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    Volume 36 Issue 1
    Jan.  2011
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    GAO Yong-juan, LING Wen-li, QIU Xiao-fei, CHEN Zi-wan, BAI Xiu-juan, 2011. La-Ce Isotopic System: Application Status and Advances. Earth Science, 36(1): 33-42. doi: 10.3799/dqkx.2011.004
    Citation: GAO Yong-juan, LING Wen-li, QIU Xiao-fei, CHEN Zi-wan, BAI Xiu-juan, 2011. La-Ce Isotopic System: Application Status and Advances. Earth Science, 36(1): 33-42. doi: 10.3799/dqkx.2011.004

    La-Ce Isotopic System: Application Status and Advances

    doi: 10.3799/dqkx.2011.004
    • Received Date: 2010-05-31
    • Publish Date: 2011-01-01
    • Element Ce shows variable valences in the nature, which accounts for the decoupling between La-Ce and Sm-Nd isotopic system. In addition to a radiometric application, the La-Ce system thus sheds new light on a set of studies such as crust recycling in mantle components, oxidation events during outer sphere evolution of the Earth and metallogenesis. This paper consists of two parts. The first part summarizes the application status of the La-Ce system, its analytical problem faced as well as developing trends in experimental technique and geological application. The second half describes a new chemical procedure for La-Ce separation and purification. Analytical results for some USGS standards and some gabbroic rocks from the Neoproterozoic Huangling complex, interior of the Yangtze craton, are also reported.

       

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    • Amakawa, H., Ingri, J., Masuda, A., et al., 1991. Isotopic compositions of Ce, Nd and Sr in ferromanganesenodules from the Pacific and Atlantic oceans, the Baltic and Barents seas and the Gulf of Bothnia. Earth and Planetary Science Letters, 105: 554-565. doi: 10.1016/0012-821X(91)90192-K
      Amakawa, H., Nozaki, Y., Masuda, A., 1996. Precise determination of variations in the 138Ce/142Ce ratios of marine ferromanganese nodules. Chemical Geology, 131(1-4): 183-195. doi: 10.1016/0009-2541(96)00066-6
      Chang, T.L., Qian, Q.Y., Zhao, M.T., et al., 1995. The absolute isotopic composition of cerium. International Journal of Mass Spectrometry and Ion Processes, 142(1-2): 125-131. doi: 10.1016/0168-1176(95)90677-A
      Chen, D.Q., Chen, G., 1990. Practical geochemistry of rare earth elements. Metallurgical Industry Press, Beijing, 18-21(in Chinese).
      Chen, F.K., Li, Q.L., Li, C.F., et al., 2005. Prospect of high precision mass spectrometer in isotope geochemistry. Earth Science—Journal of China University of Geosciences, 30(6): 639-645 (in Chinese with English abstract). http://www.researchgate.net/publication/286961723_Prospect_of_high_precision_mass_spectrometer_in_isotope_geochemistry
      Dickin, A.P., 1987. Cerium isotope geochemistry of ocean island basalts. Nature, 326(19): 283-284. doi: 10.1038/326283a0
      Dickin, A.P., 2005. Radiogenic isotope geology. Cambridge University Press, New York, 246.
      Eugster, O., Tera, F., Burnett, D.S., et al., 1970. The isotopic composition of gadolinium and neutron-capture effects in some meteorites. Geophysics Research, 75(14): 2753-2768. doi: 10.1029/JB075i014p02753
      Hayashi, T., Tanimizu, M., Tanaka, T., 2004. Origin of negative Ce anomalies in Barberton sedimentary rocks, deduced from La-Ce and Sm-Nd isotope systematics. Precambrian Research, 135: 345-357. doi: 10.1016/j.precamres.2004.09.004
      Lee, S.G., Masuda, A., Shimizu, H., et al., 2001. Crustal evolution history of Korean Peninsula in East Asia: the significance of Nd, Ce isotopic and REE data from the Korean Precambrian gneisses. Geochemical Journal, 35: 175-187. doi: 10.2343/geochemj.35.175
      Li, C.F., Chen, F.K., Wang, F., 2008. Precise measurement of Nd isotopic ratio of micro-samples using NdO+ method. Earth Science —Journal of China University of Geosciences, 33(2): 243-250 (in Chinese with English abstract). doi: 10.3799/dqkx.2008.032
      Li, Z.C., Fang, X., 1998. Ce isotope—a new useful geochemical tracer. Geology and Mineral Resources of South China, (2): 1-8 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HNKC199802000.htm
      Li, Z.C., Fang, X., Liu, W.G., 2002. La-Ce system and Ce isotope geochemistry. China University of Geosciences Press, Wuhan (in Chinese).
      Li, Z.C., Huang, G.C., Liu, W.G., 2000. The source of manganese and iron in Xinrong manganese deposit, western GuangDong—Nd, Ce isotopic evidences. Mineral Resource and Geology, 14(6): 408-411 (in Chinese with English abstract).
      Liu, C.Q., Xie, G.H., Akimasa, M., 1995. Geochemistry of Cenozoic basalts from East China (Ⅱ) Sr, Nd, and Ce isotopic compositions. Geochimica, 24(3): 203-214 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQHX503.000.htm
      Makishima, A., Masuda, A., 1993. Primordial Ce isotopic composition of the solar system. Chemical Geology, 106(3-4): 197-205. doi: 10.1016/0009-2541(93)90026-F
      Makishima, A., Masuda, A., 1994. Ce isotope ratios of N-type MORB. Chemical Geology, 118(1-4): 1-8. doi: 10.1016/0009-2541(94)90166-X
      Makishima, A., Nakamura, E., 1991. Precise measurement of cerium isotope composition in rock samples. Chemical Geology, 94(1): 1-11. doi: 10.1016/0168-9622(91)90035-U
      Makishima, A., Shimizu, H., Masuda, A., 1987. Precise measurement of Cerium and Lanthanum isotope ratios. Mass Spectroscopy, 35: 64-72. doi: 10.5702/massspec.35.64
      Masuda, A., Shimizu, H., Nakai, S., 1988. 138La β-decay constant estimated from geochronological studies. Earth and Planetary Science Letters, 89(3-4): 316-322. doi: 10.1016/0012-821X(88)90119-7
      Norman, E.B., Nelson, M.A., 1983a. Half-life and decay scheme of 138La. Physical Review C (Nuclear Physics), 27(3): 1321-1324. doi: 10.1103/PhysRevC.27.1321
      Norman, E.B., Nelson, M.A., 1983b. On the half-life of 138La. Nature, 306: 503-504. doi: 10.1038/306503d0
      Rehkämper, M., Gärtner, M., Galer, S.J.G., et al., 1996. Separation of Ce from other rare-earth elements with application to Sm-Nd and La-Ce chronometry. Chemical Geology, 129(3-4): 201-208. doi: 10.1016/0009-2541(95)00143-3
      Rosman, K.J.R., Taylor, P.D.P., 1999. Report of the IUPAC Subcommittee for isotopic abundance measurements. Pure Appllication Chemistry, 71: 1593-1607. doi: 10.1351/pac199971081593
      Sato, J., Hirose, T., 1981. Half-life of 138La. Radiochemical Radioanalytical Letter, 46: 145-152. http://www.researchgate.net/publication/284573972_Half-life_of_138La
      Shimizu, H., Lee, S.G., Masuda, A., et al., 1996. Geochemistry of Nd and Ce isotopes and REE abundaces in Precambrain orthogneiss clasts from the Kamiaso conglomerate, Central Japan. Geochemical Journal, 30: 57-69. doi: 10.2343/geochemj.30.57
      Shimizu, H., Nakai, S., Tasaki, S., et al., 1988. Geochemistry of Ce and Nd isotopes and REE abundances in the Amȋtsoq gneisses, West Greenland. Earth and Planetary Science Letters, 91(1-2): 159-169. doi: 10.1016/0012-821X(88)90158-6
      Shimizu, H., Umemoto, N., Masuda, A., et al., 1990. Source of iron-formation in the Archean Isua and Malene supracrustals, West Greenland: evidence from La-Ce and Sm-Nd isotopic data and REE abundances. Geochimica et Cosmochimica Acta, 54: 1147-1154. doi: 10.1016/0016-7037(90)90445-Q
      Tanaka, T., Masuda, A., 1982. The La-Ce geochronometer: a new dating method. Nature, 300: 515-518. doi: 10.1038/300515a0
      Tanaka, T., Shimizu, H., Kawata, Y., et al., 1987. Combined La-Ce and Sm-Nd isotope systematics in petrogenetic studies. Nature, 327: 113-117. doi: 10.1038/327113a0
      Tanaka, T., Shimizu, H., Kawata, Y., et al., 1988. Mantle and crustal Ce/Nd isotope systematics. Nature, 333: 404. doi: 10.1038/333404a0
      Tanimizu, M., Hayashi, T., Tanaka, T., 2004. Development of Ce isotopic analysis for cosmochemistry using the dynamic multicollector technique. Journal of Mass Spectrometry Society Japan, 52: 177-181. doi: 10.5702/massspec.52.177
      Tanimizu, M., Tanaka, T., 2002. Coupled Ce-Nd isotope systematics and rare earth elements differentiation of the moon. Geochimica et Cosmochimica Acta, 66(22): 4007-4014. doi: 10.1016/S0016-7037(02)00961-4
      Tazoe, H., Obata, H., Amakawa, H., et al., 2007. Precise determination of the cerium isotopic compositions of surface seawater in the Northwest Pacific Ocean and Tokyo Bay. Marine Chemistry, 130(1-2): 1-14. doi: 10.1016/j.marchem.2006.05.008
      White, W.M., Hofmann, A.W., Puchelt, H., 1987. Isotope geochemistry of Pacific mid-ocean ridge basalt. Geophysics Research, 92(B6): 4881-4893. doi: 10.1029/JB092iB06p04881
      Yang, H.M., Duan, G.L., Ling, W.L., 2009. A certificating study on La-Ce rock reference material and Ce isotopic standard solution. Geochimica, 38(2): 179-186 (in Chinese with English abstract). http://www.cqvip.com/qk/92960X/200902/29647542.html
      陈德潜, 陈刚, 1990. 实用稀土元素地球化学. 北京: 冶金工业出版社, 18-21.
      陈福坤, 李秋立, 李潮峰, 等, 2005. 高精度质谱计在同位素地球化学的应用前景. 地球科学——中国地质大学学报, 30(6): 639-645. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200506000.htm
      李潮峰, 陈福坤, 王芳, 2008. 采用氧化物方式高精度测量微量样品钕同位素比值. 地球科学——中国地质大学学报, 33(2): 243-250. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200802013.htm
      李志昌, 方向, 1998. Ce同位素——一个新的地球化学示踪器. 华南地质与矿产, (2): 1-8. https://www.cnki.com.cn/Article/CJFDTOTAL-HNKC199802000.htm
      李志昌, 方向, 刘文贵, 2002. La-Ce法与Ce同位素地球化学. 武汉: 中国地质大学出版社.
      李志昌, 黄圭成, 刘文贵, 2000. 粤西新榕锰矿成矿物质来源的Ce, Nd同位素证据. 矿产与地质, 14(6): 408-411. https://www.cnki.com.cn/Article/CJFDTOTAL-KCYD200006013.htm
      刘丛强, 解广轰, 增田彰正, 1995. 中国东部新生代玄武岩的地球化学(Ⅱ)Sr、Nd、Ce同位素组成. 地球化学, 24(3): 203-214. doi: 10.3321/j.issn:0379-1726.1995.03.001
      杨红梅, 段桂玲, 凌文黎, 2009. La-Ce法岩石标准物质和Ce同位素标准溶液研制. 地球化学, 38(2): 179-186. doi: 10.3321/j.issn:0379-1726.2009.02.011
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