地下储氢研究进展及展望

doi:10.3799/dqkx.2024.001

地下储氢研究进展及展望

doi: 10.3799/dqkx.2024.001

王璐¹,
金之钧^1,2, ,,
吕泽宇¹,
苏宇通¹

1. 北京大学能源研究院, 北京 100871;
2. 中国石化石油勘探开发研究院, 北京 100083

基金项目:

国家重点研发计划(No.2019YFA0708504)

国家自然科学基金委员会重大项目(No.42090020).

详细信息

作者简介:
王璐(1997-),女,博士研究生;主要从事天然氢气与固体储氢方面的研究工作.ORCID:0000-0003-3645-5077.E-mail:1901110610@pku.edu.cn

通讯作者:
金之钧(1957-),男,中国科学院院士,长期从事石油地质理论研究和能源战略研究.E-mail:jinzj1957@pku.edu.cn

中图分类号: P66
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- 被引次数: 0
出版历程
- 收稿日期: 2023-11-21

Research Progress in Underground Hydrogen Storage

Wang Lu¹,
Jin Zhijun^{1,2
, ,},
Zeiyu Lü¹,
Su Yutong¹

1. Institute of Energy, Peking University, Beijing 100871, China;
2. Sinopec Exploration & Production Research Institute, Beijing 100083, China

摘要

摘要: 随着氢气地位的进一步提高，大规模储氢逐渐得到重视.通过大量的调研文献对地下储氢库的特征、氢气与矿物的相互作用进行了阐述，并总结了粘土矿物和煤层对氢气的吸附特点.研究结果表明：（1）地下储氢库中，盐穴储氢是目前最好的方式；（2）温度、压力、硬脂酸浓度和有机酸碳数的变化会影响矿物的氢润湿性，从而影响盖层密封能力；（3）粘土矿物、煤层等可以吸附氢气，可为地下储氢新材料提供思路.基于以上研究和分析，指出了地下储氢目前存在的主要的难题，展望了地下储氢的未来发展前景，以期为地下储氢库的选址实施提供参考.并对地下多孔材料作为大规模储氢新材料的可行性做了简要概述，以期为寻求多样化、适宜化的储氢材料作出贡献.
- 地下储氢库 /
- 大规模储氢 /
- 氢润湿性 /
- 矿物储氢 /
- 吸附储氢
Abstract: As the importance of hydrogen continues to grow, large-scale hydrogen storage is receiving increasing focus. This paper extensively examines the classification, advantages, and drawbacks of underground hydrogen storage facilities through comprehensive literature research, providing a theoretical foundation for the implementation of such storage systems. Furthermore, it elucidates the interactions between hydrogen and minerals, and highlights the hydrogen adsorption characteristics of clay minerals and coal seams, offering novel insights into addressing challenges related to large-scale hydrogen storage and lowcost adsorption-based storage. The study findings reveal that (1) hydrogen storage facilities are primarily categorized into salt cavern storage, depleted oil and gas reservoir storage, and aquifer storage, with salt cavern storage currently being the most favorable option; (2) variations in temperature, pressure, concentration of fatty acids, and organic acid carbon number affect the hydrogen wettability of minerals, thus impacting caprock sealing capacity; and (3) certain clay minerals, coal seams, and other materials can adsorb hydrogen, presenting potential avenues for new underground hydrogen storage materials. Based on the above research and analysis, the main problems existing in underground hydrogen storage are pointed out, and the future development prospect of underground hydrogen storage is prospected, in order to provide reference for the site selection and implementation of underground hydrogen storage. The feasibility of underground porous material as a new large-scale hydrogen storage material is briefly summarized, in order to contribute to the search for diversified and suitable hydrogen storage materials.
- hydrogen /
- natural hydrogen /
- underground hydrogen storage /
- large-scale hydrogen storage /
- hydrogen wettability

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