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    福建白垩纪红层火山岩夹层时代及构造意义

    陈淑华 林慈銮 徐维光 赵骏杰

    陈淑华, 林慈銮, 徐维光, 赵骏杰, 2020. 福建白垩纪红层火山岩夹层时代及构造意义. 地球科学, 45(7): 2508-2523. doi: 10.3799/dqkx.2020.035
    引用本文: 陈淑华, 林慈銮, 徐维光, 赵骏杰, 2020. 福建白垩纪红层火山岩夹层时代及构造意义. 地球科学, 45(7): 2508-2523. doi: 10.3799/dqkx.2020.035
    Chen Shuhua, Lin Ciluan, Xu Weiguang, Zhao Junjie, 2020. Age and Tectonic Significance of Volcanic Rocks in Cretaceous Red Beds in Fujian. Earth Science, 45(7): 2508-2523. doi: 10.3799/dqkx.2020.035
    Citation: Chen Shuhua, Lin Ciluan, Xu Weiguang, Zhao Junjie, 2020. Age and Tectonic Significance of Volcanic Rocks in Cretaceous Red Beds in Fujian. Earth Science, 45(7): 2508-2523. doi: 10.3799/dqkx.2020.035

    福建白垩纪红层火山岩夹层时代及构造意义

    doi: 10.3799/dqkx.2020.035
    基金项目: 

    中国地质科学院地质研究所台湾海峡两岸地质条件及地质系统图件编制 DD20160345

    详细信息
      作者简介:

      陈淑华(1985-), 女, 工程师, 从事地质矿产综合研究

    • 中图分类号: P56

    Age and Tectonic Significance of Volcanic Rocks in Cretaceous Red Beds in Fujian

    • 摘要: 为了研究福建省白垩纪红层形成的时代及构造背景,在政和-大埔断裂以西选取典型红层盆地,对不同盆地内火山岩夹层进行LA-ICP-MS锆石同位素定年和岩石地球化学分析.同位素U-Pb测年结果显示:沙县组的时限较长,为127~87 Ma,其总体时代应大致相当于晚白垩世早期,下部层段跨入早白垩世晚期;崇安组年龄为100.0±1.2 Ma,形成时代为晚白垩世早期.岩石地球化学结果表明,白垩纪红层中的火山岩为壳源成因,是处伸展环境下,为构造活动引起区域断陷拉张作用形成的一套钙碱性系列流纹岩.

       

    • 图  1  福建省白垩纪红层分布及采样位置

      Fig.  1.  Distribution and sampling location of the Cretaceous red beds in Fujian Province

      图  2  福建白垩纪红层火山岩野外及镜下照片

      a.建瓯流纹质晶屑岩屑凝灰岩;b.建瓯流纹质晶屑岩屑凝灰岩镜下特征;c.白沙沉凝灰岩;d.白沙沉凝灰岩镜下特征;e.泰宁风洞流纹质晶屑弱熔结凝灰岩;f.风洞流纹质晶屑弱熔结凝灰岩镜下特征;g. 泰宁大金湖流纹质晶屑凝灰岩;h. 大金湖流纹质晶屑凝灰岩镜下特征;i.上杭流纹质角砾岩屑凝灰岩;j.上杭流纹质角砾岩屑凝灰岩镜下特征;k.武平流纹质晶屑凝灰岩;l.武平流纹质晶屑凝灰岩镜下特征

      Fig.  2.  Field photos and photomicrographs of the Cretaceous red bed volcanic rocks in Fujian Province

      图  3  火山岩TAS图解

      Le Bas(1986)

      Fig.  3.  TAS diagram of volcanic rocks

      图  4  硅-碱关系

      据据Irvine and Baragar(1971)

      Fig.  4.  Diagram of SiO2-(K2O+Na2O)

      图  5  火山岩AFM图解

      Irvine and Baragar(1971)

      Fig.  5.  A-F-M diagrams of volcanic rocks

      图  6  An-Ab-Or三角图解

      据据Irvine and Baragar(1971)

      Fig.  6.  An-Ab-O diagrams of volcanic rocks

      图  7  微量元素洋中脊花岗岩(ORG)标准化蛛网图

      Pearce et al.(1984)

      Fig.  7.  Oceanic ridge granite trace element patterns

      图  8  火山岩稀土配分模式图

      Boynton(1984)

      Fig.  8.  REE patterns of volcanic rocks

      图  9  样品锆石U-Pb测年谐和图(单位:Ma)

      Fig.  9.  The U-Pb concordia diagram of zircons samples

      图  10  微量元素构造背景判别图

      a. Nb-Y图解;b. Rb-(Y+Nb)图解;WPG.板内花岗岩;VAG.火山弧花岗岩;syn-COLG.同碰撞花岗岩;ORG.洋脊花岗岩;图a中断线是产于异常洋脊的ORG的边界线;LCC.下陆壳;AFC.地壳混染与分离结晶作用; 据Pearce(1984, 1996

      Fig.  10.  Discrimination diagrams of tectonic settings by trace elements

      图  11  R1-R2构造环境判别图

      1.地幔分异产物;2.板块碰撞前;3.碰撞后隆起;4.造山晚期;5.非造山;6.同碰撞;7.造山后;据Batchelor and Bowden(1985)

      Fig.  11.  Diagrams of tectonic settings by R1-R2

      图  12  戈蒂尼-里特曼指数图

      A区.板内稳定区;B区.造山带区(岛弧及活动大陆边缘);C区. A及B区演化的碱性火山岩; 据Rittmann(1973)

      Fig.  12.  Index diagram of lgδ-lgτ

      表  1  建瓯盆地JOTW样品LA-ICP-MS锆石U-Pb数据

      Table  1.   LA-ICP-MS U-Pb abundance of zircons from sample JOTW in Jianou basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      2 491.44 264.83 1.86 0.047 7 0.002 8 0.120 4 0.006 5 0.018 5 0.000 4 87 133 115 6 118 2
      4 205.05 281.76 0.73 0.053 0 0.003 5 0.140 7 0.008 3 0.019 7 0.000 4 328 150 134 7 126 3
      5 1 055.23 675.42 1.56 0.051 4 0.002 3 0.141 3 0.006 6 0.019 7 0.000 3 257 108 134 6 126 2
      6 448.27 477.47 0.94 0.047 5 0.0030 0.120 3 0.006 4 0.018 5 0.000 4 72 144 115 6 118 2
      7 108.62 119.91 0.91 0.057 5 0.008 7 0.146 7 0.019 2 0.019 3 0.001 0 522 335 139 17 123 6
      8 1 200.21 812.79 1.48 0.047 6 0.002 4 0.123 0 0.005 3 0.018 8 0.000 3 76 115 118 5 120 2
      9 296.24 351.40 0.84 0.056 5 0.004 4 0.149 5 0.009 8 0.019 6 0.000 5 472 169 141 9 125 3
      11 463.03 397.40 1.17 0.053 0 0.003 5 0.144 6 0.009 2 0.019 9 0.000 4 328 153 137 8 127 2
      12 380.58 462.79 0.82 0.050 3 0.002 7 0.124 5 0.006 4 0.018 2 0.000 4 206 122 119 6 116 2
      13 535.76 302.40 1.77 0.052 5 0.005 0 0.126 7 0.011 4 0.017 9 0.000 5 306 217 121 10 115 3
      14 325.74 285.01 1.14 0.051 5 0.003 6 0.131 4 0.008 5 0.018 8 0.000 4 261 158 125 8 120 2
      15 393.87 438.88 0.90 0.050 8 0.002 9 0.128 3 0.007 4 0.018 5 0.000 4 235 131 123 7 118 2
      16 349.09 262.30 1.33 0.050 0 0.004 0 0.124 2 0.007 8 0.018 7 0.000 5 195 174 119 7 120 3
      18 459.63 410.12 1.12 0.051 0 0.003 6 0.135 3 0.008 5 0.019 6 0.000 4 243 163 129 8 125 2
      19 323.01 312.96 1.03 0.055 4 0.003 7 0.135 0 0.008 3 0.018 1 0.000 4 428 150 129 7 115 3
      21 967.26 828.83 1.17 0.046 4 0.0028 0.117 0 0.006 6 0.018 3 0.000 3 20 146 112 6 117 2
      22 393.58 497.70 0.79 0.047 5 0.002 6 0.123 5 0.006 4 0.018 7 0.000 3 72 126 118 6 120 2
      23 210.09 229.60 0.92 0.049 4 0.003 8 0.124 6 0.008 5 0.018 9 0.000 5 169 170 119 8 121 3
      24 168.68 245.10 0.69 0.052 3 0.003 5 0.136 6 0.008 2 0.019 3 0.000 4 302 156 130 7 123 3
      25 206.58 240.15 0.86 0.046 8 0.003 5 0.122 3 0.008 1 0.018 9 0.000 4 39 170 117 7 121 3
      26 183.89 163.26 1.13 0.052 9 0.004 2 0.125 2 0.007 4 0.018 4 0.000 5 324 181 120 7 118 3
      27 192.29 271.53 0.71 0.047 8 0.004 0 0.123 8 0.010 2 0.018 7 0.000 7 100 180 118 9 120 4
      29 189.35 152.62 1.24 0.049 9 0.004 8 0.125 3 0.009 5 0.019 7 0.000 7 191 207 120 9 126 4
      下载: 导出CSV

      表  2  白沙盆地BsTW样品LA-ICP-MS锆石U-Pb数据

      Table  2.   LA-ICP-MS U-Pb abundance of zircons from sample BsTW in Baisha basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      3 138.12 393.06 0.35 0.050 9 0.001 8 0.127 5 0.002 8 0.018 2 0.000 3 236 80 122 3 116 2
      4 232.13 396.70 0.59 0.051 9 0.001 8 0.136 5 0.003 0 0.019 1 0.000 3 280 79 130 3 122 2
      5 233.64 455.61 0.51 0.049 3 0.001 9 0.126 3 0.003 3 0.018 6 0.000 3 161 87 121 3 119 2
      7 133.70 217.41 0.61 0.050 4 0.002 1 0.132 9 0.004 1 0.019 1 0.000 3 214 94 127 4 122 2
      9 172.86 294.62 0.59 0.048 8 0.001 8 0.128 1 0.003 1 0.019 1 0.000 3 137 85 122 3 122 2
      10 293.04 602.21 0.49 0.048 0 0.001 6 0.125 6 0.002 5 0.019 0 0.000 3 101 79 120 2 121 2
      14 221.74 474.93 0.47 0.048 6 0.002 0 0.126 3 0.003 8 0.018 9 0.000 3 128 94 121 3 120 2
      15 998.71 755.95 1.32 0.049 0 0.001 7 0.125 5 0.002 6 0.018 6 0.000 3 148 79 120 2 119 2
      18 131.46 141.49 0.93 0.048 7 0.002 3 0.122 3 0.004 6 0.018 2 0.000 3 136 107 117 4 116 2
      19 274.94 358.98 0.77 0.048 1 0.001 8 0.124 8 0.003 0 0.018 8 0.000 3 104 84 119 3 120 2
      20 203.19 260.87 0.78 0.050 4 0.002 1 0.131 3 0.004 2 0.018 9 0.000 3 214 95 125 4 121 2
      21 222.66 258.82 0.86 0.048 9 0.001 9 0.126 2 0.003 5 0.018 7 0.000 3 145 90 121 3 119 2
      24 267.44 396.11 0.68 0.048 8 0.001 8 0.127 5 0.003 2 0.018 9 0.000 3 140 86 122 3 121 2
      下载: 导出CSV

      表  3  泰宁盆地风洞14611TW样品LA-ICP-MS锆石U-Pb数据

      Table  3.   LA-ICP-MS U-Pb abundance of zircons from sample 14611TW in Fengdong of Taining basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      2 120.4 186.76 0.64 0.0481 0.002 2 0.103 1 0.003 7 0.015 5 0.000 2 105 104 100 3 99 1
      3 112.6 133.85 0.84 0.0489 0.003 1 0.112 5 0.006 3 0.016 7 0.000 3 143 142 108 6 107 2
      4 148.9 217.33 0.69 0.050 9 0.002 2 0.114 2 0.003 6 0.016 3 0.000 2 238 95 110 3 104 1
      5 284.9 648.43 0.44 0.047 5 0.001 7 0.108 1 0.002 3 0.016 5 0.000 2 74 82 104 2 106 1
      6 118.1 202.25 0.58 0.048 7 0.003 6 0.107 1 0.007 2 0.015 9 0.000 3 135 164 103 7 102 2
      7 249.9 454.79 0.55 0.048 5 0.001 8 0.103 5 0.002 4 0.015 5 0.000 2 123 83 100 2 99 1
      8 232.3 493.45 0.47 0.050 0 0.001 8 0.109 6 0.002 5 0.015 9 0.000 2 197 82 106 2 102 1
      9 290.4 616.31 0.47 0.048 4 0.001 7 0.101 6 0.002 1 0.015 2 0.000 2 120 80 98 2 97 1
      10 104.3 180.26 0.58 0.052 4 0.002 4 0.116 2 0.004 0 0.016 1 0.000 2 302 99 112 4 103 2
      11 555.5 836.37 0.66 0.051 9 0.002 1 0.113 7 0.003 3 0.015 9 0.000 2 280 90 109 3 102 1
      12 133.6 174.96 0.76 0.049 9 0.002 2 0.111 5 0.003 8 0.016 2 0.000 2 192 100 107 4 104 2
      15 93.21 142.06 0.66 0.048 0 0.003 8 0.100 7 0.007 4 0.015 2 0.000 3 97 180 97 7 97 2
      16 138.8 362.02 0.38 0.050 8 0.002 0 0.112 5 0.003 2 0.016 1 0.000 2 231 89 108 3 103 1
      17 298.4 683.01 0.44 0.051 3 0.002 0 0.112 9 0.003 2 0.016 0 0.000 2 256 88 109 3 102 1
      18 458.2 931.71 0.49 0.050 6 0.001 7 0.112 7 0.002 1 0.016 2 0.000 2 222 75 109 2 103 1
      20 207.3 456.18 0.45 0.049 6 0.001 8 0.107 4 0.002 7 0.015 7 0.000 2 174 84 104 2 101 1
      21 169.7 347.64 0.49 0.048 8 0.001 8 0.109 5 0.002 7 0.016 3 0.000 2 139 84 106 2 104 1
      23 411.5 942.11 0.44 0.050 4 0.001 7 0.110 0 0.002 0 0.015 8 0.000 2 212 74 106 2 101 1
      24 140.5 276.71 0.51 0.052 5 0.002 1 0.117 6 0.003 3 0.016 3 0.000 2 306 87 113 3 104 1
      下载: 导出CSV

      表  4  泰宁盆地大金湖TNTW样品LA-ICP-MS锆石U-Pb数据

      Table  4.   LA-ICP-MS U-Pb abundance of zircons from sample TNTW in Fengdong of Taining basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      1 45.3 72.9 0.62 0.057 6 0.008 4 0.112 6 0.011 8 0.015 9 0.000 7 517 320 108 11 101 4
      3 159.0 291.0 0.55 0.050 5 0.003 9 0.103 5 0.006 9 0.015 3 0.000 4 220 178 100 6 98 2
      4 53.9 65.9 0.82 0.048 5 0.011 2 0.078 9 0.012 9 0.015 5 0.000 9 124 470 77 12 99 6
      5 52.8 75.0 0.70 0.048 5 0.005 7 0.090 6 0.008 3 0.015 9 0.000 5 124 252 88 8 102 3
      6 74.4 137.8 0.54 0.054 2 0.007 4 0.097 3 0.008 9 0.013 6 0.000 4 389 311 94 8 87 3
      7 217.0 447.0 0.48 0.045 9 0.002 9 0.096 0 0.005 1 0.015 5 0.000 3 23 222 78 93 5 99 2
      8 148.0 246.0 0.60 0.050 3 0.004 1 0.100 5 0.007 3 0.015 2 0.000 4 209 189 97 7 97 2
      9 118.0 212.0 0.56 0.051 5 0.004 2 0.105 8 0.007 8 0.015 5 0.000 4 265 189 102 7 99 3
      10 37.3 48.8 0.76 0.058 3 0.011 4 0.105 2 0.012 3 0.015 9 0.001 0 543 431 102 11 102 7
      12 118.0 109.0 1.08 0.058 1 0.009 4 0.102 4 0.012 2 0.015 0 0.000 8 600 361 99 11 96 5
      13 42.6 67.6 0.63 0.042 2 0.008 6 0.093 8 0.015 9 0.015 1 0.000 9 348 99 91 15 97 6
      14 119.0 178.0 0.67 0.053 0 0.005 7 0.100 2 0.007 0 0.015 1 0.000 4 328 244 97 6 97 3
      16 271.0 286.0 0.95 0.048 6 0.004 6 0.097 7 0.008 2 0.014 9 0.000 6 132 207 95 8 95 4
      17 71.8 139.0 0.51 0.056 4 0.006 3 0.105 6 0.009 0 0.015 5 0.000 5 478 250 102 8 99 3
      18 58.0 97.9 0.59 0.051 1 0.006 8 0.096 8 0.008 9 0.015 4 0.000 6 243 285 94 8 99 4
      19 75.2 101.0 0.74 0.045 8 0.007 6 0.086 6 0.009 8 0.015 8 0.000 7 347 82 84 9 101 4
      20 71.2 82.5 0.86 0.067 8 0.013 8 0.103 1 0.012 7 0.015 2 0.000 6 865 432 100 12 97 4
      21 142 234.0 0.61 0.045 3 0.003 7 0.102 4 0.007 5 0.016 4 0.000 4 272 44 99 7 105 3
      22 56.5 63.4 0.89 0.055 7 0.006 5 0.103 0 0.009 1 0.015 3 0.000 6 443 258 99 8 98 4
      23 87.0 83.3 1.04 0.046 2 0.006 0 0.092 6 0.008 8 0.016 2 0.000 6 249 285 90 8 104 4
      25 40.6 61.8 0.66 0.064 1 0.015 9 0.111 2 0.016 9 0.015 9 0.001 0 746 544 107 15 102 6
      26 198.0 408.0 0.49 0.049 7 0.002 9 0.109 2 0.005 4 0.016 3 0.000 3 189 142 105 5 104 2
      27 178.0 213.0 0.83 0.049 1 0.005 8 0.102 3 0.010 9 0.015 5 0.000 5 150 259 99 10 99 3
      28 320.0 443.0 0.72 0.048 2 0.003 1 0.104 1 0.005 8 0.015 9 0.000 4 109 148 101 5 101 2
      29 196.0 274.0 0.72 0.044 4 0.003 7 0.097 9 0.007 0 0.016 1 0.000 4 272 94 95 6 103 2
      30 63.6 76.8 0.83 0.062 2 0.014 1 0.107 8 0.010 1 0.016 1 0.000 6 680 500 104 9 103 4
      下载: 导出CSV

      表  5  上杭盆地ShTW样品LA-ICP-MS锆石U-Pb数据

      Table  5.   LA-ICP-MS U-Pb abundance of zircons from sample ShTW in Shanghang basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      1 600.36 412.67 1.45 0.047 3 0.003 2 0.096 0 0.0063 0.0147 0.000 2 62 153 93 6 94 2
      2 212.37 115.46 1.84 0.050 1 0.019 1 0.100 6 0.037 6 0.014 6 0.001 2 199 706 97 35 93 8
      3 475.00 465.15 1.02 0.052 8 0.003 1 0.103 0 0.005 9 0.014 1 0.000 2 322 128 100 5 91 1
      4 477.34 416.10 1.15 0.049 0 0.003 1 0.099 0 0.006 2 0.014 7 0.000 2 147 144 96 6 94 1
      5 1 011.51 704.36 1.44 0.046 9 0.002 4 0.093 5 0.004 6 0.014 5 0.000 2 42 118 91 4 93 1
      6 454.99 472.90 0.96 0.048 9 0.003 0 0.096 9 0.005 7 0.014 4 0.000 2 142 137 94 5 92 1
      7 951.05 403.43 2.36 0.050 6 0.004 4 0.098 3 0.008 4 0.014 1 0.000 3 223 190 95 8 90 2
      8 513.29 472.52 1.09 0.047 1 0.003 1 0.098 1 0.006 4 0.015 1 0.000 2 56 152 95 6 97 2
      9 765.05 482.08 1.59 0.049 6 0.003 8 0.102 9 0.007 8 0.015 0 0.000 3 178 171 99 7 96 2
      10 551.34 479.21 1.10 0.051 6 0.003 9 0.105 2 0.007 7 0.014 8 0.000 3 266 163 102 7 95 2
      11 1 116.74 525.37 2.13 0.047 6 0.004 4 0.099 8 0.009 0 0.015 2 0.000 3 80 206 97 8 97 2
      12 229.68 109.03 2.11 0.049 0 0.007 3 0.097 6 0.014 2 0.014 4 0.000 5 149 316 95 13 92 3
      13 536.86 474.44 1.13 0.052 0 0.005 1 0.101 3 0.009 6 0.014 1 0.000 3 287 209 98 9 90 2
      14 465.70 439.72 1.06 0.048 9 0.003 0 0.100 5 0.006 1 0.014 9 0.000 2 141 139 97 6 95 1
      15 2 406.64 529.16 4.55 0.052 0 0.002 9 0.105 8 0.005 7 0.014 8 0.000 2 284 122 102 5 94 1
      16 650.03 510.54 1.27 0.049 9 0.002 9 0.100 7 0.005 7 0.014 6 0.000 2 189 131 97 5 94 1
      17 596.32 317.25 1.88 0.050 9 0.009 9 0.105 3 0.019 9 0.015 0 0.000 7 237 395 102 18 96 4
      18 360.64 219.61 1.64 0.053 2 0.005 8 0.109 3 0.011 6 0.014 9 0.000 4 338 229 105 11 95 2
      19 571.81 466.22 1.23 0.051 3 0.007 5 0.100 8 0.014 4 0.014 2 0.000 5 256 305 98 13 91 3
      20 1 294.90 861.69 1.50 0.049 2 0.002 1 0.098 2 0.004 1 0.014 5 0.000 2 156 98 95 4 93 1
      21 847.18 558.48 1.52 0.050 8 0.003 3 0.103 4 0.006 5 0.014 8 0.000 2 232 142 100 6 94 1
      22 2 487.35 744.17 3.43 0.048 1 0.002 6 0.095 5 0.005 0 0.014 4 0.000 2 103 124 93 5 92 1
      23 628.40 473.44 1.33 0.047 7 0.002 8 0.099 5 0.005 6 0.015 1 0.000 2 83 133 96 5 97 1
      24 498.85 377.03 1.32 0.053 1 0.003 5 0.108 4 0.007 0 0.014 8 0.000 2 334 144 105 6 95 1
      下载: 导出CSV

      表  6  武平盆地WPTW样品LA-ICP-MS锆石U-Pb数据

      Table  6.   LA-ICP-MS U-Pb abundance of zircons from sample WPTW in Wuping basin

      测点 (10-6 Th/U 同位素比值 同位素年龄(Ma)
      Th U 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s 207Pb/ 206Pb 1s 207Pb/ 235U 1s 206Pb/ 238U 1s
      4 562.19 1 583.39 0.36 0.050 0 0.002 5 0.101 5 0.004 8 0.014 7 0.000 2 196 111 98 4 94 1
      5 324.18 374.19 0.87 0.047 0 0.003 4 0.097 5 0.006 8 0.015 0 0.000 3 50 164 95 6 96 2
      9 1 217.35 522.16 2.33 0.047 1 0.002 7 0.096 9 0.005 4 0.014 9 0.000 2 55 131 94 5 95 1
      11 126.21 241.26 0.52 0.048 2 0.008 7 0.100 0 0.017 6 0.015 1 0.000 6 107 377 97 16 96 4
      13 457.46 498.01 0.92 0.048 4 0.003 1 0.098 8 0.006 2 0.014 8 0.000 2 119 144 96 6 95 1
      17 374.88 413.99 0.91 0.048 3 0.004 0 0.096 8 0.007 7 0.014 5 0.000 3 114 183 94 7 93 2
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