高温地热流体中硼的地球化学研究进展

刘明亮; 正安婷; 尚建波; 郭清海

doi:10.3799/dqkx.2022.235

高温地热流体中硼的地球化学研究进展

doi: 10.3799/dqkx.2022.235

刘明亮^{1, 2, ,},
正安婷²,
尚建波²,
郭清海^{3, 4, ,}

1.
长江大学油气地球化学与环境湖北省重点实验室, 湖北武汉 430100
2.
长江大学资源与环境学院, 湖北武汉 430100
3.
中国地质大学自然资源部深部地热资源重点实验室, 湖北武汉 430078
4.
中国地质大学环境学院, 湖北武汉 430078

基金项目:

国家自然科学基金项目 41902257

宁夏回族自治区重点研发计划项目 2022BEG03060

自然资源部深部地热资源重点实验室开放基金项目 KLDGR2022G01

智慧长江与水电科学湖北省重点实验室开放基金项目 ZH2102000113

详细信息

作者简介:
刘明亮（1989—），男，副教授，主要从事地热领域的研究工作. ORCID：0000-0003-3545-8129. E-mail：lml2008@cug.edu.cn

通讯作者:
郭清海，E-mail: qhguo2006@gmail.com

中图分类号: P641.3
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出版历程
- 收稿日期: 2022-06-08
- 刊出日期: 2023-03-25

Progress in Study of Boron Geochemistry in High Temperature Geothermal Fluids

Liu Mingliang^{1, 2
,
,},
Zheng Anting²,
Shang Jianbo²,
Guo Qinghai^{3, 4
, ,}

1.
Hubei Key Laboratory of Petroleum Geochemistry and Environment, Yangtze University, Wuhan 430100, China
2.
College of Resources and Environment, Yangtze University, Wuhan 430100, China
3.
Key Laboratory of Deep Geothermal Resources, Ministry of Natural Resources, China University of Geosciences, Wuhan 430078, China
4.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China

摘要

摘要: 硼是高温地热流体中典型的特征元素之一，探讨其物质来源和富集规律，对认识地热系统的形成与演化以及地热资源的合理开发具有重要的指导意义.同时，硼也是一种典型的有害元素，伴随地热流体排放到地表后，会对地热区及周边环境造成严重的负面效应.近年来，在高温地热资源正在被大规模开发利用的背景下，高温地热流中硼的地球化学起源及其环境效应研究已引起国内外相关学者的广泛关注.本文综述了高温地热流体中硼的地球化学特征、物质来源以及环境地质效应，在此基础上总结了后期需要进一步加强的方向，以期为地热资源的合理开采、地热田周边地区的环境保护提供借鉴思路和指导作用.
- 地球化学 /
- 硼 /
- 环境效应 /
- 地热系统 /
- 高温地热流体
Abstract: Boron is one of the typical characteristic elements in high temperature geothermal fluids. Its origin and enrichment in geothermal fluids are of great significance to understanding the formation and evolution of geothermal system and the rational development of geothermal resources. At the same time, boron is one of the harmful elements, and will cause serious negative effects on the geothermal area and its surrounding environment as geothermal fluids discharged to the surface. In recent years, under the background of large-scale exploitation and utilization of high temperature geothermal resources, the origin of boron in high temperature geothermal fluids and its environmental effects have attracted extensive attention. In this paper, the geochemistry characteristics, sources and environmental geological effects of boron in geothermal fluids are reviewed, aiming to provide insights for the rational exploitation of geothermal resources and the environmental protection near the geothermal areas.
- geochemistry /
- boron /
- environmental effect /
- geothermal system /
- high temperature geothermal fluid

HTML全文

图 1 世界范围内典型高温地热系统地热水中B含量与δ¹¹B值关系

数据来源于Oi et al.（1996）、Aggarwal et al.（2000）、Vengosh et al.(2002, 1991)、Leeman et al.（2005）、Millot et al.(2007, 2012)、Bernard et al.（2011）、吕苑苑等（2014）、Yuan et al.（2014）、Zhang et al.（2015）、Battistel et al.（2016）、Wu et al.（2016）

Fig. 1. Plot of B concentration vs. δ¹¹B value of geothermal waters in typical high temperature geothermal systems worldwide

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图 2 西藏地热水中硼富集机制（改自Liu et al., 2019）

Fig. 2. Boron enrichment mechanisms of geothermal waters in Tibet (modified from Liu et al., 2019)

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表 1 世界范围内典型高温地热系统地热水中B含量和B同位素特征

Table 1. Boron concentrations and δ¹¹B values of geothermal waters in typical high temperature geothermal systems worldwide

典型地热区	采样温度（℃）	B（mg/L)	δ¹¹B(‰)	数据来源
新西兰Negwha地热田	38~180	259.2~1 101.6	‒3.8~‒3.2	Aggarwal et al., 2003
新西兰Taupo火山地热区	205~320	17.5~82.1	‒6.7~‒1.9	Bégué et al., 2017
法国Limagne盆地	12~73	0.6~6.9	‒6.3~12.6	Millot et al., 2007
日本Kagoshimadi地热区	29~102	0.6~24.8	2.1~39.4	Oi et al., 1996
意大利Vulcano地热田	21~99	3.0~9.1	‒7~1	Leeman et al., 2005
意大利Cimino‒Vico火山区	25~62	0.1~1.6	‒8.4~‒4.1	Battistel et al., 2016
墨西哥Los Humeros地热田	‒	214.0~725.0	‒1.7~0.3	Bernard et al., 2011
以色列Dead Sea地热区	15~39	20.5~31.3	51.7~54.9	Vengosh et al., 1991
土耳其Menderes Massif地热区	35~224	1.1~54.2	‒2.3~18.7	Vengosh et al., 2002
希腊Milos Island地热区	63~116	1.7~99.0	2.1~40.5	Wu et al., 2016
美国黄石国家公园	32~140	0.4~28.5	‒9.3~4.4	Palmer et al., 1990
印度尼西亚Java地热区	33.2~102.0	2.7~93.2	‒2.4~28.7	Purnomo et al., 2016
中国西藏羊八井地热田	86~87	10.2~165.4	‒13.8~‒8.4	Yuan et al., 2014；Zhang et al., 2015
中国西藏羊易地热田	79~89	38.5~45.7	‒9.7~‒5.0	Yuan et al., 2014
中国西藏搭格架地热田	37~86	1.1~106.9	‒16.3~‒11.7	吕苑苑等，2014；Liu et al., 2019
中国西藏曲卓木地热田	57~77	21.9~44.6	‒11.3~‒7.1	Liu et al., 2019
中国云南热海地热田	56~96	4.6~10.5	‒6.3~‒4.5	吕苑苑等，2014
中国吉林长白山火山地热区	21~82	0.2~4.4	‒13.3~35.9	Zhao et al., 2019

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