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    南阿尔金玉苏普阿勒克塔格花岗岩体锆石U-Pb年代学、地球化学特征及地质意义

    高栋 吴才来 郜源红 张昕 陈红杰 郭文峰 吴迪 郑坤

    高栋, 吴才来, 郜源红, 张昕, 陈红杰, 郭文峰, 吴迪, 郑坤, 2019. 南阿尔金玉苏普阿勒克塔格花岗岩体锆石U-Pb年代学、地球化学特征及地质意义. 地球科学, 44(11): 3812-3828. doi: 10.3799/dqkx.2018.279
    引用本文: 高栋, 吴才来, 郜源红, 张昕, 陈红杰, 郭文峰, 吴迪, 郑坤, 2019. 南阿尔金玉苏普阿勒克塔格花岗岩体锆石U-Pb年代学、地球化学特征及地质意义. 地球科学, 44(11): 3812-3828. doi: 10.3799/dqkx.2018.279
    Gao Dong, Wu Cailai, Gao Yuanhong, Zhang Xin, Chen Hongjie, Guo Wenfeng, Wu Di, Zheng Kun, 2019. Zircon U-Pb Geochronology, Geochemistry of the Yusupuleke Granite Pluton in South Altyn and Its Geological Implications. Earth Science, 44(11): 3812-3828. doi: 10.3799/dqkx.2018.279
    Citation: Gao Dong, Wu Cailai, Gao Yuanhong, Zhang Xin, Chen Hongjie, Guo Wenfeng, Wu Di, Zheng Kun, 2019. Zircon U-Pb Geochronology, Geochemistry of the Yusupuleke Granite Pluton in South Altyn and Its Geological Implications. Earth Science, 44(11): 3812-3828. doi: 10.3799/dqkx.2018.279

    南阿尔金玉苏普阿勒克塔格花岗岩体锆石U-Pb年代学、地球化学特征及地质意义

    doi: 10.3799/dqkx.2018.279
    基金项目: 

    中国地质调查局项目 121201102000150005-06

    中国地质调查局项目 12120115027001

    中国地质调查局项目 DD20160022-06

    国家自然科学基金项目 41272079

    国家自然科学基金项目 41872071

    详细信息
      作者简介:

      高栋(1991-), 男, 博士, 矿物学、岩石学、矿床学专业

      通讯作者:

      吴才来

    • 中图分类号: P581

    Zircon U-Pb Geochronology, Geochemistry of the Yusupuleke Granite Pluton in South Altyn and Its Geological Implications

    • 摘要: 玉苏普阿勒克塔格岩体是南阿尔金出露面积较大的花岗岩体之一.为了查明该岩体的成因与形成的构造环境,探讨南阿尔金地区的岩浆演化过程,对该岩体进行了岩石学、地球化学及锆石U-Pb年代学方面的研究.研究结果表明玉苏普阿勒克塔格岩体主要由中粗粒似斑状黑云二长花岗岩及中细粒含斑黑云二长花岗岩组成.本次研究获得中粗粒似斑状黑云二长花岗岩的锆石U-Pb年龄为442~448 Ma,中细粒含斑黑云二长花岗岩的锆石U-Pb年龄为423~430 Ma.岩石地球化学显示,早期花岗岩具有准铝质特征(A/CNK=0.97),晚期花岗岩具有弱过铝质特征(A/CNK=1.04).两期花岗岩均属于高钾钙碱性Ⅰ型花岗岩,轻稀土富集重稀土亏损,具有Eu的弱负异常.两期花岗岩都富集Rb、Th、K等元素,亏损Ba、P、Sr、Ti等元素.根据两期花岗岩的形成时代,结合区域地质背景认为玉苏普阿勒克塔格岩体形成于活动大陆边缘环境,是早古生代南阿尔金洋向北俯冲碰撞,在构造体制转换阶段幔源岩浆上涌新生地壳发生部分熔融形成.

       

    • 图  1  阿尔金造山带构造单元及划分玉苏普阿勒克塔格岩体地质简图

      图 1a吴才来等(2016)修改

      Fig.  1.  Tectonic subdivision of the Altyn orogenic belt and simplified geological map of Yusupuleke pluton

      图  2  玉苏普阿勒克塔格岩体花岗岩及暗色包体野外照片与镜下照片

      a~c.中粗粒似斑状黑云二长花岗岩野外照片及镜下照片(正交偏光);d~f.中细粒含斑黑云二长花岗岩野外照片及镜下照片(正交偏光);g.暗色闪长质包体野外照片;h~i.与暗色包体接触位置寄主花岗岩镜下照片(单偏光):斜长石呈环带结构,磷灰石呈嵌晶结构; Pl.斜长石;Kfs.钾长石;Bt.黑云母;Hb.角闪石;Ap.磷灰石

      Fig.  2.  Field pictures and microphotographs of the granites and enclaves in Yusupuleke pluton

      图  3  玉苏普阿勒克塔格岩体早期花岗岩锆石阴极发光图像和锆石U-Pb年龄谐和图

      Fig.  3.  Cathodoluminescence (CL) images of representative zircon grains and zircon U-Pb concordia plot of the early granites in Yusupuleke pluton

      图  4  玉苏普阿勒克塔格岩体晚期花岗岩锆石阴极发光图像和锆石U-Pb年龄谐和图

      Fig.  4.  Cathodoluminescence (CL) images of representative zircon grains and zircon U-Pb concordia plot of the late granites in Yusupuleke pluton

      图  5  玉苏普阿勒克塔格岩体花岗岩A/NK-A/CNK图(a)和K2O-SiO2图(b)

      a.据Maniar and Piccoli(1989);b.据Rickwood(1989)

      Fig.  5.  A/NK vs. A/CNK classification diagram(a) and K2O vs. SiO2 classification diagram (b) of the granites in Yusupuleke pluton

      图  6  玉苏普阿勒克塔格岩体花岗岩球粒陨石标准化稀土元素配分曲线图(a, c)及原始地幔标准化微量元素蛛网图(b, d)

      标准化值据Sun and McDonough(1989)

      Fig.  6.  Chondrite-normalized REE distribution patterns (a, c) and primitive mantle normalized trace element patterns (b, d) for the granites in Yusupuleke pluton

      图  7  玉苏普阿勒克塔格岩体花岗岩P2O5-SiO2成因类型判别图

      Fig.  7.  P2O5 vs. SiO2 discrimination diagram of petrogenetic types for granites in Yusupuleke pluton

      图  8  玉苏普阿勒克塔格岩体花岗岩La/Yb-La图解

      Allègre and Minster(1978)

      Fig.  8.  La/Yb vs. La classification diagram of granites in Yusupuleke pluton

      图  9  Y-Zr、Zr/Al2O3-TiO2/Al2O3、Th/Yb-Ta/Yb判别图解

      a,b.据Muller and Groves (1994);c.据Gorton and Schandl (2000)

      Fig.  9.  Y-Zr, Zr/Al2O3-TiO2/Al2O3, Th/Yb-Ta/Yb discrimination diagrams

      表  1  玉苏普阿勒克塔格岩体花岗岩LA⁃MC⁃ICP⁃MS锆石U⁃Pb定年测试结果

      Table  1.   LA⁃MC⁃ICP⁃MS zircon U⁃Pb isotopic data of the granites in Yusupuleke pluton

      样品号及分析点号 含量(10-6 同位素比值 年龄(Ma)
      Pb Th U Th/ U 207Pb/ 206Pb 207Pb/ 235U 206Pb/ 238U 206Pb/ 238U
      15CL155-3-03 75 92.3 190.7 0.48 0.055 7 0.000 6 0.548 4 0.012 6 0.071 4 0.001 7 444.7 10.4
      15CL155-3-06 71 86.4 192.8 0.45 0.055 5 0.000 7 0.547 0 0.013 4 0.071 4 0.001 5 444.7 8.9
      15CL155-3-07 25.4 29.7 69.0 0.43 0.056 7 0.001 0 0.557 7 0.018 0 0.071 2 0.001 6 443.6 9.7
      15CL155-3-08 57.4 71.8 148.4 0.48 0.055 3 0.000 6 0.534 4 0.011 7 0.070 1 0.001 4 436.8 8.7
      15CL155-3-09 24.6 29.7 70.7 0.42 0.055 4 0.000 9 0.536 1 0.014 6 0.070 2 0.001 6 437.5 9.6
      15CL155-3-10 55.6 67.5 143.4 0.47 0.056 3 0.001 9 0.547 1 0.024 2 0.070 4 0.001 7 438.8 10.2
      15CL155-3-11 81 96.9 215.8 0.45 0.056 1 0.001 2 0.549 9 0.015 4 0.071 2 0.001 6 443.3 9.7
      15CL155-3-12 34.3 39.7 94.8 0.42 0.057 4 0.001 6 0.559 8 0.025 3 0.070 6 0.001 7 439.5 10.0
      15CL155-3-16 62 74.3 152.1 0.49 0.055 9 0.000 5 0.546 4 0.011 9 0.070 9 0.001 5 441.5 9.3
      15CL155-3-17 15.7 19.1 40.8 0.47 0.054 1 0.001 2 0.526 6 0.020 1 0.070 5 0.001 7 439.4 10.2
      15CL155-3-18 52.2 62.8 120.4 0.52 0.057 7 0.001 4 0.562 7 0.029 9 0.070 4 0.002 4 438.8 14.5
      15CL155-3-21 28.1 34.7 85.2 0.41 0.054 3 0.000 6 0.527 8 0.013 1 0.070 5 0.001 6 439.2 9.4
      15CL155-3-23 176 214.8 425.4 0.50 0.055 3 0.000 4 0.546 9 0.013 8 0.071 7 0.001 7 446.4 10.5
      15CL155-3-24 25.8 31.2 71.1 0.44 0.054 7 0.000 6 0.540 8 0.015 6 0.071 7 0.001 9 446.7 11.4
      15CL155-3-25 40.6 47.9 109.7 0.44 0.054 6 0.000 6 0.548 6 0.015 3 0.072 8 0.002 0 453.1 11.8
      15CL155-3-26 48.7 59.0 124.2 0.47 0.055 1 0.000 5 0.545 0 0.012 9 0.071 8 0.001 5 446.9 9.3
      15CL155-3-27 126 166.5 321.0 0.52 0.056 2 0.000 5 0.560 3 0.016 5 0.072 2 0.001 7 449.3 10.5
      15CL155-3-29 64 82.2 172.8 0.48 0.054 2 0.000 6 0.522 7 0.012 7 0.069 9 0.001 7 435.7 10.0
      15CL155-3-30 112 138.8 282.1 0.49 0.057 2 0.001 4 0.555 4 0.019 8 0.070 3 0.001 5 438.0 9.0
      15CL156-3-01 32.9 37.9 113.1 0.33 0.055 6 0.001 3 0.556 8 0.014 2 0.072 5 0.001 6 451.5 9.8
      15CL156-3-02 218 267.2 655.7 0.41 0.055 9 0.001 0 0.547 7 0.010 3 0.071 0 0.001 2 442.0 7.5
      15CL156-3-03 137 170.5 341.5 0.50 0.056 7 0.000 9 0.574 0 0.012 5 0.073 4 0.001 6 456.4 9.9
      15CL156-3-04 298 363.0 963.3 0.38 0.056 4 0.000 8 0.562 4 0.012 1 0.072 2 0.001 4 449.4 8.7
      15CL156-3-05 228 269.0 685.6 0.39 0.058 1 0.000 9 0.580 2 0.017 7 0.072 3 0.001 7 449.7 10.0
      15CL156-3-06 125 166.2 222.8 0.75 0.058 8 0.001 0 0.596 5 0.017 2 0.073 4 0.001 5 456.8 8.9
      15CL156-3-08 222 257.7 676.8 0.38 0.055 6 0.000 5 0.553 6 0.013 2 0.072 1 0.001 6 448.9 9.9
      15CL156-3-09 134 156.7 412.3 0.38 0.056 9 0.000 8 0.558 0 0.015 6 0.071 0 0.0014 442.0 8.2
      15CL156-3-10 149 175.9 469.4 0.37 0.055 7 0.000 5 0.540 6 0.010 9 0.070 4 0.001 4 438.3 8.4
      15CL156-3-11 201 238.9 637.2 0.37 0.056 3 0.000 5 0.553 9 0.014 4 0.071 3 0.001 6 444.1 9.7
      15CL156-3-14 66 74.5 164.4 0.45 0.059 3 0.001 8 0.597 4 0.032 0 0.072 8 0.001 9 452.8 11.4
      15CL156-3-15 207 229.7 649.8 0.35 0.056 5 0.000 6 0.565 8 0.015 6 0.072 5 0.001 6 451.4 9.8
      15CL156-3-16 141 160.4 487.9 0.33 0.055 5 0.000 4 0.565 1 0.016 1 0.073 8 0.001 9 459.3 11.3
      15CL156-3-17 68 82.1 177.9 0.46 0.054 9 0.000 6 0.543 9 0.011 8 0.071 8 0.001 4 447.2 8.5
      15CL156-3-18 211 251.1 756.0 0.33 0.058 7 0.001 8 0.572 8 0.026 8 0.070 5 0.001 5 439.4 9.1
      15CL156-3-19 362 443.3 1 094.1 0.41 0.057 8 0.001 0 0.564 9 0.019 9 0.070 8 0.001 5 440.9 9.1
      15CL156-3-20 125 155.6 335.1 0.46 0.055 1 0.000 5 0.541 2 0.013 2 0.071 2 0.001 7 443.4 10.0
      15CL156-3-23 199 252.3 480.9 0.52 0.055 5 0.000 4 0.539 1 0.010 8 0.070 5 0.001 4 439.0 8.3
      15CL156-3-24 148 174.1 502.0 0.35 0.055 7 0.000 4 0.556 9 0.012 4 0.072 5 0.001 6 451.3 9.4
      15CL156-3-25 234 267.4 657.2 0.41 0.057 6 0.000 6 0.578 5 0.009 8 0.072 8 0.001 5 453.3 9.1
      15CL156-3-26 181 212.5 554.2 0.38 0.055 1 0.000 3 0.558 1 0.012 2 0.073 5 0.001 6 456.9 9.4
      15CL156-3-27 62.4 67.2 276.0 0.24 0.055 5 0.000 7 0.555 9 0.014 6 0.072 6 0.001 5 451.6 9.3
      15CL156-3-28 188 218.7 542.8 0.40 0.055 2 0.000 3 0.563 2 0.012 1 0.074 0 0.001 6 460.5 9.5
      15CL156-3-29 196 209.7 612.8 0.34 0.061 4 0.000 4 0.601 6 0.013 5 0.071 1 0.001 4 442.6 8.7
      15CL156-3-30 171 198.8 535.2 0.37 0.055 5 0.000 4 0.566 3 0.012 9 0.074 0 0.001 7 460.4 10.1
      15CL152-3-02 527 611.3 3 508.1 0.17 0.056 7 0.000 3 0.526 0 0.010 7 0.067 2 0.001 2 419.3 7.4
      15CL152-3-05 67 91.7 210.5 0.44 0.056 2 0.002 2 0.537 8 0.022 7 0.069 5 0.002 0 433.1 11.9
      15CL152-3-07 520 670.5 2 134.2 0.31 0.056 3 0.000 4 0.538 3 0.017 1 0.069 3 0.001 9 432.2 11.7
      15CL152-3-08 708 867.7 2 001.9 0.43 0.062 4 0.000 4 0.587 7 0.016 6 0.068 3 0.002 0 425.8 11.8
      15CL152-3-10 1 039 1 034.3 4 081.8 0.25 0.064 1 0.000 8 0.589 2 0.010 6 0.066 8 0.001 5 416.8 9.2
      15CL152-3-11 829 1 047.3 3 544.0 0.30 0.057 6 0.000 5 0.546 1 0.019 1 0.068 6 0.002 0 427.9 12.2
      15CL152-3-12 487 792.5 2 131.4 0.37 0.058 8 0.000 8 0.548 3 0.011 7 0.067 8 0.001 9 422.6 11.4
      15CL152-3-13 570 735.7 2 321.0 0.32 0.057 6 0.000 4 0.544 7 0.016 6 0.068 5 0.001 8 427.1 11.0
      15CL152-3-18 466 617.1 1 600.3 0.39 0.057 2 0.000 6 0.539 4 0.010 3 0.068 5 0.001 4 426.9 8.8
      15CL152-3-20 908 1 112.9 3 189.6 0.35 0.060 8 0.000 5 0.565 4 0.012 3 0.067 5 0.001 4 420.9 8.5
      15CL152-3-22 151 141.4 791.5 0.18 0.062 9 0.002 2 0.583 5 0.027 7 0.067 1 0.001 2 418.9 7.2
      15CL152-3-25 347 421.0 1 055.6 0.40 0.061 5 0.001 2 0.565 5 0.013 0 0.066 7 0.001 2 416.3 7.5
      15CL152-3-27 706 977.0 2 177.4 0.45 0.059 6 0.000 7 0.557 8 0.016 2 0.067 8 0.001 4 422.8 8.6
      15CL152-3-28 467 672.6 2 477.9 0.27 0.055 6 0.000 5 0.526 1 0.018 5 0.068 6 0.002 3 427.5 14.1
      15CL152-3-29 344 519.7 900.4 0.58 0.056 6 0.000 5 0.525 7 0.011 9 0.067 4 0.001 2 420.3 7.5
      15CL152-3-30 474 692.5 1 403.0 0.49 0.056 5 0.000 5 0.531 4 0.011 0 0.068 2 0.001 5 425.2 9.3
      15CL154-3-01 138 185.0 200.5 0.92 0.057 3 0.000 6 0.548 3 0.019 6 0.069 3 0.002 1 432.1 12.9
      15CL154-3-03 1 263 649.8 3 332.3 0.20 0.084 1 0.002 4 0.771 8 0.018 7 0.066 7 0.001 0 416.1 6.1
      15CL154-3-05 387 656.3 1 248.6 0.53 0.059 1 0.000 4 0.565 5 0.012 7 0.069 3 0.001 5 432.2 9.2
      15CL154-3-06 1 614 984.7 6 076.2 0.16 0.076 4 0.001 1 0.738 9 0.025 6 0.070 0 0.001 7 436.4 10.4
      15CL154-3-07 243 354.7 442.8 0.80 0.059 1 0.000 6 0.548 7 0.016 1 0.067 3 0.001 5 419.9 9.2
      15CL154-3-08 578 560.7 2 600.4 0.22 0.062 3 0.000 6 0.589 0 0.013 8 0.068 6 0.002 1 427.9 12.7
      15CL154-3-09 106 136.6 324.2 0.42 0.055 5 0.000 5 0.535 1 0.014 5 0.069 9 0.001 9 435.5 11.2
      15CL154-3-10 593 716.2 1 586.9 0.45 0.059 5 0.002 2 0.573 6 0.030 5 0.069 6 0.001 4 434.0 8.3
      15CL154-3-11 783 886.7 2 293.1 0.39 0.063 2 0.001 8 0.608 8 0.030 1 0.069 6 0.001 5 433.7 9.3
      15CL154-3-13 603 741.1 1 457.0 0.51 0.062 2 0.001 2 0.599 3 0.013 5 0.069 9 0.001 6 435.7 9.8
      15CL154-3-14 704 827.5 1 712.1 0.48 0.063 4 0.000 9 0.585 3 0.012 2 0.067 0 0.001 4 418.3 8.4
      15CL154-3-17 83 109.0 195.0 0.56 0.055 0 0.001 2 0.520 5 0.017 4 0.068 6 0.001 5 427.8 9.2
      15CL154-3-18 155 227.1 211.2 1.08 0.054 7 0.001 3 0.515 5 0.017 9 0.068 3 0.001 7 426.2 10.0
      15CL154-3-22 625 614.6 1 792.9 0.34 0.065 4 0.002 0 0.603 5 0.016 5 0.067 1 0.001 6 418.6 9.5
      15CL154-3-23 496 528.7 1 603.8 0.33 0.061 3 0.001 4 0.586 8 0.022 8 0.069 3 0.001 9 432.1 11.5
      15CL154-3-24 521 627.6 1 283.2 0.49 0.061 8 0.001 3 0.596 5 0.017 6 0.070 0 0.001 3 436.2 7.7
      15CL154-3-27 60 77.8 163.6 0.48 0.055 8 0.000 8 0.537 7 0.018 8 0.069 9 0.002 0 435.3 11.9
      15CL154-3-28 385 518.7 1 288.3 0.40 0.055 9 0.000 6 0.537 2 0.011 9 0.069 7 0.001 4 434.1 8.6
      15CL154-3-29 97 103.6 242.2 0.43 0.070 4 0.004 5 0.674 1 0.067 7 0.068 4 0.002 5 426.6 15.3
      15CL154-3-30 798 842.6 2 525.7 0.33 0.067 2 0.000 8 0.629 7 0.023 0 0.067 9 0.002 1 423.3 12.5
      下载: 导出CSV

      表  2  玉苏普阿勒克塔格岩体花岗岩化学成分

      Table  2.   Chemical composition of granites in Yusupuleke pluton

      样品 15CL
      147-2
      15CL
      148-2
      15CL
      149-2
      15CL
      150-2
      15CL
      155-2
      15CL
      156-2
      15CL
      156-5
      15CL
      151-2
      15CL
      152-2
      15CL
      153-2
      15CL
      154-2
      期次 早期花岗岩 晚期花岗岩
      SiO2 66.22 71.20 73.98 74.57 69.52 68.82 69.50 74.05 77.91 74.10 76.05
      TiO2 0.82 0.40 0.13 0.16 0.54 0.60 0.58 0.29 0.20 0.20 0.19
      Al2O3 13.81 13.65 13.31 13.35 14.09 13.57 14.06 13.20 11.15 13.53 12.29
      Fe2O3 1.80 0.86 0.52 0.59 0.89 1.00 0.91 1.89 0.65 0.46 0.46
      FeO 2.52 1.55 0.62 0.75 2.90 2.93 2.28 0.08 1.05 1.25 1.08
      MnO 0.068 0.045 0.028 0.035 0.071 0.072 0.065 0.031 0.033 0.032 0.033
      MgO 1.57 0.76 0.21 0.21 0.63 0.89 1.24 0.45 0.22 0.22 0.14
      CaO 2.88 1.33 1.12 1.00 1.90 1.89 2.42 0.93 0.97 0.96 0.83
      Na2O 3.97 2.83 3.15 3.19 3.53 3.27 3.23 3.63 2.64 3.28 3.01
      K2O 3.39 5.76 5.97 5.46 4.95 4.61 4.63 4.30 4.40 5.15 5.24
      P2O5 0.210 0.096 0.029 0.045 0.130 0.160 0.150 0.068 0.040 0.045 0.045
      H2O+ 1.61 0.95 0.36 0.34 0.45 1.37 0.66 0.84 0.46 0.58 0.35
      LOI 2.627 1.426 0.887 0.594 0.701 2.064 0.833 1.030 0.699 0.744 0.571
      Total 99.89 99.91 99.95 99.96 99.85 99.89 99.90 99.95 99.96 99.95 99.95
      TFeO 4.253 2.364 1.098 1.286 3.729 3.926 3.125 1.800 1.642 1.681 1.513
      ALK 7.58 8.72 9.21 8.70 8.57 8.07 7.94 8.03 7.10 8.49 8.30
      K/Na 0.853 2.038 1.896 1.710 1.401 1.409 1.436 1.188 1.669 1.573 1.748
      DI 76.34 86.93 92.49 91.84 83.15 81.67 80.24 90.2 91.46 90.91 92.7
      AR 2.578 3.683 4.437 4.021 3.267 3.085 2.823 3.557 3.773 3.775 4.388
      MF 72.64 75.63 83.46 86.09 85.49 81.35 71.66 80.18 88.3 88.54 91.07
      A/CNK 0.893 1.025 0.972 1.028 0.962 0.981 0.953 1.071 1.024 1.063 1.013
      A/NK 1.352 1.253 1.141 1.197 1.259 1.305 1.360 1.242 1.223 1.233 1.156
      Li 24.9 33.1 59.3 76.1 28.9 25.8 62.1 40.7 69.2 32.3 61.2
      Be 3.18 3.77 4.36 5.77 3.35 3.67 4.23 7.95 4.23 6.33 5.74
      Sc 11.1 6.3 1.4 3.1 9.3 9.8 8.3 3.8 2.7 2.8 2.5
      Cr 15.7 11.5 2.9 4.9 8.3 7.9 19.5 8.1 2.4 3.6 2.9
      Co 10.3 4.2 0.9 1.1 4.2 6.1 7.6 3.3 1.2 1.3 1.3
      Ni 9.41 4.95 0.64 1.45 2.47 2.87 9.82 3.32 0.39 0.60 0.63
      Cu 10.2 3.5 1.5 5.3 8.5 6.1 5.8 6.6 2.7 3.8 1.9
      Zn 69.8 43.9 21.7 29.8 72.4 80.8 50.0 69.1 32.0 41.1 32.1
      Ga 23.0 19.1 19.3 20.0 23.1 22.1 20.1 19.3 18.2 22.9 20.0
      Rb 156 278 345 343 171 183 227 309 279 313 329
      Sr 171 100 61 52 102 140 145 78 52 60 47
      Zr 338 194 83 110 428 347 234 167 153 161 154
      Nb 27.1 24.3 13.5 24.8 29.4 27.0 22.7 22.5 22.1 22.7 26.5
      Cs 2.38 8.49 9.64 12.49 6.57 2.20 12.35 13.79 9.98 7.18 12.03
      Cd 0.075 0.058 0.030 0.037 0.077 0.063 0.090 0.020 0.043 0.046 0.044
      Ba 430 497 308 232 891 586 472 204 150 241 220
      Hf 10.6 6.2 2.7 3.7 14.9 10.5 6.5 5.4 5.0 5.3 4.5
      Ta 2.40 3.13 1.83 3.18 2.18 1.78 2.52 4.13 2.72 2.91 2.86
      Pb 15.4 30.0 35.0 42.4 23.0 22.1 21.9 31.1 27.9 34.8 32.1
      Th 30.1 39.2 42.2 37.0 26.7 19.7 47.6 40.1 75.1 64.5 50.8
      U 4.10 6.58 3.90 3.88 3.61 2.67 5.45 6.68 7.18 6.33 5.84
      Bi 0.29 0.09 0.10 0.10 0.16 0.12 0.12 0.24 0.13 0.06 0.06
      V 71.7 25.2 7.2 8.2 26.1 36.4 46.7 21.1 4.9 8.4 9.4
      Mo 0.79 0.51 0.06 0.08 0.56 0.42 0.29 0.45 0.15 0.24 0.25
      In 0.074 0.055 0.033 0.051 0.077 0.092 0.085 0.098 0.048 0.047 0.049
      Sb 0.73 0.31 0.09 0.08 0.34 0.30 0.11 0.17 0.14 0.12 0.19
      W 1.69 0.92 0.41 0.80 1.00 0.70 0.47 0.80 0.57 0.82 1.47
      Y 56.5 49.1 29.8 38.6 47.6 61.4 53.0 43.2 40.0 46.2 40.0
      La 99.4 50.1 36.6 36.8 78.5 70.4 59.9 43.5 60.9 51.0 54.8
      Ce 181 98.6 72.7 66.6 147 136 121 81.7 116 98.5 102
      Pr 20.5 12.0 9.12 8.34 16.9 17.2 14.4 9.54 13.9 11.7 11.8
      Nd 72.3 45.6 32.7 31.1 61.8 67.0 54.2 33.9 50.4 42.8 42.1
      Sm 12.9 9.70 6.34 6.82 11.0 13.6 10.9 6.62 10.4 9.08 8.11
      Eu 1.60 0.97 0.64 0.65 2.02 1.55 1.36 0.78 0.59 0.69 0.66
      Gd 11.8 8.77 5.21 6.29 10.0 12.4 9.64 6.21 8.85 7.99 7.11
      Tb 1.90 1.59 0.84 1.18 1.63 2.13 1.64 1.11 1.44 1.42 1.21
      Dy 10.7 9.38 4.92 7.05 9.22 12.3 9.76 6.90 7.94 8.26 7.03
      Ho 2.13 1.85 1.00 1.44 1.85 2.42 1.94 1.49 1.52 1.68 1.44
      Er 5.71 5.00 3.01 3.97 4.94 6.31 5.34 4.46 4.06 4.81 4.17
      Tm 1.02 0.88 0.59 0.76 0.87 1.03 0.99 0.91 0.71 0.93 0.81
      Yb 6.19 5.24 3.82 4.88 5.40 6.06 6.12 6.09 4.26 6.03 5.49
      Lu 0.84 0.78 0.58 0.75 0.74 0.86 0.93 0.92 0.76 0.97 0.90
      (La/Yb)N 11.53 6.86 6.87 5.41 10.42 8.33 7.02 5.12 10.26 6.06 7.16
      ΣREE 428.0 250.5 178.0 176.7 351.4 348.8 298.3 204.0 282.2 245.8 247.3
      LREE 387.7 217.0 158.1 150.3 316.7 305.4 261.9 175.9 252.7 213.7 219.1
      HREE 40.26 33.49 19.96 26.31 34.70 43.49 36.35 28.08 29.53 32.10 28.17
      LR/HR 9.63 6.48 7.92 5.71 9.13 7.02 7.20 6.27 8.56 6.66 7.78
      δEu 0.39 0.32 0.33 0.30 0.58 0.36 0.40 0.37 0.18 0.24 0.26
      Nb/Ta 11.32 7.76 7.36 7.82 13.50 15.21 9.02 5.44 8.12 7.79 9.26
      Zr/Hf 32.02 31.54 30.66 29.47 28.63 33.14 36.03 31.06 30.67 30.48 34.23
      Rb/Sr 0.91 2.78 5.63 6.60 1.66 1.31 1.57 3.95 5.32 5.18 7.04
      Rb/Ba 0.36 0.56 1.12 1.48 0.19 0.31 0.48 1.51 1.86 1.30 1.50
        注:主量元素单位为%;稀土及微量元素单位为10-6;ALK=K2O+Na2O; A/CNK=Al2O3/(Na2O+K2O+CaO);A/NK=Al2O3/(Na2O+K2O);DI.分异指数;AR.碱度率指数;MF.镁铁指数.
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    • 收稿日期:  2018-12-17
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