鄂尔多斯盆地伊陕斜坡东北部马家沟组马五<sub>5</sub>亚段白云岩地球化学特征及其成因

于春勇; 崔军平

doi:10.3799/dqkx.2019.954

鄂尔多斯盆地伊陕斜坡东北部马家沟组马五₅亚段白云岩地球化学特征及其成因

doi: 10.3799/dqkx.2019.954

于春勇,
崔军平^,

西北大学大陆动力学国家重点实验室, 陕西西安 710069

基金项目:

国家自然科学基金重点项目 41630312

国家重点研发计划课题 2017YFC0603106

“十三五”国家重大专项 2017ZX05005002-008

国家自然科学基金面上项目 41772121

详细信息

作者简介:
于春勇(1989-), 男, 博士, 从事盆地热演化及碳酸盐岩沉积、储层等方面研究工作

通讯作者:
崔军平

中图分类号: P54;P58;P59
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出版历程
- 收稿日期: 2018-12-11
- 刊出日期: 2019-08-15

Geochemical Characteristics and Genesis of Dolomite in Majiagou Ma₅⁵ Submember of the Northeast Yishan Slope, Ordos Basin

Yu Chunyong,
Cui Junping^,

State Key Laboratory for Continental Dynamics, Northwest University, Xi'an 710069, China

摘要

摘要: 鄂尔多斯盆地伊陕斜坡东北部奥陶系马家沟组马五₅亚段优质白云岩储层发育，多口井在该层系钻获高产工业气流，展现出巨大的天然气勘探潜力，而关于该层系白云岩储层的成因机理至今未达成共识.为此，在岩石学特征分析基础上，通过对白云岩碳、氧、锶同位素及微量元素等测试资料的系统分析，深入探讨了鄂尔多斯盆地伊陕斜坡东北部马五₅亚段白云岩的成因机理.结果表明：研究区马五₅亚段主要发育泥、粉细晶白云岩和豹斑灰云岩3种类型，前者主要发育于马五₅亚段底部，后两者主要发育于马五微晶白云岩₅亚段中上部，是主要的天然气储集体；粉细晶白云岩和豹斑灰云岩白云石有序度均较低，平均值分别为0.86、0.68，δ¹³C值多数与同期海水一致，δ¹⁸O值均显著偏负；多数粉细晶白云岩⁸⁷Sr/⁸⁶Sr值较同期海水显著偏正，豹斑灰云岩与同期海水一致；总体具有高Fe、Mn、Na、K和低Sr含量特征，豹斑灰云岩Fe、Mn、Na含量介于泥晶灰岩与粉细晶白云岩之间；稀土元素含量总体较低，且稀土元素配分模式相似，轻稀土元素富集，重稀土元素亏损，具明显Eu负异常和弱Ce正异常.综上认为研究区白云石化流体主要为海源性流体，早期可能有大气淡水的混入，两类优质白云岩均应形成于局限台地潮间-潮下带环境中的浅埋藏期回流渗透作用阶段.基于上述岩石学和地球化学特征，建立了研究区马五₅亚段纵向的沉积与成岩序列模式，为研究区优质白云岩储层的预测提供了理论依据.
- 白云岩成因 /
- 同位素 /
- 微量元素 /
- 马五₅亚段 /
- 伊陕斜坡 /
- 鄂尔多斯盆地 /
- 地球化学
Abstract: The high-quality dolomite reservoirs of the Ma₅⁵ formation in the Ordovician Majiagou formation in the northern part of the Ordos Basin Yishan slope are developed. Many wells drill high-yield industrial gas streams in this layer, demonstrating huge potential for natural gas exploration. The genetic mechanism of dolomite reservoirs has not yet reached a consensus. Based on the petrological characteristics, the carbon, oxygen isotopic compositions, strontium isotopes and trace elements were discussed deeply to study the origin of dolomites in Ma₅⁵ formation of Northern Yishan slope Ordos Basin. There are three types of mud microcrystalline dolomite, ine-grained dolomite and leopard spots limy dolomite in the Ma₅⁵ submember of the study area. The former is mainly developed at the bottom of the Ma₅⁵ submember, the latter two are mainly developed in the upper middle part of the Ma₅⁵ submember and are the main natural gas reservoirs; The fineness of fine-grained dolomite and leopard spots limy dolomite is low, with average values of 0.86 and 0.68, respectively.The δ¹³C value is mostly consistent with seawater in the same period, and the δ¹⁸O value is significantly negative; most fine-grained dolomite ⁸⁷Sr The/⁸⁶Sr value is significantly more positive than the seawater value in the same period. The leopard spots limy dolomite is consistent with the seawater in the same period; the dolomites are characteried by high Fe, Mn, Na, K content, and low Sr content, and the leopard spots limy dolomite contains Fe, Mn, and Na contents, which are between mud microcrystalline dolomite and fine-crystalline dolomite; the dolomites have very low REE content and similar REE distribution patterns, which are generally characterized by the enrichment of light REE, losses of heavy REE, obviously negative anomaly of Eu and slightly positive anomaly of Ce. In summary, the dolomitization fluids in the study area are mainly sea-sourced fluids. In the early stage, there may be mixed air freshwater. Both types of high-quality dolomite are formed in the shallow burial stage of the tidal period in the intertidal-tidal zone of the restricted platform. Based on the above petrological and geochemical characteristics, the longitudinal sedimentary and diagenetic sequence models of the Ma₅⁵ sub-section of the study area are established, which provides a theoretical basis for the prediction of high-quality dolomitereservoirs in the study area.
- dolomite genesis /
- isotope /
- trace elements /
- Ma₅⁵ /
- Yishan slope /
- Ordos Basin /
- geochemistry

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图 1 区域地质概况及研究区位置

Fig. 1. Regional geology and research area

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图 2 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段碳酸盐岩岩石学特征

a.泥晶角砾灰岩，角砾结构造发育（红色箭头指向）；b.亮晶球粒藻灰岩，网状孔隙内亮晶方解石胶结，隐藻丰富形成藻粘结结构，局部压实或溶蚀形成砂砾状结构（红色箭头指向）；c.泥晶白云岩，发育少量石膏假晶（红色圈区）；d.粉细晶白云岩，具纹层构造，灰岩与粉细晶白云岩互层，白云岩由半自形-自形，晶间残余灰质组分（红色箭头指向）；e.粉细晶白云岩，具残余颗粒结构，晶间残余灰泥（蓝色箭头指向）；f.粉细晶白云岩，白云石呈自形-半自形，具残余砂屑结构(红色圈区），粒间孔发育；g.粉细晶白云岩，白云石呈自形-半自形粒状，具残余砂屑结构，粒间孔发育，缝合线中充填炭质沥青（红色箭头指向）；h.豹斑灰云岩，见介形虫碎片（红色圈区），发育残余泥晶灰岩板块(红色箭头指向）；i.豹斑灰云岩，发育残余泥晶灰岩板块(红色箭头指向）.

Fig. 2. Petrological characteristics of carbonate rocks in the Ma₅⁵ member of the northeast Yishan slope, Ordos Basin

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图 3 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段碳酸盐岩碳、氧同位素相关关系

Fig. 3. Carbon and oxygen isotope correlation of carbonate rocks in the Ma₅⁵member of northeast Yishan slope, Ordos Basin

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图 4 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段锶同位素分布

Fig. 4. Strontium isotopes distribution in Ma₅⁵ formation of northeast Yishan slope, Ordos Basin

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图 5 鄂尔多斯盆伊陕斜坡东北部马五₅亚段碳酸盐岩Sr-Na、Sr-Fe、Sr-Mn微量元素含量分布

Fig. 5. Scatter diagram of content of trace element Sr-Na Sr-Fe、Sr-Mn in Ma₅⁵ formation of northeast Yishan slope, Ordos Basin

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图 6 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段碳酸盐岩稀土元素分布特征

Fig. 6. REE distribution of dolomites in Ma₅⁵ formation of northeast Yishan slope, Ordos Basin

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图 7 台地内海侵及高位体系域准层序的沉积与成岩序列模式

Fig. 7. Sedimentary and diagenetic sequence patterns of quasi stratigraphic sequences in transgression and high system regions of carbonate platform

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表 1 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段碳酸盐岩碳、氧、锶同位素及Mn/Sr特征

Table 1. Carbon, oxygen, strontium isotopes and Mn/Sr characteristics of carbonate rocks in the Ma₅⁵ member of the northeast of the Yishan slope in the Ordos Basin

井号	样品编号	井深(m)	层位	岩性	δ¹⁸O(‰)	δ¹³C(‰)	⁸⁷Sr/⁸⁶Sr	Mn/Sr
D48	D48-11	3 020.28	马五₅	泥晶灰岩	-9.79	-1.74	0.708 879	0.20
D50	D50-14	2 918.78	马五₅	泥晶灰岩	-9.36	-1.63	-	0.13
兴县剖面	XX11-M55-33-2	17.80	马五₅	泥晶灰岩	-8.86	-1.77	-	0.17
兴县剖面	XX12-M55-35-1	25.00	马五₅	泥晶灰岩	-9.26	-1.75	0.708 654	0.12
兴县剖面	XX37-M55-53A-2	33.00	马五₅	泥晶灰岩	-8.94	-1.23	-	0.16
兴县剖面	XX37-M55-53B-1	35.00	马五₅	泥晶灰岩	-8.75	-0.89	-	0.12
D48	D48-1	3 012.30	马五₅	粉细晶白云岩	-8.23	-0.45	0.710 004	1.03
D48	D48-2	3 013.20	马五₅	粉细晶白云岩	-10.19	-1.83	0.709 327	1.08
D48	D48-4	3 014.00	马五₅	粉细晶白云岩	-7.82	-0.78	0.710 067	0.73
D48	D48-5	3 014.82	马五₅	粉细晶白云岩	-8.93	-1.70	0.709 350	0.82
D48	D48-6	3 016.17	马五₅	粉细晶白云岩	-10.11	-2.19	0.708 819	0.29
D48	D48-8	3 017.52	马五₅	粉细晶白云岩	-9.82	-1.94	0.709 310	0.64
D48	D48-9	3 018.83	马五₅	粉细晶白云岩	-10.00	-1.64	-	0.55
D48	D48-12	3 021.18	马五₅	粉细晶白云岩	-9.56	-1.03	0.708 919	0.60
兴县剖面	XX9-M55-24	8.00	马五₅	粉细晶白云岩	-10.59	-2.79	-	1.06
兴县剖面	XX10-M55-26A	9.00	马五₅	粉细晶白云岩	-8.90	-2.05	0.709 270	1.53
兴县剖面	XX10-M551-27-2	9.50	马五₅	粉细晶白云岩	-9.69	-2.68	-	1.17
D48	D48-2a	3 023.04	马五₅	豹斑灰云岩	-9.89	-1.63	-	0.47
D48	D48-15	3 023.59	马五₅	豹斑灰云岩	-10.04	-1.14	0.708 879	0.51
兴县剖面	XX11-M55-32-1	17.50	马五₅	豹斑灰云岩	-8.48	-0.92	-	0.25
兴县剖面	XX11-M55-32-2	17.50	马五₅	豹斑灰云岩	-7.78	-0.36	-	0.64
兴县剖面	XX11-M55-33-1	17.80	马五₅	豹斑灰云岩	-8.98	-1.03	-	0.64
兴县剖面	XX12-M55-35-2	25.00	马五₅	豹斑灰云岩	-9.45	-1.63	0.708 789	0.30
兴县剖面	XX37-M55-53A-1	33.00	马五₅	豹斑灰云岩	-8.13	-0.12	-	0.32
兴县剖面	XX37-M55-53B-2	35.00	马五₅	豹斑灰云岩	-9.14	-0.41	-	0.51

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表 2 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段微量元素组成分布特征

Table 2. Trace elements in Member Ma₅⁵ of Northeast Yishan Slope, Ordos Basin.

井号	样品编号	深度(m)	层位	岩性	元素含量(10^-⁶)
井号	样品编号	深度(m)	层位	岩性	Fe	Mn	Sr	Na	K
D48	D48-11	3020.28	马五₅	泥晶灰岩	551.00	29.00	147.22	44.00	405.00
D50	D50-14	2918.78	马五₅	泥晶灰岩	161.00	14.00	109.39	21.00	118.00
兴县剖面	XX11-M55-33-2	17.80	马五₅	泥晶灰岩	424.00	35.00	207.87	14.00	154.00
兴县剖面	XX12-M55-35-1	25.00	马五₅	泥晶灰岩	412.00	21.00	174.38	22.00	227.00
兴县剖面	XX37-M55-53A-2	33.00	马五₅	泥晶灰岩	399.00	28.00	180.24	27.00	284.00
兴县剖面	XX37-M55-53B-1	35.00	马五₅	泥晶灰岩	353.00	24.00	201.20	24.00	198.00
D48	D48-1	3012.30	马五₅	细粉晶白云岩	1 155.00	94.00	91.10	122.00	208.00
D48	D48-2	3013.20	马五₅	细粉晶白云岩	1 198.00	67.00	61.80	87.00	298.00
D48	D48-4	3014.00	马五₅	细粉晶白云岩	1 095.00	58.00	79.02	109.00	352.00
D48	D48-5	3014.82	马五₅	细粉晶白云岩	1 160.00	57.00	69.32	70.00	232.00
D48	D48-6	3016.17	马五₅	细粉晶白云岩	584.00	42.00	145.45	38.00	180.00
D48	D48-8	3017.52	马五₅	细粉晶白云岩	1 132.00	62.00	97.53	99.00	421.00
D48	D48-9	3018.83	马五₅	细粉晶白云岩	1 284.00	63.00	114.92	110.00	354.00
D48	D48-12	3021.18	马五₅	细粉晶白云岩	793.00	48.00	79.78	28.00	124.00
兴县剖面	XX9-M55-24	8.00	马五₅	细粉晶白云岩	1 339.00	64.00	60.10	38.00	234.00
兴县剖面	XX10-M55-26A	9.00	马五₅	细粉晶白云岩	1 611.00	78.00	51.15	163.00	432.00
兴县剖面	XX10-M551-27-2	9.50	马五₅	细粉晶白云岩	1 456.00	92.00	78.33	51.00	217.00
D48	D48-2a	3023.04	马五₅	豹斑灰云岩	806.00	39.00	83.17	42.00	275.00
D48	D48-15	3023.59	马五₅	豹斑灰云岩	910.00	44.00	86.53	52.00	664.00
兴县剖面	XX11-M55-32-1	17.50	马五₅	豹斑灰云岩	677.00	36.00	145.15	28.00	211.00
兴县剖面	XX11-M55-32-2	17.50	马五₅	豹斑灰云岩	1 044.00	43.00	66.71	32.00	355.00
兴县剖面	XX11-M55-33-1	17.80	马五₅	豹斑灰云岩	863.00	69.00	107.45	30.00	170.00
兴县剖面	XX12-M55-35-2	25.00	马五₅	豹斑灰云岩	835.00	38.00	128.50	31.00	315.00
兴县剖面	XX37-M55-53A-1	33.00	马五₅	豹斑灰云岩	956.00	39.00	121.05	64.00	534.00
兴县剖面	XX37-M55-53B-2	35.00	马五₅	豹斑灰云岩	1 223.00	52.00	101.29	26.00	274.00

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表 3 鄂尔多斯盆地伊陕斜坡东北部马五₅亚段不同碳酸盐岩稀土元素含量

Table 3. Analytical data of rare earth element of different types of carbonate rocks in Ma₅⁵ formation of northeastYishan Slope, Ordos Basin.

井号	样品编号	深度(m)	地层名称	岩性	稀土元素含量(10^-⁶)
井号	样品编号	深度(m)	地层名称	岩性	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	δEu	δCe
D50	D50-14	2 918.78	马五₅	泥晶灰岩	4.52	9.41	1.02	3.65	0.61	0.10	0.62	0.07	0.32	0.07	0.16	0.02	0.10	0.01	0.50	1.07
D48	D48-11	3 020.28	马五₅	泥晶灰岩	2.19	3.88	0.41	1.54	0.25	0.05	0.29	0.04	0.21	0.04	0.10	0.01	0.09	0.01	0.57	1.00
兴县剖面	XX11-M55-32-2	17.50	马五₅	泥晶灰岩	1.45	2.50	0.26	0.95	0.17	0.03	0.19	0.03	0.15	0.03	0.09	0.01	0.08	0.01	0.51	1.00
兴县剖面	XX12-M55-35-1	25.00	马五₅	泥晶灰岩	3.28	6.08	0.67	2.58	0.45	0.08	0.49	0.06	0.28	0.05	0.11	0.01	0.10	0.01	0.52	1.01
兴县剖面	XX37-M55-53A-2	33.00	马五₅	泥晶灰岩	3.33	6.27	0.68	2.64	0.47	0.10	0.50	0.07	0.35	0.07	0.18	0.03	0.19	0.03	0.63	1.02
兴县剖面	XX37-M55-53B-1	35.00	马五₅	泥晶灰岩	4.40	7.99	0.86	3.23	0.61	0.11	0.60	0.07	0.39	0.07	0.18	0.02	0.16	0.03	0.56	1.01
D48	D48-1	3 012.30	马五₅	粉细晶白云岩	0.37	0.81	0.10	0.43	0.11	0.02	0.10	0.02	0.09	0.02	0.05	0.01	0.04	0.00	0.58	1.03
D48	D48-2	3 013.20	马五₅	粉细晶白云岩	0.45	0.93	0.12	0.48	0.13	0.03	0.12	0.02	0.10	0.02	0.06	0.01	0.05	0.01	0.73	0.98
D48	D48-4	3 014.00	马五₅	粉细晶白云岩	0.35	0.74	0.09	0.37	0.09	0.02	0.09	0.02	0.09	0.02	0.05	0.01	0.05	0.01	0.68	1.02
D48	D48-5	3 014.82	马五₅	粉细晶白云岩	0.80	1.75	0.18	0.72	0.12	0.03	0.14	0.02	0.11	0.02	0.07	0.01	0.05	0.01	0.71	1.12
D48	D48-6	3 016.17	马五₅	粉细晶白云岩	2.34	4.39	0.46	1.63	0.25	0.04	0.28	0.04	0.18	0.03	0.10	0.01	0.08	0.01	0.46	1.04
D48	D48-8	3 017.52	马五₅	粉细晶白云岩	1.72	3.53	0.41	1.61	0.30	0.07	0.32	0.04	0.19	0.04	0.11	0.01	0.09	0.01	0.69	1.03
D48	D48-9	3 018.83	马五₅	粉细晶白云岩	1.16	2.41	0.28	1.17	0.25	0.05	0.24	0.03	0.17	0.03	0.09	0.01	0.07	0.01	0.62	1.04
D48	D48-12	3 021.18	马五₅	粉细晶白云岩	1.03	1.92	0.20	0.72	0.12	0.03	0.12	0.02	0.11	0.02	0.06	0.01	0.06	0.01	0.76	1.04
兴县剖面	XX9-M55-24	8.00	马五₅	粉细晶白云岩	0.72	1.40	0.16	0.65	0.11	0.03	0.13	0.02	0.09	0.02	0.04	0.01	0.05	0.01	0.77	1.01
兴县剖面	XX10-M55-26A	9.00	马五₅	粉细晶白云岩	0.89	1.78	0.21	0.82	0.16	0.04	0.18	0.03	0.15	0.03	0.10	0.01	0.10	0.01	0.72	1.01
兴县剖面	XX10-M551-27-2	9.50	马五₅	粉细晶白云岩	1.21	2.38	0.27	1.09	0.23	0.06	0.27	0.04	0.22	0.04	0.13	0.02	0.13	0.02	0.74	1.02
D48	D48-2a	3 023.04	马五₅	豹斑灰云岩	1.06	1.93	0.20	0.75	0.14	0.03	0.13	0.02	0.11	0.02	0.07	0.01	0.04	0.01	0.68	1.03
D48	D48-15	3 023.59	马五₅	豹斑灰云岩	1.45	2.56	0.28	1.02	0.18	0.04	0.18	0.03	0.14	0.03	0.08	0.01	0.09	0.01	0.68	0.99
兴县剖面	XX11-M55-32-1	17.50	马五₅	豹斑灰云岩	1.81	3.40	0.36	1.40	0.28	0.05	0.30	0.04	0.21	0.04	0.11	0.01	0.11	0.02	0.53	1.04
兴县剖面	XX11-M55-32-2	17.50	马五₅	豹斑灰云岩	1.45	2.50	0.26	0.95	0.17	0.03	0.19	0.03	0.15	0.03	0.09	0.01	0.08	0.01	0.51	1.00
兴县剖面	XX11-M55-33-1	17.80	马五₅	豹斑灰云岩	1.70	2.93	0.30	1.15	0.22	0.04	0.22	0.03	0.15	0.03	0.07	0.01	0.08	0.01	0.56	1.01
兴县剖面	XX12-M55-35-2	25.00	马五₅	豹斑灰云岩	2.28	4.01	0.43	1.64	0.31	0.06	0.30	0.04	0.20	0.04	0.10	0.01	0.06	0.01	0.60	0.99
兴县剖面	XX37-M55-53A-1	33.00	马五₅	豹斑灰云岩	2.34	3.98	0.42	1.54	0.31	0.07	0.33	0.05	0.25	0.05	0.13	0.02	0.15	0.02	0.67	0.98
兴县剖面	XX37-M55-53B-2	35.00	马五₅	豹斑灰云岩	2.30	3.78	0.39	1.42	0.29	0.06	0.29	0.04	0.21	0.04	0.11	0.01	0.10	0.01	1.34	0.95

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