江山-绍兴构造带陈蔡岩群斜长角闪岩变质时代、地球化学特征及其构造演化意义

陈林燊; 陈汉林; 龚俊峰; 章凤奇; 孟立丰; 林秀斌; 杨树锋

doi:10.3799/dqkx.2018.526

江山-绍兴构造带陈蔡岩群斜长角闪岩变质时代、地球化学特征及其构造演化意义

doi: 10.3799/dqkx.2018.526

浙江大学地球科学学院, 浙江杭州 310027

基金项目:

国家科技重大专项 2017ZX05008001

国家重点研发计划 2016YFC0601004

国家科技重大专项 2016ZX05003001

详细信息

作者简介:
陈林燊(1992-), 男, 硕士生, 主要从事变质岩构造属性研究工作

通讯作者:
陈汉林

中图分类号: P588.14+.5
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出版历程
- 收稿日期: 2018-04-21
- 刊出日期: 2019-04-15

Metamorphic Episodes, Geochemical Characteristics of Chencai Amphibolite and Its Tectonic Implications in Jiangshan-Shaoxing Fault Zone

School of Earth Sciences, Zhejiang University, Hangzhou 310027, China

摘要

摘要: 目前前人对于陈蔡岩群的变质时限和形成环境的认识观点不一.斜长角闪岩作为陈蔡岩群的重要岩石单元，是认识整个陈蔡岩群原岩性质和构造演化最重要的窗口之一.对陈蔡岩群中的斜长角闪岩开展了详细的年代学和岩石地球化学研究.SHRIMP U-Pb定年结果显示，斜长角闪岩锆石加权平均年龄为424.0±3.6 Ma，代表了峰期变质事件时间，并保留了新元古代晚期到早古生代早期的变质年龄记录；地球化学特征和判别图解表明，陈蔡岩群斜长角闪岩原岩为洋岛碱性玄武岩，结合野外观察到的斜长角闪岩与大理岩密切共生现象，认为其原岩可能为一套来自洋岛-海山体系的洋岛玄武岩-碳酸盐岩组合.陈蔡岩群的原岩可能是在古南华洋板块向扬子板块俯冲过程中形成的增生楔岩石组合，在早古生代晚期经历了角闪岩相变质作用.
- 陈蔡岩群 /
- 斜长角闪岩 /
- 锆石U-Pb定年 /
- 地球化学 /
- 洋岛玄武岩 /
- 构造演化
Abstract: Currently, predecessors hold different views on metamorphic ages and formation background of the Chencai Group. As the representative rock unit of the Chencai Group, the amphibolite is an important window for understanding its protolith property and tectonic evolution. Therefore, in this paper in detailed it analyzes the amphibolite from the Chencai Group, including geochronology and whole rock geochemistry.SHRIMP U-Pb dating data from the amphibolite, the weighted mean age of 424.0±3.6 Ma records the timing of the main metamorphic event and simultaneously preserves the record of the metamorphic age from Late Neoproterozoic to Ordovician. Based on the geochemical characteristics and discrimination diagrams, it is proposed that the protolith of the amphibolite from the Chencai Group is ocean island alkali basalt (OIB). Field observation presents the paragenetic association of the amphibolite with marble, further implying that the protolith of the amphibolite-marble assemblage could be OIB-carbonate rock assemblage from the oceanic island-seamount system. The protolith of the Chencai Group is probably the rock assemblage of the accretionary wedge which formed in the subduction of the South China Proterozoic ocean beneath the Yangtze block. The amphibolite-facies metamorphism occurred in the late period of Early Paleozoic.
- Chencai Group /
- amphibolite /
- zircon U-Pb dating /
- geochemistry /
- ocean island alkali basalt /
- tectonic evolution

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图 1 陈蔡地区位置示意图(a)和地质简图(b)

Fig. 1. Location schematic diagram (a) and simplified geological map of the Chencai area

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图 2 斜长角闪岩露头野外照片

a.采样点1；b.采样点2

Fig. 2. Field photographs of the amphibolite outcrops

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图 3 斜长角闪岩样品镜下照片

a~d.主要镜下结构特征；e~j.代表性矿物组合; Hbl.角闪石；Pl.斜长石；Ser.绢云母；Bt.黑云母；Chl.绿泥石；Grt.石榴石

Fig. 3. Microscope photographs of the amphibolite samples

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图 4 斜长角闪岩样品锆石CL图像及²⁰⁶Pb/²³⁸U年龄

圆圈代表锆石测试点位置

Fig. 4. CL images and ²⁰⁶Pb/²³⁸U ages of zircon of the amphibolite samples, circles show laser ablation spots of U-Pb analyses

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图 5 斜长角闪岩样品(13CC-1)锆石U-Pb年龄谐和图(a)、加权平均年龄(b)和年龄相关密度曲线及直方图(c)

Fig. 5. U-Pb zircon concordia plot (a), weighted averaged age (b) and relative U-Pb age probability density plots and histogram (c) of amphibolite sample (13CC-1)

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图 6 斜长角闪岩样品微量元素蛛网图

图a为样品和N-MORB、E-MORB、OIB、IAB相对于原始地幔标准化微量元素蛛网图；图b为陈蔡岩群不同原岩类型的斜长角闪岩相对于原始地幔标准化微量元素蛛网图.原始地幔标准化数据引自McDonough et al.(1992); N-MORB、E-MORB、OIB数据引自Sun and McDonough(1989); IAB平均值数据杨婧等(2016)；含榴斜长角闪岩和斜长角闪岩数据引自Zhao et al.(2015)

Fig. 6. Trace elements spider diagrams for the amphibolite samples

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图 7 斜长角闪岩样品球粒陨石标准化稀土元素配分模式

a为样品和N-MORB、E-MORB、OIB、IAB相对于球粒陨石标准化稀土元素配分模式图；b为陈蔡岩群不同原岩类型的斜长角闪岩相对于球粒陨石标准化稀土元素配分模式图.球粒陨石标准化数据以及N-MORB、E-MORB、OIB数据均引自Sun and McDonough(1989); IAB平均值数据杨婧等(2016)；含榴斜长角闪岩和斜长角闪岩数据引自Zhao et al.(2015)

Fig. 7. Chondrite-normalized REE diagrams for the amphibolite samples

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图 8 斜长角闪岩样品TiO₂-F图解(a)和西蒙南图解(b)

图a据Misra(1971); 图b转王仁民等(1987)

Fig. 8. TiO₂-F (a) and Simonen diagram (b) for the amphibolite samples

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图 9 斜长角闪岩样品的Zr/TiO₂-Nb/Y图解(a)、La/Yb-ΣREE图解(b)、硅-碱图解(c)和TiO₂-Zr/P₂O₅图解(d)

图a据Winchester and Floyd(1977)；图b据Allègre and Minster(1978); 图c据Irvine and Baragar(1971); 图d据Winchester and Floyd(1976)

Fig. 9. Zr/TiO₂-Nb/Y diagram (a), La/Yb-REE diagram (b), SiO₂-(Na₂O+K₂O) diagram (c) and TiO₂-Zr/P₂O₅ diagram (d) for the amphibolite samples

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图 10 斜长角闪岩样品Nb-Zr-Y图解(a)和TiO₂-MnO-P₂O₅图解(b)

图a据Meschede(1986); 图b据Pearce and Cann(1973)

Fig. 10. Nb-Zr-Y diagram (a) and TiO₂-MnO-P₂O₅ diagram (b) for the amphibolite samples

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表 1 陈蔡岩群早古生代晚期变质年龄

Table 1. Constraints on the metamorphic age of Chencai Group

样品	岩性	方法	年龄(Ma)	文献
109-3	石榴黑云斜长片麻岩	LA-ICP-MS及SHRIMP	444.5±3.8 430.8 ±4.3	向华，2008
04SC74	变质辉长岩	SHRIMP	454±29	Li et al., 2010
01SC40	变泥质岩	SHRIMP	447±7	Li et al., 2010
04SC75	混合岩	SHRIMP	433±3	Li et al., 2010
01SC37	片麻状花岗岩	SHRIMP	435±4	Li et al., 2010
04SC74	变质辉长岩	Hbl ⁴⁰Ar/³⁹Ar	426±2	Li et al., 2010
04SC88-1	变泥质岩	Bi ⁴⁰Ar/³⁹Ar	425±7	Li et al., 2010
WG-105B	斜长角闪岩	SHRIMP	428±9	Wang et al., 2012
SL07-1	片麻岩	LA-ICP-MS	452.8±2.6	李海滨，2013
SL07-2	片麻岩	LA-ICP-MS	451±1.8	李海滨，2013
1199m	混合岩	LA-ICP-MS	438.3±2.7	Yao et al., 2014a
1199m-1	混合岩	LA-ICP-MS	438.0± 3.6	Yao et al., 2014a
1199g	辉长岩包体	LA-ICP-MS	453.2±3.5	Yao et al., 2014a
CH1211-1	含榴黑云斜长片麻岩	SHRIMP	436.4±7.8	高林志等，2014
CH1211-2	含榴矽线黑云斜长片麻岩	SHRIMP	431±6	高林志等，2014
cc1303	铁镁质麻粒岩	LA-ICP-MS	437±3	Zhao et al., 2015
cc1401-1	铁镁质麻粒岩	LA-ICP-MS	437±4	Zhao et al., 2015
cc1401-2	铁镁质麻粒岩	LA-ICP-MS	438±2	Zhao et al., 2015
cc1305	石榴石斜长角闪岩	LA-ICP-MS	435±3	Zhao et al., 2015
cc1401-3	斜长角闪岩	LA-ICP-MS	445±5	Zhao et al., 2015
cc1402-3	斜长角闪岩	LA-ICP-MS	449±4	Zhao et al., 2015
cc1405-1	黑云斜长角闪岩	LA-ICP-MS	436±3	Zhao et al., 2015
JS248-1	大理岩	LA-ICP-MS	440.5±4.6	董学发，2016
JS016	斜长角闪岩	LA-ICP-MS	432.1±7.3	董学发，2016
JS224-1	斜长角闪岩	LA-ICP-MS	442.0±2.2	董学发，2016
S202-1	斜长角闪岩	LA-ICP-MS	420.6±1.8	王存智等，2016
45-2	斜长角闪岩	LA-ICP-MS	424.6±4.2	杨东，2016

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表 2 陈蔡岩群斜长角闪岩样品主量元素(%)分析结果

Table 2. Major elements (%) analytic results of the amphibolite samples of the Chencai Group

主量元素	13CC-1	13CC-2	13CC-3	13CC-5	13CC-6	13CC-8	13CC-9	13CC-10
SiO₂	43.72	45.45	42.62	45.67	44.20	45.35	47.10	44.97
TiO₂	2.73	3.44	5.52	3.58	2.81	2.67	2.28	2.61
Al₂O₃	14.43	14.53	12.83	14.64	16.00	15.39	13.85	14.17
TFe₂O₃	19.88	16.52	19.82	17.88	16.44	17.21	17.19	19.26
MgO	3.14	4.77	4.52	4.17	5.46	3.31	3.65	3.13
CaO	8.78	8.12	8.65	7.52	9.51	6.88	7.23	8.23
Na₂O	2.25	3.04	2.27	4.16	2.80	5.46	3.39	4.59
K₂O	2.48	1.03	1.27	1.05	1.61	0.50	1.51	1.07
MnO	0.37	0.23	0.28	0.25	0.19	0.19	0.21	0.34
P₂O₅	1.45	0.72	1.16	0.86	0.43	1.20	1.45	1.50
LOI	0.74	1.42	1.67	1.12	1.27	2.62	2.95	1.01
TOTAL	99.97	99.27	100.61	100.90	100.72	100.79	100.80	100.87
Mg^#	24.01	36.61	31.32	31.81	39.91	27.78	29.81	24.53

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表 3 陈蔡岩群斜长角闪岩样品微量元素和稀土元素(10^-6)分析结果

Table 3. Trace and rare earth elements (10^-6) analytic results of the amphibolite samples of the Chencai Group

元素	13CC-1	13CC-2	13CC-3	13CC-5	13CC-6	13CC-8	13CC-9	13CC-10
Li	13.61	16.04	9.01	19.36	14.88	26.46	20.69	8.45
Be	6.20	2.36	2.23	2.15	1.59	2.86	2.82	2.84
Sc	21.32	18.46	18.68	17.37	21.30	21.23	17.91	20.30
Ti	14 682.55	21 787.78	23 548.79	21 140.90	17 892.67	17 582.43	12 777.29	14 154.53
V	5.91	113.12	207.77	108.73	175.27	48.70	20.00	21.28
Cr	155.81	134.76	6.05	13.26	15.40	12.56	4.35	3.36
Mn	5 730.37	4 172.91	4 535.90	4 280.45	2 344.58	3 587.78	3 359.81	5 440.17
Co	29.03	37.01	39.87	37.18	52.31	27.25	24.73	28.16
Ni	98.89	50.72	35.86	16.39	56.22	9.20	3.73	3.85
Cu	82.56	60.20	111.57	77.54	17.22	34.02	22.25	83.96
Zn	216.54	193.80	203.37	198.47	165.41	229.98	185.56	194.81
Ga	25.27	25.82	21.97	25.85	22.66	31.54	23.36	23.32
Rb	56.06	32.71	28.98	24.20	37.14	16.38	35.28	25.66
Sr	265.90	384.95	258.28	330.84	463.99	345.62	318.32	328.27
Y	63.19	40.83	35.58	45.68	25.96	63.56	51.86	62.44
Zr	545.37	458.77	51.90	478.77	227.49	723.82	571.47	607.34
Nb	58.82	49.19	24.12	46.47	27.68	72.98	58.06	67.03
Mo	2.15	0.89	0.59	1.05	0.68	2.55	2.73	2.01
Cd	0	0	0	0	0	0	0	0
Sn	6.69	5.34	2.07	4.42	3.04	6.13	5.20	5.23
Cs	2.65	2.68	2.65	1.81	2.63	2.08	3.56	1.70
Ba	398.44	279.59	309.42	232.36	616.18	236.10	462.43	222.18
La	64.54	46.23	37.57	50.21	24.29	74.96	56.97	60.41
Ce	139.97	99.95	84.53	107.64	53.80	161.64	125.09	133.58
Pr	14.97	13.80	12.44	14.30	7.36	15.65	17.55	17.27
Nd	79.79	56.79	53.47	60.80	30.95	83.23	73.05	79.35
Sm	16.25	11.56	11.13	12.48	6.35	17.84	14.90	16.65
Eu	4.29	3.26	3.35	3.42	2.11	4.62	4.26	4.27
Gd	15.55	10.91	10.40	11.89	6.23	16.93	13.98	15.76
Tb	2.47	1.71	1.59	1.87	0.95	2.63	2.18	2.50
Dy	13.76	9.31	8.36	10.24	5.17	14.24	11.60	13.71
Ho	2.59	1.71	1.49	1.89	0.94	2.61	2.10	2.53
Er	7.34	4.76	3.99	5.26	2.59	7.25	5.72	7.01
Tm	1.00	0.64	0.50	0.70	0.34	0.97	0.74	0.95
Yb	6.29	4.00	3.05	4.39	2.15	6.17	4.59	5.96
Lu	0.95	0.60	0.45	0.67	0.32	0.94	0.68	0.90
Hf	13.74	11.65	1.91	12.19	5.25	18.16	13.97	14.97
Ta	3.77	3.26	0.86	3.10	1.71	5.01	3.82	4.30
W	0.89	1.15	0.10	0.29	0.40	0.60	0.37	0.41
Pb	8.54	4.76	3.67	4.28	4.92	5.25	4.87	5.47
Bi	0.17	0.10	0.08	0.06	0.08	0.06	0.06	0.06
Th	8.61	6.48	2.98	6.64	2.69	9.23	6.67	7.16
U	1.63	1.24	0.32	1.22	0.41	1.99	1.27	1.30
∑REE	369.73	265.23	232.33	285.76	143.56	409.67	333.42	360.86
LREE/HREE	6.40	6.89	6.79	6.74	6.68	6.92	7.02	6.32
(La/Yb)_N	7.36	8.29	8.84	8.20	8.09	8.72	8.90	7.27
(La/Sm)_N	2.56	2.58	2.18	2.60	2.47	2.71	2.47	2.34
(Gd/Yb)_N	2.05	2.26	2.82	2.24	2.39	2.27	2.52	2.19
δEu	0.81	0.87	0.94	0.85	1.01	0.80	0.89	0.79
δCe	1.06	0.96	0.95	0.97	0.98	1.10	0.96	1.00
注：(La/Yb)_N、(La/Sm)_N、(Gd/Yb)_N为球粒陨石标准化值，以及δEu、δCe采用的标准化值均引自Sun and McDonough(1989).

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