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    激光剥蚀电感耦合等离子体质谱副矿物U-Th-Pb定年新进展

    罗涛 胡兆初

    罗涛, 胡兆初, 2022. 激光剥蚀电感耦合等离子体质谱副矿物U-Th-Pb定年新进展. 地球科学, 47(11): 4122-4144. doi: 10.3799/dqkx.2022.365
    引用本文: 罗涛, 胡兆初, 2022. 激光剥蚀电感耦合等离子体质谱副矿物U-Th-Pb定年新进展. 地球科学, 47(11): 4122-4144. doi: 10.3799/dqkx.2022.365
    Luo Tao, Hu Zhaochu, 2022. Recent Advances in U-Th-Pb Dating of Accessory Minerals by Laser Ablation Inductively Coupled Plasma Mass Spectrometry. Earth Science, 47(11): 4122-4144. doi: 10.3799/dqkx.2022.365
    Citation: Luo Tao, Hu Zhaochu, 2022. Recent Advances in U-Th-Pb Dating of Accessory Minerals by Laser Ablation Inductively Coupled Plasma Mass Spectrometry. Earth Science, 47(11): 4122-4144. doi: 10.3799/dqkx.2022.365

    激光剥蚀电感耦合等离子体质谱副矿物U-Th-Pb定年新进展

    doi: 10.3799/dqkx.2022.365
    基金项目: 

    国家杰出青年科学基金项目 41725013

    国家自然科学基金项目 41903015

    国家自然科学基金项目 42142005

    国家自然科学基金项目 41873029

    湖北省自然科学基金项目 2020CFA045

    详细信息
      作者简介:

      罗涛(1989-),男,副研究员,主要从事副矿物U-Th-Pb年代学和激光剥蚀等离子体质谱机理研究.ORCID:0000-0003-0869-6527. E-mail:466096427@qq.com466096427@qq.com

      通讯作者:

      胡兆初,E-mail: zchu@vip.sina.com

    • 中图分类号: P597

    Recent Advances in U-Th-Pb Dating of Accessory Minerals by Laser Ablation Inductively Coupled Plasma Mass Spectrometry

    • 摘要: 激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)副矿物U-Th-Pb定年技术为精确厘定地质演化历史、探讨成岩成矿等重要地质作用过程提供重要的时间参数,是地质年代学快速发展的重要技术支撑.总结了LA-ICP-MS副矿物U-Th-Pb定年技术在元素分馏校正、非基体匹配分析、标准样品研发、普通铅校正、高空间分辨率及高效率分析等方面取得的重要进展.展望未来,需更进一步深入探讨和研究元素分馏及基体效应机理,研发更多种类的高质量副矿物标样,建立更多更准确、更精密、更高空间分辨率及更高效的LA-ICP-MS副矿物U-Th-Pb定年新方法和新技术,以实现从更微观和更精细的角度探讨地质问题,并持续为高效解决地球与行星科学研究领域重大科学问题提供关键支撑.

       

    • 图  1  2011-2021年发表与U-Th-Pb定年相关论文数据统计结果

      数据源于Web of science核心数据库. a.三种测试方法支撑发表论文数对比;b.由激光剥蚀技术支撑发表U-Th-Pb相关论文数量前十的地域分布情况

      Fig.  1.  Articles related with U-Th-Pb geochronology published from 2011 to 2021

      图  2  LA-ICP-MS分析过程中元素分馏及基体效应示意图(a)和193 nm准分子激光ns-LA-ICP-MS分析不同副矿物时Pb/U比值瞬时信号图(b)

      图 2a修改自罗涛(2018)

      Fig.  2.  Schematic diagram of elemental fractionation and matrix effect in LA-ICP-MS analysis (a) and time- resolved Pb/U ratio of different accessory minerals analyzed with 193 nm excimer ns-LA-ICP-MS (b)

      图  3  采用纳秒和飞秒激光分别以NIST610玻璃为外标分析锆石、独居石、磷钇矿和榍石结果

      归一化206Pb/238U比值由各矿物测试206Pb/238U值除以其推荐值

      Fig.  3.  Normalized 206Pb/238U ages of different accessory minerals by calibration against NIST 610 with ns- and fs-LA-ICP-MS

      图  4  正常剥蚀和水蒸气辅助剥蚀时,以锆石为外标LA-ICP-MS分析不同副矿物(锆石、榍石、独居石和磷钇矿)的U-Pb年龄结果

      a.剥蚀池中加入水蒸气;b.水蒸气稳定引入装置;c.不同分析模式获得的年龄结果

      Fig.  4.  The obtained U-Pb ages of different accessory minerals calibrated with zircon in normal ablation mode and water vapor-assisted ablation mode

      图  5  含普通铅标准样品和待测样品207Pb法普通铅校正及分馏校正图解

      Fig.  5.  The calibration procedure of common lead and U-Pb elemental fractionation

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    出版历程
    • 收稿日期:  2022-06-30
    • 网络出版日期:  2022-12-07
    • 刊出日期:  2022-11-25

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