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    东菲律宾海新型铁锰结壳中元素的赋存状态

    徐兆凯 李安春 于心科 蒋富清 孟庆勇

    徐兆凯, 李安春, 于心科, 蒋富清, 孟庆勇, 2008. 东菲律宾海新型铁锰结壳中元素的赋存状态. 地球科学, 33(3): 329-336.
    引用本文: 徐兆凯, 李安春, 于心科, 蒋富清, 孟庆勇, 2008. 东菲律宾海新型铁锰结壳中元素的赋存状态. 地球科学, 33(3): 329-336.
    XU Zhao-kai, LI An-chun, YU Xin-ke, JIANG Fu-qing, MENG Qing-yong, 2008. Elemental Occurrence Phases of the New-Type Ferromanganese Crusts from the East Philippine Sea. Earth Science, 33(3): 329-336.
    Citation: XU Zhao-kai, LI An-chun, YU Xin-ke, JIANG Fu-qing, MENG Qing-yong, 2008. Elemental Occurrence Phases of the New-Type Ferromanganese Crusts from the East Philippine Sea. Earth Science, 33(3): 329-336.

    东菲律宾海新型铁锰结壳中元素的赋存状态

    基金项目: 

    国家自然科学基金重点项目 90411014

    国家重点基础研究与发展计划项目 2007CB815903

    国家自然科学基金面上项目 40576032

    国家自然科学基金面上项目 40506016

    详细信息
      作者简介:

      徐兆凯(1978-), 男, 博士, 从事海洋地质学研究.E-mail: zhaokaixu@126.com

      通讯作者:

      李安春, E-mail: acli@ms.qdio.ac.cn

    • 中图分类号: P736

    Elemental Occurrence Phases of the New-Type Ferromanganese Crusts from the East Philippine Sea

    • 摘要: 为了解东菲律宾海新型铁锰结壳中元素的赋存状态, 采用化学提取方法对3个结壳样品进行了物相分析.不同类型结壳中成矿和稀土元素的赋存状态总体一致, 表明它们形成于相近的地质和海洋环境中.成矿元素中的Fe和Cu绝大部分赋存在残渣态中, Mn、Co和Ni则主要赋存在锰氧化物结合态、有机结合态和残渣态中, 并且埋藏型结壳样品锰氧化物结合态中赋存了相对更高比例的成矿元素.三价稀土元素主要集中在锰氧化物结合态中.两个沉积物表层结壳样品中的Ce主要集中在残渣态中.而埋藏型结壳样品中的Ce则主要赋存在锰氧化物结合态中, 这可能与该样品此相态中赋存了相对较多的Mn有关.呈碳酸盐结合态和有机结合态的稀土元素含量仅各占稀土总量的1%左右, 表明两者对结壳中稀土元素的富集作用很小.

       

    • 图  1  元素赋存状态分析实验流程图

      Fig.  1.  Experimental flow chart used in the elemental occurrence phase analysis

      图  2  新型铁锰结壳不同赋存状态稀土元素页岩标准化配分模式

      Fig.  2.  Shale-normalized REE distribution patterns in different phases of the new-type ferromanganese crusts

      表  1  新型铁锰结壳样品特征

      Table  1.   Characteristics of the new-type ferromanganese crusts

      表  2  新型铁锰结壳中不同赋存状态Fe、Mn、Cu、Co和Ni测试结果(%)

      Table  2.   Analysis results of Fe, Mn, Cu, Co and Ni in different phase of the new-type ferromanganese crusts

      表  3  新型铁锰结壳中不同赋存状态稀土元素测试结果(%)

      Table  3.   Analysis results of REE in different phases of the new-type ferromanganese crusts

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    • 收稿日期:  2007-12-28
    • 刊出日期:  2008-05-25

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