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    胶北地块斜长角闪岩的岩石学与年代学研究

    陈爽 李旭平 段文勇 孙光明 冯庆达

    陈爽, 李旭平, 段文勇, 孙光明, 冯庆达, 2018. 胶北地块斜长角闪岩的岩石学与年代学研究. 地球科学, 43(3): 716-732. doi: 10.3799/dqkx.2018.903
    引用本文: 陈爽, 李旭平, 段文勇, 孙光明, 冯庆达, 2018. 胶北地块斜长角闪岩的岩石学与年代学研究. 地球科学, 43(3): 716-732. doi: 10.3799/dqkx.2018.903
    Chen Shuang, Li Xuping, Duan Wenyong, Sun Guangming, Feng Qingda, 2018. Petrological and Geochronological Study of Amphibolite from Jiaobei Terrane. Earth Science, 43(3): 716-732. doi: 10.3799/dqkx.2018.903
    Citation: Chen Shuang, Li Xuping, Duan Wenyong, Sun Guangming, Feng Qingda, 2018. Petrological and Geochronological Study of Amphibolite from Jiaobei Terrane. Earth Science, 43(3): 716-732. doi: 10.3799/dqkx.2018.903

    胶北地块斜长角闪岩的岩石学与年代学研究

    doi: 10.3799/dqkx.2018.903
    基金项目: 

    山东科技大学校创新团队项目 2015TDJH101

    国家自然科学基金项目 41272072

    国际(地区)合作与交流项目 41761144061

    详细信息
      作者简介:

      陈爽(1992-), 博士研究生, 矿物岩石学专业

      通讯作者:

      李旭平

    • 中图分类号: P597

    Petrological and Geochronological Study of Amphibolite from Jiaobei Terrane

    • 摘要: 胶北地块位于华北克拉通东部陆块,胶-辽-吉活动带的南端.胶北地区荆山杂岩中存在一组与高压基性麻粒岩密切共生的斜长角闪岩,是构成前寒武纪变质基底的重要组成部分.岩石学矿物学研究表明,斜长角闪岩记录了3个阶段的变质作用:峰期变质矿物组合(M1)为角闪石1+斜长石+榍石,根据NCKFMASHTO体系的成分视剖面图和角闪石压力计估算出温度条件T=660~715 ℃,压力条件P=0.65~0.71 GPa;其后经历了退变质作用(M2),矿物组合为角闪石2+绿帘石+斜长石+绿泥石+钠长石,估算温压条件为537~630 ℃/0.41~0.58 GPa;晚期发生前绿片岩相退变质作用(M3),其矿物组合为钠长石+葡萄石+绿泥石+方解石,其温压条件 < 400 ℃/0.35 GPa.斜长角闪石的CL图像显示其具有较弱的阴极发光效应和弱震荡环带,Th/U比值相对较小(0.06~0.43),锆石形态和内部结构指示锆石形成于深熔作用过程,21个锆石的LA-ICP-MS定年研究的结果表明,斜长角闪岩记录的最老206Pb/238U年龄为2 075±25 Ma,上交点年龄为1 845±23 Ma(MSWD=0.35),该组年龄记录了斜长角闪岩峰期变质作用时代的上限.斜长角闪岩在原岩形成以后,可能曾经历麻粒岩相变质作用,并记录了在胶-辽-吉带~1.85 Ga碰撞闭合过程中的深熔事件,此后经历了角闪岩相变质作用,及其二次退变质作用,终结于前绿片岩相的变质温压条件.

       

    • 图  1  (a) 胶东地区地质构造简图和研究区马连庄-河头店一带地质图及采样位置(b)

      a据周喜文等(2004)Tam et al.(2011)修改;b据李旭平等(2013)

      Fig.  1.  (a) Geological schematic map of the Jiaodong district; (b) geological map and sample localities in malianzhuang-hetoudian of study area

      图  2  胶北地块斜长角闪岩的显微结构照片

      a.样品09LY21的峰期(M1)角闪石颗粒较大(Amp1),可见三连点结构,与斜长石(Pl)共生(单偏光图像);b.样品09LY21背散射(BSE)图像;c.样品09LY23峰期后(M2)角闪石边缘发生退变质形成退变角闪石(Amp2),斜长石(Pl)开始退变质为钠长石(Ab)(单偏光图像);d.样品09LY23背散射(BSE)图像;e.样品09LY23中可见晚期(M3)出现葡萄石(Prh)脉体(单偏光图像);f.样品09LY23中斜长石(Pl)边缘浑圆,角闪石(Amp1)港湾状边缘(正交偏光图像);g.样品09LY23中可见晚期(M3)出现方解石(Cal)脉体,斜长石(Pl)完全退变质为钠长石(Ab)端元(正交偏光图像);h.样品09LY23中部分角闪石(Amp2)退变质为绿帘石(Ep),靠近方解石脉的斜长石均为钠长石(Ab)(背散射图像)

      Fig.  2.  Photomicrographs of amphibolite from Jiaobei terrane

      图  3  胶北地块斜长角闪岩中角闪石的Si-Mg/(Mg+Fe2+)成分分类图

      Leake et al.(1997)

      Fig.  3.  Si-Mg/(Mg+Fe2+) diagram of amphibole from amphibolites in the Jiaobei terrane

      图  4  胶北地块斜长角闪岩中角闪石的Al-Ti (a)和Ti-(Na+K)(b)成分图解

      靳是琴(1991)

      Fig.  4.  Amphibole chemistry from amphibolites in the Jiaobei terrane Al-Ti (a) diagram and Ti-(Na+K) (b) diagram

      图  5  胶北地块斜长角闪岩(09LY21)在NCKFMASHTO体系下的P-T视剖面

      图中矿物代号:Hb为角闪石;Bi为黑云母;Pl为斜长石;Ab为钠长石;Ep为绿帘石;Ttn为榍石;L为熔体;H为水,全岩成分分析是利用德国鲁尔大学矿物、地质、地球物理研究生化学实验室X-射线荧光光谱仪(Philips PW 1400)分析测定,在NCKFMASHTO体系标准化之后的摩尔百分比为:SiO2=51.85、Al2O3=8.51、CaO=11.28、MgO=11.77、FeO=11.37、K2O=0.59、Na2O=3.31、TiO2=0.72、O=0.51

      Fig.  5.  P-T pseudosections for the amphibolite sample (09LY21) from Jiaobei terrane in the systems of NCKFMASHTO

      图  6  样品09LY21锆石阴极发光图像和206Pb/238Pb年龄

      Fig.  6.  6Representative cathodoluminescence (CL) images of zircons from sample 09LY21 with 206Pb/238Pb ages

      图  7  样品09LY21中LA-ICP-MS锆石U-Pb年龄谐和图

      Fig.  7.  Concordia diagram of LA-ICP-MS zircons U-Pb ages from sample 09LY21

      图  8  样品09LY21锆石分析微区球粒陨石标准化稀土元素配分曲线

      Fig.  8.  Chondrite-normalized REE patterns of different zircons from the sample 09LY21

      图  9  样品09LY21锆石微量元素特征图解

      a.Eu/Eu*与年龄关系图解;b.∑REE与年龄关系图解; c.Ce/Ce*与年龄关系图解; d.锆石的Th, U含量和Th/U比值图解

      Fig.  9.  Trace elements and REE discrimination plots for zircon from the sample 09LY21

      图  10  胶北斜长角闪岩与胶-辽-吉带古元古代变质演化P-T-t轨迹图

      变质相边界桑隆康和马昌前(2012); Z.沸石相;P-P.葡萄石—绿纤石相;LA.硬柱石-钠长石-绿泥石相;BS.蓝片岩相;GS.绿片岩相;EA.绿帘角闪岩相;A.角闪岩相;G.麻粒岩相; 1.胶北高压泥质麻粒岩(周喜文等,2004);2.胶北高压泥质麻粒岩(王舫等,2010);3.胶北高压泥质麻粒岩(Tam et al., 2012a);4.胶北中压泥质麻粒岩(Tam et al., 2012b);5.胶北高压基性麻粒岩(Tam et al., 2012c);6.胶北高压基性麻粒岩(Liu et al., 2013);7.三家子石榴斜长角闪岩(刘平华等,2017);8.胶北斜长角闪岩(本文)

      Fig.  10.  P-T-t projection showing the P-T-t paths determined in this study for amphibolite (a and red bold lines), and previous metamorphic P-T-t paths depicted by other researchers from the Jiao-Liao-Ji belt

      表  1  胶北地块斜长角闪岩中角闪石化学成分(%)特征

      Table  1.   Amphibole compositions (%) in the amphibolites from Jiaobei terrane

      样品编号 09LY21 09LY23 09LY23
      Amp1 Amp1 Amp1 Amp1 Amp1 Amp1 Amp1 Amp1 Amp1 Amp1 Amp2 Amp2 Amp2 Amp2 Amp2
      SiO2 42.25 42.38 41.95 41.94 42.04 45.74 45.12 43.96 44.65 43.00 46.21 47.67 48.36 46.7 48.67
      TiO2 1.61 1.60 1.72 1.59 1.76 1.01 1.01 1.23 1.11 1.21 0.15 0.75 0.22 0.53 0.09
      Al2O3 11.16 11.29 11.42 11.46 11.41 8.42 9.07 9.93 10.08 10.28 7.67 7.46 5.72 7.83 5.68
      FeO 16.77 16.44 17.25 16.86 17.31 15.68 16.57 15.64 16.49 16.63 18.22 14.57 17.63 14.94 15.89
      MnO 0.33 0.34 0.37 0.32 0.36 0.37 0.34 0.31 0.32 0.32 0.34 0.32 0.39 0.36 0.31
      MgO 9.78 9.70 9.20 9.73 9.28 11.88 10.47 10.55 10.66 10.29 9.27 12.49 9.89 12.03 11.78
      CaO 11.35 11.54 11.35 11.35 11.29 11.19 11.49 11.47 12.1 11.61 11.84 11.76 11.87 11.71 12.08
      Na2O 1.7 1.56 1.58 1.65 1.60 1.14 1.35 1.33 1.27 1.34 1.19 1.08 0.91 1.01 0.87
      K2O 1.25 1.26 1.26 1.23 1.25 0.70 0.72 0.99 0.90 1.04 0.29 0.52 0.21 0.53 0.19
      Sum 96.20 96.11 96.10 96.13 96.30 96.13 96.14 95.41 97.58 95.72 95.18 96.62 95.20 95.64 95.56
      Oxygens 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23
      Si 6.47 6.48 6.45 6.43 6.45 6.90 6.84 6.71 6.69 6.60 7.11 7.09 7.38 7.04 7.34
      Al 1.53 1.52 1.55 1.57 1.55 1.10 1.16 1.29 1.31 1.40 0.89 0.91 0.62 0.96 0.66
      Al 0.49 0.52 0.52 0.50 0.51 0.39 0.47 0.50 0.47 0.46 0.50 0.39 0.41 0.43 0.35
      Ti 0.19 0.18 0.20 0.18 0.20 0.11 0.12 0.14 0.13 0.14 0.02 0.08 0.03 0.06 0.01
      Fe3+ 0.29 0.33 0.32 0.29 0.32 0.52 0.50 0.45 0.43 0.37 0.61 0.62 0.76 0.59 0.71
      Fe2+ 1.86 1.77 1.89 1.88 1.9 1.45 1.60 1.54 1.63 1.77 1.73 1.19 1.49 1.29 1.29
      Mn 0.04 0.04 0.05 0.04 0.05 0.05 0.04 0.04 0.04 0.04 0.04 0.04 0.05 0.05 0.04
      Mg 2.23 2.21 2.11 2.23 2.12 2.67 2.37 2.40 2.38 2.35 2.13 2.77 2.25 2.70 2.65
      Ca 1.86 1.89 1.87 1.87 1.86 1.81 1.87 1.88 1.94 1.91 1.95 1.87 1.94 1.89 1.95
      Na 0.50 0.46 0.47 0.49 0.47 0.33 0.40 0.39 0.37 0.40 0.36 0.31 0.27 0.29 0.25
      K 0.24 0.25 0.25 0.24 0.25 0.13 0.14 0.19 0.17 0.20 0.06 0.10 0.04 0.10 0.04
      Mg/(Mg+Fe) 0.55 0.56 0.53 0.54 0.53 0.65 0.60 0.61 0.59 0.57 0.55 0.70 0.60 0.68 0.67
      下载: 导出CSV

      2  胶北地块斜长角闪岩中代表性矿物化学成分(%)特征

      2.   Representative mineral compositions (%) in the amphibolites from Jiaobei terrane

      样品 09LY23 09LY21
      矿物点数 钠长石 斜长石 绿帘石 绿帘石 绿泥石 葡萄石 斜长石 绿帘石 榍石
      5 3 2 2 2 2 3 2 1
      SiO2 65.18 64.09 37.36 38.40 25.70 42.92 64.74 37.22 30.87
      TiO2 0.03 0.07 0.23 0.19 0.06 0.04 0.02 0.27 36.83
      Al2O3 20.79 22.49 27.14 27.24 19.20 28.12 24.09 26.64 1.90
      Cr2O3 0.01 0.01 0.01 0.00 0.01 0.00 0.01 0.00 0.02
      Fe2O3 0.07 0.12 7.66 8.21 1.17 0.14 0.20 8.29 0.00
      FeO 0.00 0.00 0.99 0.07 23.50 0.00 0.00 1.50 0.52
      MnO 0.00 0.00 0.24 0.17 0.28 0.01 0.00 0.51 0.05
      MgO 0.01 0.01 0.00 0.03 15.47 0.01 0.03 0.06 0.02
      CaO 1.31 2.96 23.57 23.72 0.16 18.20 3.94 22.84 29.19
      Na2O 11.36 8.91 0.08 0.05 0.27 2.49 8.44 0.11 0.03
      K2O 0.09 0.07 0.01 0.00 0.07 0.08 0.12 0.03 0.01
      Totals 98.84 98.73 97.29 98.08 85.88 92.01 101.59 97.46 99.44
      Oxygens 8.00 8.00 12.50 12.50 14.00 11.00 8.00 12.50 5.00
      Si 2.90 2.85 2.95 3.00 2.76 2.99 2.80 2.95 1.01
      Al 0.00 0.00 0.01 0.01 0.00 0.00 0.00 0.02 0.07
      Ti 1.09 1.18 2.53 2.51 2.43 2.31 1.23 2.49 0.91
      Cr 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
      Fe3+ 0.00 0.00 0.46 0.48 0.09 0.01 0.01 0.50 0.00
      Mg 0.00 0.00 0.07 0.01 2.11 0.00 0.00 0.10 0.00
      Fe2+ 0.00 0.00 0.02 0.01 0.03 0.00 0.00 0.03 0.01
      Mn 0.00 0.00 0.00 0.00 2.48 0.00 0.00 0.01 0.00
      Na 0.98 0.77 2.00 1.98 0.02 1.36 0.71 1.94 0.00
      Ca 0.06 0.14 0.01 0.01 0.06 0.34 0.18 0.02 1.03
      K 0.01 0.00 0.00 0.00 0.01 0.01 0.01 0.00 0.00
      Sum 5.04 4.95 8.05 8.00 10.00 7.02 4.94 8.05 3.04
      An 5.94 15.44 20.35
      Ab 93.55 84.12 78.94
      下载: 导出CSV

      表  3  胶北斜长角闪岩(09LY21、09LY23)温压估算结果

      Table  3.   P-T estimates for amphibolite(09LY21、09LY23)in Jiaobei terrane

      样品号 样品 SiHb Xab KD LnKD AlHbT T(℃) P(GPa)
      Amp1 6.473 0.79 1.295 0.259 2.015 715.316 0.658
      Amp1 6.485 0.79 1.312 0.272 2.037 711.444 0.668
      09LY21 Amp1 6.449 0.79 1.263 0.234 2.068 716.084 0.683
      Amp1 6.433 0.79 1.242 0.216 2.072 718.967 0.685
      Amp1 6.448 0.79 1.262 0.232 2.063 716.692 0.681
      Amp1 6.896 0.85 2.36 0.859 1.496 650.188 0.411
      Amp1 6.845 0.85 2.216 0.796 1.621 651.864 0.471
      09LY23 Amp1 6.713 0.85 1.898 0.641 1.787 665.453 0.55
      Amp1 6.69 0.85 1.847 0.614 1.779 670.396 0.546
      Amp1 6.597 0.85 1.667 0.511 1.859 682.051 0.584
      Amp2 7.043 0.97 3.179 1.157 1.480 607.684 0.403
      Amp2 7.087 0.97 3.38 1.218 1.307 609.695 0.321
      09LY23 Amp2 7.38 0.97 5.456 1.697 1.029 563.795 0.189
      Amp2 7.037 0.97 3.152 1.148 1.391 614.334 0.361
      Amp2 7.339 0.97 5.052 1.620 1.010 574.368 0.180
      注:温度计算采用Blundy and Holland(1990),压力计算采用Schmidt(1992).
      下载: 导出CSV

      表  4  胶北地块斜长角闪岩锆石(09LY21)LA-ICP-MS U-Pb分析结果

      Table  4.   LA-ICP-MS zircon U-Pb dating data from amphibolite (09LY21) in Jiaobei terrane

      测点号 Th (10-6) U (10-6) Th/U 206Pb/238U ±(%) 207Pb/235U ±(%) 207Pb/206Pb ±(%) 206Pb/238U σ 207Pb/235U σ 207Pb/206Pb σ
      1 2 492 3 464 0.72 0.379 7 1.4 6.706 2 1.5 0.128 0 3.0 2 075 25 2 073 13 2 071 52
      2 153 854 0.18 0.304 0 1.5 4.833 3 2.1 0.115 3 3.3 1 711 23 1 791 18 1 884 59
      3 1 934 4 477 0.43 0.346 6 1.4 5.597 3 1.4 0.117 1 3.0 1 918 23 1 916 12 1 912 53
      4 70 463 0.15 0.331 0 1.4 5.277 0 1.6 0.115 6 3.1 1 843 23 1 865 14 1 889 54
      5 257 990 0.26 0.311 3 2.5 4.592 3 4.6 0.106 9 5.2 1 747 38 1 748 39 1 748 93
      8 119 692 0.17 0.332 2 1.4 5.183 2 1.4 0.113 1 3.0 1 849 22 1 850 12 1 850 53
      9 645 2 483 0.26 0.277 4 1.3 4.371 5 1.3 0.114 3 2.9 1 578 19 1 707 11 1 869 52
      10 87 521 0.17 0.333 8 1.4 5.221 1 1.4 0.113 4 3.0 1 857 22 1 856 12 1 855 53
      13 160 1 019 0.16 0.332 2 1.3 5.179 5 1.3 0.113 1 2.9 1 849 21 1 849 11 1 849 52
      14 72 531 0.13 0.322 6 1.3 5.006 0 1.4 0.112 5 3.0 1 802 21 1 820 12 1 841 53
      15 72 630 0.11 0.327 2 1.4 5.031 1 1.5 0.111 5 3.0 1 825 22 1 825 13 1 824 53
      16 73 583 0.13 0.326 6 1.3 5.020 6 1.4 0.111 5 3.0 1 822 21 1 823 12 1 824 53
      17 76 495 0.15 0.324 3 1.4 4.990 9 1.4 0.111 6 3.0 1 811 21 1 818 12 1 826 53
      18 80 578 0.14 0.337 8 1.6 5.379 2 2.2 0.115 5 3.4 1 876 26 1 882 19 1 887 60
      22 309 1 098 0.28 0.327 4 1.3 5.031 8 1.3 0.111 5 2.9 1 826 21 1 825 11 1 823 52
      25 94 698 0.13 0.330 5 1.3 5.141 1 1.3 0.112 8 2.9 1 841 21 1 843 11 1 845 52
      26 284 1 163 0.24 0.331 2 1.3 5.138 2 1.3 0.112 5 2.9 1 844 21 1 842 11 1 840 52
      27 502 8 560 0.06 0.329 3 1.3 5.094 5 1.3 0.112 2 2.9 1 835 21 1 835 11 1 836 51
      28 1 162 6 966 0.17 0.328 5 1.3 5.083 2 1.3 0.112 2 2.9 1 831 21 1 833 11 1 836 51
      29 139 808 0.17 0.326 2 1.3 5.006 0 1.3 0.111 3 2.9 1 820 21 1 820 11 1 821 52
      30 96 671 0.14 0.321 3 1.3 4.860 9 1.4 0.109 7 2.9 1 796 21 1 796 12 1 795 52
      下载: 导出CSV

      表  5  胶北地块斜长角闪岩锆石(09LY21)LA-ICP-MS稀土元素和微量元素测试结果(10-6)

      Table  5.   LA-ICP-MS zircon REE and mean trace-element data from amphibolite (09LY21) in Jiaobei terrane

      测点号 Y Nb La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Hf Ta ∑REE Lu/Hf Eu/Eu* Ce/Ce* (La/Yb)N (La/Sm)N (Gd/Yb)N
      1 896.26 6.89 5.930 37.33 4.360 30.30 11.36 42.820 26.73 4.99 50.27 20.36 108.95 28.76 347.04 75.96 10 240.90 4.680 795 0.007 4 7.23 1.72 0.012 26 0.337 0 0.063 7
      2 803.52 4.04 2.100 22.20 1.421 10.44 5.08 12.180 16.64 4.98 59.37 24.03 114.76 26.00 268.41 53.84 9 139.18 1.544 621 0.005 9 3.68 3.05 0.005 61 0.266 9 0.051 3
      3 1 039.40 6.69 8.460 39.92 4.340 25.03 9.59 75.62 20.61 5.00 56.85 24.55 140.50 39.23 494.88 103.04 11 184.80 3.330 1 048 0.009 2 16.00 1.60 0.012 26 0.569 5 0.034 5
      4 476.81 1.94 0.056 8.82 0.065 0.36 1.07 1.070 6.08 2.92 36.69 15.46 76.73 17.37 188.11 36.54 9 612.42 1.088 391 0.003 8 1.01 31.31 0.000 21 0.033 8 0.026 7
      5 486.96 2.53 1.553 14.53 0.900 5.92 2.58 13.24 8.76 2.82 34.75 14.55 73.01 17.80 196.21 38.31 9 994.19 1.589 425 0.003 8 7.67 2.96 0.005 68 0.388 6 0.036 9
      8 1 205.55 2.87 0.040 12.69 0.053 0.80 2.23 0.618 15.36 6.97 91.29 38.66 192.59 43.32 452.66 90.09 8 542.40 1.125 947 0.010 5 0.24 57.07 0.000 06 0.011 6 0.028 1
      9 2 183.22 11.68 7.720 76.47 6.380 38.20 16.63 14.48 47.52 14.82 173.80 67.13 302.14 65.15 648.09 123.50 9 513.55 5.390 1 602 0.013 0 1.47 2.51 0.008 54 0.299 7 0.060 7
      10 683.12 3.48 2.090 17.56 0.976 5.03 2.17 2.130 10.18 3.89 52.50 21.66 106.15 24.44 253.41 49.40 8 815.19 1.630 552 0.005 6 1.15 3.01 0.005 92 0.621 8 0.033 2
      13 1 255.94 3.58 0.130 14.94 0.199 2.41 2.93 1.140 17.53 7.38 95.88 39.32 192.06 43.54 451.31 89.52 8 854.67 1.364 958 0.010 1 0.38 18.47 0.000 21 0.028 6 0.032 1
      14 663.97 2.20 0 9.05 0.034 0.44 1.46 0.444 10.01 4.06 52.00 21.20 102.27 23.77 250.83 50.39 8 959.63 0.951 526 0.005 6 0.26 82.64 0 0 0.033 0
      15 631.57 1.95 0.031 8.90 0.033 0.68 1.48 0.570 11.35 4.09 50.69 20.13 97.41 22.25 239.10 46.83 9 011.79 1.260 504 0.005 2 0.30 60.83 0.000 09 0.013 5 0.039 3
      16 571.47 1.74 0 9.27 0.023 0.56 1.70 0.424 9.89 4.06 46.29 18.50 87.24 19.56 208.52 41.24 8 707.77 0.988 447 0.004 7 0.25 125.13 0 0 0.039 2
      17 716.62 1.99 0 9.31 0.025 0.42 1.83 0.456 12.49 4.57 56.26 23.15 111.07 25.80 267.63 54.41 8 347.96 1.126 567 0.006 5 0.22 115.61 0 0 0.038 6
      18 729.30 2.10 0.341 9.88 0.044 0.65 1.90 0.469 12.13 4.50 57.07 23.23 112.34 25.77 273.43 54.50 9 074.33 1.006 576 0.006 0 0.23 16.98 0.000 89 0.115 9 0.036 7
      22 778.78 3.33 1.053 14.29 0.033 0.39 1.72 0.253 11.33 4.52 59.06 23.96 116.42 27.04 281.43 56.10 10 141.30 2.480 598 0.005 5 0.13 9.75 0.002 68 0.395 2 0.033 3
      25 905.36 3.23 0.656 11.49 0.258 1.54 1.79 0.539 12.00 5.21 68.45 29.07 143.97 33.40 343.88 69.16 10 769.70 2.040 721 0.006 4 0.27 6.85 0.001 37 0.236 6 0.028 9
      26 1 554.97 6.35 0.329 24.19 0.307 2.95 4.19 1.150 24.08 9.51 122.14 50.44 238.31 52.63 526.29 102.32 8 983.52 2.060 1 159 0.011 4 0.27 17.11 0.000 45 0.050 7 0.037 9
      27 720.19 3.47 0.925 6.88 0.564 4.33 3.81 2.300 15.21 5.02 56.08 20.56 92.63 20.42 205.60 37.53 7 314.13 1.870 472 0.005 1 0.80 2.28 0.003 23 0.156 7 0.061 2
      28 3 104.76 29.68 3.620 54.77 2.800 20.72 14.67 20.660 58.31 20.05 244.33 94.93 449.34 102.61 1075.63 196.70 11 053.50 15.240 2 359 0.017 8 1.88 4.00 0.002 41 0.159 3 0.044 8
      29 1 265.33 4.50 0.037 14.55 0.051 0.77 2.36 0.736 16.72 7.20 95.13 40.16 196.53 44.70 464.46 91.96 8 938.02 1.577 975 0.010 3 0.26 68.62 0.000 06 0.010 1 0.029 8
      30 1 007.91 2.98 0.131 10.91 0.068 0.87 2.11 0.610 13.79 5.81 77.21 32.29 158.11 36.06 376.80 72.03 8 838.76 1.369 787 0.008 1 0.26 28.11 0.000 25 0.040 1 0.030 3
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