VMS Deposits in the Northern Xinjiang: Geological Characteristics and Metallogeny
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摘要: VMS矿床是中亚造山带的重要矿床类型，在新疆中亚造山带（即新疆北部）主要分布于阿尔泰和东天山的阿舍勒、克兰、麦兹和卡拉塔格矿集区.含矿层位主要有下‒中志留统红柳峡组、上志留统‒下泥盆统康布铁堡组下亚组和上亚组、下‒中泥盆统阿舍勒组和下石炭统小热泉子组海相火山沉积岩系.矿区发育喷流岩，如含铁碧玉岩、重晶石、硅质岩、铁锰质大理岩、黄铁矿层、绿泥石岩.VMS成矿系统中发育多种矿化类型，“双层结构”（层状或透镜状矿体和补给通道相脉状矿体）是其中之一，还有与火山热液有关的脉状矿化、与次火山热液有关的脉状和浸染状矿化.VMS矿床形成于3个成矿期，即早‒中志留世（428~438 Ma）、早‒中泥盆世（379~413 Ma）和早石炭世（332~359 Ma）.硫来自下伏火山岩、海水硫酸盐无机还原作用和硫酸盐细菌还原作用.成矿流体以中低温（300~120 ℃）低盐度（2%~10% NaCleq）为特色，成矿流体为深循环海水混合不同比例的岩浆水.VMS成矿系统中由于受火山机构、岩相、矿化类型、矿化部位、成矿流体来源、物理化学条件等因素影响，造成了成矿元素组合复杂.Abstract: Volcanogenic massive sulfide (VMS) is one of the most important deposit types in the Central Asian Orogenic Belt (CAOB). In the CAOB in Xinjiang (northern Xinjiang), VMS deposits are mainly distributed in the Ashele, Kelan, Maizi, and Kalatag ore dense districts of the Altay and the East Tianshan. The orebodies occurr in marine volcanic sedimentary rocks from the Lower-Middle Silurian Hongliuxia Formation, the Upper Silurian-Lower Devonian Kangbutiebao Formation, the Lower-Middle Devonian Ashele Formation, and the Lower Carboniferous Xiaorequanzi Formation. Exhalation rocks are developed in these ore districts, such iron-bearing jasper rock, barite, siliceous rock, ferromanganese marble, pyrite layer, and chlorite rock. There are many mineralization types developed in VMS metallogenic system, including the "two-layered structure" (layered/lenticular type and vein type from recharge zone), vein type related to volcanic hydrothermal fluids, and disseminated/vein type associated with sub-volcanic hydrothermal fluids. The VMS deposits in Xinjiang formed in three metallogenic periods: the Early-Middle Silurian (428-438 Ma), the Early-Middle Devonian (379-413 Ma), and Early Carboniferous (332-359 Ma). Sulfur of these deposits is derived from the underlying volcanic rock, inorganic sulfate reduction of seawater, and bacterial sulfate reduction. Ore-forming fluids are characterized by medium-low temperature (300-120 ℃) and low salinity (2%-10% NaCleq), and are deep-circulation seawater mixed with magmatic water in different proportions. The VMS metallogenic system is affected by volcanic structure, lithofacies, mineralization type, ore-forming fluids source, and physical-chemical condition, which results in a complex combination of mineralization elements.
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Key words:
- mineral deposits /
- geological characteristics /
- VMS deposit /
- metallogeny /
- Central Asian Orogenic Belt /
- Xinjiang
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图 1 新疆阿尔泰区域地质及主要VMS矿床分布略图
图据Yang et al.（2018a）；VMS矿床名称：1.萨尔朔克金多金属矿；2.阿舍勒铜锌矿；3.大东沟铅锌矿；4.乌拉斯钩多金属矿；5.铁木尔特铅锌铜多金属矿；6.塔拉特铅锌铁矿；7.哈克哈仁铅锌矿；8.铁列克萨依铅锌矿；9.可可塔勒铅锌矿；10.萨吾斯铅锌矿
Fig. 1. Simplified regional geological map of the Altay mountains, Xinjiang, showing the locations of important VMS deposits
图 3 卡拉塔格矿集区地质和铜多金属矿分布略图
图据Deng et al.（2020）和相关文献
Fig. 3. Regional geology and distribution of Cu-dominant deposits in the Kalatag ore dense district
图 5 阿舍勒铜锌矿Ⅰ和Ⅱ号矿化带9勘探线剖面
图据新疆哈巴河阿舍勒铜业股份有限公司，2019，阿舍勒铜矿深边部补充勘查年度报告修改
Fig. 5. Cross-section of No.9 prospecting line of the Ⅰ and Ⅱ mineralized zones in the Ashele Cu-Zn deposit
图 6 黄滩金铜锌矿区地质略图
图据新疆西拓矿业有限公司，2019，新疆哈密市黄滩金铜锌矿详查报告修改
Fig. 6. Geological sketch map of the Huangtan Au-Cu-Zn deposit
图 7 黄滩金铜锌矿勘探线剖面
图据新疆西拓矿业有限公司，2019，新疆哈密市黄滩金铜锌矿详查报告修改
Fig. 7. Cross-section of the Huangtan Au-Cu-Zn deposit
图 8 小热泉子铜锌矿Ⅰ和Ⅲ矿段地质略图
图据吐鲁番工企矿冶有限责任公司，2016，新疆吐鲁番小热泉子铜矿资源储量核实报告
Fig. 8. Geological sketch map of the No. Ⅰ and Ⅲ mining districts in the Xiaorequanzi Cu-Zn deposit
图 9 小热泉子铜锌矿Ⅲ矿段A⁃A’勘探线剖面
图据吐鲁番工企矿冶有限责任公司，2016，新疆吐鲁番小热泉子铜矿资源储量核实报告
Fig. 9. A⁃A' prospecting line of the No. Ⅲ mining district in the Xiaorequanzi Cu-Zn deposit
图 10 新疆北部VMS矿床年龄直方图
Fig. 10. Age histograms for the VMS deposits in the North Xinjiang
图 12 新疆北部VMS矿床黄铁矿中流体40Ar/36Ar-3He/4He关系
ASW据Burnard et al.（1999）；TAG据Zeng et al.（2001）；Wetar据Herrington et al.（2011）；阿舍勒铜锌矿据张志欣等（2014）；萨尔朔克金多金属矿据Yang et al.（2018e）；黄土坡矿段据柴凤梅等（2017）；乌拉斯沟多金属矿据Yang et al.（2021a）；黄滩金铜锌矿和小热泉子铜锌矿为本文数据
Fig. 12. 40Ar/36Ar-3He/4He diagram of the VMS deposits in the North Xinjiang
图 13 新疆北部VMS矿床硫同位素对比
铁木尔特据耿新霞等（2010）和Yu et al.（2019）；乌拉斯沟据卢琦园等（2018）和Yang et al.（2021a）；大东沟据刘敏等（2008）；塔拉特据本报告；苏普特据申茂德未刊资料；可可塔勒据王京彬等（1998）、Wan et al.（2010b）、Yu et al.（2020）；阿舍勒据陈毓川等（1996）、王登红（1996）、Wan et al.，2010a、Yang et al.（2018b）和本文；萨尔朔克据杨富全等（2015）和本文；红海‒黄土坡据毛启贵等（2015）和Cheng et al.（2020）；小热泉子据刘申态等（2011）和本文；黄滩据Zhang et al.（2022）
Fig. 13. Sulfur isotope correlation map of VMS deposits in northern Xinjiang
表 1 新疆北部主要VMS型矿床地质特征
Table 1. Geological characteristics of main VMS deposits in northern Xinjiang
矿床名称 矿种 成矿带 容矿岩系 侵入岩 矿体规模 矿体形态 矿石构造 金属矿物 非金属矿物 矿石品位 围岩蚀变 规模 资料来源 阿舍勒 Cu，Zn 阿尔泰南缘 阿舍勒组玄武岩、英安岩、流纹质凝灰岩 闪长岩、英安斑岩 矿化蚀变带14条，主矿体长900 m，枢纽倾伏长1 520 m，距地表埋深25~ 1 500 m，厚5~120 m 层状 （致密）块状、条带状、条纹状、斑杂状、稠密浸染状、浸染状、细脉状、网脉状 黄铁矿、黄铜矿、闪锌矿，次为方铅矿、锌砷黝铜矿、黝铜矿 石英、绢(白)云母、绿泥石、重晶石、方解石、白云石、长石 Cu 2.46%，Zn 2.93%，Pb 0.41%，Ag 18.37 g/t，Au 0.36 g/t，S 22.66% 硅化、黄铁绢英岩化、绿泥石化、绢云母化、碳酸盐化、青磐岩化 大型 陈毓川等，1996; 本文 萨尔朔克 Au, Cu, Zn, Pb 阿尔泰南缘 阿舍勒组凝灰岩 流纹斑岩、辉绿岩脉 蚀变带长247~500 m，宽50~220 m.矿体长91~490 m，厚0.69~81.00 m，最大垂深470 m 脉状、透镜状、不规则状 条带状、条纹状、块状、浸染状、细脉状、网脉状 黄铜矿、黄铁矿、方铅矿、闪锌矿、自然金，少量磁黄铁矿 石英、斜长石、绢云母、绿泥石、白云母、方解石、次闪石 平均Au 1.24~14.5 g/t，Cu 0.37%~2.2%，Zn 0.91%~11.19%，Pb 0.21%~2.12% 硅化、绢云母化、黄铁矿化、绿泥石化、绿帘石化 中型 杨富全等，2015及相关文献 铁木尔特 Pb, Zn，Cu，Fe 阿尔泰南缘 康布铁堡组上亚组第二岩性段大理岩、绿泥石英片岩、变钙质砂岩、层状矽卡岩 石英钠长斑岩脉、基性岩脉 矿体30个，长50~600 m，厚0.6~32.6 m，延深50~ 834 m 似层状、透镜状，与地层整合 致密块状、块状、浸染状、条带状、条纹状、细脉-浸染状、角砾状 方铅矿、闪锌矿、黄铜矿、磁黄铁矿、黄铁矿、磁铁矿、辉铜矿、辉铋矿、自然铋、毒砂 方解石、石英、长石、绿泥石、阳起石、透闪石、石榴石、角闪石、绿帘石、重晶石、萤石 平均Pb 0.16%~7.29%，Zn 0.49%~8.13%，Cu 0.12%~1.53%，Au 0.03~1.60 g/t，Ag 0.28~88.18 g/t，TFe 21.12%~33.97% 矽卡岩化、硅化 中型 Yang et al., 2021b及相关文献 塔拉特矿 Pb, Zn, Fe 阿尔泰南缘 康布铁堡组下亚组第二岩性段黑云母变粒岩、变晶屑凝灰岩、变火山角砾岩、大理岩和黑云母片岩 斜闪煌斑岩脉、辉绿岩脉 9个矿体，最大矿体长920 m，厚度0.41~10.88 m 层状、似层状、透镜状、脉状，与地层整合 致密块状、块状、细脉状、网脉状、条带状、纹层状、（稠密）浸染状、角砾状 （胶状）黄铁矿、（铁）闪锌矿、方铅矿、磁铁矿、赤铁矿，少量黄铜矿、磁黄铁矿、毒砂和微量辉钼矿 黑云母、角闪石、透辉石、石英、白云母、方解石、石榴石、绿帘石、绿泥石、阳起石 平均Pb 1.92%，Zn 2.19%，TFe 7.01%~14.74% 矽卡岩化（石榴石、绿帘石、阳起石、透闪石、绿泥石、黑云母）、硅化和碳酸盐化 中型 新疆维吾尔自治区有色地质勘查局七0六队, 2012, 新疆阿勒泰市塔拉特铁铅锌矿A2、A3、A4异常普查报告 大东沟 Pb，Zn 阿尔泰南缘 康布铁堡组上亚组第二岩性段变钙质砂岩、大理岩 未发现侵入岩 23个矿体，规模较大的3个矿体长300~600 m，厚0.34~9.75 m 似层状、透镜状 纹层状、块状、浸染状、条带状、细脉浸染状 主要为方铅矿、闪锌矿、黄铁矿、黄铜矿，少量磁铁矿、毒砂、磁黄铁矿 石英、长石、绢云母、黑云母、白云母、绿泥石、角闪石和方解石 Pb+Zn品位为1.43%~8.97%，局部Au 6.59 g/t 绢云母化、碳酸盐化、矽卡岩化、硅化、叶腊石化、高岭土化、黄铁矿化 中型 刘敏等，2008；Yang et al., 2021b及相关文献 乌拉斯沟 Zn，Cu，Fe 阿尔泰南缘 康布铁堡组上亚组第二岩性段绿泥石英片岩、变晶屑凝灰岩、大理岩、变钙质砂岩和变凝灰质砂岩 未发现侵入岩 16条主要矿体，长50~500 m，厚2.78~ 12.79 m，延深超过385 m 层状、透镜状 致密块状、块状、条带状、条纹状、浸染状、稠密浸染状、细脉状、网脉状、团块状 主要为磁铁矿、黄铁矿、闪锌矿、黄铜矿，少量方铅矿、磁黄铁矿 石英、方解石、绢云母、白云母、绿泥石、辉石、角闪石、透闪石、阳起石、绿帘石 平均品位Cu 0.12%~1.13 %，Zn 0.77%~2.10%，TFe 11.32%~23.26%，Au 0.12~0.37 g/t，Ag 1.69~4.45 g/t 硅化、绿泥石化、绿帘石化、阳起石化、绢云母化、方解石化、黄铁矿化 中型 Yang et al., 2021a及相关文献 可可塔勒 Pb，Zn 阿尔泰南缘 康布铁堡组上亚组变质粉砂岩、凝灰岩和热水沉积岩 次火山岩（花岗斑岩、石英斑岩）；花岗岩 11条主要矿体，长100~ 1 700 m，厚3.6~39.0 m，延深200~690 m 层状、似层状 块状、稠密浸染状、条带状、条纹状、稀疏浸染状、细脉状、网脉状 黄铁矿、磁黄铁矿、方铅矿、闪锌矿，次为毒砂、黄铜矿、硫锑矿、黝铜矿、斑铜矿、白铁矿 石英、长石、白云母、方解石、透辉石、铁铝榴石、黑云母、角闪石、绿帘石 Pb 1.51%，Zn 3.16% 钠化、钾化、绿泥石化、阳起石化、黑云母化、硅化 大型 王京彬等，1998 铁列克萨依 Pb，Zn 阿尔泰南缘 康布铁堡组上亚组变钙质砂岩、变凝灰岩、变质流纹岩 未发现侵入岩 6条矿体，长200~620 m, 厚0.61~ 6.90 m 层状、似层状 条带状、条纹状、浸染状 黄铁矿、磁黄铁矿、方铅矿、闪锌矿 石英、方解石 平均品位Pb+Zn 1.02%~4.58% 硅化 中型 申茂徳未刊资料 萨吾斯 Pb，Zn 阿尔泰南缘 康布尔堡组上亚组变质凝灰岩，变质钙质砂岩、变质流纹岩 流纹斑岩 2个矿化带，长1 200~ 2 600 m.矿体17个，厚1.2~15.32 m，延深70~400 m 脉状、透镜状、似层状 条带状、细脉状、浸染状 磁铁矿、黄铁矿、磁黄铁矿、闪锌矿、方铅矿、黄铜矿、毒砂 石榴石、石英、方解石、透闪石、黑云母、白云母 平均品位Pb+Zn 2.95%~3.99% 碳酸盐化、绢云母化、钠长石化、矽卡岩化 中型 刘国仁等，2010 阿克哈仁 Pb，Zn 阿尔泰南缘 康布铁堡组上亚组火山角砾岩、流纹岩、大理岩 流纹斑岩 15个矿体，长数十米至数百米，宽1~10 m 似层状、透镜状，板柱状 细脉状、浸染状 方铅矿，少量黄铁矿、闪锌矿 萤石、重晶石、石英、方解石 Pb 2.89%，Zn 0.13% 钾化、硅化、钠化 小型 王京彬等，1998 大桥 Pb，Zn，Fe 阿尔泰南缘 康布铁堡组上亚组凝灰岩、变质流纹岩、大理岩 花岗斑岩脉 主要矿体5条，矿体长60~100 m，宽6~32 m 似层状、透镜状 块状、细脉状、浸染状 方铅矿、闪锌矿、磁铁矿 石英、长石、黑云母 Pb 0.16%，Zn 0.11%~5.33%，Cu 0.16%~0.65%，TFe 22.15% 钾化、硅化、绢云母化、绿泥石化、绿帘石化 小型 王京彬等，1998 红海-黄土坡 Cu，Zn 卡拉塔格-小热泉子 下-中志留统红柳峡组凝灰岩、角砾凝灰岩 闪长玢岩、花岗闪长岩 2个蚀变带.主矿体长1 100 m，厚度0.75~ 52.74 m，平均15.53 m 似层状、透镜状、脉状 致密块状、块状、稠密浸染状、浸染状、条带状、条纹状、角砾状、细脉状、网脉状、团块状 黄铁矿、黄铜矿和闪锌矿，少量方铅矿、磁铁矿、银金矿、碲银矿、黝铜矿、砷黝铜矿、磁黄铁矿 石英、绢云母、白云母、绿泥石、重晶石，少量方解石、斜长石、绿帘石、阳起石 Cu 0.20%~22.02%，平均品位1.16%，Zn 0.50%~43.26%，平均品位1.68% 硅化、绢云母化、黄铁矿化、绿泥石化 中型 Deng et al., 2018；本文 黄滩 Au，Cu，Zn 卡拉塔格-小热泉子 下-中志留统红柳峡组凝灰岩、火山角砾岩、安山岩、沉凝灰岩 石英闪长岩 黄滩矿段矿体34个，长50~400 m，厚0.82~ 40.81 m，埋深20~420 m 似层状、透镜状、脉状 条带状、条纹状、致密块状、块状、稠密浸染状、浸染状、细脉状、网脉状 黄铁矿、黄铜矿、闪锌矿，少量方铅矿、磁黄铁矿、毒砂、硫锑铅矿、黝铜矿、自然金、银金矿、针碲金银矿 重晶石、石英、绢云母，少量碳酸盐、斜长石、绿泥石、白云母、角闪石 平均Au 1.13~4.07g/t，Cu 0.12%~1.72%，Zn 0.12%~4.49%，Ag 1.29~47.85 g/t 硅化、黄铁矿化、绢云母化、青磐岩化 中型 新疆西拓矿业有限公司, 2019, 新疆哈密市黄滩金铜锌矿详查报告 小热泉子 Cu，Zn 卡拉塔格-小热泉子 下石炭统小热泉子组凝灰岩、安山岩、英安岩、凝灰质砂岩 英安斑岩、流纹斑岩、钠长斑岩 3个矿段，88条矿体，长50~500 m，厚1.66~32.52 m 似层状、透镜状 条带状、条纹状、块状、浸染状、细脉状、网脉状 黄铁矿、黄铜矿、闪锌矿、方铅矿、磁黄铁矿、黝铜矿 石英、绢云母、绿泥石、重晶石、长石、方解石 平均Cu 0.52%~ 1. 61%，Zn 0.44%~1.92%，Au 0.31~4.86 g/t 绿泥石化、硅化、黄铁矿化 中型 吐鲁番工企矿冶有限责任公司, 2016, 新疆吐鲁番小热泉子铜矿资源储量核实报告 
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表 2 新疆北部VMS型矿床年代学数据
Table 2. Summary of geochronological data for VMS deposits in North Xinjiang
矿床名称 岩石或矿石 测试方法 年龄(Ma) 资料来源 阿舍勒铜锌矿Ⅰ号矿化带 凝灰岩 锆石LA-ICP-MS U-Pb法 387.0 ± 4.2 Yang et al., 2014 玄武岩 锆石LA-ICP-MS U-Pb法 388.0 ± 3.3 Yang et al., 2014 层状矿体矿石 黄铁矿Re-Os法 389.1±9.9 笔者未刊资料 脉状矿体矿石 黄铁矿、黄铜矿Re-Os法 395.6±8.4 笔者未刊资料 阿舍勒铜锌矿Ⅱ号矿化带 流纹岩 锆石LA-ICP-MS U-Pb 394.1±3.1 Yang et al., 2018a 阿舍勒铜锌矿Ⅴ号矿化带 英安斑岩 锆石LA-ICP-MS U-Pb 379.4±0.8 Yang et al., 2014 萨尔朔克金多金属矿 流纹斑岩 锆石LA-ICP-MS U-Pb 382.8±1.7 Yang et al., 2014 流纹斑岩 锆石LA-ICP-MS U-Pb 386.2±1.5 沈雪华等，2016 流纹斑岩 锆石LA-ICP-MS U-Pb 384.0±1.2 Gao et al., 2020 凝灰岩中脉状矿石 黄铜矿Re-Os法 388±17 杨成栋未刊资料 凝灰岩中脉状矿石 闪锌矿Rb-Sr法 387±21 杨成栋未刊资料 流纹斑岩中脉状矿石 黄铜矿Re-Os法 385.9±9.1 杨成栋未刊资料 流纹斑岩中脉状矿石 黄铜矿Re-Os法 383±11 Gao et al., 2020 大东沟铅锌矿 变质流纹岩 锆石LA-ICP-MS U-Pb法 400.7±1.6 耿新霞等，2012 变质流纹岩 锆石LA-ICP-MS U-Pb法 388.9±3.2 耿新霞等，2012 变质流纹岩 锆石LA-ICP-MS U-Pb法 396.7 ± 1.4 单强等，2012 变质凝灰岩 锆石LA-ICP-MS U-Pb法 397.1±4.5 Zheng et al., 2015 变质凝灰岩 锆石LA-ICP-MS U-Pb法 391.1±4.2 Zheng et al., 2015 矿石 闪锌矿和黄铁矿Rb-Sr法 392±4 Yang et al., 2021b 铁木尔特多金属矿 变质流纹岩 锆石SHRIMP U-Pb法 402.0±6.6 单强等，2011 变质凝灰岩 锆石LA-ICP-MS U-Pb法 405±5 郑义等，2013 变质凝灰岩 锆石LA-ICP-MS U-Pb法 396±5 郑义等，2013 矿石 闪锌矿和黄铁矿Rb-Sr法 394.2±3.7 Yang et al., 2021b 乌拉斯沟多金属矿 变质凝灰岩 锆石LA-ICP-MS U-Pb法 397.9±2.8 Yang et al., 2021a 矿石 闪锌矿和黄铁矿Rb-Sr法 391.3±2.7 Yang et al., 2021b 塔拉特铅锌铁矿 变质流纹岩 锆石SHRIMP U-Pb法 408.7±5.3 Chai et al., 2009 变质流纹岩 锆石SHRIMP U-Pb法 412.6±3.5 Chai et al., 2009 浅粒岩 锆石LA-ICP-MS U-Pb法 405.5±0.7 Yang et al., 2018a 可可塔勒铅锌矿 变质流纹岩 锆石LA-ICP-MS U-Pb法 410.5±1.3 Yang et al., 2018c 变质英安岩 锆石LA-ICP-MS U-Pb法 394.8±1.9 Yang et al., 2018c 变质流纹岩 锆石LA-ICP-MS U-Pb法 400.8±8.4 单强等，2011 矿石 闪锌矿Rb-Sr法 398.2±3.3 Yang et al., 2018c 铁列克萨依铅锌矿 变质流纹岩 锆石LA-ICP-MS U-Pb法 400.4±2.1 柴凤梅等，2012 萨吾斯铅锌矿 变质流纹岩 锆石SIMS U-Pb法 401.0±2.7 刘伟等，2014 变质流纹岩 锆石LA-ICP-MS U-Pb法 386.0±2.3 Yang et al., 2018a 红海-黄土坡铜锌矿 含角砾凝灰岩 锆石LA-ICP-MS U-Pb法 423.3±2.9 Cheng et al., 2020 酸性火山熔岩 锆石SIMS U-Pb法 416.3±5.9 毛启贵等，2010 凝灰岩 锆石U-Pb法 440.4±2.9 Deng et al., 2016 英安岩 锆石LA-ICP-MS U-Pb法 440.1±1.2 Chai et al., 2019 安山岩 锆石LA-ICP-MS U-Pb法 439.7±0.9 Chai et al., 2019 凝灰岩 锆石LA-ICP-MS U-Pb法 442.0±1.1 Chai et al., 2019 层状矿体矿石 黄铁矿Re-Os法 427.9 ±5.5 Yang et al., 2018d 层状矿体矿石 黄铜矿Re-Os法 429.5±10.0 Cheng et al., 2020 层状矿体矿石 黄铜矿Re-Os法 434.2±3.9 Deng et al., 2016 层状矿体矿石 黄铁矿Re-Os法 436.1±2.3 Mao et al., 2019 矿石 硫化物Rb-Sr法 432.2 ±3.1 Yang et al., 2018d 黄铁绢云岩 绢云母Ar-Ar法 438.8 ±3.0 Deng et al., 2018 黄铁绢云岩 绢云母K-Ar法 424±7 毛启贵等，2010 红石铜矿 流纹斑岩 锆石SHRIMP U-Pb法 439±7 龙灵利等，2017 矿石 黄铜矿Re-Os法 431.8±2.7 Deng et al., 2016 黄铁绢云岩 绢云母Ar-Ar法 446.4±4.6 Deng et al., 2018 黄铁绢云岩 绢云母Ar-Ar法 441.5±3.2 Deng et al., 2018 黄滩金铜锌矿 英安岩 锆石LA-ICP-MS U-Pb法 434.3±3.1 笔者未刊资料 凝灰岩 锆石LA-ICP-MS U-Pb法 438.2±5.7 Sun et al., 2020 层状矿体矿石 黄铜矿Re-Os法 430±15 Zhang et al., 2022 脉状矿体矿石 黄铁矿Re-Os法 436.5±4.2 耿新霞等，2022 脉状矿体矿石 黄铁矿Re-Os法 437.9±6.6 Sun et al., 2020 小热泉子铜锌矿 凝灰质砂岩 锆石LA-ICP-MS U-Pb法 357.3 ± 2.4 Mao et al., 2020 凝灰岩 锆石LA-ICP-MS U-Pb法 354.5±3.9 张志欣未刊资料 凝灰质砂岩 锆石LA-ICP-MS U-Pb法 352.5±4.4 张志欣未刊资料 英安斑岩 锆石LA-ICP-MS U-Pb法 341.9±3.1 张志欣未刊资料 钠长斑岩 锆石LA-ICP-MS U-Pb法 331.6±6.6 张志欣未刊资料 英安岩 锆石LA-ICP-MS U-Pb法 359.5 ± 3.4 Mao et al., 2020 矿化花岗斑岩 锆石LA-ICP-MS U-Pb法 354.7 ± 3.2 Mao et al., 2020 矿石 黄铜矿Re-Os法 354 ± 11 Mao et al., 2020 矿石 硫化物Rb-Sr法 358.6±2.8 张志欣未刊资料 矿石 黄铜矿Re-Os法 355.3±5.7 张志欣未刊资料
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