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    川西坳陷新场气田须家河组五段烃源岩分子地球化学特征

    吴小奇 陈迎宾 刘全有 王萍 曾华盛 王彦青 胡烨 黎华继

    吴小奇, 陈迎宾, 刘全有, 王萍, 曾华盛, 王彦青, 胡烨, 黎华继, 2019. 川西坳陷新场气田须家河组五段烃源岩分子地球化学特征. 地球科学, 44(3): 859-871. doi: 10.3799/dqkx.2018.236
    引用本文: 吴小奇, 陈迎宾, 刘全有, 王萍, 曾华盛, 王彦青, 胡烨, 黎华继, 2019. 川西坳陷新场气田须家河组五段烃源岩分子地球化学特征. 地球科学, 44(3): 859-871. doi: 10.3799/dqkx.2018.236
    Wu Xiaoqi, Chen Yingbin, Liu Quanyou, Wang Ping, Zeng Huasheng, Wang Yanqing, Hu Ye, Li Huaji, 2019. Molecular Geochemical Characteristics of Source Rocks in the 5th Member of Upper Triassic Xujiahe Formation, Xinchang Gas Field, West Sichuan Depression. Earth Science, 44(3): 859-871. doi: 10.3799/dqkx.2018.236
    Citation: Wu Xiaoqi, Chen Yingbin, Liu Quanyou, Wang Ping, Zeng Huasheng, Wang Yanqing, Hu Ye, Li Huaji, 2019. Molecular Geochemical Characteristics of Source Rocks in the 5th Member of Upper Triassic Xujiahe Formation, Xinchang Gas Field, West Sichuan Depression. Earth Science, 44(3): 859-871. doi: 10.3799/dqkx.2018.236

    川西坳陷新场气田须家河组五段烃源岩分子地球化学特征

    doi: 10.3799/dqkx.2018.236
    基金项目: 

    国家自然科学基金项目 41625009

    国家科技重大专项 2016ZX05002-006

    中国科学院A类战略性先导科技专项 XDA14010402

    国家自然科学基金项目 U1663201

    国家自然科学基金项目 41872122

    详细信息
      作者简介:

      吴小奇(1982-), 男, 高级工程师, 博士, 主要从事天然气地质与地球化学研究

      通讯作者:

      刘全有

    • 中图分类号: P618.13

    Molecular Geochemical Characteristics of Source Rocks in the 5th Member of Upper Triassic Xujiahe Formation, Xinchang Gas Field, West Sichuan Depression

    • 摘要: 上三叠统须家河组五段是川西坳陷新场气田勘探的热点层系之一.对新场须五段泥质烃源岩进行了分子地球化学分析,结果表明:新场须五段泥岩可溶抽提物姥植比介于0.26~1.70之间,C27-C29规则甾烷中C27和C29甾烷相对含量平均值分别为31.2%和44.6%,伽马蜡烷/C30藿烷比值介于0.11~0.34,MPI1F1和4-/1-MDBT均与成熟度呈正相关.新场须五段泥岩有机质生源中,陆源高等植物略占优势,但低等水生生物和藻类也具有一定的贡献;泥岩主要沉积于湖泊环境,部分沉积于缺氧的盐水环境.成熟度对一些芳烃化合物指标具有明显影响,成熟度超过1.25%的煤系烃源岩样品的三芴系列和成熟度超过1.2%的样品的MDBTs/MDBFs比值不能直接用于沉积环境的判别.

       

    • 图  1  川西坳陷新场气田位置(a)及须五段顶面埋深图(b)

      吴小奇等(2016)修改

      Fig.  1.  Location (a) and burial depth of the T3x5 top surface (b) of the Xinchang gas field in the West Sichuan Depression

      图  2  新场须五段泥质烃源岩Pr/nC17和Ph/nC18相关图

      Fig.  2.  Correlation between Pr/nC17 and Ph/nC18 of the T3x5 argillaceous source rocks in the Xinchang gas field

      图  3  新场须五段泥质烃源岩Pr/nC17、Ph/nC18和Pr/Ph三角图

      底图据王铁冠等(1995)

      Fig.  3.  Ternary diagram among Pr/nC17, Ph/nC18 and Pr/Ph of the T3x5 argillaceous source rocks in the Xinchang gas field

      图  4  新场须五段泥岩甾烷(m/z=217)和萜烷(m/z=191)化合物分布

      Fig.  4.  Distribution of sterane (m/z=217) and terpane (m/z=191) compounds of the T3x5 mudstone in the Xinchang gas field

      图  5  新场须五段泥质烃源岩C29/C27甾烷比值和成熟度关系

      Fig.  5.  Correlation between C29/C27 sterane ratio and thermal maturity of the T3x5 mudstone in the Xinchang gas field

      图  6  新场须五段泥岩芳烃化合物分布

      Fig.  6.  Distribution of aromatic compounds of the T3x5 mudstone in the Xinchang gas field

      图  7  新场须五段泥岩Ro与MPI1(a)和F1(b)关系

      川北T3xLi et al.(2015);西加盆地据Radke et al.(1982)

      Fig.  7.  Correlations between Ro and MPI1 (a) and Ro and F1 (b) of the T3x5 mudstone in the Xinchang gas field

      图  8  新场须五段泥岩三芴系列相对含量分布

      底图据程克明等(1995)

      Fig.  8.  Ternary diagram among three fluorene series of the T3x5 mudstone in the Xinchang gas field

      图  9  新场须五段泥岩氧芴/硫芴(a)和芴/硫芴(b)随成熟度的变化

      Fig.  9.  Variations of OF/SF (a) and F/SF (b) with thermal maturity of the T3x5 mudstone in the Xinchang gas field

      图  10  新场须五段泥岩DBT/P(a)和MDBTs/MDBFs(b)与Pr/Ph的关系

      底图a据Hughes et al.(1995);底图b据Radke et al.(2000)

      Fig.  10.  Correlations between DBT/P and Pr/Ph (a) and MDBTS/MDBFs and Pr/Ph (b) of the T3x5 mudstone in the Xinchang gas field

      图  11  新场须五段泥岩MDBTs/MDBFs(a)和4-/1-MDBT(b)与Ro的关系

      Fig.  11.  Correlations between MDBTs/MDBFs and Ro (a) and 4-/1-MDBT and Ro (b) of the T3x5 mudstone in the Xinchang gas field

      表  1  新场须五段泥岩分子地球化学参数

      Table  1.   Molecular geochemical parameters of the T3x5 mudstone in the Xinchang gas field

      井号 深度(m) 主峰碳 Ro OEP CPI Pr/Ph Ts/Tm 伽马蜡烷/
      αβC30藿烷
      αααC27
      (%)
      αααC28
      (%)
      αααC29
      (%)
      MPI1 F1 DBT/P MDBTs/
      MDBFs
      F(%) OF(%) SF(%) 4-MDBT/
      1-MDBT
      X503 2 788.0 C18 0.91 1.01 1.13 1.22 0.97 0.11 22.0 17.7 60.3 0.726 0.525 0.08 0.21 25.5 58.2 16.4 6.27
      X503 2 864.0 C18 0.93 0.97 1.12 1.57 0.63 0.14 23.1 20.0 56.9 0.750 0.529 0.08 0.30 35.8 45.3 18.9 5.98
      X503 2 903.0 C22 1.11 0.94 1.17 0.75 0.87 0.15 28.2 21.7 50.1 0.771 0.534 0.08 0.21 32.6 52.6 14.8 6.90
      X503 2 935.0 C19 1.10 1.02 1.09 1.69 0.80 0.32 27.9 23.2 48.8 0.821 0.542 0.08 0.21 30.8 54.2 15.0 6.83
      X503 2 968.0 C22 1.07 0.91 1.16 0.41 0.98 0.19 32.0 25.6 42.3 0.887 0.534 0.07 0.65 52.1 25.5 22.4 8.79
      X503 2 976.0 C18, C22 1.18 0.95 1.24 1.33 0.82 0.15 28.5 22.6 48.9 0.835 0.532 0.09 0.38 40.1 40.0 19.8 7.56
      X503 3 189.0 C22 1.23 0.91 1.12 0.48 1.01 0.16 35.3 26.2 38.5 1.033 0.586 0.09 1.40 53.3 16.7 30.0 11.52
      X503 3 210.0 C22 1.25 0.91 1.11 0.43 0.73 0.30 33.0 27.0 40.0 0.943 0.599 0.10 0.76 43.8 26.6 29.6 13.28
      X503 3 219.0 C22 1.26 0.94 1.15 1.32 1.05 0.21 33.7 25.8 40.5 1.193 0.599 0.06 2.49 45.7 13.3 41.0 11.28
      XY-1 3 030.8 C25 1.30 1.06 1.13 1.19 1.14 0.14 34.1 26.2 39.7 1.065 0.580 0.10 2.03 32.9 18.3 48.8 11.33
      XY-1 3 058.8 C25 1.32 1.04 1.11 0.26 1.05 0.14 39.7 25.6 34.7 1.036 0.585 0.07 2.64 44.2 13.0 42.8 11.80
      XY-2 3 058.3 C18 1.25 0.92 1.07 1.70 1.04 0.34 30.6 25.4 44.0 1.018 0.571 0.08 0.86 45.7 25.7 28.6 11.61
      XY-2 3 090.0 C19 1.20 1.00 1.17 0.93 0.71 0.25 32.6 26.5 40.9 0.999 0.576 0.10 2.18 36.5 16.3 47.1 10.50
      XC28 3 288.0 C22 1.27 0.92 1.12 0.30 0.99 0.15 35.4 26.4 38.2 1.036 0.614 0.08 2.34 53.5 11.7 34.8 14.65
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