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    石英E'心的热力学特征及其指示意义

    邱登峰 刘全有 云金表 朱东亚 孟庆强 刘佳宜 孙冬胜

    邱登峰, 刘全有, 云金表, 朱东亚, 孟庆强, 刘佳宜, 孙冬胜, 2019. 石英E'心的热力学特征及其指示意义. 地球科学, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193
    引用本文: 邱登峰, 刘全有, 云金表, 朱东亚, 孟庆强, 刘佳宜, 孙冬胜, 2019. 石英E'心的热力学特征及其指示意义. 地球科学, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193
    Qiu Dengfeng, Liu Quanyou, Yun Jinbiao, Zhu Dongya, Meng Qingqiang, Liu Jiayi, Sun Dongsheng, 2019. The Thermodynamic Characteristics of Quartz E' Center and Their Significance. Earth Science, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193
    Citation: Qiu Dengfeng, Liu Quanyou, Yun Jinbiao, Zhu Dongya, Meng Qingqiang, Liu Jiayi, Sun Dongsheng, 2019. The Thermodynamic Characteristics of Quartz E' Center and Their Significance. Earth Science, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193

    石英E'心的热力学特征及其指示意义

    doi: 10.3799/dqkx.2018.193
    基金项目: 

    国家自然科学基金项目 41625009

    中国科学院战略性先导科技专项(A类) XDA14010404

    国家自然科学基金项目 41602161

    详细信息
      作者简介:

      邱登峰(1982-), 男, 高级工程师, 研究方向为盆地构造动力学及年代学

    • 中图分类号: P546

    The Thermodynamic Characteristics of Quartz E' Center and Their Significance

    • 摘要: 石英EPR是一种利用矿物吸收的累积辐射能进行测年的技术方法,尽管多用于第四纪,但石英E'心在热活化后极大增强的EPR信号为拓展EPR的测年范围提供了契机.然而石英E'心的热活化条件及形成转化机理存在诸多争议.通过对花岗岩和断层带样品施加人工γ辐照,并通过步进式的阶梯退火实验,运用电子顺磁共振技术测定了不同辐射条件及温度条件下的石英E'心信号强度,探讨了石英E'心的增长和成因机理.结果表明,石英E'心可在常温常规γ辐照和高温加热2种条件下增长,并分别探讨了常温和高温E'心的测年方法及其地质意义.常温E'心的信号强度在150℃以下相对稳定,可用常规附加剂量法标定EPR信号强度以求取累积辐射能,常用于测定第四纪范围内断层的形成年龄;石英E'心在热活化后信号得到极大增强,可测定第四纪前的地质年龄,但需采用已知年龄的石英E'心热力学峰值强度作标杆或通过高剂量的γ辐照或中子辐照使氧空位再生,建立石英氧空位的剂量响应曲线以标定高温E'心代表的累积辐射能.E'心的热力学峰值通过步进式的阶梯退火实验确定,其在高温和常温时的信号强度比(I2/I1)具有记录辐射能和地质计时的意义.

       

    • 图  1  不同样品E′心信号强度随温度变化

      Fig.  1.  The signal intensity of quartz E′ center in both samples at several temperature points

      图  2  不同人工辐照剂量样品达到E′心峰值时的温度点

      Fig.  2.  The temperature points at which the peak signal intensities of E′ center are reached in samples with different artificial γ ray irradiation dose

      图  3  不同辐照剂量样品在热力学试验后获取的E′心最大值

      Fig.  3.  The peak signal intensity of E′ center after thermodynamic experiments in samples with different artificial γ ray irradiation dose

      图  4  样品1的自然样品不同方位下多次测量EPR信号强度的离散性

      以样品1的自然样品为例,在完全相同的参数条件下,在0°、120°、240°三个方位下固定样品管位置重复测试6次,共测量18次,它们的标准偏差和相对标准偏差分别为1 759和7.2%

      Fig.  4.  The multiple measurement discrepancy of EPR signal intensity under different directions of natural sample of number 1

      图  5  不同温度点下样品E′心信号强度的剂量响应关系

      Fig.  5.  The dose response relationship of E′ center signal intensity under several temperature points in both samples

      图  6  样品I2/I1值与辐照剂量的关系

      Fig.  6.  The relationship between I2/I1 ratio of samples and artificial γ ray irradiation dose

      图  7  氧空位、E′心、Al心的结构模型

      Rink and Odom(1991)改编. a.石英正常的晶格位置;b.连接硅原子的桥接氧移位,形成氧空位;c.氧空位处捕获一个自由电子,形成E′心;d. Al心

      Fig.  7.  Structure model of oxygen vacancy, E′ center and Al center

      图  8  石英中E′心、Al心和Ti心在加热后EPR信号强度的变化

      Toyoda(2005).石英中Al心和Ti心的信号强度随温度升高而下降,而E′心在300 ℃左右信号强度达到最强后才开始下降

      Fig.  8.  Change of intensity of the EPR signals of the E′, Al and Ti centers in quartz

      图  9  Al心和热处理E′心的剂量响应

      Toyoda and Hattori(2000)Toyoda(2005)Toyoda et al.(2016). Al心的强度增加而E′心在200 Gy以上饱和,表明饱和是由于氧空位的数量有限

      Fig.  9.  The dose response relationship of Al center and thermal activated E′ center

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    • 收稿日期:  2017-08-27
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