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    四川会理芭蕉箐地区钠长岩地球化学、年代学特征及其意义

    刘亚杰 徐争启 宋昊 李涛 张苏恒 姚建

    刘亚杰, 徐争启, 宋昊, 李涛, 张苏恒, 姚建, 2024. 四川会理芭蕉箐地区钠长岩地球化学、年代学特征及其意义. 地球科学, 49(3): 893-906. doi: 10.3799/dqkx.2022.231
    引用本文: 刘亚杰, 徐争启, 宋昊, 李涛, 张苏恒, 姚建, 2024. 四川会理芭蕉箐地区钠长岩地球化学、年代学特征及其意义. 地球科学, 49(3): 893-906. doi: 10.3799/dqkx.2022.231
    Liu Yajie, Xu Zhengqi, Song Hao, Li Tao, Zhang Suheng, Yao Jian, 2024. Geochemical and Chronological Characteristics and Significance of Albite in Bajiaojing Area, Huili, Sichuan. Earth Science, 49(3): 893-906. doi: 10.3799/dqkx.2022.231
    Citation: Liu Yajie, Xu Zhengqi, Song Hao, Li Tao, Zhang Suheng, Yao Jian, 2024. Geochemical and Chronological Characteristics and Significance of Albite in Bajiaojing Area, Huili, Sichuan. Earth Science, 49(3): 893-906. doi: 10.3799/dqkx.2022.231

    四川会理芭蕉箐地区钠长岩地球化学、年代学特征及其意义

    doi: 10.3799/dqkx.2022.231
    基金项目: 

    国家自然科学基金项目 41872079

    中国核工业地质局科研项目 202137-3

    成都理工大学珠峰科学研究计划项目 2021ZF11413

    四川省应用基础研究项目 2020YJ0361

    详细信息
      作者简介:

      刘亚杰(1995—),男,硕士研究生,主要从事矿床地球化学方面研究. ORCID:0000-0002-7872-1284. E-mail:chinaajie@qq.com

      通讯作者:

      徐争启, ORCID: 0000-0002-0266-149X. E-mail: 547510779@qq.com

    • 中图分类号: P597

    Geochemical and Chronological Characteristics and Significance of Albite in Bajiaojing Area, Huili, Sichuan

    • 摘要: 四川会理芭蕉箐地区位于康滇地轴中南段,是我国少有的元古宙产铀地区,其构造条件复杂,研究程度低,钠长岩作为本区重要的含铀岩石,对其更是鲜有报道,严重限制了进一步的铀矿勘查.在结合前人研究的基础上,通过对芭蕉箐地区1841铀矿化点的野外地质调查、钠长岩元素地球化学分析及锆石U-Pb年代学测试分析,发现研究区钠长岩分为岩浆钠长岩与交代钠长岩,样品富集Th、U、Zr、REE等元素,相对贫Ba、K、Sr、Rb等元素,测年结果显示两类钠长岩主要峰值年龄为~2.3 Ga与~1.8 Ga.钠长岩岩石来源主要为下地壳变质泥岩部分熔融且有幔源物质加入,形成于陆内拉张构造环境.其原岩的形成与2.4~2.3 Ga期间发生在扬子地台西南缘的碰撞事件有关,并在1.8 Ga左右经历岩浆作用形成钠长岩,同时铀元素在此处大量富集.其年代学数据记录的两次岩浆活动,是Columbia超大陆聚合在扬子地块西南缘的响应.

       

    • 图  1  研究区地质简图(据耿元生等,2017

      Fig.  1.  Simplified tectonic map of Bajiaojing area (modified after Geng et al., 2017)

      图  2  芭蕉箐1841铀矿化区钠长岩野外与镜下照片

      a和c. 岩浆成因钠长岩;b和d. 交代成因钠长岩;Tur. 电气石

      Fig.  2.  Field and microscopic photos of albitite in Bajiaojing 1841 uranium mineralization area

      图  3  芭蕉箐1841铀矿化区钠长岩微量元素蛛网图(a)与稀土元素分布型式(b)(据Sun and McDonough, 1989

      Fig.  3.  Spider map of trace elements (a) and ree distribution pattern (b) of albitite in Bajiaojing 1841 uranium mineralization area (modified after Sun and McDonough, 1989)

      图  4  样品DH01锆石U-Pb年龄谐和图(a)与年龄直方图(b)

      Fig.  4.  Zircon U-Pb age concordance diagram (a) and age histogram (b) of sample DH01

      图  5  交代钠长岩DH01锆石Th/U比值(据Vavra et al., 1999

      Fig.  5.  Zircon Th/U ratio of metasomatic albite DH01 (modified after Vavra et al., 1999)

      图  6  交代钠长岩DH01中锆石阴极发光照片和年龄(Ma)

      Fig.  6.  Cathodoluminescent (CL) images and age (Ma) of metasomatic albite DH01

      图  7  样品DB02锆石U-Pb年龄谐和图(a)和年龄直方图(b)

      Fig.  7.  Zircon U-Pb age concordance diagram (a) and age histogram (b) of sample DB02

      图  8  岩浆钠长岩DB02锆石Th/U比值(据Vavra et al., 1999

      Fig.  8.  Zircon Th/U ratio of magmatic albite DB02 (modified after Vavra et al., 1999)

      图  9  岩浆钠长岩DB02中锆石阴极发光照片和年龄(Ma)

      Fig.  9.  Cathodoluminescent (CL) images and age (Ma) of magmatic albite DB02

      图  10  芭蕉箐地区岩浆钠长岩AR-SiO2判别图解(底图据Wright, 1969

      Fig.  10.  AR vs SiO2 diagram for classification of magmatic albite in Bajiaojing (modified after Wright, 1969)

      图  11  岩浆钠长岩Yb+Ta-Rb构造环境判别图(底图据Pearce et al., 1984

      Fig.  11.  Yb+Ta-Rb discrimination diagram of tectonic setting for magmatic albite (modified after Pearce et al., 1984)

      图  12  芭蕉箐地区钠长岩A/MF-C/MF源区判别图解(底图据Altherr et al., 2000

      Fig.  12.  Distinguishing diagram of A/MF-C/MF source area of albite in Bashojing (modified after Altherr et al., 2000) A/MF. Al2O3/(FeOT+MgO); C/MF. CaO/(FeOT+MgO)

      表  1  钠长岩主量元素测试结果(%)

      Table  1.   Test results of major elements in albite (%)

      编号 MgO Al2O3 SiO2 P2O5 Na2O K2O CaO TiO2 MnO FeO Fe2O3 H2O LOI 总量 A/CNK A/NK Mg#
      DH04 0.61 18.18 59.10 0.37 8.87 0.70 0.41 3.21 0.22 0.38 4.57 0.40 1.77 98.79 1.82 1.90 19.59
      DB02 1.01 18.43 63.19 0.18 7.82 1.49 0.46 0.70 0.04 0.49 3.68 0.27 1.98 99.75 1.89 1.98 32.15
      DB03 1.30 16.62 62.91 0.29 7.63 1.17 1.48 1.53 0.09 1.30 2.54 0.34 2.73 99.94 1.62 1.89 39.28
      DB05 0.31 14.01 70.50 0.27 6.06 0.41 0.22 0.70 0.03 0.58 3.76 0.80 2.08 99.74 2.09 2.16 12.17
      DB07 0.57 16.70 62.87 0.36 6.14 0.85 0.32 0.79 0.02 0.55 5.30 1.78 3.49 99.74 2.29 2.39 16.15
      下载: 导出CSV

      表  2  钠长岩微量元素测试结果(10‒6

      Table  2.   Test results of trace elements in albite (10‒6)

      编号 Sc Ni V Cr Cu Ga Rb Sr Y Zr Nb Ba Hf Ta Pb Th U
      DH04 22.4 22.0 170 77.6 3 592 14.5 13.7 32.3 123.0 339.0 17.50 98.4 5.66 1.39 365.00 9.74 2 506.00
      DB02 37.6 15.7 260 128.0 10 107 25.2 32.3 72.5 167.0 1 640.0 6.57 237.0 12.90 0.76 1 383.00 20.70 1 520.00
      DB03 29.2 16.0 155 98.8 9 859 21.4 22.1 53.8 182.0 1 690.0 14.40 116.0 14.10 1.46 1484.00 25.00 1 950.00
      DB05 16.5 92.8 123 61.1 1 174 14.2 18.1 13.8 26.2 95.9 1.96 26.2 2.88 0.26 2.75 11.90 9.84
      DB07 14.6 138.0 129 60.9 1 859 26.4 30.0 26.5 53.1 135.0 3.29 38.0 4.09 0.40 13.70 9.74 12.80
      下载: 导出CSV

      表  3  钠长岩稀土元素测试结果(10‒6

      Table  3.   Test results of rare earth elements in albite (10‒6)

      编号 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ΣREE LREE/HREE (La/Yb)N δEu δCe
      DH04 40.00 114.0 17.20 77.5 26.50 10.10 31.70 5.76 29.80 5.14 11.00 1.24 6.38 0.78 377.10 3.11 4.50 1.06 1.06
      DB02 27.00 184.0 29.00 159.0 55.50 28.60 54.50 10.10 54.60 8.68 20.40 2.29 10.70 1.04 645.41 2.98 1.81 1.57 1.43
      DB03 25.70 188.0 29.10 149.0 54.10 27.30 54.10 9.73 53.50 8.57 19.90 2.28 10.70 1.07 633.05 2.96 1.72 1.53 1.48
      DB05 8.75 18.2 2.75 11.5 3.66 0.90 4.94 0.86 5.12 0.93 2.62 0.38 2.31 0.33 63.25 2.62 2.72 0.65 0.90
      DB07 215.00 398.0 49.90 161.0 26.00 3.67 25.40 2.75 10.80 1.79 5.33 0.64 3.67 0.52 904.47 16.77 42.02 0.43 0.91
      下载: 导出CSV

      表  4  交代钠长岩DH01锆石U-Pb同位素LA-ICPMS

      Table  4.   Zircon U-Pb isotope LA-ICPMS of metasomatic albitite DH01

      测点号 含量(10‒6) 同位素比值 同位素年龄(Ma)

      Th/U
      Th U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ
      DH01-01 112.73 444.57 0.14 0.002 7.08 0.119 0.38 0.003 1 876.9 27.8 1 820.2 14.2 1 768.7 14.8 96% 0.25
      DH01-02 259.61 427.82 0.24 0.004 13.87 0.388 0.42 0.009 3 088.6 24.4 2 741.0 26.6 2 271.5 41.8 81% 0.51
      DH01-03 233.19 317.45 0.11 0.002 5.01 0.084 0.32 0.003 1 901.9 39.4 1 882.3 17.2 1 869.0 17.9 97% 0.73
      DH01-05 234.42 456.47 0.15 0.002 8.15 0.134 0.40 0.004 1 879.6 27.0 1 875.7 16.9 1 872.9 17.2 96% 0.51
      DH01-06 182.57 269.52 0.15 0.002 8.78 0.160 0.43 0.005 1 898.2 30.9 1 892.1 16.5 1 875.4 21.5 99% 0.68
      DH01-07 78.85 93.04 0.12 0.002 5.38 0.108 0.34 0.004 1 901.9 39.4 1 882.3 17.2 1 869.0 17.9 99% 0.85
      DH01-08 77.70 108.08 0.11 0.002 5.29 0.119 0.34 0.004 1 854.0 41.2 1 867.7 19.2 1 880.9 20.4 99% 0.72
      DH01-09 303.20 231.72 0.11 0.002 5.34 0.105 0.34 0.004 1 879.6 27.0 1 875.7 16.9 1 872.9 17.2 99% 1.31
      DH01-10 237.26 155.15 0.11 0.002 5.31 0.106 0.34 0.004 1 854.0 31.5 1 870.9 17.1 1 884.4 18.0 99% 1.53
      DH01-11 127.18 267.35 0.15 0.002 8.99 0.168 0.43 0.005 2 180.6 27.8 2 121.6 15.0 2 057.9 16.0 99% 0.48
      DH01-12 178.54 220.29 0.11 0.002 5.30 0.090 0.34 0.003 1 854.0 29.2 1 868.9 14.5 1 882.8 16.2 99% 0.81
      DH01-13 76.62 184.84 0.17 0.003 11.25 0.189 0.49 0.005 2 283.3 28.1 2 278.4 18.1 2 275.4 29.2 98% 0.41
      DH01-14 105.39 188.86 0.12 0.002 5.82 0.103 0.35 0.004 2 190.7 28.2 2 241.5 16.6 2 286.2 22.8 99% 0.56
      DH01-15 304.42 457.28 0.14 0.002 8.43 0.167 0.42 0.006 2 352.8 27.5 2 336.6 17.2 2 315.3 21.5 99% 0.67
      DH01-16 163.96 286.41 0.19 0.003 13.44 0.262 0.53 0.007 2 309.3 31.6 2 315.1 16.7 2 319.0 20.6 99% 0.57
      DH01-17 174.21 161.88 0.18 0.003 13.30 0.241 0.53 0.006 2 339.8 25.3 2 337.7 14.1 2 325.6 18.4 99% 1.08
      DH01-18 136.12 274.35 0.15 0.003 8.97 0.156 0.44 0.005 2 347.8 25.6 2 344.6 14.9 2 330.5 21.2 99% 0.50
      DH01-19 130.62 269.82 0.19 0.003 14.68 0.237 0.54 0.005 2 329.3 29.3 2 334.9 16.0 2 335.9 20.7 99% 0.48
      DH01-20 206.31 335.00 0.15 0.002 9.00 0.137 0.43 0.004 2 538.9 33.3 2 556.5 20.2 2 568.7 33.0 99% 0.62
      DH01-21 114.50 241.79 0.15 0.002 9.07 0.147 0.44 0.005 2 520.1 26.1 2 544.3 15.8 2 573.9 21.7 99% 0.47
      DH01-22 94.97 152.15 0.14 0.002 8.09 0.148 0.43 0.005 2 684.9 29.9 2 701.2 17.2 2 720.5 24.3 98% 0.62
      DH01-23 119.80 227.31 0.12 0.002 5.45 0.104 0.34 0.004 1 898.2 30.9 1 892.1 16.5 1 875.4 21.5 99% 0.53
      DH01-24 73.25 103.01 0.17 0.003 11.40 0.246 0.49 0.008 2 783.0 25.5 2 794.6 15.5 2 800.3 23.0 99% 0.71
      下载: 导出CSV

      表  5  岩浆钠长岩DB02锆石U-Pb同位素LA-ICPMS

      Table  5.   Zircon U-Pb isotope LA-ICPMS of magmatic albitite DB02

      测点号 含量(10‒6 Th/U 同位素比值 年龄(Ma)

      Pb Th U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ
      DB02-01 25.7 232.0 238.0 0.97 0.136 0.001 8 6.802 0.144 0.361 0.006 8 2 181.2 22.5 2 086.0 18.8 1 988.6 32.4 95%
      DB02-02 47.1 17.0 56.6 0.30 0.111 0.001 2 4.936 0.069 0.323 0.004 2 1 813.0 19.6 1 808.5 11.8 1 805.6 20.5 99%
      DB02-03 30.9 84.9 89.9 0.94 0.106 0.001 8 3.821 0.185 0.257 0.010 9 1 736.1 31.5 1 597.3 39.0 1 472.5 56.0 91%
      DB02-04 88.1 48.9 109.0 0.45 0.113 0.001 0 3.555 0.071 0.227 0.004 2 1 850.0 15.7 1 539.5 15.8 1 321.3 21.8 84%
      DB02-05 150.1 86.4 315.1 0.27 0.168 0.003 0 5.503 0.403 0.231 0.014 7 2 538.9 29.6 1 901.1 63.0 1 338.8 77.1 65%
      DB02-06 188.6 182.4 446.0 0.41 0.141 0.001 8 7.959 0.217 0.415 0.013 7 2 243.5 21.9 2 226.4 24.6 2 239.1 62.2 99%
      DB02-07 121.6 177.7 394.5 0.45 0.114 0.001 2 4.890 0.062 0.311 0.004 2 1 864.8 13.9 1 800.5 10.8 1 745.7 20.7 96%
      DB02-08 128.1 37.2 356.8 0.10 0.107 0.001 1 4.676 0.078 0.315 0.004 8 1 766.7 18.4 1 763.0 14.0 1 767.0 23.7 99%
      DB02-09 119.8 131.0 326.9 0.40 0.108 0.001 5 4.661 0.140 0.314 0.010 7 1 773.2 25.2 1 760.3 25.1 1 762.7 52.4 99%
      DB02-10 89.2 258.0 236.8 1.09 0.114 0.001 0 5.252 0.072 0.335 0.004 7 1 862.0 15.7 1 861.1 11.8 1 860.9 22.6 99%
      DB02-11 153.7 70.5 217.6 0.32 0.112 0.001 1 5.033 0.273 0.328 0.017 4 1 825.6 16.8 1 824.8 45.9 1 828.8 84.4 99%
      DB02-12 200.0 395.7 272.3 1.45 0.167 0.004 3 10.092 1.082 0.477 0.063 4 2 532.4 44.0 2 443.3 99.1 2 514.5 276.6 97%
      DB02-13 104.0 217.9 585.2 0.37 0.098 0.002 6 3.704 0.447 0.272 0.032 3 1 577.5 48.9 1 572.2 96.4 1 552.2 163.6 98%
      DB02-14 212.2 477.6 560.1 0.85 0.103 0.002 3 3.985 0.379 0.293 0.033 1 1 680.6 41.2 1 631.1 77.3 1 657.6 164.9 98%
      DB02-15 90.0 163.2 952.7 0.17 0.091 0.001 9 2.915 0.369 0.252 0.035 8 1 455.6 39.4 1 385.7 95.8 1 448.2 184.3 95%
      DB02-16 116.3 143.7 484.3 0.30 0.103 0.001 9 4.063 0.299 0.292 0.021 3 1 677.5 39.8 1 646.9 60.0 1 653.0 106.3 99%
      DB02-17 161.5 119.2 407.9 0.29 0.126 0.002 6 6.429 0.324 0.382 0.025 3 2 038.9 4.6 2 036.3 44.3 2 084.7 118.2 97%
      DB02-18 169.2 136.6 415.0 0.33 0.117 0.002 3 5.536 0.345 0.347 0.027 0 1 916.7 34.9 1 906.2 53.6 1 919.2 129.3 99%
      DB02-19 147.7 165.7 422.4 0.39 0.105 0.001 6 4.405 0.199 0.310 0.018 6 1 718.2 23.1 1 713.3 37.5 1 738.9 91.8 98%
      DB02-20 98.3 190.4 426.7 0.45 0.123 0.002 8 4.071 0.218 0.238 0.013 7 2 005.9 45.2 1 648.6 43.8 1 377.6 71.3 82%
      DB02-21 115.0 123.6 303.1 0.41 0.139 0.002 3 3.126 0.139 0.166 0.008 5 2 220.7 28.9 1 439.1 34.3 989.8 47.0 63%
      DB02-22 182.4 195.1 462.8 0.42 0.144 0.002 4 7.714 1.116 0.420 0.066 9 2 270.1 27.9 2 198.3 130.0 2 261.0 303.8 97%
      DB02-23 79.9 294.6 812.6 0.36 0.105 0.001 6 4.409 0.094 0.306 0.005 6 1 710.8 27.9 1 714.1 17.7 1 718.9 27.6 99%
      DB02-24 156.6 122.1 183.4 0.67 0.106 0.002 3 4.420 0.118 0.308 0.009 5 1 733.0 38.9 1 716.2 22.0 1 729.9 46.8 99%
      DB02-25 70.9 134.6 463.8 0.29 0.058 0.001 2 0.634 0.051 0.079 0.006 1 531.5 46.3 498.9 31.7 492.0 36.5 98%
      DB02-26 53.0 829.7 579.9 1.43 0.109 0.001 8 4.067 0.096 0.271 0.005 5 1 781.2 29.6 1 647.8 19.3 1 543.7 27.9 93%
      DB02-27 73.9 101.4 122.5 0.83 0.110 0.001 6 3.676 0.121 0.240 0.006 5 1 802.2 25.8 1 566.2 26.4 1 388.0 33.8 87%
      DB02-28 49.1 96.7 225.3 0.43 0.112 0.001 6 4.455 0.143 0.287 0.007 9 1 825.6 25.3 1 722.6 26.6 1 625.6 39.4 94%
      DB02-29 9.8 47.5 151.0 0.31 0.054 0.001 4 0.377 0.020 0.050 0.001 7 390.8 62.0 325.0 14.6 311.8 10.5 95%
      DB02-30 58.3 81.4 153.4 0.53 0.058 0.000 8 0.510 0.008 0.064 0.000 7 522.3 31.5 418.7 5.7 401.3 4.3 95%
      DB02-31 92.4 512.9 636.5 0.81 0.107 0.001 3 3.443 0.172 0.231 0.011 2 1 749.7 22.1 1 514.2 39.4 1 341.7 58.4 87%
      DB02-32 31.0 120.3 317.0 0.38 0.055 0.001 2 0.310 0.019 0.040 0.001 5 413.0 48.1 274.6 14.8 251.2 9.6 91%
      DB02-33 103.4 386.1 649.0 0.60 0.098 0.003 9 2.094 0.185 0.138 0.009 3 1 588.9 74.4 1 146.9 60.6 832.2 52.7 68%
      DB02-34 119.0 135.4 1 080.2 0.13 0.112 0.001 4 5.042 0.083 0.327 0.005 6 1 832.4 22.2 1 826.3 14.1 1 822.5 27.3 99%
      DB02-35 98.2 344.5 140.6 2.45 0.156 0.006 4 7.922 1.417 0.446 0.085 0 2 416.7 68.7 2 222.2 161.3 2 376.7 378.8 93%
      下载: 导出CSV
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