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    东天山巴里坤地区晚石炭世双峰式火山岩年代学、地球化学及其构造意义

    罗婷 陈继平 廖群安 王国灿 胡朝斌 王良玉

    罗婷, 陈继平, 廖群安, 王国灿, 胡朝斌, 王良玉, 2018. 东天山巴里坤地区晚石炭世双峰式火山岩年代学、地球化学及其构造意义. 地球科学, 43(9): 3018-3035. doi: 10.3799/dqkx.2018.603
    引用本文: 罗婷, 陈继平, 廖群安, 王国灿, 胡朝斌, 王良玉, 2018. 东天山巴里坤地区晚石炭世双峰式火山岩年代学、地球化学及其构造意义. 地球科学, 43(9): 3018-3035. doi: 10.3799/dqkx.2018.603
    Luo Ting, Chen Jiping, Liao Qun'an, Wang Guocan, Hu Chaobin, Wang Liangyu, 2018. Geochronology, Geochemistry and Geological Significance of the Late Carboniferous Bimodal Volcanic Rocks in the Balikun Area, Eastern Tianshan. Earth Science, 43(9): 3018-3035. doi: 10.3799/dqkx.2018.603
    Citation: Luo Ting, Chen Jiping, Liao Qun'an, Wang Guocan, Hu Chaobin, Wang Liangyu, 2018. Geochronology, Geochemistry and Geological Significance of the Late Carboniferous Bimodal Volcanic Rocks in the Balikun Area, Eastern Tianshan. Earth Science, 43(9): 3018-3035. doi: 10.3799/dqkx.2018.603

    东天山巴里坤地区晚石炭世双峰式火山岩年代学、地球化学及其构造意义

    doi: 10.3799/dqkx.2018.603
    基金项目: 

    中国地质调查局项目 1212011120509

    中国地质调查局项目 DD20160006

    中国地质调查局项目 12120114042801

    中国地质调查局项目 1212011120503

    详细信息
      作者简介:

      罗婷(1987-), 女, 博士, 从事岩浆岩及其相关矿产研究工作.E-mail:179175768@qq.com

    • 中图分类号: P581

    Geochronology, Geochemistry and Geological Significance of the Late Carboniferous Bimodal Volcanic Rocks in the Balikun Area, Eastern Tianshan

    • 摘要: 新疆东天山博格达-哈尔里克造山带巴里坤地区晚石炭世双峰式火山岩很好地记录了中亚造山带西南缘晚古生代时期洋陆转换阶段复杂的岩浆作用过程,对该过程的详细剖析能更好地理解中亚造山带的地质历史.通过对晚石炭统二道沟组火山岩详细的岩石学、地球化学、锆石U-Pb年代学和Sr-Nd同位素组成的研究,结合区域上已有的研究成果,获得了如下认识:(1)东天山博格达-哈尔里克造山带晚石炭统二道沟组火山岩形成于晚石炭世早期(308~312 Ma),为陆相喷发的产物.火山岩具明显的双峰式组合特征,基性火山岩端元由高钾-钾玄岩系列的玄武岩、粗面玄武岩、玄武粗安岩及同成分的火山碎屑岩组成;酸性火山岩端元由粗面岩、流纹岩组成.(2)岩石地球化学和同位素特征显示,该套双峰式火山岩具有相似的地球化学特征,是相同源区岩浆演化的产物,为深部受到俯冲流体交代的软流圈上涌(尖晶石-石榴石橄榄岩5%~25%部分熔融)形成具有明显Nb、Ta亏损的基性火山岩,岩浆经过结晶分异作用形成酸性火山岩,进而形成晚石炭世双峰式火山岩组合.(3)该套双峰式火山岩是早石炭世双峰式火山岩的延续,代表了该区域弧后盆地基础上的持续裂开.

       

    • 图  1  中亚及邻区构造简图(a),东天山及其邻区构造简图(b),东天山巴里坤地区晚古生代岩浆岩分布(c)

      图b据Xiao et al.(2010);图c据孙桂华(2007)

      Fig.  1.  Tectonic sketch of Central Asian and adjacent regions (a), tectonic sketch of eastern Tianshan and its adjacent areas (b), and the distribution of Late Paleozoic volcanic rocks in the Balikun area, eastern Tianshan (c)

      图  2  东天山巴里坤地区晚石炭统二道沟组(C2e)火山岩野外照片

      a.酸性火山岩露头;b.基性火山岩与酸性火山岩互层;c.基性火山岩露头

      Fig.  2.  Field photos of volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      图  3  东天山巴里坤地区晚石炭统二道沟组典型地质实测剖面

      Fig.  3.  The typical geological sections for volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      图  4  东天山巴里坤地区晚石炭统二道沟组典型火山岩野外(a, c, e)及显微照片(b, d, f)

      图a, c, e分别为玄武岩、粗面玄武岩、流纹岩野外照片;图b, d, f分别为玄武岩、粗面玄武岩、流纹岩镜下照片,正交偏光;Cpx.单斜辉石;Kfs.碱性长石;Qz.石英

      Fig.  4.  Field photos (a, c, e) and photomicrographs (b, d, f) of volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      图  5  东天山巴里坤地区晚石炭统二道沟组火山岩锆石LA-ICP-MS U-Pb谐和年龄及锆石阴极发光照片

      Fig.  5.  LA-ICP-MS zircon U-Pb age concordia diagrams, weighted mean ages and representative CL images of zircons from the volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      图  6  东天山巴里坤地区石炭纪火山岩TAS图解(a)和SiO2-K2O图解(b)

      图a据Winchester and Floyd(1977);图b据Peccerillo and Taylor(1976)

      Fig.  6.  TAS diagram (a) and SiO2 vs. K2O diagram (b) for the classification of the Carboniferous volcanic rocks in the Balikun area, eastern Tianshan

      图  7  东天山巴里坤地区石炭纪火山岩微量元素原始地幔标准化配分图解及稀土元素球粒陨石标准化配分图解

      标准化值据Sun and McDonough(1989)

      Fig.  7.  Primitive mantle normalized multi-element patterns and chondrite-normalized rare earth element (REE) patterns for the volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      图  8  东天山巴里坤地区石炭纪火山岩初始Sr-Nd同位素图解

      地幔数据来自Zindler and Hart(1986);二叠纪塔里木玄武岩数据来自Tang et al.(2011);东西准噶尔数据来自Su et al.(2012)夏林圻等(2008);阿尔泰数据来自Long et al.(2011)

      Fig.  8.  Initial Sr-Nd isotope data for the Carboniferous volcanic rocks in the Balikun area, eastern Tianshan

      图  9  东天山巴里坤地区石炭纪火山岩Ba/Nb-Ba/La图解(a),Nb/Zr vs. Th/Zr图解(b),Th/Yb-Ta/Yb图解(c),Ba/Nb-La/Nb图解(d)

      图c据Pearce et al.(1990);图d据Jahn et al.(1999);MORB,OIB,原始地幔据Sun and McDonough(1989);地壳平均值据Taylor and McLennan(1985)Condie(1993);沉积物平均值据Condie(1993)

      Fig.  9.  Plots of Ba/Nb vs. Ba/La diagram (a), Nb/Zr vs. Th/Zr diagram (b), Th/Yb vs. Ta/Yb diagram (c) and Ba/Nb vs. La/Nb diagram (d) for the Carboniferous volcanic rocks in the Balikun area, eastern Tianshan

      图  10  东天山巴里坤地区石炭纪火山岩Sm/Yb-Sm变化图解

      底图据Aldanmaz et al.(2000)

      Fig.  10.  Plots of Sm/Yb-Sm diagram for the Carboniferous volcanic rocks in the Balikun area, eastern Tianshan

      图  11  东天山巴里坤地区石炭纪火山岩(a)Hf/3-Th-Ta和(b)Rb-Y+Nb构造判别图解

      A.N型大洋中脊玄武岩;B.E型大洋中脊玄武岩和板内玄武岩;C.板内碱性玄武岩;D.钙碱性玄武岩;E.岛弧拉斑玄武岩;ORG.大洋中脊花岗岩;Syn-ColG.同碰撞花岗岩;VAG.岛弧花岗岩;WPG.板内花岗岩;据Pearce et al.(1984)Pearce and Peate(1995)

      Fig.  11.  Tectonic discrimination diagrams of Hf/3-Th-Ta (a) and Rb vs. Y+Nb (b) for the Carboniferous volcanic rocks in the Balikun area, eastern Tianshan

      表  1  东天山巴里坤地区晚石炭世二道沟组火山岩锆石LA-ICP-MS U-Pb定年分析结果

      Table  1.   Analysis results of zircon U-Pb age from the volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      点号 232Th/238U Pb(10-6) 232Th(10-6) 238U(10-6) 同位素比值 年龄(Ma)
      207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/235U 1σ 206Pb/238U 1σ
      D9481-4 0.68 117 616 906 0.0674 0.0043 0.4529 0.0284 0.0493 0.0008 20 310 5 351
      D9481-6 0.61 70 801 1324 0.0565 0.0038 0.3681 0.0232 0.0491 0.0009 17 309 5 317
      D9481-7 0.47 55 148 316 0.0605 0.0041 0.3973 0.0261 0.0490 0.0010 19 308 6 331
      D9481-9 0.53 466 1349 2522 0.0675 0.0061 0.4316 0.0327 0.0486 0.0009 23 306 5 345
      D9481-10 0.86 175 485 566 0.0690 0.0040 0.4576 0.0259 0.0491 0.0008 18 309 5 376
      D9481-13 0.72 758 8865 12263 0.0642 0.0039 0.4236 0.0245 0.0490 0.0009 17 309 6 329
      D9481-15 0.80 180 609 760 0.0619 0.0041 0.4283 0.0313 0.0491 0.0008 22 309 5 335
      D9481-16 0.72 1412 643 894 0.0645 0.0039 0.4258 0.0239 0.0492 0.0008 17 309 5 343
      D9481-18 0.61 179 757 1244 0.0692 0.0046 0.4552 0.0309 0.0490 0.0011 22 309 7 342
      D9481-21 0.82 137 558 683 0.0696 0.0051 0.4533 0.0311 0.0488 0.0009 22 307 5 359
      D9481-22 0.67 356 966 1437 0.0666 0.0039 0.4364 0.0238 0.0484 0.0008 17 305 5 349
      D9481-24 0.74 238 788 1067 0.0591 0.0030 0.4295 0.0205 0.0532 0.0009 15 334 5 360
      8687-2-1 0.60 97 418 696 0.0524 0.0061 0.3592 0.0426 0.0495 0.0016 32 311 10 314
      8687-2-3 1.00 321 1605 1602 0.0538 0.0039 0.3684 0.0258 0.0494 0.0010 19 311 6 302
      8687-2-4 0.49 115 475 972 0.0526 0.0051 0.3516 0.0326 0.0489 0.0015 24 308 9 324
      8687-2-5 0.74 153 700 948 0.0526 0.0047 0.3579 0.0325 0.0491 0.0012 24 309 8 313
      8687-2-6 0.61 184 795 1305 0.0564 0.0048 0.3820 0.0318 0.0491 0.0013 23 309 8 311
      8687-2-7 0.84 527 2586 3072 0.0530 0.0032 0.3615 0.0229 0.0492 0.0012 17 310 7 293
      8687-2-8 0.71 162 739 1048 0.0539 0.0055 0.3603 0.0342 0.0491 0.0014 26 309 8 305
      8687-2-9 1.05 289 1413 1348 0.0533 0.0044 0.3593 0.0295 0.0492 0.0013 22 310 8 308
      8687-2-10 0.63 171 794 1266 0.0496 0.0044 0.3363 0.0279 0.0494 0.0014 21 311 9 305
      8687-2-11 0.90 270 1306 1450 0.0568 0.0059 0.3886 0.0345 0.0502 0.0014 25 316 9 309
      8687-2-12 1.26 386 2305 1834 0.0554 0.0044 0.3890 0.0321 0.0503 0.0016 23 316 10 268
      8687-2-13 0.92 397 1957 2118 0.0514 0.0040 0.3585 0.0289 0.0502 0.0016 22 316 10 317
      8687-2-14 0.65 180 811 1250 0.0479 0.0042 0.3319 0.0293 0.0498 0.0014 22 313 9 323
      8687-2-15 0.88 175 889 1005 0.0492 0.0048 0.3440 0.0354 0.0497 0.0015 27 313 9 315
      8687-2-16 0.59 285 1142 1928 0.0551 0.0043 0.3880 0.0323 0.0502 0.0013 24 316 8 344
      8687-2-17 1.04 343 1709 1645 0.0531 0.0038 0.3655 0.0255 0.0497 0.0011 19 313 7 306
      CN12-12-1-3 0.49 32 68 139 0.0597 0.0042 0.4029 0.0275 0.0500 0.0010 20 315 6 310
      CN12-12-1-4 0.34 128 230 675 0.0526 0.0036 0.3455 0.0222 0.0495 0.0010 17 312 6 321
      CN12-12-1-7 0.85 178 405 476 0.0631 0.0035 0.4561 0.0276 0.0507 0.0009 19 319 5 358
      CN12-12-1-8 0.77 38 134 174 0.0535 0.0028 0.3697 0.0199 0.0496 0.0007 15 312 4 310
      CN12-12-1-11 0.69 30 248 359 0.0601 0.0047 0.4091 0.0325 0.0494 0.0009 23 311 6 322
      CN12-12-1-13 0.53 70 152 285 0.0572 0.0033 0.3794 0.0212 0.0492 0.0007 16 310 5 303
      CN12-12-1-14 0.35 182 68 193 0.0606 0.0037 0.4040 0.0241 0.0491 0.0008 17 309 5 329
      CN12-12-1-15 1.04 111 281 271 0.0595 0.0034 0.4064 0.0227 0.0499 0.0008 16 314 5 296
      CN12-12-1-22 0.70 34 75 107 0.0477 0.0029 0.3187 0.0192 0.0495 0.0008 15 311 5 322
      CN12-12-1-23 0.68 73 172 253 0.0553 0.0031 0.3757 0.0207 0.0496 0.0006 15 312 4 307
      CN12-12-1-24 0.75 34 140 187 0.0660 0.0045 0.4374 0.0288 0.0494 0.0010 20 311 6 309
      CN12-8-1-1 0.63 88 207 329 0.0503 0.0025 0.3314 0.0159 0.0480 0.0006 12 302 4 297
      CN12-8-1-4 0.32 16 33 105 0.0543 0.0023 0.3672 0.0164 0.0490 0.0008 12 309 5 300
      CN12-8-1-5 0.56 112 186 331 0.0678 0.0080 0.4282 0.0338 0.0494 0.0011 24 311 6 366
      CN12-8-1-6 1.03 116 326 317 0.0620 0.0042 0.4115 0.0287 0.0510 0.0014 21 321 9 339
      CN12-8-1-7 0.80 54 280 350 0.0548 0.0028 0.3623 0.0179 0.0488 0.0009 13 307 5 306
      CN12-8-1-8 0.55 74 351 637 0.0582 0.0028 0.3890 0.0178 0.0492 0.0007 13 310 4 322
      CN12-8-1-9 0.67 35 165 246 0.0679 0.0039 0.4489 0.0250 0.0491 0.0009 18 309 5 306
      CN12-8-1-10 0.51 78 353 689 0.0560 0.0031 0.3829 0.0213 0.0490 0.0007 16 308 4 336
      CN12-8-1-11 0.55 85 389 713 0.0600 0.0028 0.4019 0.0187 0.0490 0.0006 14 308 4 311
      CN12-8-1-12 0.51 83 377 745 0.0647 0.0084 0.4021 0.0292 0.0494 0.0008 21 311 5 339
      CN12-8-1-13 0.80 54 280 350 0.0553 0.0025 0.3695 0.0170 0.0488 0.0007 13 307 5 299
      CN12-8-1-14 0.53 140 202 385 0.0558 0.0029 0.3700 0.0207 0.0477 0.0007 15 300 4 287
      下载: 导出CSV

      表  2  东天山巴里坤地区晚石炭世二道沟组火山岩主量元素、微量元素分析测试结果

      Table  2.   Analysis results of major elements and trace elements of volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      岩性 粗面玄武岩 玄武岩 玄武质粗安岩 玄武安山岩 流纹岩
      年龄 312Ma 308Ma
      样品 8687-2 12-7-2 D8687-1H D9480-2H D9480-6H D7391-1H 8166-1 D8166-1H D8677-1H D8324-1H 8677-2 12-6-1 D9480-1H PM12-11-1H PM12-8-1 PM12-9-2 PM12-12-1 PM12-14-2 12-10-2 12-12-2 12-12-3 9481-2 9481 D9480-5 D9480-7 D9481-3
      主量元素(%)
      SiO2 46.9 50.2 46.9 50.8 51.7 52.0 51.5 51.4 51.1 54.5 55.6 54.6 55.1 56.8 71.4 73.1 72.5 72.4 72.7 72.9 71.2 70.5 72.0 70.5 70.0 74.5
      Al2O3 16.45 17.75 17.35 16.80 16.90 15.20 17.85 17.95 17.80 17.20 14.80 16.30 16.80 16.15 14.00 13.80 13.85 14.10 13.55 12.70 13.95 14.15 14.20 13.65 14.35 12.20
      BaO 0.07 0.14 0.10 0.05 0.05 0.04 0.17 0.17 0.19 0.18 0.14 0.06 0.06 0.11 0.07 0.07 0.04 0.07 0.03 0.05 0.05 0.04 0.05 0.06 0.06 0.06
      CaO 7.80 7.03 6.29 8.62 6.66 9.12 5.78 5.79 6.75 4.92 5.48 7.15 2.83 2.71 0.49 0.20 0.45 0.14 0.64 0.28 0.32 0.31 0.08 1.08 0.88 0.57
      Fe2O3 11.13 8.96 9.98 9.69 9.65 7.84 8.88 8.94 8.75 8.71 9.43 9.22 8.48 9.27 2.56 2.50 2.67 2.74 2.74 3.45 3.53 3.38 2.96 2.76 2.92 2.62
      K2O 1.67 2.79 1.18 1.18 1.00 1.24 4.33 4.34 3.47 4.50 3.13 1.84 2.97 4.37 4.10 5.37 3.49 5.53 3.28 4.67 4.56 3.58 5.18 4.55 4.58 4.83
      Na2O 3.74 3.66 3.25 2.42 3.36 3.75 3.25 3.18 3.19 4.12 3.36 3.54 4.96 4.56 5.17 4.45 5.70 4.44 5.84 4.34 5.11 5.82 4.80 4.95 5.33 3.84
      MgO 5.99 4.79 7.22 6.50 4.98 2.87 3.42 3.44 4.43 3.01 3.83 2.81 3.21 1.96 0.23 0.33 0.29 0.39 0.04 0.34 0.41 0.37 0.09 0.20 0.18 0.26
      MnO 0.17 0.20 0.09 0.18 0.14 0.13 0.14 0.14 0.12 0.10 0.10 0.15 0.19 0.14 0.05 0.05 0.04 0.05 0.02 0.06 0.06 0.05 0.05 0.04 0.04 0.05
      P2O5 0.15 0.34 0.28 0.18 0.27 0.37 0.55 0.54 0.35 0.51 0.50 0.42 0.47 0.52 0.04 0.03 0.04 0.04 0.05 0.04 0.05 0.05 0.01 0.04 0.04 0.04
      SrO 0.07 0.08 0.06 0.04 0.04 0.05 0.10 0.11 0.10 0.08 0.06 0.04 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 <0.01 0.01 <0.01 0.01
      TiO2 0.90 1.02 1.02 0.98 1.26 1.16 1.22 1.24 0.99 1.18 0.83 1.16 1.60 1.82 0.33 0.32 0.29 0.35 0.31 0.26 0.29 0.32 0.28 0.34 0.35 0.27
      LOI 4.46 2.53 5.58 2.66 4.52 5.59 2.49 2.35 1.75 1.66 2.70 3.23 2.83 1.79 0.59 0.43 0.49 0.33 0.65 0.29 0.43 0.38 0.31 0.87 0.64 0.66
      FeOt 10.01 8.06 8.97 8.71 8.68 7.05 7.98 8.04 7.87 7.83 8.48 8.29 7.62 8.33 2.30 2.25 2.40 2.46 2.46 3.10 3.17 3.04 2.66 2.48 2.63 2.36
      微量元素(10-6)
      La 7.5 16.5 13.0 8.1 13.7 15.5 29.5 28.5 18.8 28.6 14.7 21.6 28.2 29.8 23.3 30.8 29.7 33.7 24.8 28.4 33.3 33.3 29.5 33.8 26.6 29.7
      Ce 17.8 35.2 26.4 19.5 31.6 34.3 60.4 58.0 38.9 58.1 30.6 44.8 63.8 72.1 55.0 67.6 66.7 74.7 65.5 68.1 77.9 79.4 60.0 74.7 59.6 67.2
      Pr 2.31 4.36 3.10 2.72 4.16 4.32 7.18 6.86 4.71 6.77 3.76 5.35 8.05 9.75 7.05 8.72 7.89 8.97 7.04 8.46 9.70 9.40 7.76 8.61 7.69 7.72
      Nd 11.2 18.1 12.5 11.9 17.6 18.1 28.7 26.9 18.5 26.4 15.4 22.4 33.0 40.2 26.4 32.4 30.8 33.0 26.7 35.4 40.2 37.7 31.5 31.6 27.7 29.3
      Sm 2.92 4.20 2.72 3.39 4.47 4.31 6.45 5.66 3.83 5.42 3.63 5.10 8.14 9.58 5.97 7.18 6.83 6.66 6.73 8.43 9.02 8.93 7.68 7.24 6.64 6.90
      Eu 0.97 1.16 0.89 0.98 1.44 1.33 1.44 1.62 1.31 1.57 0.93 1.41 2.19 2.74 1.07 0.98 0.64 1.09 1.18 0.75 0.87 0.87 0.61 1.16 1.11 0.64
      Gd 3.20 3.94 2.79 3.72 4.96 4.71 5.48 5.17 3.94 5.60 3.56 4.66 8.54 10.85 6.48 8.03 8.06 7.25 7.19 8.46 9.39 9.65 7.57 7.53 7.20 7.58
      Tb 0.57 0.61 0.41 0.62 0.81 0.69 0.81 0.76 0.60 0.73 0.50 0.72 1.28 1.78 1.09 1.38 1.42 1.37 1.34 1.56 1.74 1.86 1.35 1.31 1.35 1.35
      Dy 3.32 3.70 2.19 4.18 5.30 3.91 4.79 4.54 3.47 4.54 2.90 4.24 8.02 10.60 7.24 9.13 9.43 8.25 8.17 9.71 10.60 12.20 8.76 8.79 8.78 8.53
      Ho 0.72 0.73 0.55 0.87 1.09 0.76 0.94 0.90 0.74 0.92 0.64 0.86 1.66 2.15 1.45 1.97 2.02 1.85 1.69 2.06 2.24 2.60 1.98 1.91 1.83 1.90
      Er 1.99 2.20 1.45 2.70 3.28 2.28 2.84 2.58 2.12 2.46 1.77 2.61 4.49 6.19 4.26 5.79 5.88 5.45 5.10 6.42 6.95 7.96 6.55 5.53 5.73 5.65
      Tm 0.30 0.34 0.28 0.36 0.48 0.73 0.44 0.43 0.35 0.39 0.27 0.39 0.68 0.94 0.72 0.94 0.94 0.94 0.83 1.06 1.12 1.34 1.05 0.82 0.88 0.88
      Yb 1.82 2.08 1.52 2.43 3.10 2.03 2.64 2.62 1.91 2.44 1.83 2.55 4.43 5.78 4.78 5.88 6.09 5.89 5.12 6.72 7.09 8.55 6.71 5.66 5.54 5.67
      Lu 0.33 0.32 0.22 0.40 0.49 0.29 0.45 0.40 0.27 0.35 0.29 0.40 0.68 0.83 0.67 0.81 0.86 0.85 0.82 1.05 1.19 1.34 1.13 0.90 0.89 0.82
      Y 18.1 19.7 12.5 24.7 29.9 22.2 26.4 26.7 19.8 26.7 16.8 23.1 46.1 62.5 39.9 54.6 54.4 51.0 46.4 55.6 61.3 69.4 54.6 54.2 54.1 53.7
      Rb 30.4 55.7 27.8 23.1 22.2 36.2 91.0 89.7 52.5 132.0 72.6 29.3 62.0 147.5 94.9 136.5 75.6 142.5 53.9 107.0 102.5 78.7 100.5 122.5 110.0 104.0
      Ba 702 1315 881 452 433 399 1635 1620 1785 1695 1325 565 561 1020 589 596 367 623 257 435 493 322 506 528 500 474
      Th 1.49 4.98 4.66 1.30 2.76 3.14 9.97 9.29 5.23 8.62 4.24 6.73 5.11 6.27 10.05 12.30 8.70 12.50 11.30 9.45 10.15 11.45 10.50 12.50 12.15 8.21
      U 0.46 1.56 1.54 0.37 0.88 1.17 3.22 3.08 1.37 2.91 1.46 2.13 2.26 2.06 4.05 3.65 2.80 4.20 3.80 2.61 3.06 3.38 3.36 3.21 3.57 3.06
      Nb 1.7 4.1 3.5 2.8 4.8 5.2 7.2 7.2 4.6 7.1 3.5 4.9 9.1 11.0 13.4 16.4 12.3 16.5 13.5 11.5 12.6 14.2 14.8 14.9 14.8 11.3
      Ta 0.1 0.3 0.4 0.2 0.4 0.6 0.5 0.6 0.5 0.6 1.0 0.4 0.6 0.9 1.2 1.4 1.2 1.5 1.2 1.0 1.1 1.3 1.2 1.1 1.0 1.3
      Zr 53 109 107 102 151 125 186 192 123 188 93 134 304 460 452 472 477 511 461 430 484 538 509 545 552 444
      Hf 1.6 2.9 2.7 2.6 4.1 3.0 4.7 4.6 3.1 4.4 2.4 3.4 7.6 9.9 10.8 11.5 11.3 12.2 11.1 11.3 11.8 14.0 12.4 13.6 13.9 10.4
      Sr 623 739 562 360 375 495 984 959 951 687 520 296 143.0 266 90.4 32.2 38.6 45.0 36.2 27.8 44.4 35.2 27.6 43.0 28.9 41.3
      Cr 170 90 580 160 110 30 50 40 110 30 120 10 10 20 20 10 60 40 70 20 10 90 80 20 10 20
      Ni 32.2 42.9 148.0 48.4 39.3 12.2 23.1 23.3 39.2 21.3 50.8 5.6 15.6 4.9 0.8 0.5 1.3 1.1 1.2 3.0 1.4 2.1 1.6 0.9 1.3 0.9
      Co 32.1 32.4 43.8 34.4 29.5 18.8 21.9 22.8 27.6 22.6 31.4 20.3 20.5 17.1 1.5 1.3 1.2 1.6 0.9 1.7 1.4 1.9 1.2 1.6 2.0 1.5
      V 304 301 351 287 288 212 330 335 273 309 218 317 163 187 27 10 20 12 <5 20 7 20 11 20 45 14
      Cs 1.60 2.40 4.47 0.82 2.34 1.36 3.25 3.17 1.09 2.08 1.22 0.30 0.90 0.76 0.83 0.76 0.37 0.65 0.25 0.46 0.31 0.47 0.36 0.52 0.33 0.45
      Pb 4.2 14.4 7.4 3.4 11.3 5.4 23.6 24.0 16.7 23.3 16.6 15.4 11.4 8.0 10.3 10.3 14.0 14.5 14.3 12.3 15.8 14.3 8.6 12.6 9.2 12.1
      Ti 5140 6130 5710 5450 7130 6700 7200 6850 5600 6460 4880 6510 9220 10000 1790 1750 1650 1910 1850 1600 1750 1970 1710 1970 2130 1530
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      表  3  东天山巴里坤地区晚石炭统二道沟组火山岩Sr-Nd同位素分析数据

      Table  3.   Analysis results of Sr-Nd isotopes of volcanic rocks from Late Carboniferous Erdaogou Formation in the Balikun area, eastern Tianshan

      岩性 基性火山岩 酸性火山岩
      年龄 312Ma 308Ma
      样品 12-7-2 12-6-3 9480-2 9480-6 8687-1 8687-2 7391-1 12-10-2 12-12-2 12-12-3
      87Rb/86Sr 0.218253 0.071330 0.185805 0.171424 0.141298 0.143238 0.211764 4.311508 11.145200 6.684823
      87Sr/86Sr 0.705002 0.704377 0.704741 0.704681 0.704656 0.704614 0.705246 0.721127 0.749926 0.732665
      (87Sr/86Sr)i 0.704033 0.704060 0.703916 0.703920 0.704029 0.703978 0.704306 0.702229 0.701075 0.703364
      (87Sr/86Sr)CHUR(t) 0.704133 0.704133 0.704133 0.704133 0.704133 0.704133 0.704133 0.704138 0.704138 0.704138
      147Sm/144Nd 0.140771 0.131657 0.172821 0.154077 0.158164 0.132008 0.144458 0.152914 0.144466 0.136120
      143Nd/144Nd 0.512801 0.512818 0.512952 0.512910 0.512781 0.512899 0.512809 0.512897 0.512927 0.512911
      εNd(t) 5.412316 6.107609 7.082188 7.009665 4.328323 7.674911 5.421479 6.779782 7.697956 7.714132
      TDM1Nd(Ga) 0.729979 0.617509 0.738810 0.614251 1.012592 0.469086 0.751172 0.635089 0.491713 0.470332
      TDM2Nd(Ga) 0.630504 0.573926 0.494141 0.500249 0.718391 0.446100 0.629715 0.515698 0.440889 0.439596
      注:误差为2σ.同位素校正公式:(87Sr/86Sr)i=(87Sr/86Sr)样品+87Rb/86Sr(eλt-1),λRb=1.42×10-11·a-1εNd(t)=[(143Nd/144Nd)样品/(143Nd/144Nd)CHUR(t)-1]×104,(143Nd/144Nd)CHUR(t)= 0.512638-0.1967×(eλt-1).λSm=6.54×10-12·a-1;亏损地幔的Sm-Nd同位素组成采用(143Nd/144Nd)CHUR=0.51315,(147Sm/144Nd)CHUR=0.2137.
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