Petrogeochemical Characteristics and Tectonic Significance of Middle Jurassic Intrusive Pluton in Xiajiabao Area, Qingyuan, Northern Liaoning
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摘要: 辽北清原地区位于华北板块北缘东段，是研究古太平洋构造域的典型地区之一.研究区中生代岩浆岩的成因及构造背景对认识古太平洋构造域的演化具有重要意义.本次研究对清原夏家堡地区辉长苏长岩、石英闪长岩和花岗闪长岩进行了锆石U-Pb年代学和岩石地球化学分析.锆石U-Pb测年结果表明，辉长苏长岩形成于中侏罗世晚期（（163.8±2.4）Ma），石英闪长岩形成于中侏罗世中期（（169.9±2.2）Ma），花岗闪长岩形成于中侏罗世中期（169.9~167.3 Ma）.岩石地球化学特征上，辉长苏长岩和石英闪长岩属于钙碱性系列岩石，具有低硅、富铝、高镁及较高的Mg#，弱富集轻稀土元素（LREEs），富集Rb、Ba、K、Sr等大离子亲石元素（LILEs），亏损Nb、Ta等高场强元素（HFSEs），Eu呈微弱的正异常或无异常；花岗闪长岩具有较高的硅、铝和全碱含量，具有高钾钙碱性I型花岗岩地球化学特征，Sr/Yb值较高，Eu具弱的负异常，富集LREEs和LILEs（Rb、K、Ba等），亏损HFSEs（Nb、Ta等）.上述地球化学特征表明辉长苏长岩和石英闪长岩的原始岩浆应起源于受俯冲板片析出流体所交代的岩石圈地幔部分熔融；花岗闪长岩是俯冲背景下受流体交代的下地壳基性火成岩部分熔融的产物.结合区域构造演化史和区域岩浆活动时空分布规律，认为辽北清原夏家堡地区中侏罗世侵入体的形成与古太平洋板块的俯冲作用有关.Abstract: Qingyuan area in northern Liaoning, located at the eastern segment of the northern margin of the North China Craton, is one of the typical areas to study the paleo-Pacific ocean tectonic domain. The petrogenesis and tectonic setting of Mesozoic magmatic rocks in the study area are of great significance for understanding the evolution of the paleo-Pacific tectonic domain. This study focuses on the zircon U-Pb geochronology and geochemistry of gabbronorite, quartz diorite and granodiorite in the Xiajiapu area of Qingyuan. Zircon U-Pb dating results show that gabbronorite, quartz diorite and granodiorite were emplaced in the (163.8±2.4) Ma, (169.9±2.2) Ma and 169.9-167.3 Ma respectively. Geochemical characteristics of Gabbronorite and quartz diorite show that they have low SiO2 content, high Al2O3 content and high Mg# value, which are typical of the calc-alkaline series. Samples are weakly enriched in LREEs and enriched in LILEs (e.g., Rb, Ba, K, Sr) and depleted in HFSEs (e.g., Nb, Ta, ), and Eu shows weak positive or no anomaly; Granodiorite shows a high content of SiO2, Al2O3 and total-alkali, which is typical of the high-K calc-alkaline Ⅰ-type granite. Samples have high Sr/Yb values and weak Eu negative anomalies, and they are enriched in LREEs and LILEs (e.g., Rb, K and Ba) and depleted in HREEs and HFSEs (e.g., Nb, Ta). Based on these data, we conclude that primary magma of gabbronorite and quartz diorite is likely derived from partial melting of lithospheric mantle, which is metasomatized by fluid from subducted oceanic slab. Granodiorite is derived mainly from partial melting of mafic rocks in lower crust, which is metasomatized by fluid. Combining with regional tectonic evolution and spatial distribution of magmatic activity, we suggest that the origin of Middle Jurassic intrusive rocks in Xiajiapu area, Qingyuan, northern Liaoning might be related to the subduction of paleo-Pacific plate.
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Key words:
- paleo Pacific /
- Ⅰ type granite /
- petrogenesis /
- Middle Jurassic /
- intermediate mafic intrusive rock /
- petrology /
- geochemistry
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图 2 清原夏家堡一带区域地质图及采样位置
底图据辽宁省地质矿产调查院, 2017, 辽宁1∶5万夏家堡、猴石、北三家、清原县幅区域地质矿产调查报告修改
Fig. 2. Regional geological map of the Xiajiabao region, Qingyuan with sampling location
图 3 清原夏家堡不同类型岩石野外照片和镜下照片
a.辉长苏长岩野外露头；b和c.花岗闪长岩和石英闪长岩野外露头；d~g.辉长苏长岩镜下照片；e~h.石英闪长岩镜下照片；f~i.花岗闪长岩镜下照片. Pl.斜长石；Qz.石英；Bi.黑云母；Hy.紫苏辉石；Aug.普通辉石；Hb.角闪石；Chl.绿泥石；（+）.正交偏光镜；（-）.单偏光镜
Fig. 3. The outcrop photographs and photomicrographs of different types rock in Xiajiabao area, Qingyuan
图 4 清原地区夏家堡侵入岩的锆石阴极发光(CL)图像
Fig. 4. Cathodoluminescence images (CL) of representative zircons for Xiajiabao intrusive rocks in Qingyuan
图 5 清原地区夏家堡一带不同类型岩石的U-Pb年龄谐和图
Fig. 5. Zircon U-Pb concordia diagrams for different types rock in Xiajiabao aera, Qingyuan
图 8 夏家堡地区中基性侵入岩成因判别图解及构造判别图解
a. TFeO-MgO-Al2O3图解，据Pearce and Gale（1977）、Jia et al.（2022）修改；1.扩张性中央岛；2.岛弧及活动大陆边缘；3.洋中脊玄武岩；4.洋岛玄武岩；5.大陆玄武岩；b. K2O-TiO2-P2O5图解，据Pearce et al.（1975）修改；c. La/Nb-Ba/Nb图解，底图据张超等（2020）；d. La/Yb-Nb/Y图解，底图据张超等（2020）. MORB.洋中脊玄武岩；OIB.洋岛玄武岩；Dupal OIB. Doupal洋岛玄武岩
Fig. 8. Petrogenetic and Tectonic discrimination diagrams of intermediate-mafic intrusive rocks in Xiajiabao area.
图 9 夏家堡地区花岗闪长岩成因判别图解
a.（K2O+Na2O）/CaO-（Zr+Nb+Ce+Y）图解；b. TFeO/MgO-（Zr+Nb+Ce+Y）图解；c. Zr-10 000 Ga/Al图解；d. Nb-10 000 Ga/Al图解，据Whalen et al.（1987）修改；e. K2O-Na2O图解，底图据曹花花（2013）修改；f. Sr/Yb图解，据张旗等（2006）修改. FG.高分异I、S、M型花岗岩；OTG.未分异I、S、M型花岗岩. 黄泥冷岩体数据王广伟等（2018）；李家台岩体数据刘锦（2017）
Fig. 9. Petrogenetic discrimination diagrams of granodiorite in Xiajiabao area.
图 10 华北克拉通北缘东段侏罗纪岩浆活动分布
底图据关庆彬（2018）修改；年龄数据孙德有等(2005a, 2005b)、张艳斌等（2002）、Miao et al.（2005）、Gao et al.（2007）、Ge et al.（2007）、张春艳等（2007）、许文良等(2008, 2013)、赵院冬等（2009）、Wu et al.（2011）、武鹏飞等（2013）、张超等（2014）、Zhang et al.（2016）、顾承串等（2016）、王超等（2016）、刘锦（2017）、王广伟等（2018）、关庆彬（2018）、任永健（2019）、王聚胜等（2019）、张笑鸣（2021）、张立仕等（2021）
Fig. 10. Distribution of Jurassic magmatic rocks in the eastern part of the northern margin of the North China Craton
图 11 清原夏家堡花岗闪长岩构造判别图解
底图据Pearce et al.（1984）修改；VAG.火山弧花岗岩；syn-COLG.同碰撞花岗岩；WPG.板内花岗岩；ORG.洋中脊花岗岩. 黄泥冷岩体数据据王广伟等（2018）；李家台岩体数据据刘锦（2017）
Fig. 11. Tectonic discrimination diagrams of Xiajiabao grandiorite
表 1 辽北清原地区夏家堡侵入体LA⁃IPC⁃MS锆石U⁃Pb同位素分析结果
Table 1. LA-ICP-MS zircon U-Pb dating results for the Xiajiabao pluton in the Qingyuan area, Northern Liaoning
样品号 Th U Th/U 同位素比值 年龄(Ma) （10-6） 207Pb/
206Pb1σ 207Pb/
235U1σ 206Pb/
238U1σ 207Pb/
206Pb1σ 207Pb/
235Pb1σ 206Pb/
238U1σ 21QY01-01 70 117 0.60 0.049 5 0.004 8 0.180 6 0.017 0 0.026 5 0.000 9 170 146 169 15 169 6 21QY01-02 87 158 0.55 0.049 8 0.006 2 0.205 2 0.024 7 0.029 9 0.001 2 186 194 190 21 190 8 21QY01-03 89 164 0.54 0.050 7 0.006 5 0.198 2 0.024 8 0.028 4 0.001 2 227 201 184 21 180 8 21QY01-04 40 80 0.50 0.050 2 0.006 8 0.175 7 0.023 0 0.025 4 0.001 1 205 213 164 20 162 7 21QY01-05 74 145 0.51 0.052 6 0.005 7 0.187 1 0.019 6 0.025 8 0.001 0 311 167 174 17 164 6 21QY01-06 300 847 0.35 0.049 4 0.002 5 0.171 4 0.008 7 0.025 2 0.000 7 166 68 161 8 160 4 21QY01-07 14 69 0.20 0.049 7 0.008 5 0.200 6 0.033 2 0.029 2 0.001 5 183 266 186 28 186 9 21QY01-08 72 160 0.45 0.048 3 0.004 9 0.175 1 0.017 4 0.026 3 0.000 9 116 156 164 15 167 6 21QY01-09 92 143 0.65 0.048 7 0.004 7 0.180 0 0.017 1 0.026 8 0.000 9 134 148 168 15 170 6 21QY01-10 92 196 0.47 0.049 2 0.004 3 0.168 8 0.014 4 0.024 9 0.000 8 158 132 158 13 158 5 21QY01-11 68 157 0.44 0.049 8 0.004 7 0.179 3 0.016 4 0.026 1 0.000 9 184 142 167 14 166 6 21QY01-12 37 85 0.43 0.053 0 0.006 3 0.187 7 0.021 8 0.025 7 0.001 0 327 189 175 19 164 6 21QY01-13 102 156 0.66 0.049 2 0.004 8 0.179 4 0.017 0 0.026 4 0.000 9 159 148 168 15 168 6 21QY01-14 71 128 0.56 0.049 0 0.005 5 0.176 7 0.019 3 0.026 2 0.001 0 147 174 165 17 166 6 21QY01-15 32 73 0.44 0.049 3 0.006 3 0.181 6 0.022 8 0.026 7 0.001 0 163 211 169 20 170 6 21QY01-16 81 171 0.47 0.049 6 0.004 3 0.174 9 0.014 9 0.025 5 0.000 8 178 133 164 13 163 5 21QY01-17 138 214 0.65 0.049 1 0.005 0 0.168 1 0.016 7 0.024 8 0.000 9 153 156 158 15 158 6 21QY01-18 42 100 0.42 0.049 0 0.005 6 0.174 7 0.019 6 0.025 8 0.000 9 148 183 163 17 164 6 21QY01-19 308 738 0.42 0.051 4 0.002 3 0.184 2 0.008 3 0.026 0 0.000 7 260 57 172 7 165 4 21QY01-20 76 119 0.64 0.050 7 0.009 4 0.171 7 0.031 1 0.024 6 0.000 9 228 350 161 27 156 6 21QY01-21 158 211 0.75 0.050 3 0.006 6 0.171 8 0.022 0 0.024 8 0.000 8 209 281 161 19 158 5 21QY01-22 77 120 0.64 0.049 5 0.007 4 0.180 2 0.026 0 0.026 4 0.001 2 173 237 168 22 168 7 21QY01-23 33 82 0.340 0.049 9 0.008 5 0.178 8 0.029 6 0.026 0 0.001 2 191 267 167 26 165 8 21QY01-24 264 436 0.61 0.049 8 0.003 0 0.180 3 0.010 6 0.026 3 0.000 7 187 86 168 9 167 5 21QY01-25 39 79 0.50 0.049 9 0.008 8 0.203 2 0.034 8 0.029 5 0.001 5 191 272 188 29 188 9 21QY02-01 549 291 1.89 0.049 1 0.002 6 0.184 3 0.009 8 0.027 2 0.000 8 152 71 172 8 173 5 21QY02-02 620 374 1.67 0.049 8 0.002 4 0.186 5 0.009 2 0.027 1 0.000 8 187 64 174 8 173 5 21QY02-03 290 217 1.33 0.049 4 0.003 4 0.177 1 0.012 2 0.026 0 0.000 8 165 100 166 11 166 5 21QY02-04 89 82 1.09 0.047 9 0.005 8 0.173 7 0.020 5 0.026 3 0.001 0 96 190 163 18 167 6 21QY02-05 158 130 1.22 0.048 6 0.005 4 0.182 0 0.019 9 0.027 2 0.001 1 127 172 170 17 173 7 21QY02-06 154 130 1.19 0.049 0 0.004 4 0.182 0 0.016 1 0.026 9 0.000 9 147 135 170 14 171 6 21QY02-07 159 138 1.15 0.049 1 0.005 5 0.183 1 0.020 0 0.027 1 0.001 0 151 174 171 17 172 7 21QY02-08 184 135 1.35 0.049 4 0.003 8 0.186 6 0.014 3 0.027 4 0.000 9 167 114 174 12 174 6 21QY02-09 88 121 0.73 0.049 1 0.004 2 0.179 0 0.015 1 0.026 5 0.000 9 151 128 167 13 168 6 21QY02-10 224 127 1.75 0.048 9 0.006 0 0.181 9 0.022 0 0.027 0 0.001 1 142 196 170 19 172 7 21QY02-11 389 212 1.82 0.049 5 0.004 1 0.187 6 0.015 2 0.027 5 0.000 9 170 122 175 13 175 6 21QY02-12 1 054 425 2.50 0.049 2 0.002 2 0.181 0 0.008 4 0.026 7 0.000 7 159 59 169 7 170 5 21QY02-13 355 218 1.61 0.049 5 0.003 1 0.178 1 0.011 3 0.026 1 0.000 8 170 90 166 10 166 5 21QY02-14 1 362 692 1.96 0.054 1 0.002 1 0.199 8 0.008 2 0.026 8 0.000 7 376 46 185 7 170 5 21QY02-15 282 188 1.49 0.049 6 0.003 6 0.184 7 0.013 2 0.027 0 0.000 9 174 105 172 11 172 5 21QY02-16 169 153 1.11 0.049 7 0.003 4 0.179 9 0.012 3 0.026 3 0.000 8 180 101 168 11 167 5 21QY02-17 198 138 1.43 0.048 9 0.004 7 0.176 0 0.016 7 0.026 1 0.000 9 144 147 165 14 166 6 21QY02-18 30 43 0.69 0.049 6 0.008 7 0.186 9 0.031 9 0.027 3 0.001 3 178 273 174 27 174 8 21QY02-19 895 408 2.17 0.049 6 0.002 6 0.182 0 0.009 8 0.026 6 0.000 8 177 73 170 8 169 5 21QY02-20 292 209 1.39 0.045 0 0.002 7 0.165 2 0.009 9 0.026 6 0.000 8 ‒20 74 155 9 169 5 21QY02-21 558 330 1.70 0.049 4 0.002 5 0.181 3 0.009 5 0.026 6 0.000 8 168 71 169 8 169 5 21QY02-22 1 225 445 2.78 0.049 0 0.002 0 0.180 6 0.007 7 0.026 8 0.000 7 147 53 169 7 170 5 21QY02-23 188 132 1.43 0.049 8 0.004 6 0.182 7 0.016 6 0.026 6 0.000 9 187 141 170 14 169 6 21QY02-24 269 164 1.64 0.051 4 0.005 3 0.187 4 0.018 7 0.026 4 0.001 0 261 159 174 16 168 6 21QY02-25 267 181 1.47 0.049 1 0.003 0 0.180 5 0.011 1 0.026 7 0.000 8 152 88 169 10 170 5 21QY04-01 230 158 1.45 0.060 1 0.004 7 0.218 7 0.016 7 0.026 4 0.000 9 606 108 201 14 168 6 21QY04-02 406 229 1.75 0.049 2 0.003 0 0.180 8 0.011 1 0.026 6 0.000 8 158 87 169 10 169 5 21QY04-03 509 259 1.96 0.048 6 0.002 8 0.178 9 0.010 2 0.026 7 0.000 8 128 78 167 9 170 5 21QY04-04 206 134 1.54 0.049 9 0.005 7 0.187 1 0.020 9 0.027 2 0.001 1 191 180 174 18 173 7 21QY04-05 280 185 1.52 0.049 1 0.003 5 0.180 6 0.012 9 0.026 7 0.000 8 153 106 169 11 170 5 21QY04-06 370 219 1.70 0.050 1 0.004 4 0.194 8 0.016 6 0.028 2 0.001 0 201 132 181 14 179 6 21QY04-07 583 294 1.96 0.048 9 0.002 5 0.179 3 0.009 2 0.026 6 0.000 7 143 70 167 8 169 5 21QY04-08 207 183 1.14 0.055 5 0.003 2 0.205 5 0.011 8 0.026 9 0.000 8 431 77 190 10 171 5 21QY04-09 664 332 2.00 0.049 2 0.002 4 0.179 2 0.008 9 0.026 4 0.000 7 156 66 167 8 168 5 21QY04-10 227 154 1.47 0.052 0 0.003 6 0.189 3 0.013 0 0.026 4 0.000 8 284 101 176 11 168 5 21QY04-11 187 105 1.79 0.050 7 0.011 4 0.213 9 0.047 3 0.030 6 0.001 7 225 336 197 40 195 10 21QY04-12 102 91 1.12 0.049 8 0.005 0 0.188 4 0.018 6 0.027 4 0.001 0 187 156 175 16 174 6 21QY04-13 236 203 1.16 0.055 5 0.003 6 0.201 9 0.013 1 0.026 4 0.000 8 433 91 187 11 168 5 21QY04-14 126 121 1.04 0.050 1 0.006 1 0.187 8 0.022 5 0.027 2 0.001 1 199 194 175 19 173 7 21QY04-15 220 171 1.28 0.050 5 0.003 1 0.186 7 0.011 4 0.026 8 0.000 8 219 87 174 10 171 5 21QY04-16 266 167 1.59 0.050 3 0.004 3 0.182 8 0.015 5 0.026 4 0.000 9 207 131 170 13 168 6 21QY04-17 372 208 1.78 0.049 7 0.003 1 0.178 9 0.011 4 0.026 2 0.000 8 180 92 167 10 166 5 21QY04-18 196 158 1.24 0.049 8 0.004 4 0.178 4 0.015 4 0.026 0 0.000 9 184 131 167 13 166 6 21QY04-19 117 105 1.12 0.052 2 0.008 8 0.184 7 0.030 5 0.025 6 0.001 0 296 344 172 26 163 6 21QY04-20 205 165 1.25 0.050 3 0.003 9 0.190 4 0.014 4 0.027 5 0.000 9 209 114 177 12 175 6 21QY04-21 425 246 1.72 0.055 6 0.003 6 0.203 5 0.013 2 0.026 6 0.000 8 434 90 188 11 169 5 21QY04-22 287 202 1.43 0.051 7 0.003 7 0.189 1 0.013 3 0.026 6 0.000 8 273 104 176 11 169 5 21QY04-23 338 202 1.67 0.049 4 0.003 5 0.182 5 0.012 9 0.026 8 0.000 8 167 104 170 11 171 5 21QY04-24 154 141 1.10 0.055 8 0.005 0 0.202 1 0.017 8 0.026 3 0.000 9 445 133 187 15 167 6 21QY04-25 251 186 1.35 0.049 3 0.003 1 0.187 4 0.012 0 0.027 6 0.000 8 163 92 174 10 176 5 21QY05-01 292 539 0.54 0.163 2 0.003 3 10.398 9 0.260 4 0.462 3 0.011 7 2 489 19 2 471 23 2 450 52 21QY05-02 325 199 1.64 0.050 1 0.004 2 0.189 0 0.015 5 0.027 4 0.000 9 198 125 176 13 174 6 21QY05-03 729 652 1.11 0.164 5 0.003 3 10.207 1 0.256 4 0.450 4 0.011 4 2 502 19 2 454 23 2 397 51 21QY05-04 288 193 1.49 0.055 2 0.003 4 0.199 0 0.012 0 0.026 2 0.000 8 421 83 184 10 166 5 21QY05-05 480 310 1.54 0.051 2 0.003 0 0.191 6 0.011 2 0.027 1 0.000 8 251 82 178 10 173 5 21QY05-06 855 543 1.59 0.050 3 0.002 3 0.175 3 0.008 2 0.025 3 0.000 7 207 59 164 7 161 4 21QY05-07 519 270 1.92 0.053 5 0.003 3 0.194 9 0.012 1 0.026 4 0.000 8 350 87 181 10 168 5 21QY05-08 61 126 0.48 0.165 4 0.003 9 10.408 9 0.285 5 0.456 7 0.011 9 2 511 21 2 472 25 2 425 53 21QY05-09 231 319 0.73 0.164 2 0.003 4 10.205 2 0.257 8 0.451 0 0.011 4 2 499 20 2 454 23 2 400 51 21QY05-10 235 175 1.33 0.046 1 0.007 6 0.166 1 0.026 8 0.026 2 0.001 0 577 290 156 23 166 6 21QY05-11 15 310 0.05 0.164 5 0.003 5 9.952 2 0.256 4 0.438 9 0.011 2 2 503 20 2 430 24 2 346 50 21QY05-12 226 200 1.12 0.165 3 0.003 5 10.803 0 0.276 0 0.474 1 0.012 1 2 511 20 2 506 24 2 502 53 21QY05-13 425 221 1.92 0.049 6 0.002 9 0.179 5 0.010 6 0.026 3 0.000 8 176 84 168 9 167 5 21QY05-14 238 372 0.64 0.160 3 0.007 2 9.709 4 0.348 0 0.439 3 0.011 8 2 459 77 2 408 33 2 347 53 21QY05-15 157 311 0.51 0.164 2 0.003 7 7.177 4 0.190 0 0.317 1 0.008 1 2 500 20 2 134 24 1 775 40 21QY05-16 417 252 1.67 0.049 8 0.003 7 0.175 9 0.012 8 0.025 6 0.000 8 184 108 165 11 163 5 21QY05-17 140 317 0.44 0.164 3 0.003 4 9.857 1 0.251 9 0.435 1 0.011 0 2 501 20 2 422 24 2 329 50 21QY05-18 258 269 0.96 0.165 1 0.003 6 10.972 5 0.288 1 0.482 0 0.012 4 2 509 20 2 521 24 2 536 54 21QY05-19 282 149 1.89 0.050 3 0.003 4 0.182 0 0.012 1 0.026 3 0.000 8 207 98 170 10 167 5 21QY05-20 607 348 1.75 0.051 3 0.003 0 0.191 7 0.011 3 0.027 1 0.000 8 252 83 178 10 173 5 21QY05-21 241 224 1.08 0.164 8 0.003 6 10.253 0 0.267 7 0.451 2 0.011 5 2 506 20 2 458 24 2 401 51 21QY05-22 259 164 1.59 0.050 7 0.003 3 0.183 7 0.011 8 0.026 3 0.000 8 227 93 171 10 167 5 21QY05-23 151 278 0.54 0.164 2 0.003 4 10.230 0 0.259 9 0.452 1 0.011 4 2 499 20 2 456 23 2 404 51 21QY05-24 319 307 1.04 0.165 0 0.003 4 10.096 5 0.255 9 0.443 8 0.011 2 2 508 19 2 444 23 2 368 50 21QY05-25 352 353 1.00 0.164 6 0.003 5 9.997 6 0.258 3 0.440 6 0.011 2 2 504 20 2 435 24 2 353 50 
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表 2 中侏罗世侵入体主量元素(%)和微量元素(10-6)分析结果
Table 2. Major elements (%) and trace elements (10-6) data for the Middle Jurassic pluton
样品号 21QY01 21QY02 21QY03 21QY04 21QY05 21QY06 SiO2 52.50 64.10 52.89 53.55 68.02 53.22 TiO2 0.87 0.51 1.01 0.98 0.41 0.65 Al2O3 15.74 16.54 18.99 18.79 14.93 17.73 Fe2O3 4.87 1.14 4.36 4.06 1.34 4.59 FeO 5.20 2.60 4.52 4.60 1.16 4.51 MnO 0.16 0.04 0.15 0.14 0.04 0.12 MgO 6.13 1.14 3.64 3.56 0.74 5.26 CaO 8.53 2.77 7.46 7.20 2.16 6.83 Na2O 3.01 4.58 4.47 4.31 3.83 3.86 K2O 0.83 3.40 0.79 1.06 4.30 0.83 P2O5 0.29 0.20 0.33 0.33 0.11 0.14 LOI 1.43 2.71 1.15 0.95 2.61 2.11 Total 99.55 99.72 99.75 99.51 99.64 99.86 A/CNK 0.74 1.02 0.87 0.88 1.00 0.90 A/NK 2.69 1.47 3.99 3.64 1.36 2.44 Mg# 56 38 47 47 38 55 La 18.12 38.19 17.26 19.10 22.71 12.48 Ce 38.45 78.15 38.87 44.19 44.08 26.70 Pr 4.85 8.68 5.08 5.71 4.69 3.30 Nd 18.27 30.13 21.07 23.40 15.59 13.04 Sm 4.11 5.41 4.69 5.14 2.68 2.86 Eu 1.34 1.46 1.66 1.69 0.69 1.03 Gd 3.87 4.84 4.57 4.88 2.39 2.68 Tb 0.52 0.67 0.65 0.72 0.30 0.39 Dy 2.66 3.17 3.28 3.65 1.51 1.97 Ho 0.56 0.69 0.69 0.78 0.32 0.42 Er 1.47 1.89 1.76 1.99 0.91 1.14 Tm 0.24 0.32 0.28 0.33 0.15 0.19 Yb 1.28 1.75 1.47 1.69 0.88 1.02 Lu 0.24 0.36 0.26 0.31 0.20 0.19 Y 18.52 20.95 17.95 19.98 8.99 10.98 LREE 85.14 162.02 88.63 99.22 90.44 59.41 HREE 10.83 13.69 12.97 14.34 6.67 7.99 LREE/HRE 7.86 11.83 6.84 6.92 13.57 7.44 REE 95.97 175.71 101.59 113.57 97.11 67.40 (La/Yb)N 9.54 14.68 7.89 7.64 17.37 8.27 (La/Sm)N 2.77 4.44 2.32 2.34 5.32 2.74 (Ce/Yb)N 7.77 11.52 6.82 6.78 12.93 6.78 δEu 1.01 0.86 1.09 1.02 0.82 1.12 δCe 0.97 1.00 0.99 1.01 0.98 0.98 Rb 78.36 74.88 13.79 17.19 67.02 27.29 Ba 361.90 887.50 457.20 530.30 538.60 346.80 Th 0.45 2.30 0.41 0.51 2.31 0.59 U 0.11 0.45 0.07 0.12 0.26 0.24 Nb 5.87 10.96 4.35 5.07 6.51 3.00 Ta 0.72 0.74 0.42 0.43 0.55 0.46 La 18.12 38.19 17.26 19.10 22.71 12.48 Ce 38.45 78.15 38.87 44.19 44.08 26.70 Sr 536.00 458.80 760.90 720.00 104.90 363.50 Nd 18.27 30.13 21.07 23.40 15.59 13.04 Sm 4.11 5.41 4.69 5.14 2.68 2.86 Zr 116.60 240.90 75.65 97.95 170.90 71.69 Hf 2.04 5.49 1.80 2.40 4.20 1.82 Tb 0.52 0.67 0.65 0.72 0.30 0.39 Y 18.52 20.95 17.95 19.98 8.99 10.98 P 1 263.14 859.03 1 453.10 1 419.49 459.43 615.27 Ti 5 227.94 3 033.33 6 075.81 5 883.54 2 463.62 3 898.72 K 6 909.28 28 197.70 6 519.65 8 773.21 35 667.59 6 902.51 Al 83 277.56 87 518.70 100 512.14 99 419.70 79 039.80 93 844.80
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