桂中昆仑关A型花岗岩锆石U-Pb年代学与地球化学特征

刘飞; 李堃; 黄圭成; 邱啸飞; 严乐佳; 陆世才

doi:10.3799/dqkx.2018.180

桂中昆仑关A型花岗岩锆石U-Pb年代学与地球化学特征

doi: 10.3799/dqkx.2018.180

刘飞^1,2,,
李堃^1,2, ,,
黄圭成^1,2,
邱啸飞^1,2,
严乐佳³,
陆世才³

1.
中国地质调查局武汉地质调查中心, 湖北武汉 430205
2.
中国地质调查局花岗岩成岩成矿地质研究中心, 湖北武汉 430205
3.
中国冶金地质总局广西地质勘查院, 广西南宁 530022

基金项目:

中国地质调查局地质矿产调查项目 121201009000150012

详细信息

作者简介:
刘飞(1988-), 男, 工程师, 主要从事区域地质调查工作

通讯作者:
李堃

中图分类号: P581
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- 被引次数: 0
出版历程
- 收稿日期: 2018-03-14
- 刊出日期: 2018-07-15

Zircon U-Pb Geochronology and Geochemical Characteristics of the Kunlunguan A-Type Granite in Central Guangxi

Liu Fei^{1,2
,},
Li Kun^{1,2
, ,},
Huang Guicheng^1,2,
Qiu Xiaofei^1,2,
Yan Lejia³,
Lu Shicai³

1.
Wuhan Center of China Geological Survey, Wuhan 430205, China
2.
Research Center of Granitic Diagenesis and Mineralization, China Geological Survey, Wuhan 430205, China
3.
Guangxi Geological Exploration Institute of China Metallurgical Geology Bureau, Nanning 530022, China

摘要

摘要: 华南腹地燕山期岩浆活动、成因及其构造意义存在争议.本文选取桂中地区昆仑关花岗岩为研究对象，进行了系统的年代学、地球化学和Sm-Nd同位素研究.锆石LA-ICP-MS U-Pb定年结果为97.7±1.3 Ma（MSWD=1.6），表明昆仑关花岗岩是燕山晚期岩浆活动产物.地球化学分析显示，岩体富硅（SiO₂=69.42%~72.52%），富碱（全碱=7.43%~8.43%），富钾（K₂O=4.00%~5.02%，K₂O/Na₂O比值=1.17~1.62），富铝（Al₂O₃=13.65%~14.25%），低钙（CaO=1.20%~2.78%）；富集Rb、Th、U、K、Pb，亏损Ba、Nb、Sr、P、Ti；轻稀土富集，重稀土亏损，具明显Eu负异常（δEu=0.45~0.61），稀土元素分配图呈典型的"右倾"型；里德曼指数（δ）为2.06~2.41，属高钾钙碱性系列，铝饱和指数（A/CNK）为0.93~1.16，属准铝质-过铝质岩石.岩体的ε_Nd（t）介于-7.68~-10.31，二阶段Nd模式年龄（T_DM2）为1.52~1.73 Ga，均值1.58 Ga.岩石学、地球化学和Sm-Nd同位素特征表明昆仑关花岗岩为A型花岗岩，是在伸展构造环境中及低压、高温条件下由古元古代华夏基底部分熔融形成，并伴有幔源岩浆的混合.结合邻区同期次的岩浆活动和成矿作用，表明100~90 Ma华南腹地经历了一次重要的岩石圈拉张事件.
- 昆仑关岩体 /
- A型花岗岩 /
- 华南 /
- 燕山晚期 /
- 岩石圈拉张 /
- 地球化学
Abstract: For studying the Late Yanshan magmatism in South China hinterland, and analyzing its petrogenesis and tectonic significance, this paper carries out systematical geochronological, geochemical and Sm-Nd isotopic investigations on the Kunlunguan granitic pluton in central Guangxi. LA-ICP-MS zircon U-Pb dating yields a weighted mean ²⁰⁶Pb/²³⁸U age of 97.7±1.3 Ma (MSWD=1.6), implying its Late Yanshan intrusion time. Geochemical compositions show that it is enriched in Si (SiO₂=69.42%-72.52%), alkali (total alkali=7.43%-8.43%), K(K₂O=4.00%-5.02%, K₂O/Na₂O=1.17-1.62), Al(Al₂O₃=13.65%-14.25%), but depleted in Ca(CaO=1.20%-2.78%). Rb, Th, U, K, Pb elements are enriched in the intrusion while Ba, Nb, Sr, P, Ti elements are depleted. REE is characterized by obvious negative Eu anomalies (δEu=0.45-0.61), and exhibits right-dipping patterns with LREE enrichment. Its aluminum saturation index value (A/CNK) ranges from 0.93 to 1.16, while redman index value (δ) ranges from 2.06 to 2.41, indicating the intrusion belongs to high-K calc-alkaline series and metaluminous to peraluminous rocks. Its ε_Nd(t) value varies between -7.68 to -10.31, and the correspondent two-stage Nd isotopic modal ages range from 1.52 to 1.73 Ga (average value is 1.58 Ga). Mineralogy and geochemical characteristics indicate that Kunlunguan pluton is A-type granite. It has formed by partial melting of the Cathaysia paleoproterozoic felsic crustal material, being mixed with some mantle drived mafic malts, under a low-pressure, high-temperature condition at an extensional tectonic setting. Taking the igneous and metallogenic events in central Guangxi and adjacent areas into consideration, this study suggests that the lithosphere of South China hinterland thinned in 100-90 Ma.
- Kunlunguan pluton /
- A-type granite /
- South China /
- Late Yanshan /
- lithosphere extension /
- geochemistry

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图 1 华南板块现今大地构造位置图(a)；研究区大地构造位置(b)；昆仑关岩体地质简图(c)

1.寒武系；2.泥盆系；3.石炭系；4.二叠系；5.三叠系；6.古近系；7.第四系；8.主体；9.补体；10.采样位置及编号.a据Li et al.(2014)；b据乔龙(2016)；c据广西地质局区域地质测量队(广西地质局区域地质测量队，1973；广西1:200 000南宁幅地质图及报告)

Fig. 1. Simplified tectonic position of South China map (a) and Simplified tectonic position of research region (b) and Simplified geologic map of Kunlunguan pluton (c)

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图 2 昆仑关花岗岩野外露头图(a)和镜下特征图(b)

Kf.钾长石；Pl.斜长石；Q.石英；Bi.黑云母

Fig. 2. Filed photograph (a) and photomicrograph (b) of the Kunlunguan granite

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图 3 昆仑关花岗岩锆石阴极发光照片及表面年龄

Fig. 3. Cathodoluminescence (CL) images and corresponding U-Pb apparent ages of the Kunlunguan granite

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图 4 昆仑关花岗岩锆石年龄谐和图

Fig. 4. U-Pb concordia diagrams for zircons from the Kunlunguan granite

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图 5 昆仑关花岗岩SiO₂-K₂O图解(a)和A/NK-A/CNK图解(b)

图a据Collins et al.(1982)；图b据Middlemost(1994)

Fig. 5. SiO₂-K₂O diagram (a) and A/NK-A/CNK diagram of the Kunlunguan granite (b)

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图 6 昆仑关花岗岩稀土元素分配模式图及微量元素蛛网图

球粒陨石数据参考Sun and McDonough(1989)

Fig. 6. Chondrite normalized REE and primitive mantle normalized multi-element diagrams for the Kunlunguan granite

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图 7 A型花岗岩判别图

据Whalen et al.(1987)

Fig. 7. A-type granite discrimination diagrams

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图 8 昆仑关花岗岩Harker图解

Fig. 8. Harker diagrams of Kunlunguan granite

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图 9 桂中及邻区花岗岩类及变沉积岩的t-ε_Nd(t)

底图据Chen and Jahn(1998)

Fig. 9. t-ε_Nd(t) diagram of granitiod rocks and meta-sedimentary rocks in Central Guangxi and adjacent aera

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图 10 昆仑关花岗岩Nb-Y-Ce图解(a)；R₁-10 000 Ga/Al图解(b)；Rb-(Y+Nb)图解(c)

A₁.大陆裂谷、地幔柱或热点环境；A₂.后碰撞、后造山环境；AA.非造山；PA.后造山；syn-COLG.同碰撞花岗岩；WPG.板内花岗岩；ORG.洋脊花岗岩；post-COLG.后碰撞花岗岩；VAG.火山弧花岗岩；图a据Eby(1992)；图b据洪大卫等(1995)；图c据Pearce et al.(1984)

Fig. 10. Nb-Y-Ce diagram (a) and R₁ vs 10 000 Ga/Al diagram (b) and Rb vs (Y+Nb) diagram (c) of Kunlunguan granite

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表 1 昆仑关岩体LA-ICP-MS锆石U-Pb同位素定年结果

Table 1. U-Pb isotopic ratios and apparent ages of zircons from the Kunlunguan granite

点号	Th(10^-6)	U(10^-6)	Th/U	同位素比值						表面年龄(Ma)								谐和度(%)
点号	Th(10^-6)	U(10^-6)	Th/U	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	²⁰⁸Pb/²³²Th	1σ	谐和度(%)
KLG10-1	68	372	0.18	0.070 13	0.002 58	1.345 72	0.045 71	0.136 50	0.002 11	931.5	75.9	865.7	19.8	824.8	11.9	908.8	42.5	95
KLG10-2	438	425	1.03	0.049 92	0.003 36	0.103 23	0.006 35	0.015 21	0.000 37	190.8	152.8	99.8	5.8	97.3	2.3	87.4	3.3	97
KLG10-3	106	191	0.55	0.061 76	0.004 48	0.124 13	0.008 79	0.014 77	0.000 39	664.8	155.5	118.8	7.9	94.5	2.5	92.6	4.9	77
KLG10-4	82	183	0.45	0.066 13	0.005 39	0.131 95	0.008 99	0.015 15	0.000 39	810.8	170.4	125.8	8.1	96.9	2.4	97.3	5.4	74
KLG10-5	415	892	0.47	0.046 34	0.001 89	0.096 21	0.003 60	0.015 00	0.000 21	16.8	92.6	93.3	3.3	96.0	1.3	85.3	2.8	97
KLG10-6	585	1 100	0.53	0.061 90	0.002 93	0.127 95	0.005 48	0.015 09	0.000 30	672.2	101.8	122.3	4.9	96.5	1.9	107.0	3.5	76
KLG10-7	604	848	0.71	0.050 63	0.002 29	0.112 27	0.005 25	0.015 95	0.000 30	233.4	103.7	108.0	4.8	102.0	1.9	79.3	3.1	94
KLG10-8	624	1 084	0.58	0.045 06	0.001 64	0.097 24	0.003 65	0.015 40	0.000 27			94.2	3.4	98.5	1.7	95.5	3.3	95
KLG10-9	118	179	0.66	0.070 71	0.005 24	0.138 32	0.008 90	0.014 95	0.000 46	950.0	151.9	131.5	7.9	95.7	2.9	103.7	6.0	68
KLG10-10	144	284	0.51	0.067 69	0.002 24	1.291 35	0.045 61	0.136 89	0.002 89	858.9	68.5	841.9	20.2	827.0	16.4	883.0	52.2	98
KLG10-11	75	421	0.18	0.051 56	0.003 89	0.105 09	0.006 98	0.015 61	0.000 36	264.9	174.1	101.5	6.4	99.9	2.3	111.2	8.1	98
KLG10-12	347	766	0.45	0.046 16	0.002 27	0.095 57	0.004 89	0.014 85	0.000 25	5.7	114.8	92.7	4.5	95.0	1.6	88.4	3.7	97
KLG10-13	395	882	0.45	0.048 21	0.002 47	0.098 53	0.004 85	0.014 89	0.000 25	109.4	124.1	95.4	4.5	95.3	1.6	87.5	3.6	99
KLG10-14	221	351	0.63	0.050 59	0.003 38	0.105 58	0.006 41	0.015 31	0.000 31	220.4	153.7	101.9	5.9	98.0	1.9	92.3	4.4	96
KLG10-16	223	161	1.39	0.080 50	0.006 54	0.158 88	0.012 67	0.015 34	0.000 51	1 209.3	160.3	149.7	11.1	98.1	3.2	94.3	5.4	58
KLG10-18	542	1 112	0.49	0.051 98	0.002 53	0.113 71	0.004 97	0.016 09	0.000 29	283.4	111.1	109.4	4.5	102.9	1.8	106.7	4.2	93
KLG10-19	125	261	0.48	0.053 85	0.004 61	0.109 23	0.008 93	0.015 27	0.000 44	364.9	189.8	105.3	8.2	97.7	2.8	108.1	7.1	92
KLG10-20	280	370	0.76	0.060 25	0.005 23	0.122 67	0.008 95	0.015 72	0.000 42	613.0	188.9	117.5	8.1	100.5	2.7	108.4	6.2	84
KLG10-21	644	1 191	0.54	0.052 42	0.002 44	0.112 08	0.004 79	0.015 54	0.000 28	305.6	105.5	107.9	4.4	99.4	1.8	96.8	4.2	91

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表 2 昆仑关花岗岩全岩主量元素(%)和微量元素(10^-6)组成

Table 2. Major (%) and trace element (10^-6) compositions of the Kunlunguan granite

样品	KLG02	KLG03	KLG04	KLG05	KLG06	KLG07	KLG09	KLG10	KLG11	KLG12
SiO₂	70.12	71.36	72.52	69.78	70.75	73.36	70.24	71.33	69.42	70.34
Al₂O₃	14.25	13.83	14.20	13.65	14.04	13.60	14.06	13.66	14.06	14.20
Fe₂O₃	1.30	0.57	0.02	0.97	0.41	0.40	0.72	0.92	1.01	0.54
FeO	1.76	1.97	1.47	2.08	2.18	1.37	2.12	1.76	1.99	2.20
FeO^T	2.93	2.48	1.49	2.95	2.55	1.73	2.76	2.59	2.90	2.69
CaO	1.22	2.00	1.28	2.64	2.30	1.49	2.34	1.96	2.78	1.65
MgO	1.28	1.09	0.72	1.76	1.26	0.63	1.35	1.11	1.78	1.26
K₂O	4.75	4.51	5.02	4.20	4.31	4.78	4.40	4.77	4.00	4.72
Na₂O	3.00	3.23	3.41	3.23	3.30	3.40	3.24	2.94	3.43	3.18
TiO₂	0.51	0.44	0.27	0.53	0.45	0.31	0.49	0.48	0.50	0.48
P₂O₅	0.18	0.16	0.19	0.21	0.16	0.11	0.18	0.19	0.21	0.18
MnO	0.04	0.05	0.03	0.05	0.05	0.04	0.05	0.05	0.07	0.05
LOI	1.18	0.37	0.56	0.48	0.35	0.18	0.36	0.42	0.38	0.73
Total	102.52	102.07	101.17	102.53	102.12	101.39	102.31	102.18	102.51	102.22
全碱	7.75	7.74	8.43	7.43	7.61	8.18	7.64	7.71	7.43	7.90
δ	2.21	2.11	2.41	2.06	2.09	2.20	2.14	2.10	2.09	2.28
A/NK	1.41	1.35	1.28	1.38	1.39	1.26	1.39	1.36	1.41	1.37
A/CNK	1.16	1.00	1.06	0.93	0.98	1.01	0.98	1.01	0.93	1.06
R₁	2 399	2 470	2 397	2 422	2 449	2 504	2 409	2 507	2 376	2 364
Pb	25.10	23.70	40.30	22.50	29.10	41.40	27.40	36.50	28.00	22.30
Cr	21.80	16.10	8.18	34.30	21.60	2.27	22.90	14.80	39.00	22.10
Ni	15.60	12.00	10.10	22.30	12.70	4.75	15.30	11.90	21.50	17.60
Rb	259	251	278	217	240	245	218	233	220	266
Sr	298	293	187	418	305	197	357	309	424	322
Ba	1020	821	633	817	892	771	935	1260	727	963
V	53.20	51.40	24.70	63.00	52.40	26.70	56.30	49.40	64.70	51.60
Nb	19.80	18.90	16.00	23.60	17.80	16.80	18.70	22.50	20.50	18.30
Ta	2.50	1.96	2.06	2.31	1.46	1.65	1.55	2.12	1.88	1.65
Zr	227	117	99.20	148	144	131	171	190	119	122
Hf	5.30	3.03	2.82	3.54	3.50	3.37	3.39	4.39	3.12	3.26
Ga	30.50	28.30	28.60	27.90	30.70	27.50	31.40	34.80	28.20	30.10
U	6.25	24.30	9.17	6.15	6.82	6.24	4.81	4.60	11.10	5.68
Th	22.40	26.80	19.90	30.50	30.00	27.30	26.10	36.00	29.80	26.00
La	56.80	56.00	36.30	47.70	66.60	48.40	61.40	70.60	59.70	45.40
Ce	114.00	110.00	71.70	96.90	138.00	96.50	119.00	154.00	122.00	90.00
Pr	12.30	12.10	7.91	11.00	13.60	10.60	12.70	14.50	12.70	10.10
Nd	39.26	34.93	28.71	39.06	38.39	37.45	31.11	49.06	39.54	31.62
Sm	7.27	6.54	5.94	7.08	6.75	7.20	6.00	8.25	7.40	6.03
Eu	1.30	1.28	0.85	1.38	1.23	1.00	1.30	1.43	1.42	1.27
Gd	6.44	6.42	4.39	5.81	6.30	5.73	5.91	6.81	6.62	5.52
Tb	0.94	0.93	0.62	0.84	0.86	0.86	0.83	0.89	0.94	0.81
Dy	5.23	5.19	3.07	4.62	4.44	4.82	4.41	4.52	5.10	4.47
Ho	0.99	0.96	0.52	0.89	0.82	0.90	0.82	0.82	0.98	0.86
Er	2.70	2.65	1.32	2.49	2.24	2.40	2.27	2.28	2.66	2.32
Tm	0.43	0.41	0.20	0.40	0.34	0.37	0.34	0.36	0.42	0.36
Yb	2.96	2.67	1.32	2.71	2.26	2.51	2.24	2.55	2.82	2.45
Lu	0.41	0.36	0.17	0.38	0.31	0.35	0.31	0.36	0.40	0.34
Y	24.20	25.00	13.30	23.40	21.20	23.80	21.00	21.50	25.00	21.80
∑REE	275.23	265.44	176.32	244.66	303.34	242.89	269.64	337.93	287.70	223.35
(La/Yb)_N	12.61	13.83	18.11	11.56	19.38	12.67	18.00	18.33	13.98	12.20
δEu	0.53	0.53	0.51	0.62	0.51	0.45	0.58	0.55	0.57	0.61
注：FeO^T=FeO+0.899 8×Fe₂O₃；全碱=K₂O+Na₂O；δ=(K₂O+Na₂O)₂/(SiO₂-43)；A/NK=Al₂O₃/(K₂O+Na₂O)；A/CNK=Al₂O₃/(CaO+K₂O+Na₂O)；R₁=4×Si+11×(Na+K)+2×(Fe+Ti).

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表 3 昆仑关花岗岩全岩Sm-Nd同位素组成

Table 3. Whole-rock Sm-Nd isotopic composition of Kunlunguan granite

样号	Sm(10^-6)	Nd(10^-6)	¹⁴⁷Sm/¹⁴⁴Nd	¹⁴³Nd/¹⁴⁴Nd	δ	T_DM2(Ga)	ε_Nd(t)
KLG02	7.27	39.26	0.112 1	0.512 156	0.000 002	1.57	-8.35
KLG03	6.54	34.93	0.113 2	0.512 170	0.000 003	1.55	-8.09
KLG04	5.94	28.71	0.125 2	0.512 064	0.000 003	1.73	-10.31
KLG05	7.08	39.06	0.109 6	0.512 184	0.000 002	1.53	-7.77
KLG06	6.75	38.39	0.106 3	0.512 130	0.000 004	1.61	-8.78
KLG07	7.20	37.45	0.116 4	0.512 193	0.000 005	1.52	-7.68
KLG09	6.00	31.11	0.116 7	0.512 158	0.000 002	1.57	-8.37
KLG10	8.25	49.06	0.101 7	0.512 114	0.000 002	1.63	-9.04
KLG11	7.40	39.54	0.113 2	0.512 162	0.000 001	1.56	-8.25
KLG12	6.03	31.62	0.115 4	0.512 165	0.000 003	1.56	-8.22
注：测试数据在热电离质谱仪Triton上分析，经校正后根据同位素稀释法公式计算获得；计算T_DM2(Ga)、εNd(t)时，t采用谐和锆石加权平均年龄97.7 Ma；参数：(¹⁴⁷Sm/¹⁴⁴Nd)_DM=0.213 7，(¹⁴³Nd/¹⁴⁴Nd)_DM=0.513 15，(¹⁴⁷Sm/¹⁴⁴Nd)_CC=0.118，(¹⁴⁷Sm/¹⁴⁴Nd)_CHUR=0.196 7，(¹⁴³Nd/¹⁴⁴Nd)_CHUR=0.512 638(DM、CC、CHUR分别代表亏损地幔、大陆地壳和球粒陨石均一库).

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表 4 桂中及邻区花岗岩类及变沉积岩的Nd同位素特征统计结果

Table 4. Nd isotopic characteristics of granitiod rocks and meta-sedimentary rocks in Central Guangxi and adjacent aera

位置	岩性	年龄(Ma)	T_DM2(Ga)	ε_Nd(t)	参考文献
昆仑关岩体古民单元	斑状黑云母花岗岩	97.7±1.3	1.52~1.63	-7.68~-10.31	本文
龙头山	潜火山岩	96.1±3.0	1.45~1.49	-6.86~-7.39	段瑞春等，2011
平天山岩体	中酸性侵入岩	96.2±0.4	1.43~1.50	-6.64~-7.38	段瑞春等，2011
三叉冲岩体	黑云母花岗岩、二云母花岗岩	101~105	1.43~1.55	-6.50~-7.80	王炯辉等，2014
德庆、新华、调村、马鞍山岩体	二长花岗岩、花岗闪长岩、流纹英安岩	99~104	1.78~1.82	-9.18~-11.39	耿红燕等，2006
大容山岩体	S型花岗岩	233±5	2.06~2.09	-12.6~-13.0	祁昌实等，2007
高州杂岩和云开群	变沉积岩	440	1.91~2.17	-10.0~-13.4	Wan et al., 2010
云开地区	片麻状花岗岩	440	2.13~1.42	-1.2~-8.4	Wan et al., 2010

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表 5 研究区及邻区100~90 Ma岩浆事件统计

Table 5. 100-90 Ma igneous events in research and adjacent aera

年龄(Ma)	矿物	方法	岩性	断裂	产状	矿产	地区	地点	来源
97.7±1.3	锆石	LA-ICP-MS	斑状黑云母花岗岩	南丹-昆仑关断裂	NW-SE	钨矿	大明山	昆仑关主体	本文
93±1	锆石	LA-ICP-MS	黑云母花岗岩	南丹-昆仑关断裂	NW-SE	钨矿	大明山	昆仑关主体	谭俊等，2008
97.6±0.5	锆石	LA-ICP-MS	黑云母花岗岩	南丹-昆仑关断裂	NW-SE	钨矿	大明山	昆仑关补体	乔龙，2016
93±1	锆石	SHRIMP	含斑黑云母花岗岩	南丹-昆仑关断裂	NW-SE	锡多金属矿	丹池成矿带	大厂矿田	蔡明海等，2006
91±1	锆石	SHRIMP	斑状花岗岩	南丹-昆仑关断裂	NW-SE	锡多金属矿	丹池成矿带	大厂矿田	蔡明海等，2006
91±1	锆石	SHRIMP	石英闪长玢岩脉	南丹-昆仑关断裂	NW-SE	锡多金属矿	丹池成矿带	大厂矿田	蔡明海等，2006
91±1	锆石	SHRIMP	花岗斑岩脉	南丹-昆仑关断裂	NW-SE	锡多金属矿	丹池成矿带	大厂矿田	蔡明海等，2006
103.3±2.4	锆石	SHRIMP	流纹斑岩	凭祥-大黎断裂	NE-SW	金矿	大瑶山	龙头山	陈富文等，2008
100.3±1.4	锆石	SHRIMP	花岗斑岩	凭祥-大黎断裂	NE-SW	金矿	大瑶山	龙头山	陈富文等，2008
96.1±3.0	锆石	LA-ICP-MS	潜火山岩	凭祥-大黎断裂	NE-SW	金矿	大瑶山	龙头山	段瑞春等，2011
96.2±0.4	锆石	LA-ICP-MS	中酸性侵入岩	凭祥-大黎断裂	NE-SW	金矿	大瑶山	平天山	段瑞春等，2011
98.3±0.6	锆石	LA-ICP-MS	中酸性侵入岩	凭祥-大黎断裂	NE-SW	金矿	大瑶山	平天山	乔龙，2016
102.8±0.9	锆石	LA-ICP-MS	石英二长岩	凭祥-大黎断裂	NE-SW	铜钼矿	大瑶山	大黎	胡升奇等，2012
101.7±1.2	锆石	LA-ICP-MS	石英二长斑岩	凭祥-大黎断裂	NE-SW	铜钼矿	大瑶山	大黎	胡升奇等，2012
95.3±1.5	锆石	LA-ICP-MS	花岗斑岩	凭祥-大黎断裂	NE-SW	铜钨矿	大瑶山	社山	秦亚等，2015
90~91	锆石	LA-ICP-MS	花岗斑岩	凭祥-大黎断裂	NE-SW	铜钨矿	大瑶山	社山	毕诗健等，2015
99±2	锆石	LA-ICP-MS	二长花岗岩	连县-郁南断裂	NE-SW		云开	德庆	耿红燕等，2006
101±7	锆石	LA-ICP-MS	花岗闪长岩	连县-郁南断裂	NE-SW		云开	杏花	耿红燕等，2006
104±3	锆石	LA-ICP-MS	花岗闪长岩	连县-郁南断裂	NE-SW		云开	调村	耿红燕等，2006
103.3±2.4	锆石	LA-ICP-MS	流纹英安岩	连县-郁南断裂	NE-SW		云开	马鞍山	耿红燕等，2006
100.7±0.5	锆石	LA-ICP-MS	白云母花岗岩	博白-梧州断裂	NE-SW	钨钼矿	云开	油麻坡补体	王炯辉等，2014
103±1	锆石	LA-ICP-MS	黑云母花岗岩	博白-梧州断裂	NE-SW	钨矿	云开	三叉冲	杨振等，2014
95.1±0.4	锆石	LA-ICP-MS	花岗岩	博白-梧州断裂	NE-SW		云开	陆川	乔龙，2016
90.2±1.5	锆石	LA-ICP-MS	石英二长斑岩	博白-梧州断裂	NE-SW		云开	马其岗	王晓地等，2017

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