization temperature and salinity plot of Xiaobaishitou W-Mo deposit

      表  1  小白石头矿床流体包裹体测温结果

      Table  1.   Microthermometric data of fluid inclusions of the Xiaobaishitou deposit

      成矿阶段 测试矿物 类型 完全均一温度(℃) 冰点/子矿物消失温度(℃) 盐度(% NaCleqv) 密度(g/cm3)
      干矽卡岩阶段 石榴石 W型 210~297 -5.6~-2.4 4.0~8.7 0.64~0.93
      C型 271~288 8.9~10.0
      湿矽卡岩阶段 绿帘石 W型 182~268 -2.0~-6.6 3.4~10.0 0.82~0.93
      氧化物阶段 白钨矿 W型 199~228 -5.1~-0.7 1.2~8.0 0.88~0.92
      W型 185~232 -4.8~-2.4 4.0~7.6 0.87~0.92
      氧化物阶段 石英 C型 199~211 8.0~8.8
      S型 212 318.9 39.7 1.18
      硫化物阶段 石英 W型 151~245 -6.1~-1.1 1.9~9.3 0.84~0.96
      C型 177~266 4.1~9.4
      碳酸盐阶段 方解石 W型 124~201 -5.7~-0.5 1.0~8.8 0.90~0.98
      下载: 导出CSV

      表  2  典型矽卡岩矿床的特征

      Table  2.   Geological characteristics of typical skarn deposits

      矽卡岩矿床 围岩 矿化特征 均一温度(℃) 盐度(% NaCleqv) 数据来源
      江西香炉山矽卡岩钨矿床 含碳泥质灰岩、黑云母花岗岩 细脉状、浸染状 143~383 0.4~9.2 吴胜华等,2014
      广东韶关市一六钨矿床 黑云母花岗岩 脉状、浸染状 152~390 1.5~45.4 唐一昂等,2017
      内蒙古红花尔基白钨矿矿床 二长花岗岩、黑云母花岗岩 脉状、浸染状 151~395 0.9~10.5 郭志军等,2016
      小白石头钨钼矿床 黑云母花岗岩、炭质灰岩 脉状、透镜状 123~297 1.0~39.7 本文
      下载: 导出CSV
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    • 收稿日期:  2018-02-19
    • 刊出日期:  2018-09-15

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