Application of Fourier Transform Ion Cyclotron Resonance Mass Spectrometry in Molecular Characterization of Dissolved Organic Matter: A Bibliometrics-Based Visual Study
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摘要: 溶解性有机质(Dissolved organic matter，DOM)是广泛分布于各类环境介质中的复杂有机混合物，对污染物和营养元素的环境行为以及全球碳循环具有深远影响. 傅里叶变换离子回旋共振质谱(Fourier transform ion cyclotron resonance mass spectrometry，FT-ICR MS)是当今研究有机混合物分子组成最为先进的质谱技术，对DOM的生态环境效应研究具有重要意义. 为了解FT-ICR MS在环境科学、地球科学领域的研究现状、热点、趋势以及典型应用，基于Web of Science数据库并结合VOSviewer软件进行文献计量学可视化分析. 结果表明：中国大陆在该研究领域的发文量最多，其次是美国. 在学科上是以环境科学为发文量最多；在期刊上是以Environmental Science & Technology期刊发文量最多. 国内高产作者为史权教授与何晨博士，国外高产作者为Thorsten Dittmar教授；相关研究热点关键词涉及空气、地下水、生物群落、饮用水消毒、水处理等为主. 此外，相关典型应用旨在帮助人们提高对DOM高通量、非靶向定性分析的认识. 首次报道了FT-ICR MS在环境地球科学中的文献计量学研究，指出了当前的研究现状与热点，彰显了FT-ICR MS在环境地球科学研究方面的巨大潜力.Abstract: Dissolved organic matter (DOM) is composed of complex organic mixtures in diverse environments and plays critical roles in governing the environmental fate and transport of pollutants and nutritious elements and the global carbon cycle. Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) is the most advanced mass technique for the molecular composition of organic matter, with great importance in elucidating the ecological and environmental significance of DOM. This bibliometrics study based on Web of Science database was performed to visually analyze the current status, hot spots, trends and typical applications of FT-ICR MS in environmental earth science research. The results show that Mainland China has the largest number of publications in this field, followed by the United States. Environmental science is the most published among all disciplines with the most prolific journal, Environmental Science & Technology. The most productive domestic and foreign authors are Prof. Shi Quan, Dr. He Cen and Prof. Thorsten Dittmar in this field, respectively. The relevant research is mainly focused on air, groundwater, biological community, drinking water disinfection and water treatment. In addition, typical applications are reviewed to facilitate our understanding in the high-throughput and non-targeted qualitative analysis of DOM. For the first time, this bibliometrics study reports the current research status and hot spots of FT-ICR MS in the molecular characterization of DOM from diverse environments, highlighting its great potential in environmental earth science research.
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图 1 基于FT-ICR MS在环境地球科学领域的发文量趋势
a.总发表文量年际产出图；b.不同国家(或地区)的总发文量年际产出图
Fig. 1. Trend chart of publication volume in environmental geoscience based on FT-ICR MS
图 2 基于FT-ICR MS在环境地球科学领域的发文量情况
a.发文量前10的学科领域占比；b.发文量前10的出版商占比；c.发文量前10的期刊占比
Fig. 2. Based on the number of papers published by FT-ICR MS in the field of environmental geoscience
图 3 发文量不少于5篇的作者合著共现网络
节点大小表示作者发文量，发文量越多节点越大. 序号1~10为作者发文量排序；括号内数字分别表示发文量、平均被引用次数、平均发表年份和总链接强度
Fig. 3. Authors with no less than 5 papers co-authored on the network
图 4 关键词密度分布
密度圆圈的颜色越深代表该关键词出现的频次越多，序号1~10代表关键词出现频次最高的前10位. 括号内数字分别表示出现频次和平均发表年份
Fig. 4. Keywords density distribution map
表 1 检索词类别和检索式
Table 1. Search term category and search mode
检索词类别 检索式(不同检索式之间用“AND”连接) 高分辨率质谱 “ultra-high resolution mass spectrometer” OR “ultra-high-resolution mass spectrometer” OR “ultrahigh-resolution mass spectrometric” OR “ultrahigh resolution mass spectrometer” OR “ultrahigh-resolution mass spectrometry” OR “ultra-high resolution mass spectrometry” OR “ultra-high-resolution mass spectrometry” OR “UHRMS” OR “Fourier transform ion cyclotron resonance mass spectrometer” OR “FT-ICR MS” OR “FTICR-MS” OR “FT-ICR-MS” OR “FT-MS” OR “FTCR MS” OR “FTMS” OR “FTICR MS” OR “FTICRMS” OR “FT-ICRMS” OR “FT ICR-MS” 有机质 “organic matter” OR “organic-matter” OR “OM” OR “natural organic matter” OR “NOM” OR “dissolved organic matter” OR “DOM” OR “HUmic-LIke Substances*” OR “HULIS*” OR “water-soluble organic matter” OR “WSOM” OR “effluent organic matter” OR “EfOM” OR “humic acid*” OR “fulvic acid*” OR “humic” OR “humic substance*” 环境
体系“water*”OR“freshwater*” OR “seawater*” OR “marine” OR “lake*” OR “river” OR “estuary*” OR “tap water*” OR “surface water*” OR “groundwater*” OR “underground water*” OR “subsoil water*” OR “subterranean water*” OR “drinking water*” OR “waste water*” OR “wastewater*” OR “reclaimed water*” OR “landfill*” OR “landfill leachate*” OR “refuse percolate*” OR “percolate*” OR “Landfill waste leachate*” OR “soil*” OR “bog*” OR “marsh*” OR “moors*” OR “sludge*” OR “sewage sludge*” OR “sediment*” OR “atmosphere” OR “gas*” OR “air” OR “meteorology” OR “aerosol*” 分子 “molecular” OR “molecular characterization” OR “molecular-level characterization” OR “molecular composition” OR “molecular component*” OR “molecular weight component*” OR “molecular formula*” OR “molecular-level comparison” OR “molecule*” 注：检索数据库为Web of Science Core Collection，检索日期：1997‒01‒01到2023‒09‒01. 
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表 2 引用次数最多的前10篇论文基本情况
Table 2. Basic information about the top 10 most cited papers
序号 第一作者 & 年份 论文标题 期刊(缩写) 被引用次数 1 Koch and Dittmar(2006) From mass to structure: an aromaticity index for high-resolution mass data of natural organic matter Rapid Commun Mass Spectrom 891 2 Hertkorn et al.(2006) Characterization of a major refractory component of marine dissolved organic matter Geochim Cosmochim Acta 601 3 Stenson et al. (2003) Exact masses and chemical formulas of individual Suwannee river fulvic acids from ultrahigh resolution electrospray ionization Anal Chem 473 4 Stubbins et al. (2010) Illuminated darkness: molecular signatures of Congo river dissolved organic matter and its photochemical alteration as revealed by ultrahigh precision mass spectrometry Limnol Oceanogr 473 5 Kellerman et al. (2014) Chemodiversity of dissolved organic matter in lakes driven by climate and hydrology* Nat Commun 407 6 Kellerman et al.(2015) Persistence of dissolved organic matter in lakes related to its molecular characteristics* Nat Geosci 382 7 Sleighter and Hatcher(2007) The application of electrospray ionization coupled to ultrahigh resolution mass spectrometry for the molecular characterization of natural organic matter J Mass Spectrom 356 8 Sleighter and Hatcher (2008) Molecular characterization of dissolved organic matter (DOM) along a river to ocean transect of the lower Chesapeake bay by ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass Mar Chem 321 9 Lv et al.(2016) Molecular-scale investigation with ESI-FT-ICR-MS on fractionation of dissolved organic matter induced by adsorption on iron* EST 297 10 Hockaday et al.(2006) Direct molecular evidence for the degradation and mobility of black carbon in soils from ultrahigh-resolution mass spectral Org Geochem 276 注：*代表高被引论文.
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