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    三江造山带普朗斑岩型铜金钼矿床硒碲富集规律及其资源前景评估

    王雷 韦金花 欧阳荷根 吴练荣 赵晓瑜 杨帆 沃拥军 谢桂青

    王雷, 韦金花, 欧阳荷根, 吴练荣, 赵晓瑜, 杨帆, 沃拥军, 谢桂青, 2025. 三江造山带普朗斑岩型铜金钼矿床硒碲富集规律及其资源前景评估. 地球科学, 50(11): 4323-4336. doi: 10.3799/dqkx.2025.145
    引用本文: 王雷, 韦金花, 欧阳荷根, 吴练荣, 赵晓瑜, 杨帆, 沃拥军, 谢桂青, 2025. 三江造山带普朗斑岩型铜金钼矿床硒碲富集规律及其资源前景评估. 地球科学, 50(11): 4323-4336. doi: 10.3799/dqkx.2025.145
    Wang Lei, Wei Jinhua, Ouyang Hegen, Wu Lianrong, Zhao Xiaoyu, Yang Fan, Wo Yongjun, Xie Guiqing, 2025. Enrichment Regularities of Se and Te and Their Potential Resources in Pulang Porphyry Cu-Au-Mo Deposit, Sanjiang Orogenic Belt. Earth Science, 50(11): 4323-4336. doi: 10.3799/dqkx.2025.145
    Citation: Wang Lei, Wei Jinhua, Ouyang Hegen, Wu Lianrong, Zhao Xiaoyu, Yang Fan, Wo Yongjun, Xie Guiqing, 2025. Enrichment Regularities of Se and Te and Their Potential Resources in Pulang Porphyry Cu-Au-Mo Deposit, Sanjiang Orogenic Belt. Earth Science, 50(11): 4323-4336. doi: 10.3799/dqkx.2025.145

    三江造山带普朗斑岩型铜金钼矿床硒碲富集规律及其资源前景评估

    doi: 10.3799/dqkx.2025.145
    基金项目: 

    深地国家科技重大专项 2024ZD1001400

    云南省新一轮找矿突破战略行动科技支撑项目 2024

    国家自然科学青年基金项目 42103062

    国家自然科学基金重大研究计划集成项目 92462306

    云南省产教融合研究生联合培养基地项目 2023

    云南省博士研究生导师团队 2024

    详细信息
      作者简介:

      王雷(1983-),男,教授,博士生导师,从事矿床学与找矿预测研究.ORCID:0009-0005-0363-5698.E-mail:kust_wanglei@kust.edu.cn

      通讯作者:

      欧阳荷根,E-mail: oyhg1984@163.com

    • 中图分类号: P617

    Enrichment Regularities of Se and Te and Their Potential Resources in Pulang Porphyry Cu-Au-Mo Deposit, Sanjiang Orogenic Belt

    • 摘要: 近年来,普朗超大型斑岩铜多金属矿床(Cu-An-Mo)的硒(Se)和碲(Te)的富集现象备受关注,但资源前景与综合利用价值尚不明确.本研究采用LA-ICP-MS和ME-MS61r等方法,系统探究了该矿床Se和Te的主要载体矿物与空间分布规律,并对其资源前景进行了评估.研究发现,Se主要富集于黄铜矿和辉钼矿,Te主要寄主矿物为辉钼矿.空间分布上,主矿段硫化物的Se和Te含量显著高于东部矿段;但在单一勘探线剖面上,两者含量随深度变化无明显规律.从综合利用价值来看,铜精矿Se含量为170×10-6~200×10-6、钼精矿为250×10-6,均达到伴生Se矿综合回收指标;铜精矿Te含量为3.6×10-6~5.5×10-6,钼精矿为16.4×10-6(略超伴生Te矿回收标准),因矿床以铜为主的开采特点,Te综合回收价值相对有限.资源前景方面,基于已探明的5.11 Mt铜资源量估算,普朗矿床Se潜在资源量约4 440 t,达到超大型规模.

       

    • 图  1  义敦岛弧构造格架(a)和普朗斑岩型铜金钼矿床地质简图(b. 据 Cao et al., 2019Zhao et al., 2025修改)

      Fig.  1.  Tectonic framework of the Yidun island arc (a) and geological map of the Pulang porphyry Cu-Au-Mo deposit (b. modified from Cao et al. (2019) and Zhao et al.(2025))

      图  2  普朗矿床5号勘探线采样位置(a)及典型样品手标本特征(b~g)

      Ccp.黄铜矿;Py.黄铁矿;Mol.辉钼矿;Po.磁黄铁矿;Kfs.钾长石;Qtz.石英;Ep.绿帘石;Chl.绿泥石;Bt.黑云母;Pl.斜长石;Kln.高岭石

      Fig.  2.  Sampling locations (a) and hand specimen characteristics (b‒g) of representative samples along the No. 5 exploration line, Pulang deposit

      图  3  普朗矿床代表性样品的黄铁矿(Py)、黄铜矿(Ccp)、辉钼矿(Mol)和磁黄铁矿(Po)LA-ICP-MS分析点位及其硒(红色数值)和碲(蓝色数值)含量(10‒6

      Fig.  3.  LA-ICP-MS analysis spots and selenium (red values) and tellurium (blue values) contents (10‒6) in pyrite (Py), chalcopyrite (Ccp), molybdenite (Mol), and pyrrhotite (Po) from representative samples of the Pulang deposit

      图  4  普朗矿床北部矿段、首采区和东部矿段代表性勘探线硫化物的硒(a)和碲(b)含量

      德兴、城门山、鸡冠咀、鸡笼山和姚家姚家陵硫化物的硒和碲含量数据源自Xiong et al.(2022)Zhang et al.(2022)Guo et al.(2023)冷成彪等(2023)Li et al.(2024)Jiang et al.(2025)

      Fig.  4.  Selenium (a) and tellurium (b) contents in sulfides from representative exploration lines of the northern mining block, initial mining area, and eastern mining block, Pulang deposit

      图  5  普朗矿床5号勘探线各采样位置黄铁矿(a)、黄铜矿(b)和辉钼矿(c)的硒和碲平均含量(10-6

      Fig.  5.  Average selenium (Se) and tellurium (Te) contents (10-6) in pyrite (a), chalcopyrite (b), and molybdenite (c) at sampling locations along the No.5 exploration line, Pulang deposit

      表  1  普朗矿床铜精矿和钼精矿的伴生元素含量

      Table  1.   Associated element contents in copper and molybdenum concentrates from the Pulang deposit

      样品号 Cu
      (%)
      Fe
      (%)
      Mo
      (10‒6)
      Se
      (10‒6)
      Te
      (10‒6)
      Ag
      (10‒6)
      As
      (10‒6)
      Pb
      (10‒6)
      Co
      (10‒6)
      Ni
      (10‒6)
      主要金属矿物
      Cu1 19.80 31.9 8 400 170 3.8 42.2 550 750 200 99 Ccp, Py
      Cu3 21.1 32.1 8 200 180 5.3 44.9 620 490 178.5 91 Ccp, Py
      Cu5 19.90 33.0 8 190 170 5.1 42.7 660 510 230 103.5 Ccp, Py
      Cu7 19.25 31.4 6 590 170 4.4 43.5 660 600 200 115 Ccp, Py
      Cu9 20.1 33.4 7 390 180 4.5 43.4 650 590 216 107 Ccp, Py
      Cu11 21.4 33.4 8 170 200 4.6 48.5 630 690 199 99 Ccp, Py
      Cu13 21.4 32.2 6 730 180 5.0 44.7 560 580 182.5 89 Ccp, Py
      Cu15 22.1 31.9 7 810 190 4.4 45.3 464 580 168 87 Ccp, Py
      Cu17 20.5 31.9 7 060 170 4.8 44.5 560 530 196 98 Ccp, Py
      Cu19 22.4 31.6 6 430 180 4.7 44.6 750 550 165.5 80 Ccp, Py
      Cu21 21.1 32.1 6 780 180 5.5 45.1 760 630 170.5 83 Ccp, Py
      Cu23 23.1 32.4 1 790 190 3.6 46.8 580 620 153 81 Ccp, Py
      Cu25 22.8 32.6 1 930 190 4.9 46.8 530 620 160.5 82 Ccp, Py
      Cu27 22.4 32.9 1 610 200 4.7 46.8 620 590 181 86 Ccp, Py
      Cu29 21.2 31.0 6 920 190 4.6 44.2 780 520 152 74 Ccp, Py
      Mo1 2.14 4.4 > 10 000 250 16.4 45.4 67 350 34 22 Mol, Ccp
      下载: 导出CSV
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    • 收稿日期:  2025-05-22
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