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    东天山铜鱼梁铜矿区闪长玢岩SHRIMP锆石U-Pb年代学、岩石地球化学及其地质意义

    孙志远 龙灵利 王玉往 罗照华 赵路通 武承贺

    孙志远, 龙灵利, 王玉往, 罗照华, 赵路通, 武承贺, 2018. 东天山铜鱼梁铜矿区闪长玢岩SHRIMP锆石U-Pb年代学、岩石地球化学及其地质意义. 地球科学, 43(9): 3001-3017. doi: 10.3799/dqkx.2018.997
    引用本文: 孙志远, 龙灵利, 王玉往, 罗照华, 赵路通, 武承贺, 2018. 东天山铜鱼梁铜矿区闪长玢岩SHRIMP锆石U-Pb年代学、岩石地球化学及其地质意义. 地球科学, 43(9): 3001-3017. doi: 10.3799/dqkx.2018.997
    Sun Zhiyuan, Long Lingli, Wang Yuwang, Luo Zhaohua, Zhao Lutong, Wu Chenghe, 2018. SHRIMP Zircon U-Pb Geochronology and Geochemistry of Diorite Porphyrite in Tongyuliang Copper Deposit, Eastern Tianshan and Its Geological Significance. Earth Science, 43(9): 3001-3017. doi: 10.3799/dqkx.2018.997
    Citation: Sun Zhiyuan, Long Lingli, Wang Yuwang, Luo Zhaohua, Zhao Lutong, Wu Chenghe, 2018. SHRIMP Zircon U-Pb Geochronology and Geochemistry of Diorite Porphyrite in Tongyuliang Copper Deposit, Eastern Tianshan and Its Geological Significance. Earth Science, 43(9): 3001-3017. doi: 10.3799/dqkx.2018.997

    东天山铜鱼梁铜矿区闪长玢岩SHRIMP锆石U-Pb年代学、岩石地球化学及其地质意义

    doi: 10.3799/dqkx.2018.997
    基金项目: 

    国家重点基础发展研究计划(973计划)项目 2014CB440803

    国家自然科学基金项目 41202046

    中国地质调查局项目 12120113086300

    详细信息
      作者简介:

      孙志远(1989-), 男, 博士, 主要从事矿产普查与勘探方面的研究.E-mail:sunzhiyuan010@163.com

    • 中图分类号: P611;P629;P632

    SHRIMP Zircon U-Pb Geochronology and Geochemistry of Diorite Porphyrite in Tongyuliang Copper Deposit, Eastern Tianshan and Its Geological Significance

    • 摘要: 位于新疆东天山阿齐山-雅满苏成矿带东段的铜鱼梁矿床是近年来新发现的铜矿点,但带内热液型铜矿的研究和找矿勘查程度不高,通过SHRIMP锆石U-Pb定年获得矿区与成矿密切相关的闪长玢岩年龄为317.7±2.4 Ma,表明矿区在晚石炭世可能存在重要的岩浆-成矿事件.通过岩石地球化学特征研究可得铜鱼梁闪长玢岩SiO2含量为56.71%~66.03%,Mg#=49.75~55.29,Na2O+K2O=5.15%~6.40%,Na2O/K2O=4.49~53.62,铝指数A/CNK=0.9~1.1,为富钠、准铝质-过铝质、低钾(拉斑)系列岩石.稀土总量较低(39.56×10-6~60.60×10-6),具有轻稀土富集、重稀土亏损的右倾配分模式,富集Ba、U、K、Sr等大离子亲石元素(LILE),亏损Nb、Ta、Ti高场强元素(HFSE),显示弧岩浆的特征.闪长玢岩(87Sr/86Sr)i变化于0.704 030~0.704 413之间,εNdt)=1.02~6.42,具有低的锶同位素初始值和正的εNdt)值,表明其岩浆源区主要来源于亏损地幔源区.综合已有资料,认为研究区闪长玢岩形成于岛弧的构造背景,为石炭世古康古尔洋壳向南俯冲的流体交代地幔后的产物.至晚石炭世早期,古康古尔洋俯冲交代,在上升中富含铜金属元素的岩浆流体当运移到浅部时,次火山岩通过交代岩体本身或火山地层形成了铜鱼梁铜矿床.

       

    • 图  1  中亚造山带构造简图(a)和东天山地区地质矿产简图(b)

      图a据Jahn et al.(2000);图b据王京彬等(2006)

      Fig.  1.  Tectonic sketch of the Central Asian orogenic belt (a) and geological sketch and deposits distribution in the eastern Tianshan (b)

      图  2  铜鱼梁矿区地质简图

      Fig.  2.  Geological sketch of Tongyuliang ore district

      图  3  铜鱼梁矿区52勘探线剖面

      Fig.  3.  The profile of No.52 exploration line in Tongyuliang ore district

      图  4  铜鱼梁铜矿地表探槽及钻孔矿化特征

      Mal.孔雀石;Bn.斑铜矿;Ccp.黄铜矿

      Fig.  4.  The mineralized characteristics of the exploratory trench and drillhole in Tongyuliang copper deposit

      图  5  铜鱼梁闪长玢岩手标本及镜下显微照片

      Hbl.普通角闪石;Pl.斜长石;Chl.绿泥石;Mt.磁铁矿

      Fig.  5.  The hand specimens and photomicrographs of diorite porphyrite in Tongyuliang ore district

      图  6  闪长玢岩锆石U-Pb谐和年龄和CL图像

      Fig.  6.  SHRIMP zircon U-Pb concordia diagram and zircon CL images of diorite porphyrite

      图  7  铜鱼梁矿区闪长玢岩Nb/Y-Zr/TiO2图解(a)、SiO2-K2O图解(b)、Na2O-K2O图解(c)和A/CNK-A/NK图解(d)

      图a据Winchester and Floyd(1977);图b据Ringwood(1975);图c据Middlemost(1972);图d据Maniar and Piccoli(1989)

      Fig.  7.  Nb/Y-Zr/TiO2 diagram (a), SiO2-K2O diagram (b), Na2O-K2O diagram (c) and A/CNK-A/NK diagram (d) of the diorite porphyrite in Tongyuliang ore district

      图  8  闪长玢岩稀土元素球粒陨石标准化曲线(a)和微量元素原始地幔标准化曲线(b)图解

      标准数值据Sun and McDonough(1989)

      Fig.  8.  Chondrite normalized REE diagram (a) and primitive mantle normalized trace elements spider diagram (b) of the diorite porphyrite in Tongyuliang ore district

      图  9  铜鱼梁闪长玢岩εNd(t)-(87Sr/86Sr)i图解

      Zindler and Hart(1986)

      Fig.  9.  εNd(t)-(87Sr/86Sr)i diagram for the diorite porphyrite

      图  10  铜鱼梁闪长玢岩Y-Sr/Y(a)、Rb/30-Hf-3Ta(b)、Y-Nb(c)和(Y+Nb)-Rb(d)构造环境判别图

      图a据Defant and Drummond(1990);图b据Harris et al.(1986);图c据Pearce et al.(1984);图d据Pearce et al.(1984)

      Fig.  10.  The tectonic setting discrimination diagrams of Y-Sr/Y (a), Rb/30-Hf-3Ta (b), Y-Nb (c) and (Y+Nb)-Rb (d) for the diorite porphyrite in Tongyuliang ore district

      图  11  铜鱼梁闪长玢岩Rb/Y-Nb/Y和Nb/Zr-Th/Zr图解

      Kepezhinskas et al.(1997)

      Fig.  11.  Rb/Y-Nb/Y and Nb/Zr-Th/Zr diagrams of the diorite porphyrite in Tongyuliang ore district

      图  12  石炭世雅满苏岛弧带构造演化-成矿模式

      Fig.  12.  The model for the setting evolution and mineralization of Aqishan-Yamansu island arc belt during Carboniferous

      表  1  铜鱼梁闪长玢岩SHRIMP锆石U-Pb同位素分析结果

      Table  1.   SHRIMP zircons U-Pb isotopic data of diorite porphyrite from Tongyuliang copper deposit

      测试点 含量(10-6) Th/U 同位素比值 年龄(Ma)
      206Pbc Th U 207Pb/206Pb ±% 207Pb/235U ±% 206Pb/238U ±% 206Pb/238U 1σ 207Pb/206Pb 1σ 208Pb/232Th 1σ
      J4723-10-1.1 2.42 115 263 0.4377 0.0517 4.7 0.355 4.8 0.04973 1.1 317.3 3.5 725 73 329 10
      J4723-10-2.1 4.67 67 140 0.4815 0.0270 57 0.180 57 0.04890 2.3 316.0 5.6 185 452 283 53
      J4723-10-3.1 4.35 87 192 0.4521 0.0460 24 0.314 24 0.04920 1.8 315.5 4.8 680 254 344 39
      J4723-10-4.1 3.14 148 281 0.5266 0.0506 17 0.351 17 0.05039 1.5 321.0 4.0 653 194 355 31
      J4723-10-5.1 5.62 65 126 0.5207 0.0420 40 0.280 40 0.04850 2.4 314.6 5.6 834 317 353 46
      J4723-10-6.1 5.08 67 159 0.4208 0.0240 58 0.158 58 0.04870 2.6 314.0 7.2 -74 534 246 60
      J4723-10-7.1 3.21 222 258 0.8602 0.0551 13 0.380 13 0.05000 1.4 319.0 3.8 831 132 336 13
      J4723-10-8.1 6.81 65 100 0.6479 - - - - 0.04800 4.2 313.9 9.0 - - 282 77
      J4723-10-9.1 3.14 242 241 1.0071 0.0443 19 0.307 19 0.05028 1.5 320.9 4.1 481 240 301 15
      J4723-10-10.1 5.66 89 116 0.7698 0.0330 49 0.230 49 0.04980 2.4 323.6 5.9 654 328 313 33
      J4723-10-11.1 7.82 95 121 0.7827 0.0320 67 0.220 67 0.04990 2.8 322.9 7.0 497 624 327 49
      J4723-10-12.1 3.49 112 155 0.7197 0.0340 36 0.234 37 0.05021 1.9 323.3 4.9 362 332 302 29
      J4723-10-13.1 1.50 111 373 0.2978 0.0367 19 0.252 19 0.04984 1.3 316.6 3.7 -57 278 263 44
      J4723-10-14.1 0.47 69 1119 0.0614 0.0519 3.2 0.362 3.4 0.05067 1.1 319.6 3.5 394 38 346 30
      J4723-10-14.1 0.89 521 475 1.0959 0.0508 7 0.349 7.1 0.04979 1.1 315.6 3.0 495 71 310 5
      J4723-10-16.1 4.84 77 129 0.5953 0.0310 53 0.200 53 0.04650 2.4 301.4 5.4 430 403 300 41
      注:Pbc代表普通铅;“-”表示未检出.
      下载: 导出CSV

      表  2  铜鱼梁铜矿区闪长玢岩主量(%)、稀土和微量元素(10-6)地球化学数据

      Table  2.   Major elements (%), trace elements and rare earth elements (10-6) compositions of the diorite porphyrite in Tongyuliang copper deposit

      样品 ZK5201-18 ZK5201-23 J4723-5 J4723-6 J4723-10 J4723-16 J4723-17
      SiO2 57.14 64.48 56.71 66.03 61.63 61.66 61.20
      TiO2 0.92 0.44 0.68 0.37 0.55 0.45 0.45
      Al2O3 17.88 16.05 18.58 16.32 16.55 16.59 16.76
      Fe2O3 7.09 4.22 6.47 3.72 5.14 4.81 4.95
      FeO 4.30 2.33 2.97 1.57 2.48 2.69 2.61
      MnO 0.11 0.07 0.13 0.07 0.08 0.08 0.08
      MgO 4.12 2.33 4.04 1.87 3.16 2.73 2.82
      CaO 4.15 4.67 4.07 3.40 5.22 4.98 3.97
      Na2O 4.57 4.39 5.75 5.97 4.53 5.63 5.61
      K2O 0.63 0.76 0.46 0.33 1.01 0.11 0.79
      P2O5 0.20 0.13 0.17 0.11 0.14 0.13 0.14
      LOI 3.16 2.41 2.91 1.78 1.96 2.70 3.18
      TOTAL 104.27 102.29 102.93 101.55 102.44 102.55 102.55
      Na2O/K2O 7.22 5.81 12.64 18.37 4.49 53.62 7.07
      MgO# 49.75 49.79 55.29 50.92 54.27 50.30 51.20
      La 8.60 7.88 7.40 6.04 8.68 7.71 7.75
      Ce 20.20 18.80 16.90 13.60 19.80 17.60 17.60
      Pr 2.89 2.59 2.42 1.88 2.87 2.51 2.47
      Nd 13.60 11.70 11.30 8.43 13.10 11.20 11.40
      Sm 3.26 2.67 2.69 2.01 2.93 2.66 2.64
      Eu 1.19 0.93 1.08 0.67 1.04 0.90 0.92
      Gd 2.88 2.36 2.27 2.12 2.43 2.19 2.12
      Tb 0.56 0.44 0.46 0.32 0.45 0.40 0.42
      Dy 3.10 2.22 2.71 1.68 2.39 1.97 2.02
      Ho 0.57 0.43 0.57 0.36 0.44 0.44 0.46
      Er 1.52 1.25 1.34 0.96 1.40 1.13 1.34
      Tm 0.27 0.19 0.25 0.15 0.21 0.20 0.21
      Yb 1.74 1.46 1.58 1.16 1.32 1.27 1.43
      Lu 0.21 0.16 0.25 0.17 0.20 0.22 0.20
      Y 16.70 13.40 14.80 10.50 12.90 12.70 13.80
      ∑REE 60.60 53.07 51.21 39.56 57.26 50.39 50.98
      LaN/YbN 3.55 3.87 3.36 3.73 4.72 4.35 3.89
      δEu 1.16 1.10 1.30 0.99 1.16 1.10 1.15
      Rb 11.00 16.10 6.88 5.24 12.30 2.27 17.20
      Ba 143.00 83.80 60.30 173.00 269.00 53.40 159.00
      Th 0.95 1.21 0.91 0.73 1.17 1.04 1.05
      U 0.80 0.98 0.39 0.58 0.61 0.49 0.55
      Nb 3.14 1.65 1.76 1.34 1.28 1.34 1.15
      Ta 0.23 0.13 0.15 0.09 0.11 0.07 0.11
      Pb 3.50 4.28 7.22 10.90 6.47 10.60 4.98
      Sr 201.00 327.00 461.00 496.00 591.00 517.00 849.00
      Zr 121.00 151.00 94.70 135.00 132.00 149.00 163.00
      Hf 3.49 4.14 2.48 3.66 3.71 4.19 4.58
      Sc 14.60 8.74 13.80 7.32 13.60 10.20 10.60
      Sb 0.26 0.12 0.14 0.19 0.05 0.63 0.26
      Cs 0.86 1.44 1.80 0.88 0.72 0.46 0.83
      注:LaN/YbN为球粒陨石标准化值,标准化值据Sun and McDonough(1989).
      下载: 导出CSV

      表  3  铜鱼梁铜矿区闪长玢岩Rb、Sr、Sm、Nd同位素分析数据

      Table  3.   Sr and Nd isotope data of the diorite porphyrite in Tongyuliang copper deposit

      样品号 Rb(10-6) Sr(10-6) 87Rb/86Sr 87Sr/86Sr 2σ Sm(10-6) Nd(10-6) 147Sm/144Nd 143Nd/144Nd 2σ (87Sr/86Sr)i εNd(t)
      ZK5201-18 13.003 6 224 0.168 3 0.704 789 0.000 010 3.168 13.569 4 0.141 1 0.512 575 0.000 007 0.704 03 1.02
      J4723-5 8.373 0 525 0.046 2 0.704 499 0.000 013 2.803 11.817 0 0.143 4 0.512 592 0.000 011 0.704 29 1.26
      J4723-10 12.825 2 578 0.064 2 0.704 703 0.000 013 2.764 12.187 1 0.137 1 0.512 843 0.000 008 0.704 41 6.42
      注:年龄按照t=318Ma计算.
      下载: 导出CSV
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    • 收稿日期:  2018-03-20
    • 刊出日期:  2018-09-15

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