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    粤北下庄铀矿田辉绿岩岩石地球化学、磷灰石U-Pb年龄及其与铀成矿关系

    李海东 钟福军 刘文泉 潘家永 田世洪 曹栩 郑国栋

    李海东, 钟福军, 刘文泉, 潘家永, 田世洪, 曹栩, 郑国栋, 2025. 粤北下庄铀矿田辉绿岩岩石地球化学、磷灰石U-Pb年龄及其与铀成矿关系. 地球科学, 50(11): 4405-4423. doi: 10.3799/dqkx.2025.089
    引用本文: 李海东, 钟福军, 刘文泉, 潘家永, 田世洪, 曹栩, 郑国栋, 2025. 粤北下庄铀矿田辉绿岩岩石地球化学、磷灰石U-Pb年龄及其与铀成矿关系. 地球科学, 50(11): 4405-4423. doi: 10.3799/dqkx.2025.089
    Li Haidong, Zhong Fujun, Liu Wenquan, Pan Jiayong, Tian Shihong, Cao Xu, Zheng Guodong, 2025. Petrogeochemistry, Apatite U-Pb Geochronology of Diabase, and Its Relationship with Uranium Mineralization in Xiazhuang Uranium Ore Field, North Guangdong. Earth Science, 50(11): 4405-4423. doi: 10.3799/dqkx.2025.089
    Citation: Li Haidong, Zhong Fujun, Liu Wenquan, Pan Jiayong, Tian Shihong, Cao Xu, Zheng Guodong, 2025. Petrogeochemistry, Apatite U-Pb Geochronology of Diabase, and Its Relationship with Uranium Mineralization in Xiazhuang Uranium Ore Field, North Guangdong. Earth Science, 50(11): 4405-4423. doi: 10.3799/dqkx.2025.089

    粤北下庄铀矿田辉绿岩岩石地球化学、磷灰石U-Pb年龄及其与铀成矿关系

    doi: 10.3799/dqkx.2025.089
    基金项目: 

    铀资源探采与核遥感全国重点实验室(东华理工大学)自主部署项目 2025QZ-KF-01

    国家自然科学基金项目 42272090

    国家自然科学基金项目 42362011

    国家自然科学基金项目 42002095

    中国核工业地质局项目 202239

    中国地质调查局花岗岩成岩成矿地质研究中心开放基金项目 PMGR202107

    中国铀业有限公司‒东华理工大学核资源与环境国家重点实验室联合创新基金项目 NRE2021-01

    中国铀业有限公司‒东华理工大学核资源与环境国家重点实验室联合创新基金项目 NRE2021-09

    中国铀业有限公司‒东华理工大学核资源与环境国家重点实验室联合创新基金项目 2022NRE-LH-05

    详细信息
      作者简介:

      李海东(1990—),男,高级工程师,博士,从事地质教学和科研工作. ORCID:0009-0006-2558-5393. E-mail:1019026804@qq.com

      通讯作者:

      钟福军,E-mail:zhongfujun602@126.com

    • 中图分类号: P581

    Petrogeochemistry, Apatite U-Pb Geochronology of Diabase, and Its Relationship with Uranium Mineralization in Xiazhuang Uranium Ore Field, North Guangdong

    • 摘要: 粤北下庄铀矿田发育五组近似等间距展布的北西西向辉绿岩脉,其与铀成矿关系密切.为查明辉绿岩成因及其与铀成矿关系,通过辉绿岩岩石地球化学、磷灰石U-Pb年代学及成矿期石英H-O同位素分析,结合区域构造背景,系统研究了辉绿岩的成岩时代、成因及其对铀成矿的控制机制.结果表明:(1)辉绿岩形成于两期岩浆活动(200~180 Ma和150~ 140 Ma),分别对应早侏罗世和晚侏罗世;(2)辉绿岩富集大离子亲石元素和强不相容元素;稀土元素球粒陨石标准化配分曲线呈右倾型,无明显Eu、Ce负异常,具有板内玄武岩属性,源于地幔部分熔融并受俯冲流体交代;(3)早期辉绿岩(200~180 Ma)可作为有利的赋矿围岩,与其侵位相关的深大断裂为成矿流体提供通道,断裂与辉绿岩交切部位易于形成交点型铀矿化,其成矿流体具壳幔混合来源特征;晚期辉绿岩(150~140 Ma)不仅继承了早期辉绿岩的作用,还为138~122 Ma阶段的铀成矿提供了地幔流体和矿化剂ΣCO2,促进了碎裂蚀变岩型铀矿化的形成,其成矿流体主要来源于地幔流体.

       

    • 图  1  贵东矿集区地质简图(a)和下庄铀矿田地质简图(b)

      a.据邓平等(2003);b.据张展适(2011)

      Fig.  1.  Geological sketch of the Guidong region (a) and the Xiazhuang uranium ore field (b)

      图  2  下庄铀矿田辉绿岩及铀矿化的空间关系

      a. 新鲜辉绿岩(第一组),ZK67-1:245 m;b. 蚀变辉绿岩(第四组),仙人嶂矿床,地表;c. 赤铁矿化辉绿岩(第一组):ZK250-1,孔深:183.95 m;d. 赤铁矿化辉绿岩:ZK250-1,孔深:183.95 m;e. 蚀变辉绿岩(第一组):ZK250-1,孔深:488.72 m;f. 辉绿岩角砾(第五组):泉洞矿点;g. 蚀变辉绿岩(第一组):ZK250-1,孔深:491.35 m;h. 蚀变辉绿岩(第一组):竹山下矿区. Pit.沥青铀矿;Hem.赤铁矿;Py.黄铁矿;Chl.绿泥石;Kfs.钾长石

      Fig.  2.  Spatial relationship between diabase and uranium mineralization in Xiazhuang uranium ore field

      图  3  下庄铀矿田辉绿岩手标本及显微照片

      Pl.斜长石;Px.辉石;Amp.角闪石;Mt.磁铁矿

      Fig.  3.  Specimen and microscopic photos of diabase from the Xiazhuang uranium ore field

      图  4  下庄铀矿田辉绿岩磷灰石U-Pb年龄Tera-Wasserburg图

      Fig.  4.  Tera-Wasserburg diagrams of apatite U-Pb age of diabase from the Xiazhuang uranium ore field

      图  5  下庄铀矿田辉绿岩Nb/Y-Zr/TiO2(a)和SiO2-K2O(b)图

      Fig.  5.  Nb/Y-Zr/TiO2 diagram (a) and SiO2-K2O diagram (b) of diabase from the Xiazhuang uranium ore field

      图  6  下庄铀矿田辉绿岩微量元素原始地幔标准化蛛网图(a)和稀土元素球粒陨石标准化配分图(b)

      标准化数值、N-MORB、E-MORB和OIB数据引自Sun and McDonough(1989)

      Fig.  6.  Normalized patterns of trace elements (a) and REE (b) of diabase from the Xiazhuang uranium ore field

      图  7  下庄铀矿田辉绿岩Ba-Zr (a)、Rb-Zr (b)、La-Zr (c)、Nb-Zr (d)、Ta-Zr (e)、Hf-Zr (f)、U-Zr (g)和REE-Zr (h)图解

      Fig.  7.  Plots of Ba-Zr (a), Rb-Zr (b), La-Zr (c), Nb-Zr (d), Ta-Zr (e), Hf-Zr (f), U-Zr (g) and REE-Zr (h) of diabase from the Xiazhuang uranium ore field

      图  8  下庄铀矿田辉绿岩(Ta/La)N-(Hf/Sm)N (a)、Th/Zr-Nb/Zr (b)、La-La/Sm (c)图解

      a.据La Flèche et al.(1998);b.据Zhao and Zhou(2007);c.据Zhao and Zhou(2007);HIMU.高U/Pb地幔端元;DM.亏损地幔端元

      Fig.  8.  (Ta/La)N-(Hf/Sm)N diagram (a), Th/Zr-Nb/Zr diagram (b), La-La/Sm diagram (c) of diabase from the Xiazhuang uranium ore field

      图  9  下庄铀矿田辉绿岩Zr-Zr/Y图(a)、Ta/Yb-Th/Yb (b)、Zr-TiO2 (c)和2Nb-Zr/4-Y图(d)

      WPB. 板内玄武岩;IAB. 岛弧玄武岩;MORB. 洋中脊玄武岩;VAB. 火山弧玄武岩;CAB. 钙碱性玄武岩;OFB. 扩张板块边缘玄武岩;LKT. 汇聚板块边缘玄武岩;IAT. 岛弧拉斑系列;ICA. 岛弧钙碱系列;SHO. 岛弧橄榄玄粗岩系列;TH. 拉斑玄武岩;TR. 过渡玄武岩;ALK. 碱性玄武岩;A1+A2. 板内碱性玄武岩;A2+C. 板内拉斑玄武岩;B. P型MORB;D. N型MORB;C+D. 火山弧玄武岩

      Fig.  9.  Zr-Zr/Y diagram (a), Ta/Yb-Th/Yb diagram (b), Zr-TiO2 diagram (c) and 2Nb-Zr/4-Y diagram (d) of diabase from the Xiazhuang uranium ore field

      图  10  下庄铀矿田交点型和碎裂蚀变岩型典型剖面

      a. 交点型铀矿化(竹山下矿床16号勘探线);b. 碎裂蚀变岩型铀矿化(石土岭矿床3号勘探线)

      Fig.  10.  Cross-sectional diagrams of the Xiazhuang uranium deposit showing intersection-type and fractured-alteration-type mineralization

      图  11  下庄铀矿田交点型、碎裂蚀变岩型示意

      Fig.  11.  Schematic diagram of the intersection-type and fractured-alteration-type mineralization in Xiazhuang uranium ore field

      图  12  下庄铀矿田石英H-O同位素组成

      Fig.  12.  H-O isotope composition of quartz in the Xiazhuang uranium ore field

      表  1  下庄铀矿田辉绿岩主元素分析结果(%)

      Table  1.   The analytical results of major elements (%) of diabase from the Xiazhuang uranium ore field

      辉绿岩 SiO2 Al2O3 FeO Fe2O3 MgO CaO Na2O K2O MnO TiO2 P2O5 LOI Total 来源
      第一组 49.52 13.39 9.50 3.89 6.19 9.98 2.84 0.37 0.22 2.19 0.25 0.64 100.02 本文
      第一组 49.19 13.67 9.93 3.47 6.14 9.78 2.63 0.41 0.23 2.15 0.24 0.48 98.32 田晓龙,2016
      第一组 49.22 13.84 9.61 3.96 6.13 9.97 2.59 0.41 0.22 2.20 0.23 0.67 99.05 田晓龙,2016
      第一组 49.97 11.92 9.03 4.82 5.80 6.10 3.01 0.99 0.23 2.17 0.28 3.31 99.65 李子颖等,2010
      第二组 48.34 15.49 8.28 3.39 7.19 10.51 1.67 0.67 0.18 1.50 0.35 1.57 100.05 王正其等,2007
      第二组 49.80 13.60 10.04 4.75 4.61 7.46 3.14 0.65 0.20 2.00 0.45 1.67 99.48 王正其等,2007
      第二组 48.14 13.44 10.09 4.20 5.28 9.62 1.52 1.33 0.20 2.25 0.35 1.51 99.94 王正其等,2007
      第二组 48.40 14.37 8.90 4.21 6.52 9.82 2.97 0.46 0.21 2.07 0.15 0.84 99.90 王正其等,2007
      第二组 48.22 13.79 10.27 4.32 6.23 9.93 2.71 0.47 0.24 2.05 0.05 0.66 100.10 王正其等,2007
      第二组 48.14 14.20 10.60 3.51 5.14 8.15 3.41 0.93 0.21 3.36 0.05 1.00 99.86 王正其等,2007
      第二组 44.28 13.45 9.99 4.70 5.99 9.46 3.09 0.50 0.26 2.07 0.05 0.95 99.89 王正其等,2007
      第二组 49.72 13.78 9.52 3.99 5.94 9.49 2.97 0.45 0.21 2.20 0.19 0.61 100.10 陆建军等,2006
      第二组 48.68 13.78 9.88 4.35 6.46 9.68 2.90 0.41 0.20 2.30 0.19 0.56 100.50 陆建军等,2006
      第二组 48.40 15.12 8.05 4.36 6.72 10.17 2.39 0.42 0.19 2.40 0.25 0.46 99.82 陆建军等,2006
      第二组 48.18 14.92 8.89 3.87 6.57 10.10 2.83 0.61 0.25 2.30 0.28 0.45 100.20 陆建军等,2006
      第二组 48.56 14.13 8.34 3.71 6.76 9.40 2.74 0.92 0.28 2.15 0.29 1.34 100.04 李子颖等,2010
      第二组 48.00 18.23 8.16 3.54 6.73 10.11 2.39 0.57 0.21 1.93 0.26 / 100.13 李献华等,1997
      第三组 52.59 18.28 7.32 4.17 3.08 6.26 4.14 0.68 0.24 2.58 0.58 / 99.92 李献华等,1997
      第三组 44.28 12.94 9.60 7.76 3.94 7.22 2.87 0.19 0.27 4.08 0.57 4.96 99.75 本文
      第三组 48.72 14.59 8.96 3.49 6.51 10.01 2.63 0.56 0.21 2.34 0.26 0.62 98.90 田晓龙,2016
      第三组 46.60 14.04 9.17 7.37 4.60 8.13 2.39 0.47 0.30 3.46 0.41 1.31 99.45 李子颖等,2010
      第四组 49.34 12.38 10.55 5.36 4.02 8.46 2.28 0.45 0.27 3.73 0.57 1.41 99.99 本文
      第四组 51.20 12.53 10.90 5.15 3.76 7.35 2.45 0.93 0.26 2.70 0.23 0.81 98.27 田晓龙,2016
      第四组 49.28 13.30 8.93 5.15 4.38 7.28 3.41 0.55 0.22 3.17 0.42 2.40 98.49 田晓龙,2016
      第四组 49.57 13.19 8.12 6.27 5.00 7.88 2.98 0.61 0.22 2.79 0.38 2.20 100.21 李子颖等,2010
      第五组 49.43 13.20 7.55 7.29 4.12 6.46 4.77 0.52 0.23 3.74 0.50 1.60 100.24 本文
      第五组 51.75 16.42 8.28 5.03 4.02 7.27 2.58 0.72 0.23 3.18 0.54 / 100.02 李献华等,1997
      下载: 导出CSV

      表  2  下庄铀矿田不同类型矿床H、O同位素组成

      Table  2.   Hydrogen and oxygen isotopic compositions of different deposits from Xiazhuang ore field

      序号 样品号 测试矿物 δ18OH2O(‰)SMOW δDH2O(‰)SMOW 矿床 数据来源
      1 XW014 萤石 ‒6.54 ‒85 硅化带型(希望矿床) 刘金辉,1997
      2 XW014 石英 ‒1.52 ‒39.2
      3 XW026 石英 ‒4.13 ‒33.5
      4 203 石英 4.4 ‒34 交点型(仙石矿床) 邓平等,2003
      5 204 石英 1.4 ‒41
      6 0235‒1 石英 5.5 ‒42
      7 0235‒2 石英 6.6 ‒43
      8 236 石英 5.9 ‒65
      9 2401 石英 7.4 ‒70 碎裂蚀变岩型(石土岭矿床) 本文
      10 2402 石英 7.0 ‒76
      11 2403 石英 5.8 ‒80.3
      12 2404 石英 8.1 ‒82.3
      下载: 导出CSV
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